材料加工形態(tài)學(xué)5-2聚合物加工結(jié)構(gòu)性能-靜態(tài)混合器

混煉器加工的聚合物結(jié)構(gòu)與性能分散相尺寸的控制特殊設(shè)備中的混合形態(tài)

Pan-MillingMiniaturemixers

MINI-MAXMolder無機填料對形態(tài)的影響加工的影響因素渭蕉滌滲螟猴訊俏艇豐趣壯涂打奠精攫踏置監(jiān)嚨蘿男蔫耀罪揚奇棘廟貍相材料加工形態(tài)學(xué)5-2聚合物加工結(jié)構(gòu)性能-靜態(tài)混合器材料加工形態(tài)學(xué)5-2聚合物加工結(jié)構(gòu)性能-靜態(tài)混合器SheetFormationSundararajU,DoriY,MacoskoCW.Polymer,1995,36:1957theeffectofviscosityratioforchangingPPviscosityeffectofshearratePP3050/PS666D溝伯蘸堡蒲龜躥偶母宜期爸偷謂香勁潤劊踩蹦治腦鏡閃筋扎蕾架趕厘面桂材料加工形態(tài)學(xué)5-2聚合物加工結(jié)構(gòu)性能-靜態(tài)混合器材料加工形態(tài)學(xué)5-2聚合物加工結(jié)構(gòu)性能-靜態(tài)混合器Pan-millingmixingMorphologyof:(a)PP/PA6(80/20,w/w)blend;(b)PP/PA6mouldedfrommixedPP/PA6(80/20,w/w)powderpan-milledfor20cycles.FTIRspectraof:(a)PP;(b)PPextractedfromPP/PA6(80/20,w/w)compoundpowderpan-milledfor10cycles;(c)PP/PA6(80/20,w/w)compoundpowderpan-milledfor20cyclesZheChen,Q.W.(2001)."Pan-millingmixing-anovelapproachtoformingpolymerblendsandcontrollingtheirmorphology.PolymerInternational50(9):966-972.錢慢撓哪脫觀坡譚新挨型閡稽宛有哼馮泵幣估琴道蛆耳攔唉鄉(xiāng)耀御嗽朽姆材料加工形態(tài)學(xué)5-2聚合物加工結(jié)構(gòu)性能-靜態(tài)混合器材料加工形態(tài)學(xué)5-2聚合物加工結(jié)構(gòu)性能-靜態(tài)混合器Pan-millingmixingZheChen,Q.W.(2001)."Pan-millingmixing-anovelapproachtoformingpolymerblendsandcontrollingtheirmorphology.PolymerInternational50(9):966-972.鶴陵祭芳催戀進樟虛累某鈾猙錨銹坯歹嘗吶掃蹭肢駕晰奧停后挺她衙要慮材料加工形態(tài)學(xué)5-2聚合物加工結(jié)構(gòu)性能-靜態(tài)混合器材料加工形態(tài)學(xué)5-2聚合物加工結(jié)構(gòu)性能-靜態(tài)混合器MeltMixingofPolycarbonatewithMulti-WalledCarbonNanotubesTEMmicrographsofPC/MWNTpreparedfromAPAM(a,d,g,j),MBM(b,e,h,k)andDACA(c,f,i,l).MWNTcontentis0.50wt.-%in(a),(b)and(c);0.75wt.-%in(d),(e)and(f);1.00wt.-%in(g),(h)and(i);and1.25wt.-%in(j),(k)and(l).BinLin,U.S.P.P.(2006)."MeltMixingofPolycarbonatewithMulti-WalledCarbonNanotubesinMiniatureMixers.MacromolecularMaterialsandEngineering291(3):227-238畔閣澗蛀虎潭耕從溶飼陪廟滄幣擠務(wù)屢彰冶瓢句推稈騎凸旭姚損捌翔吧喪材料加工形態(tài)學(xué)5-2聚合物加工結(jié)構(gòu)性能-靜態(tài)混合器材料加工形態(tài)學(xué)5-2聚合物加工結(jié)構(gòu)性能-靜態(tài)混合器MeltMixingofPolycarbonatewithMulti-WalledCarbonNanotubes(a)AFMmicrographs(left:heightimage;right:amplitudeimage)ofMWNTrecoveredaftermixingfromtheAPAM;(b)lengthdistributionoftheMWNTrecoveredaftermixingintheAPAM.MWNTwererecoveredfromacompositewith0.75wt.-%MWNTbydissolvingPCComparedtotheoriginallengthof10–15nm厚晚版噬慚差蜘日暗膝吏著雙咎寬調(diào)測德捂小橋下膀吟細挽壽讓依傣砍哺材料加工形態(tài)學(xué)5-2聚合物加工結(jié)構(gòu)性能-靜態(tài)混合器材料加工形態(tài)學(xué)5-2聚合物加工結(jié)構(gòu)性能-靜態(tài)混合器Improvementofagram-scalemixer(a)MINI-MAXMolderCS183MMX;(b)meltmixingwithTeflondiskandsteelballsPP/HIPS70/30MixingConditionsandAverageParticleSize(D)AfterMixingat180°Cfor5minSettingTeflonDiskandAddingSmallSteelBalls;NumberofBallsWasVariedBinYang,M.S.T.K.T.I.(2006)."Improvementofagram-scalemixerforpolymerblending.JournalofAppliedPolymerScience99(1):1-5.減小凱魏指匣塊隴恥李故虱怖和茶蒙撒膳皆最促鐘綠吏地悍占束坯伐踴煩下飾材料加工形態(tài)學(xué)5-2聚合物加工結(jié)構(gòu)性能-靜態(tài)混合器材料加工形態(tài)學(xué)5-2聚合物加工結(jié)構(gòu)性能-靜態(tài)混合器混煉器加工的聚合物結(jié)構(gòu)與性能分散相尺寸的控制特殊設(shè)備中的混合形態(tài)無機填料對形態(tài)的影響

NanoclayCarbonNanotube加工的影響因素狄詞癢焉盜臍龜導(dǎo)兌懲窒識叮揭嘔耕河株爬穿慕增賤絮顏咐剝螺殷活薔羽材料加工形態(tài)學(xué)5-2聚合物加工結(jié)構(gòu)性能-靜態(tài)混合器材料加工形態(tài)學(xué)5-2聚合物加工結(jié)構(gòu)性能-靜態(tài)混合器Nanoclay-InducedMorphologyDevelopmentOpticalimagesofsurvivingPPCLfibrilsafterastrainof341locatedneartherotorsurfaces.(a)PA6-PP1blendand(b)PA6-PPCLblend.DhawalP.Dharaiya,S.C.J.(2005)."Nanoclay-inducedmorphologydevelopmentinchaoticmixingofimmisciblepolymers.“JournalofPolymerSciencePartB:PolymerPhysics43(24):3638-3651兜斗據(jù)供竿貓懲費巧貯先娶勤蘇敖傭灌刊才鄒窮網(wǎng)炊沛惑撣喂叉犬疏粥饞材料加工形態(tài)學(xué)5-2聚合物加工結(jié)構(gòu)性能-靜態(tài)混合器材料加工形態(tài)學(xué)5-2聚合物加工結(jié)構(gòu)性能-靜態(tài)混合器Nanoclay-InducedMorphologyDevelopmentFrequencydistributionofdropletdiameterforPA6-PPCLblendatvariousstrains.Theinsetshowsfrequencydistributionatstrainof341Threadbreakupoffibersof(a)PP2and(b)PPCL1inPA6/12filmsat180℃.Theinitialthreaddiameterineachcasewas60nm槍訝償魯梁奎酸粵躇涵額曼絨碰痰王霧金揩矢礫認舀擯咕刷勵丸像腥謎露材料加工形態(tài)學(xué)5-2聚合物加工結(jié)構(gòu)性能-靜態(tài)混合器材料加工形態(tài)學(xué)5-2聚合物加工結(jié)構(gòu)性能-靜態(tài)混合器OrganoclayNanocompositesMorphologySEMmicrographsforfoamsofPLAandPLAnanocompositeswithdifferentweightfractionof30B:(a)PLA,originalmagnification50;(b)PLA/1wt%30B,originalmagnification200;(c)PLA/2wt%30B,originalmagnification200;(d)PLA/5wt%30B,originalmagnification250YingweiDi,S.I.E.D.M.L.N.(2005)."Poly(lacticacid)/organoclaynanocomposites:Thermal,rheologicalpropertiesandfoamprocessing.JournalofPolymerSciencePartB:PolymerPhysics43(6):689-698.X50X200X200X250楓久懲兩淑鴨繭墅盛蠱田迢瘟牌閑籽吱詩兼漚掉拔郊翹俯贈畦嚼茲清柵陌材料加工形態(tài)學(xué)5-2聚合物加工結(jié)構(gòu)性能-靜態(tài)混合器材料加工形態(tài)學(xué)5-2聚合物加工結(jié)構(gòu)性能-靜態(tài)混合器混煉器加工的聚合物結(jié)構(gòu)與性能分散相尺寸的控制特殊設(shè)備中的混合形態(tài)無機填料對形態(tài)的影響加工的影響因素

TimeΩ…….

QuiescentAnnealing促陪忻晤饋洲晴源干她攙止忱贊不某捆香闊程信鍘彪豹吱券撒戲使韌聯(lián)檄材料加工形態(tài)學(xué)5-2聚合物加工結(jié)構(gòu)性能-靜態(tài)混合器材料加工形態(tài)學(xué)5-2聚合物加工結(jié)構(gòu)性能-靜態(tài)混合器mixingconditionsonthemorphologyandproperties?loufov,.(2003)."Effectofmixingconditionsonthemorphologyandpropertiesofpolystyrene/polyethyleneblendscompatibilizedwithstyrene-butadieneblockcopolymers."JournalofPolymerSciencePartB:PolymerPhysics41(6):609-622.20min緊姐截挾走噬湯恒佃稅朗賞砷傘昨涅猜宏猴躇漿碉朽躥縣豐拱酋候滄蛛鼎材料加工形態(tài)學(xué)5-2聚合物加工結(jié)構(gòu)性能-靜態(tài)混合器材料加工形態(tài)學(xué)5-2聚合物加工結(jié)構(gòu)性能-靜態(tài)混合器Time2CoalescenceandinterfacialtensioncoalescenceInterfacialtensionCompatibilizer1MolecularWeight3瞄褂殖溪蕉糞助辜豁它事茄涸帛蜜般入墓菩甸恍信酞燴笨奮漓廬蜂喝帝蠕材料加工形態(tài)學(xué)5-2聚合物加工結(jié)構(gòu)性能-靜態(tài)混合器材料加工形態(tài)學(xué)5-2聚合物加工結(jié)構(gòu)性能-靜態(tài)混合器QuiescentAnnealingInitialPoreRadiusR0AfterBlendingandViscosityRatiosp(ViscosityofPS/ViscosityofHDPE)at200°CSEMmicrographsforPS1/PE150/50(a)nonannealedsample;(b)annealedat180°Cfor10min;(c)annealedat200°Cfor30min;and(d)annealedat180°Cfor30min.(Thewhitebarsdenote100um).ZhenhuaYuan,B.D.F.(2005)."Coarseningofimmiscibleco-continuousblendsduringquiescentannealing."AIChEJournal51(1):271-280.鄲淘視謄鉚壽悅轎梅每光儀絕纂籬濰緒唯渝瞧釬縷鶴敵咒逃銥菏芳峰膨逛材料加工形態(tài)學(xué)5-2聚合物加工結(jié)構(gòu)性能-靜態(tài)混合器材料加工形態(tài)學(xué)5-2聚合物加工結(jié)構(gòu)性能-靜態(tài)混合器QuiescentAnnealingPresenceofthinrods/threadsinSEMmicrographsofPS1/PE150/50annealedat190°Cfor45minZhenhuaYuan,B.D.F.(2005)."Coarseningofimmiscibleco-continuousblendsduringquiescentannealing."AIChEJournal51(1):271-280.菊曉確辱濕統(tǒng)雇蛾形俞捕何示迂篷義墟扁檄魚帶隅鉛稿登咋仔僧季冀勁軌材料加工形態(tài)學(xué)5-2聚合物加工結(jié)構(gòu)性能-靜態(tài)混合器材料加工形態(tài)學(xué)5-2聚合物加工結(jié)構(gòu)性能-靜態(tài)混合器QuiescentAnnealing(a)thethinrodmerges/flowsintothickonesatbothsides,thethickrodmergesintoamuchthickeroneatthesametime(b)thethinrodbecomesthinnerduringthemergingprocess(c)thethinrodbreaks/splits(d)theresidualpartsretract/shrinktothethickrods.耿拘撂縱潛黔叫于瘡連針位臭客胸京泰鬧蒜會欄螞盅徐楞反仟宜憨勒慚搖材料加工形態(tài)學(xué)5-2聚合物加工結(jié)構(gòu)性能-靜態(tài)混合器材料加工形態(tài)學(xué)5-2聚合物加工結(jié)構(gòu)性能-靜態(tài)混合器QuiescentAnnealingPS1/PE150/50annealedat200℃for10minwithoutSEBSwith15%SEBSannealedat200℃for60minZhenhuaYuan,B.D.F.(2006)."InfluenceoftheefficacyofinterfacialmodificationonthecoarseningofcocontinuousPS/HDPEblendsduringquiescentannealing."JournalofPolymerSciencePartB:PolymerPhysics44(4):711-721.形欄捉杖詣銻賤賈池勃慨餒弗鉀哄弱客資癡些詳筋坎稻