應(yīng)用于燃油系統(tǒng)的高性能材料

AdvancedFuelSystemMaterials應(yīng)用于燃油系統(tǒng)的高性能材料SolvayShanghai蘇威（上海）有限公司JimDotySeptember14,2007MOREPLASTICSWITHMOREPERFORMANCE1Today’sTopics/內(nèi)容概要IntroductiontoFuelSystems燃油系統(tǒng)介紹FuelSystemTrends燃油系統(tǒng)的發(fā)展趨勢(shì)SolvayValueProposition蘇威的產(chǎn)品特點(diǎn)KeyProducts主要產(chǎn)品InjectionMoldedApplications注塑應(yīng)用ExtrudedApplications擠出應(yīng)用BlowMoldedApplications吹塑應(yīng)用Summary總結(jié)2MarketSummaryMarketdefinitionFUELSYSTEMS-HPPapplicationsinautomotivefuelsystemsrequiringlowpermeationandanycombinationoftemperatureresistance,fuelresistance,andchemicalresistance–connectors,senderunits,valves,fillpipesandtanksFUEL/VAPORLINE-Extrudedlineusedto

carryfuelandvaporwithinthe

automotivefuelsystemTrendsLowpermeationIncreasedfuelresistanceHighertemperature3ApplicationSlideValves(Rollover,OBVRAMODEL?AT-5001/AT-1002HSVaporLine,IntankLine,FuelLineAmodelEXT-1800<mQuickConnectAMODEL?AT-1116/A-1625FuelRailAMODEL?AS-1145HS/AS-4133HSFuelFlangeAMODEL?AT-1002HS/AT-1116HS/AS-1133HSFuelLevelIndicatorAMODEL?AT-1116HSFuelInjectorSealsTecnoflon?PL557PermeationBarrierIxefBXTSeries4FuelSystemTrends發(fā)展趨勢(shì)IncreaseduseofDirectInjectionEngines更多的使用直接噴射引擎Bothgasolineanddiesel包括汽油機(jī)和柴油機(jī)Newfuelinjectiontechnology新的燃油噴射技術(shù)Piezoelectricfuelinjectors壓電燃油噴射器Increaseduseoflowpermeationmaterials更多使用低滲透材料ReplacementofPA11/12,andPOMinquickconnects,line,andfuelsenders代替PA11/12和POM，在快速接頭，油管和送油器應(yīng)用Increaseduseofcap-lessfuelsystem(NorthAmerica)

更多的使用無接頭燃油系統(tǒng)（北美）IncreaseduseofElectro-staticdissipativecomponents(NorthAmerica)更多的使用抗靜電部件（北美）Furtherdevelopmentindieselemissioncontrol

更加深入的研究在柴油噴射控制方面Ureainjection,particulatefilters,NOXscrubbersIncreaseduseinBio-FuelsandHybridTechnology

更多的使用生物燃料和混合動(dòng)力技術(shù)Ethanol,RME&SMEBio-diesel乙醇，RME&SME生物柴油5

Euro4&5（歐洲）Maximum2g/car/24hr小于2克/車/24小時(shí)Testfuelcontains2.3%O2測(cè)試油氧含量2.3％

LevII0.5g/car/24hr0.5克/車/24小時(shí)Testfuelcontains3.3%測(cè)試油含量3.3％CertificationbasedonCARB測(cè)試燃油為CARB Phase2testfuel PZEV0.054g/car/24hr0.054克/車/24小時(shí)Testfuelcontains3.3%O2

測(cè)試含氧量3.3％CertificationbasedonCARB測(cè)試燃油為CARB

Phase2testfuel `

Amodel?PPAFlanges/Senderunits法蘭、送油單元Quickconnects快速接頭Rollovervalves翻轉(zhuǎn)閥Filterhousings過濾器外殼Levelindicators液面指示器Fuel&airrails油軌Airvalves&throttlebodies

空氣閥和節(jié)氣閥FuelLine燃油管VaporLine蒸汽管InTankLine油箱內(nèi)管Ixef?PAMXD6FillerPipes加油管FuelTank油箱LowpermeationresinsforthemostaggressiveenvironmentsSolvayProductsforFuelSystemApplications

蘇威高性能材料在燃油系統(tǒng)中的應(yīng)用6AmodelPPAis...Modifiedwithadditionof... Amodelcompoundshave…enhancedperformancecharacteristicsvs.conventionalmidrangeengineeringpolymers(CH2)6COOCNnNHHModified6,Tsemi-aromaticpolyamidePA6,THOOHCOCOHOOHCOCO(CH2)4or7Ixef PAAis...Semi-aromaticpolyarylamideUniquestructureimpartsuniqueproperties(CH2)4OCHnNOCCH2CH2HNIxefcompoundshave…thehigheststrengthtoweightratioofanysemi-crystallinematerialthelowestcostperunitofstiffnessofanysemi-crystallinematerial8SolvayValuePropositionFuelSystemsRequirements燃油系統(tǒng)的需求LowPermeation低滲透StaticChargeDissipation抗靜電HighTemperatureResistance耐高溫AlcoholResistance耐醇性Diesel&Bio-DieselResistance

耐柴油和生物燃油SolvayFuelSystemValueProposition

蘇威高性能材料在燃油系統(tǒng)中的價(jià)值9ValuePropositionFocusednewmaterialsdevelopmentAmodel?EXT-1800–ExtrusionGradeLowPermeationandhighchemicalresistance.Vaporline,In-tankline,Oilline,WaterGlycolline.Amodel?LTm–Co-extrusionwithPA11/12.LowPermeationFuelLine.LowcostsolutiontoETFE,PVDF.Ixef?BXT-1000–BlowMoldingandExtrusionGradeLowPermeation,Alcoholresistancematerialfor5/6layerblowmoldingIxef?BXT-2000–ImpactModifiedBlowMoldingandExtrusionGradeLowPermeation,Alcoholresistancematerialfor2/3layerblowmoldingConductivePortfolioAmodelA-1625HS&A-6625HSforinjectionmoldingIxefBXT-3000forBlowmolding10HighTemperatureResistance

TensileStrengthHalfLifeforGlassReinforcedPolyamidesISO2578ThermalAging耐高溫5.000HrsAmodelA-113335%GRPA6623%GRPA12185oC150oC120oCISO2578熱老化玻纖增強(qiáng)聚酰胺拉伸強(qiáng)度的半衰期11Bio-DieselResistance耐生物柴油50%Diesel+50%RMEBio-diesel+5%Water(1)100%Diesel+5%Water(1)

InitialValueAfter5,000HrsExposure@110oC(1)Solutionalsocontains100mgeachCu,Fe,Almetals(1)Solutionalsocontains100mgofCu,Fe,Almetals100％柴油+5％水（1）溶液中含有銅，鐵，鋁各100mg50％柴油+50％RME生物柴油+5％水（1）（1）溶液鐘還含有銅，鐵，鋁各100mg原始值@100°C5000小時(shí)浸泡后12Ethanol/MethanolResistance耐乙醇/甲醇Amodel?AT-1002Comparisontoacetal(POM)MechanicalStrengthSimilartoPOMafterlongtermexposureinmethanolfuelDimensionalStabilityLessdimensionalchange(swell)afterlongtermexposuretomethanolfuelFuelImmersion@60oCfor1000Hours燃油浸泡1000小時(shí)@60°CAmodel?AT-1002與POM的對(duì)比機(jī)械強(qiáng)度長(zhǎng)時(shí)間浸泡與甲醇溶液中后與POM類似尺寸穩(wěn)定性長(zhǎng)時(shí)間浸泡與甲醇溶液中后尺寸發(fā)生很小的變化13StaticChargeDissipation防靜電Applicationsrequiringstiffness,impactstrengthandstaticchargedissipationFuelflanges燃油發(fā)蘭Connectors連接器Pumpcomponents油泵部件Fuelfilterhousings燃油過濾器殼體AmodelA-1625HS應(yīng)用需要強(qiáng)度,抗沖擊和防靜電14LowPermeation低滲透TestFuelCE10Testing@60°CThefilmsampleisincontactwithfuel(300-500hours)Filmthickness~50-100micronsSimilartoSAEJ2659

====>>PermeateCollectionCupPolymerFilmVent

FuelThermalChamberToGasChromatographHelium

PurgeGas

====>>PermeationTestSetUpforFilm薄膜滲透測(cè)試試驗(yàn)用燃油CE10試驗(yàn)溫度60°C薄膜與燃油接觸（300-500小時(shí)）薄膜厚度50-100微米類似SAEJ265915LowPermeation低滲透MaterialBarrierProperties-TestFuelCE10@60oC(1)FuelCE10=45%Isooctane,45%Toluene,10%Ethanol16InjectionMoldedApplications

注塑應(yīng)用17APPLICATIONPROFILEApplication:Fuel&VaporLineQuickConnectors應(yīng)用：燃油&蒸汽管快速接頭Material（材料）:AmodelAT-1116HSApplicationRequirements應(yīng)用要求Highcontinuoususetemperature(170°C)連續(xù)使用溫度170°CLowpermeation(0.54g.mm/m2.d)

低滲透0.54g.mm/m2.dLowswellinallfuels各種燃油中保持低膨脹ResistancetoZnCl2

attack耐ZnCl2腐蝕Resistanttoallfuels耐任何燃油Costeffectivevs.GRPA12

低成本vs.GRPA12APPLICATIONPROFILE應(yīng)用解析18Application:ESDFuelLineQuickConnectors應(yīng)用：ESD燃油管快速接頭Material（材料）:AmodelA-1625HSApplicationRequirements應(yīng)用要求Highcontinuoususetemperature(170°C)連續(xù)使用溫度170°CLowpermeation低滲透(0.54g.mm/m2.d)Resistancetofuelattack耐燃油腐蝕Flexfuels,alcoholfuels,bio-fuels乙醇燃料，生物燃料ResistancetoZnCl2

attack耐ZnCl2腐蝕Electro-staticchargedissipation防靜電Costeffectivevs.conductiveGRPA12低成本VS.防靜電的GRPA12APPLICATIONPROFILE應(yīng)用解析19APPLICATIONPROFILE應(yīng)用解析Application:FuelPumpEndCap應(yīng)用：燃油泵節(jié)流閥端蓋Material材料:AmodelAT-1002HSApplicationRequirements應(yīng)用要求Resistancetoallfuels耐各種燃油腐蝕Goodelongation/impactresistanceforpressfitoftubesandconnectors在壓裝油管和連接器時(shí)有良好的斷裂生長(zhǎng)率和耐沖擊性能ImprovedthermalperformancevsPOM(120oCvs80oC)提高熱性能Superiorcreepresistancevs.POM較好的抗蠕變性vs.POMSuperiorfatigueresistancevs.POM較好的抗疲勞性vs.POMAPPLICATIONPROFILE應(yīng)用解析Application應(yīng)用:FuelRail油軌Material材料:AmodelAS-1145HSApplicationRequirements應(yīng)用要求Dimensionalstability尺寸穩(wěn)定Highstrength&stiffness高強(qiáng)度和硬度Thermalshockresistance-40oCto121oCwith0-2barpressure在0-2bar壓力下抗熱沖擊-40oC到121oCResistancetoallfuels(121oC)耐各種燃油的腐蝕(121oC)Resistancetounderhoodchemicalenvironment抵抗引擎下的化學(xué)環(huán)境Lowpermeation低滲透APPLICATIONPROFILEApplication:DieselFuelSendingUnit應(yīng)用：柴油機(jī)送油單元Material材料:AMODEL?AT-1002HSApplicationRequirements:應(yīng)用要求Chemicalresistancetodieselfuel/biodiesel@125°C在125°C下耐柴油和生物燃油IncreasedtemperatureperformanceoverPOM,PBTorPA66比POM,PBT或PA66提高了耐熱性能Highimpactandstiffnessoverthetemperaturerange(-40oCto125oC)在(-40oCto125oC)的溫度范圍外保持較高的耐沖擊性和強(qiáng)度Elongationforsnapfits,pressfits,andlivinghinges在裝配中保持良好的伸長(zhǎng)率Resistancetoacids耐酸性Creepandfatigueresistance抗蠕變和疲勞性APPLICATIONPROFILE應(yīng)用解析22APPLICATIONPROFILEAPPLICATIONPROFILE應(yīng)用解析HeadBowlApplication:DieselFuelFilter應(yīng)用：柴油過濾器Material材料:AMODEL?AS-1145HSApplicationRequirements:應(yīng)用要求Chemicalresistancetodieselfuel/biodiesel@125°C在125°C時(shí)耐柴油和生物燃油Metallikeperformance具有金屬性能Strength強(qiáng)度Stiffness硬度Creep蠕變MayneedtobeESDforfutureNorthAmericanApplications抗靜電（北美）23APPLICATIONPROFILEApplication應(yīng)用:FuelFlange燃油法蘭Material材料:AMODEL?AT-1125HSApplicationRequirements:應(yīng)用要求Chemicalresistancetohotdiesel/bio-dieselupto140°C在140°C以下耐柴油和生物燃油HighercontinuoususetemperaturethanPOM,PBTorPA66連續(xù)使用溫度高于POM,PBT或PA66Highimpactresistance抗高沖擊性Resistancetoacids耐酸性Creepandfatigueresistance抗蠕變和疲勞性APPLICATIONPROFILE應(yīng)用解析24APPLICATIONPROFILEApplication應(yīng)用:RollOverValve翻轉(zhuǎn)閥Material材料:AMODEL?AT-1002HSApplicationRequirements:應(yīng)用要求Chemicalresistancetoallfuels耐各種燃料Resistancetoacids耐酸性MeetPZEVPermeation符合PZEV標(biāo)準(zhǔn)Highimpactresistance抗高沖擊Over-moldcapability可以2次成型APPLICATIONPROFILE應(yīng)用解析25ExtrudedApplications

擠出應(yīng)用26Application應(yīng)用:Fuel&VaporLine燃油&蒸汽管Material材料:AmodelEXT-1800ApplicationRequirements應(yīng)用要求Thermalresistanceto90oCwithpeektemperaturesof115oC耐溫到90oC，短期溫度可達(dá)115oC-40oCcoldtemperatureimpactresistance-40oC的低溫下抗沖擊Resistancetoallfuels.耐化學(xué)性Lowpermeation低滲透Spinweldedconnectionstoimprovejointintegrity旋轉(zhuǎn)焊接Acidresistance耐酸Fatigueresistance耐疲勞Costeffectiveness低成本APPLICATIONPROFILE應(yīng)用解析27Application:ConvolutedTubingforIn-TankandVaporLineApplications應(yīng)用：波紋管Material材料:AmodelEXT-1800ApplicationRequirements應(yīng)用要求Thermalresistanceto90oCwithpeektemperaturesof115oC耐溫到90oC，短期溫度可達(dá)115oC-40oCcoldtemperatureimpactresistance-40oC的低溫下抗沖擊Resistancetoallfuels.耐化學(xué)性Lowpermeation低滲透Costeffectiveness低成本ImprovedFlexibility提高彈性Acidresistance耐酸性Fatigueresistance耐疲勞性APPLICATIONPROFILE應(yīng)用解析28IntroducingNewAmodel?LowTmPPA低熔點(diǎn)Amodel?PPAImprovedProcessingvs.AmodelEXT-1800改善加工vs.AmodelEXT-1800SimilartypechemistryasEXT-1800與EXT-1800類似的化學(xué)性能Muchwiderextrusionwindow更加寬的加工窗口ExtrudesinthesamerangeasETFE(290-310oC)與ETFE(290-310oC)相同的擠出溫度DesignedforCo-extrusionwithPA11/12可以與PA11/12共擠Performance性能Highelongation(>100%)高延展性大于100%)Highimpact(NoBreak@-40oC)高沖擊（不斷@-40oC)Excellentthermalaging(125oC)卓越的耐熱老化(125oC)Lowpermeation(<1.0g.mm/m2.day)低滲透(<1.0g.mm/m2.day)29Co-extrusionofAmodelLowTmPPAwithPA11andPA12低熔點(diǎn)PPA與PA11和PA12共擠Twolayersystem2層管Notielayerisrequired無需粘接層Benefits優(yōu)點(diǎn)Lowercostthan3to6layersystems低成本VS3或6層管Nopatentissues無專利限制Reductionofstiffnessofmono-layer更加柔軟VS單層管LowcostETFEReplacement低成本VSETFE管AmodelLowTmPPA低熔點(diǎn)PPAPA11or12,LowTmPPA30BlowMoldedApplications

吹塑應(yīng)用31IntroductionofIxef?PAMXD6BarrierTechnologyPolymerwithmeltpoint~235oC熔點(diǎn)~235oCGoodmeltviscosityandmeltelasticity好的熔融粘度和熔體彈性Exceptionalmeltstability(superiortoEVOH)較好的熔體穩(wěn)定性（優(yōu)于EVOH）Wideprocessingwindow(likePA6)較寬的加工范圍（類似PA6)Lowpermeation(similartoEVOH)低滲透（類似EVOH)Pinchoffdirectlyonbarrierlayer直接在阻擋層修剪Canbeusedindirectfuelcontact可直接與燃油接觸ExcellentadhesiontoPEwithtielayer與PE和粘接層的優(yōu)異的粘接性Highimpactformulationavailable可提供抗沖擊牌號(hào)Laboratoryvalidationofthemulti-layerblowmoldingprocessiscomplete實(shí)驗(yàn)室證明可以多層吹塑成型32

PermeationonMulti-layerPolyethyleneConstructionConstruction結(jié)構(gòu)1LiterClosedBottle1公升容量的密封瓶5Layers5層WallSection刨面結(jié)構(gòu)Soak浸泡Sealed密封40oC3,360hoursFuelCE10Testing測(cè)試Mini-SHED40oC24hoursisothermal24小時(shí)恒溫HydrocarbonemissionanalysisbyFIDFID檢測(cè)碳?xì)鋼]發(fā)物Propanereferencestandard參考標(biāo)準(zhǔn)丙烷2mm

PEPEBARRIER0.06mmResults結(jié)果IxefBXT-1000has30%lowerpermeationthanEVOHatthesamethickness比相同厚度的EVOH滲透低30％33MaterialBarrierProperties各種材料的阻隔性對(duì)比CE10(CTF1)TestFuel@60°C(1)CE10(CTF1testfuel)=45%Isooctane,45%Toluene,10%Ethanol34FuelResistance(Permeation)Amodel?A-6000A-4000A-1000*CFT1TestFuel@60°C,50micronfilm,ASTME96StaticTest35IxefBXT-2000Advantage–ReducedLayers90:5:595(90:10):536BlowMoldedFillerPipeDevelopment吹塑加油管的研發(fā)PE/TieLayer粘接層/IxefBXT-2000Barrierlayercanbeconductiveornon-conductive阻隔層可以抗靜電或絕緣Barrierlayer