工作場所危險品信息系統(tǒng)

工作場所危險品信息系統(tǒng)TrainingProgramWHMIS1WHMIS–Objectives

工作場所危險品信息系統(tǒng)-目的Followingthesession,youwillbeableto:ListthethreemainelementsofWHMIS列出工作場所危險品信息系統(tǒng)的3個主要組成部分Listthe6hazardclassesofcontrolledproducts列出受控產(chǎn)品的6個危險級別ListtheWHMISresponsibilities列出工作場所危險品信息系統(tǒng)的職責(zé)Listthecomponentsofamaterialsafetydatasheets列出物品安全數(shù)據(jù)表的主要內(nèi)容2WHMIS–Introduction

工作場所危險品信息系統(tǒng)介紹TheWorkplaceHazardousMaterialsInformationSystem(WHMIS)工作場所危險品信息系統(tǒng)Providesinformationabouthazardousmaterialsusedintheworkplace提供工作場所使用的危險品的信息UnderWHMIS,employeeshavetherighttoreceiveinformationabouteachcontrolledproducttheyuse–itsidentity,hazards,andsafetyprecautions.按WHMIS規(guī)定，使用者有權(quán)了解每個受控產(chǎn)品的特性、危害性和安全警示ThegoalofWHMISistoreduceinjuryanddiseasebycommunicatingspecifichealthandsafetyinformationaboutcontrolledproductssothattheinformationcanbeusedtoreduceexposuretohazardousmaterialsWHMIS的目的是通過對受控產(chǎn)品有關(guān)健康和安全方面的信息的交流，減少危險品的暴露，從而減少使用者受到傷害和患疾3WHMISIntroductioncont’d

工作場所危險品信息系統(tǒng)介紹續(xù)WHMIS工作場所危險品信息系統(tǒng)Sixhazardclasses分為6個危害級別Eighthazardsymbolsthatidentifythespecifichazardsofcontrolledproducts.包括8個標(biāo)識確定受控產(chǎn)品的危害特性ThreemainWHMISelementsareusedtocommunicatehealthandsafetyinformation3個主要部分提供健康和安全方面的信息4TheThreeMainElementsofWHMISWHMIS的3個主要部分WHMISLabels標(biāo)簽Labelsoncontrolledproductsalertworkerstotheidentityoftheproduct,hazards,andprecautionarymeasures.受控產(chǎn)品的標(biāo)簽將警示使用者識別該產(chǎn)品、危害性及預(yù)防措施MaterialSafetyDataSheets(MSDSs)材料安全數(shù)據(jù)單Technicalbulletinsprovidedetailedhazardandprecautionaryinformation技術(shù)性報告提供危害性和預(yù)防措施細節(jié)WHMISeducationandtrainingprogram教育培訓(xùn)計劃Theemployerprovideseducationandtrainingforemployeessotheycanworksafelywithandnearcontrolledproducts經(jīng)營者應(yīng)向雇員提供教育和培訓(xùn)，使接觸受控產(chǎn)品者能安全地工作EmployeesmustknowhowWHMISworks,thehazardsofcontrolledproductsintheirworkplace,andthesafeworkprocedurestheymustfollow.雇員必須了解WHMIS的內(nèi)容，工作場地的受控產(chǎn)品的危害性，必須遵守安全操作規(guī)定5HowDoesWHMISWork?MSDSs材料安全數(shù)據(jù)單WHMISLabels標(biāo)簽WHMISeducationandTraining教育和培訓(xùn)Supplier廠商Employer經(jīng)營者Informedemployee使雇員明確providesprovidesmayprovideprovides6ClassificationofControlledProducts受控產(chǎn)品分類Acontrolledproduct一個受控產(chǎn)品aproductthatfallsintooneormoreofthehazardclasses.一個產(chǎn)品可以包括不止一個危險級別Manufacturersandsuppliersclassifycontrolledproductsandassignoneormoreoftheappropriatehazardsymbols生產(chǎn)者和銷售者將受控產(chǎn)品分級，并標(biāo)上一個或多個危險標(biāo)志Theemployermusteducateandtrainemployeestorecognizetheeighthazardsymbolsandtoknowwhattheymean經(jīng)營者必須對雇員培訓(xùn)，使他們能夠識別8種危險標(biāo)志，并理解其含義7ClassA:CompressedGas

A級：壓縮氣體Thisclassincludescompressedgases,dissolvedgases,andgasesliquefiedbycompressionorrefrigeration.Ifthepressureinthecontainerisgreaterthan40psi,thegasisaClassAproduct.Thecylindermayexplodeifexposedtoheatortophysicalshock(whendropped).此級包括壓縮氣體、溶解氣體及高壓或冷凍液化的氣體。如果容器內(nèi)的氣體壓力超過了40psi，該氣體為ClassA產(chǎn)品。氣瓶置于高溫或搖晃（當(dāng)?shù)鋾r），可能爆炸8ClassB:FlammableandCombustibleMaterial

B級：易燃物Thisclassincludessolids,liquids,andgasescapableofcatchingfireinthepresenceofasparkoropenflameundernormalconditions.在普通條件下，遇火花或明火會燃燒的固體、液體和氣體9ClassB:FlammableandCombustibleMaterialcont’d

B級：易燃物續(xù)ClassBhassixdivisionsB級又包括6個分級:1. DIVISION1:FLAMMABLEGASES易燃氣體Thesearecompressedgases(ClassA)thatformflammablemixturesinair為A級的壓縮氣體，在空氣中形成易燃混合物2.DIVISION2:FLAMMABLELIQUIDS易燃液體Theseareliquidsthathaveaflashpointbelow37.80C.Aflashpointisthelowesttemperatureatwhichvaporsfromtheseliquidswillcatchfirefromnearbysparksoropenflames.閃點在37.80C以下。閃點是液體蒸汽與附近火花或明火燃燒的最低溫度10ClassB:FlammableandCombustibleMaterialcont’d

B級：易燃物續(xù)3.DIVISION3:COMBUSTIBLELIQUIDS易燃液體Theseareliquidsthathaveflashpointsof37.80Cormorebutlessthan93.30C.

閃點在37.80C～93.30C之間4.DIVISION4:FLAMMABLESOLIDS易燃固體Thisisaspecialgroupsofsolids(usuallymetals)thatmeetveryspecifictechnicalcriteriasuchastheabilitytocausefirethroughfrictionortoigniteandburnsovigorouslyandpersistentlythattheycreateahazard特殊的固體（多為金屬）在摩擦或點燃后劇烈不停燃燒，產(chǎn)生危害11ClassB:FlammableandCombustibleMaterialcont’d

B級：易燃物續(xù)5.DIVISION5:FLAMMABLEAEROSOLS易燃顆粒物Theseproductsarepackagedinaerosolcontainers.Eithertheaerosolizedproductitselforthepropellantmaycatchfire.為罐裝顆粒物，顆粒物自身或推進劑易燃6.DIVISION6:REACTIVEFLAMMABLEMATERIALS活躍的易燃物Theseproductsreactdangerouslyinoneoftwoways:在兩種方式下的反應(yīng)十分危險(1)theyspontaneouslycreateheatorcatchfireundernormalconditionsofuseortheycreateheatwhenincontactwithairtothepointwheretheybegintoburn在正常使用時，與空氣接觸產(chǎn)生大量的熱，同時達到燃點燃燒(2)theyemitaflammablegasorspontaneouslycatchfirewhenincontactwithwaterorwatervapor遇水或水蒸氣產(chǎn)生可燃氣體，同時燃燒12ClassC:OxidizingMaterial

C級：氧化物Thesematerialsincreasetheriskoffireiftheycomeincontactwithflammableorcombustiblematerials.與可燃物接觸會加劇燃燒13ClassD:PoisonousandInfectiousMaterial

D級：有毒和傳染性物質(zhì)ClassDhasthreedivisionsD級有分為4類DIVISION1:MATERIALSCAUSINGIMMEDIATEANDSERIOUSTOXICEFFECTS直接和嚴(yán)重毒性Thesematerialscancausedeathorimmediateinjurywhenapersonisexposedtosmallamounts小劑量致死或急性傷害14ClassD:PoisonousandInfectiousMaterialcont’d

D級：有毒和傳染性物質(zhì)續(xù)DIVISION2:MATERIALSCAUSINGOTHERTOXICEFFECTS其它毒性Cancauselife-threateningandseriouslong-termhealthproblemsaswellaslesssevereacuteproblemsuponrepeatedexposure.長期多次接觸可導(dǎo)致生命危險及嚴(yán)重的慢性健康問題或次嚴(yán)重的急性中毒Healthproblemsincludeimmediateskinoreyeirritation,allergicsensitization,cancer,seriousimpairmentofspecificbodyorgansandsystems,andreproductiveproblems.健康問題包括即可皮膚或眼部刺激、過敏、癌癥、嚴(yán)重的身體器官和系統(tǒng)受損以及生殖問題15ClassD:PoisonousandInfectiousMaterialcont’d

D級：有毒和傳染性物質(zhì)續(xù)DIVISION3:BIOHAZARDOUSINFECTIOUS生物感染Thesematerialscontainharmfulmicro-organismsthathavebeenclassifiedintoRiskGroups2,3,and4asdeterminedbytheWorldHealthOrganization(WHO)ortheMedicalResearchCouncilofCanada.經(jīng)世界衛(wèi)生組織或加拿大醫(yī)學(xué)研究委員會確定的第2、3、4類危險微生物16ClassE:CorrosiveMaterial

E級：腐蝕性物質(zhì)Thisclassincludescausticandacidmaterialsthatcandestroytheskinoreatthroughmetals.腐蝕性及酸可傷害皮膚或腐蝕金屬17ClassF:DangerouslyReactiveMaterial

F級：危險的活性物質(zhì)Theseproductsmayself-reactdangerously(forexample,theymayexplode)uponstandingorwhenexposedtophysicalshockorincreasedpressureortemperature,ortheyemittoxicgaseswhenexposedtowater.在放置、或因搖晃、或加大壓力、或升高溫度，可自身反應(yīng)（如爆炸），在接觸水時釋放有毒氣體18WHMISResponsibilities

工作場所危險品信息系統(tǒng)職責(zé)InCanada加拿大WHMISlegislationexistsatboththefederalandprovinciallevels.包括聯(lián)邦政府級和地方省級Federallegislation聯(lián)邦政府級establisheswhichproductsarecontrolledunderWHMIS根據(jù)工作場所危險品信息系統(tǒng)，確定對何產(chǎn)品受控dealswiththeimportationandsaleofthesematerials處理危險品的進口和銷售underWHMIS,thosewhomanufacture,import,sell,ordistributecontrolledproductsarereferredtoassuppliers.根據(jù)工作場所危險品信息系統(tǒng)，生產(chǎn)、進口、銷售、分類受控產(chǎn)品的單位都被認(rèn)為是危險品的提供者Provinciallegislation地方省級coverstheuseofhazardousmaterialsintheworkplace確定工作場所危險品使用方法identifiesemployers’responsibilities確定雇主的職責(zé)employeeswhoworkwithornearcontrolledproductsmustknowhowtohandlethemsafely雇員的安全使用受控產(chǎn)品19SummaryoftheResponsibilities職責(zé)GroupResponsibilities職責(zé)Suppliers提供者-provideup-to-dateMSDSs(notmorethan3yrsold)forallcontrolledproductstheysellorproduce對生產(chǎn)和銷售的受控產(chǎn)品提供最新的MSDSs（3年內(nèi)）-providesupplierlabelsonallcontainersofcontrolledproductstheysellorproduce對生產(chǎn)和銷售的受控產(chǎn)品包裝上貼有標(biāo)識Employers雇主-ensureemployeesunderstandinformationonMSDSs,supplierlabels,andworkplacelabelsbyprovidingeffectiveemployeeeducation經(jīng)對雇員培訓(xùn)，使其了解安全數(shù)據(jù)清單、標(biāo)簽和工作場所標(biāo)識-providetraininginspecificsafeworkprocedurestoemployeeswhoworkwithornearcontrolledproducts對接觸受控產(chǎn)品的雇員提供安全操作培訓(xùn)-ensurethatallcontainersofcontrolledproductsintheirworkplacehaveMSDSsandWHMISlabels確保工作場所受控產(chǎn)品的包裝上貼有MSDSs和WHMIS標(biāo)識-ensurethatMSDSsarereadilyaccessibletoemployees.確保雇員隨時能閱讀MSDSs20SummaryofResponsibilitiescont’d

GroupResponsibilitiesEmployees雇員-knowandunderstandtheinformationonlabelsandMSDSs理解標(biāo)識和安全數(shù)據(jù)手冊的含義-usetheinformationtheyreceivethrougheducationandtrainingtohandlecontrolledproductssafely根據(jù)學(xué)到的知識正確地安全使用受控產(chǎn)品-informemployersiflabelsareillegibleormissing通知雇主標(biāo)識難辨或脫落WCBPreventionstaffinBC-administerWHMISlegislation執(zhí)行WHMIS法規(guī)-providegeneralinformationaboutWHMIStoemployersandemployees向雇主/雇員提供WHMIS信息-ensurecompliancewithbothfederalandprovinciallegislation確保遵守聯(lián)邦和省法規(guī)21WHMISLabels

WHMIS標(biāo)識TwotypesoflabelsrequiredbyWHMIS由WHMIS要求的兩類標(biāo)識Supplierlabels供應(yīng)者標(biāo)識Suppliersareresponsibleforprovidingsupplierlabels供應(yīng)者負(fù)責(zé)提供供應(yīng)者標(biāo)識Workplacelables工作場地標(biāo)識Employersareresponsibleforprovidingworkplacelabels雇主負(fù)責(zé)提供工作場所標(biāo)識Employersmustensurealllabelsattheirworkplacearelegibleandarereplacedifdamaged雇主必須確保標(biāo)識清晰，損壞后應(yīng)立即更換ThepurposeofWHMISlabelsWHMIS標(biāo)識目的Alertsemployeestothehazardsandthesafeproceduresnecessarytoworkwithornearacontrolledproduct.雇員接觸受控產(chǎn)品時的危險警告和安全使用22SupplierLabels供應(yīng)者標(biāo)識

IncludesSevenitemsofinformation包括7項信息MustbeincludedwithinthedistinctiveWHMIShatchedborder在WHMIS

專門設(shè)計的框內(nèi)提供: 1.Productidentifier產(chǎn)品標(biāo)識符:

-Oftenthechemicalnameofaproductorthetrade name,commonname,codename,orcodenumber化學(xué)名稱或商品名稱、常用名稱、代號或條形碼. 2.Hazardsymbol(s)危險標(biāo)記: -OneormoreoftheeightWHMISsymbolsindicating thehazardclassesofthecontrolledproduct.受控產(chǎn)品的8WHMIS個分類中一個或多個危險標(biāo)識 3.Riskphrases警句:

-Phrasesthatalertemployeestothespecifichazard(s)of theproduct.警告使用者產(chǎn)品的特殊危害性 -Thereshouldbeatleastoneriskphraseforeachhazard symbol.每個危險標(biāo)識圖應(yīng)至少附一個警句

23SupplierLabelscontinued供應(yīng)者標(biāo)識續(xù)

4.Precautionarystatements預(yù)防:

-Statementsthatdescribeessentialprecautions employeesshouldtakeandspecificprotective clothingandequipment(PPE)theyshould wearwhenhandlingtheproduct.接觸產(chǎn)品時的個人防護措施和基本預(yù)防措施

5.Firstaidmeasures急救辦法:

-Statementsthatdescribeimmediatefirstaid measuresrequired.方法描述 6.Supplieridentification供應(yīng)者身份識別:

-Thenameofthesupplier,preferablywiththe addressandtelephonenumber.名稱、地址和電話 7.ReferencetoMSDS材料安全數(shù)據(jù)單的指定內(nèi)容: -AstatementindicatingthatanMSDSis available.安全數(shù)據(jù)清單可查24ProductIdHazard

symbolRiskphrasesPrecautionarystatement

FirstaidSupplierIDReferencetoMSDS25WorkplaceLabels工作場所標(biāo)識Workplacelabelsarerequiredon須Containersofcontrolledproductsproducedandusedon-site受控產(chǎn)品的包裝容器Secondarycontainersafteraproducthasbeentransferredfromtheoriginalcontainer現(xiàn)場轉(zhuǎn)移的二次容器Containerswherethesupplierlabelismissingorillegible.包裝容器上的供應(yīng)者標(biāo)識脫落或難以辨認(rèn)Workplacelabelsprovidethefollowinginformation工作場所標(biāo)識提供以下信息:Productidentifier產(chǎn)品標(biāo)識符Specificsafehandlinginformation安全操作Personalprotectiveclothingandequipmentrequired個人防護用具佩戴ReferencetotheMSDS,ifanMSDShasbeenproducedbythesupplier安全數(shù)據(jù)清單的參考提示26ExampleofaWorkplaceLabel

工作場地標(biāo)識舉例Acetone丙酮Keepawayfromheat,sparks,andflames.Wearsafetygogglesandrubbergloves.Usewithlocalexhaustventilation.遠離熱源、火星和明火，戴護目鏡和手套，在通風(fēng)條件下使用MSDSavailable可查安全數(shù)據(jù)清單27MaterialSafetyDataSheets(MSDSs)材料安全數(shù)據(jù)單MaterialSafetyDataSheet材料安全數(shù)據(jù)單Atechnicalbulletinthatprovidesspecifichazardinformation,safehandlinginformation,andemergencyproceduresforacontrolledproduct是一份技術(shù)報告，須提供受控產(chǎn)品的危害性、安全使用方法和急救處理措施WHMISrequires54itemsofinformationin9sections工作場地危險品信息系統(tǒng)要求清單包括9個部分54項內(nèi)容Ifinformationforanyoftheseitemsnotavailableornotapplicable,theMSDSmustclearlyindicatethisfact任何缺項在材料安全數(shù)據(jù)單中必須指明原因NosectionoftheMSDScanbeleftblank.材料安全數(shù)據(jù)單中每部分不可為空白28MSDScon’td材料安全數(shù)據(jù)單續(xù)9InformationSections9部分為Productinformation產(chǎn)品信息:

Identifiestheproduct,themanufacturer,andthesupplier,anditdescribestheintendeduse.指明產(chǎn)品、生產(chǎn)商和供應(yīng)者，以及用途Providesinformationaboutwheretocontactthemanufacturerandsupplierforinformationand/orincaseofemergency.提供生產(chǎn)商和供應(yīng)者的聯(lián)系方式Hazardousingredients有害成分:Liststhespecificchemicalnames, percentages,andacutetoxicitydatafortheindividualcomponents列出各成分的化學(xué)名稱、含量和急性毒理試驗數(shù)據(jù)29MSDScont’d材料安全數(shù)據(jù)單續(xù)Physicaldata理化性質(zhì):

Generalinformationonphysicalandchemicalpropertiessuchasthespecificgravity,boilingpoint,andevaporationrate比重、沸點和蒸發(fā)速度等理化性質(zhì)Fireandexplosionhazard易燃易爆的危險程度:listsconditionsunderwhichthe productmaycatchfireorexplode產(chǎn)品導(dǎo)致燃燒和爆炸的條件informationfordealingwithfireandexplosionhazards.燃燒和爆炸的處理辦法30MSDScont’d材料安全數(shù)據(jù)單續(xù)Reactivitydata反應(yīng)活性:listsconditionsandothersubstancesthatshouldbeavoidedtopreventdangerousreactions.避免發(fā)生危險化學(xué)反應(yīng)的條件和其它回避的化學(xué)物質(zhì)Toxicologicalproperties毒理:

identifieshowthesubstanceentersthebodyandthepossiblehealtheffectsfromsingleorrepeatedexposures.Italsoidentifiesiftheproducthasknownlong-termhealtheffectssuchasliverorkidneydamage,sensitization,cancer,orreproductiveeffects.在單次或多次接觸產(chǎn)品時進入體內(nèi)的方式和可能對健康造成的影響。還應(yīng)指出產(chǎn)品的慢性健康效應(yīng)如對肝、腎、致敏作用、癌癥或生殖系統(tǒng)的影響Preventivemeasures預(yù)防方法:

includesinformationonrequiredprotectiveequipment,aswellasonhowtosafelycleanupspillsandhowtosafelyuse,handle,store,disposeof,andtransporttheproduct.對所需個人防護用品，以及如何安全清除濺灑、使用、儲存，廢物處理和搬運方面的安全問題31MSDScont’d材料安全數(shù)據(jù)單續(xù)Firstai