有機推斷及有機合成_課件

1、年份年份2000年年2001年年2002年年2003題號題號（區(qū)分度）（區(qū)分度）3（0.42）5（0.27）10（0.41）26（0.23）27（0.56） 8（0.45）20（0.53）21（0.70）22（0.72） 4（0.35）13（0.43）21（0.69）22（0.72） 2930分值分值30分分29分分24分分20分分占整套試占整套試題百分比題百分比20%19.3%16 %16.7 %2000200320002003年理綜卷有機化學(xué)統(tǒng)計年理綜卷有機化學(xué)統(tǒng)計ABDCGEHAg(NH3)2OHNaOH溶液NaHCO3足量H2NiBr2NaOH醇溶液FH+足量H+例例2.2.分析以下信

2、息，完成問題。分析以下信息，完成問題。CCOOHCH2COOHCH2COOHHOF:C6H6O6E(氧化劑)+濃H2SO4D:C4H10OB:C2H4O2HOOOCCH3G:C:O2,CuH2SO4H2OC20H34O8A:H2O無支鏈，可發(fā)生銀鏡反應(yīng)RCOHORCOHO+RCOOCOR+H2OH2SO4濃C CH HC CC CO OO OH HC CO OOOH HC CH H2 2C CO OO OH HC CC CHH2 2C COOOOC COOC CHH2 2C COOOOHHHHOOC CH HO OC COOOOHHC CHH2 2C CHH2 2C CC COOOOOOC C

3、HH3 3C CO OO OC CC CH H2 2C CO OO OC CH H2 2C CH H2 2C CH H2 2C CH H3 3C CO OO OC CH H2 2C CH H2 2C CH H2 2C CH H3 3C CH H2 2C CO OO OC CH H2 2C CH H2 2C CH H2 2C CH H3 31molA1molC20H24O4Br2 HBr無機酸/水1molEC12H10O42molHO(CH2)4OH1molC20H26O6Br4C20H26O6Br2/CCl4O3/Zn H2O1molCHO1molCC2H2O21molDC11H18O7A n

4、C20H26O6加熱加壓感光高分子B+nHO(CH2)4OHCl一定條件CO+HCCHCOHCCH一定條件HCCHAB濃硫酸脫水C局部加氫DCH2CHCHCH2nCH2CCH3CHCH2nRCHO+RCHCHOHRCHCHOHRCHO稀堿CORMgX+H2OCOHR+Mg(OH)XCO+RMgXCORMgXCH2CH22+O2催化劑2CH3CHO+O2CuCH3CHOHC6H52CH3CC6H5O2+2H2OC6H5CCH3O+C6H5MgBrC6H5COMgBrCH3C6H5C6H6+Br2C6H5Br+HBrC6H5Br+MgC6H5MgBrC6H5MgBr+CH3CHOCH3CHOMgBrC6H5CH3CHOMgBrC6H5CH3CHOHC6H5+H2OMg(OH)BrC6H5COMgBrCH3C6H5C6H5COHCH3C6H5C6H5COHCH3C6H5+H2OMg(OH)Br濃 H2SO4C6H5CC6H5CH2+H2OCCH3CH2CCH2COOHCCH3CH2CCH2BrCH3BrCCH2OHCH3OHCCHOCH