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分析化學(xué)常用儀器英文名稱玻璃漏斗Glassfunnellongstem試管testtubetesttubebrushtesttubeholdertesttuberack蒸發(fā)皿evaporatingdishsmall燒杯beaker錐形瓶Erlenmeyer量筒gradcylinder洗瓶plasticwashbottle勺皿casserole,smallstopperedflask分液漏斗separaloryfunnelwaterbath/oilbathstrringbarmagneticstirrer冷凝器condenserBallastbottle圓頸燒瓶Round-buttomflask試劑瓶reagentbottles托盤天平platform.balance臺(tái)秤0.1g托盤pan指針刻度表pointerandscalecrossbeamsandslidingweights游碼分析天平two-pan/single-pananalyticalbalance滴定管buretteglassbead(basic)nozzle移液管pipette胖肚elongatedglassbulb洗耳球rubbersuctionbulb玻棒glassrod玻璃活塞stopcock容量瓶pyknowmeterflasks比重瓶(one-mark)volumetricflasks胖肚吸管one-markpipette刻度吸管graduatedpipettes實(shí)驗(yàn)儀器清單1、柜子中四、抽屜中:錐形瓶(conicalflask)250ml×4藥匙(medicinespoon)×1(Erlenmeyerflask)100ml×3滴管(driptube;dropper)×2燒杯(beaker)500ml×1玻棒(Glassstic)×2250ml×3木試管夾(testtubeclamp;testtubeholder)×1100ml×3胖肚吸管(straws)25ml×150ml×210ml×1容量瓶(volumetricflask)100ml×2乳缽(morta)×150ml×4洗耳球(earwadhingbulb)碘量瓶(iodinnumoeflask;iodineflask)500ml×3試劑瓶(reagentbottle)(無(wú)色)×2(棕色)×2配洗液:量筒(cylinder)100ml×1K2Cr2O72g+5ml水→65mlH2SO4(graduatedcylinder)10ml×1邊加邊攪拌(stir)。二、臺(tái)面上儀器:一般儀器的洗滌(wash)鐵支架(siderocradle)+蝴蝶架白瓷板(WhitePorcelainBoard)(一)清點(diǎn)儀器(tocount;tomakeaninventory)酸式滴定管(Acidburette)25ml×1配洗液(Lotion)堿式滴定管(Alkaliburette)25ml×1一般儀器的洗滌三、公用柜中:(二)滴定管(buret;burette)直型冷凝器(rectocondensor)×1容量瓶(volumetricflask)漏斗架(funnelstand)×2移液管(pipe)水浴鍋(waterbathkettle)×1溫度計(jì)(Thermometer;hygrometer;hydroscope)×1電爐(electricfurnace;electrichotplate;electricstove)四人一個(gè)《分析化學(xué)》上冊(cè)第一章緒論分析化學(xué):analyticalchemistry定性分析:qualitativeanalysis定量分析:quantitativeanalysis物理分析:physicalanalysis物理化學(xué)分析:physico-chemicalanalysis儀器分析法:instrumentalanalysis流動(dòng)注射分析法:flowinjectionanalysis;FIA順序注射分析法:sequenticalinjectionanalysis;SIA化學(xué)計(jì)量學(xué):chemometrics第二章誤差的分析數(shù)據(jù)處理絕對(duì)誤差:absoluteerror相對(duì)誤差:relativeerror系統(tǒng)誤差:systematicerror可定誤差:determinateerror隨機(jī)誤差:accidentalerror不可定誤差:indeterminateerror準(zhǔn)確度:accuracy精確度:precision偏差:debiation,d平均偏差:averagedebiation相對(duì)平均偏差:relativeaveragedebiation標(biāo)準(zhǔn)偏差(標(biāo)準(zhǔn)差):standerddeviation;S相對(duì)平均偏差:relatibestandarddeviation;RSD變異系數(shù):coefficientofvariation誤差傳遞:propagationoferror有效數(shù)字:significantfigure置信水平:confidencelevel顯著性水平:levelofsignificance合并標(biāo)準(zhǔn)偏差(組合標(biāo)準(zhǔn)差):pooledstandarddebiation舍棄商:rejectionquotient;Q化學(xué)定量分析第三章滴定分析概論滴定分析法:titrametricanalysis滴定:titration容量分析法:volumetricanalysis化學(xué)計(jì)量點(diǎn):stoichiometricpoint等當(dāng)點(diǎn):equivalentpoint電荷平衡:chargebalance電荷平衡式:chargebalanceequation質(zhì)量平衡:massbalance物料平衡:materialbalance質(zhì)量平衡式:massbalanceequation第四章酸堿滴定法酸堿滴定法:acid-basetitrations質(zhì)子自遞反應(yīng):autoprotolysisreaction質(zhì)子自遞常數(shù):autoprotolysisconstant質(zhì)子條件式:protonbalanceequation酸堿指示劑:acid-baseindicator指示劑常數(shù):indicatorconstant變色范圍:colourchangeinterval混合指示劑:mixedindicator雙指示劑滴定法:doubleindicatortitration第五章非水滴定法非水滴定法:nonaqueoustitrations質(zhì)子溶劑:protonicsolvent酸性溶劑:acidsolvent堿性溶劑:basicsolvent兩性溶劑:amphototericsolvent無(wú)質(zhì)子溶劑:aproticsolvent均化效應(yīng):differentiatingeffect區(qū)分性溶劑:differentiatingsolvent離子化:ionization離解:dissociation結(jié)晶紫:crystalviolet萘酚苯甲醇:α-naphthalphenolbenzylalcohol奎哪啶紅:quinadinered百里酚藍(lán):thymolblue偶氮紫:azoviolet溴酚藍(lán):bromophenolblue第六章配位滴定法配位滴定法:compleximetry乙二胺四乙酸:ethylenediaminetetraaceticacid,EDTA螯合物:chelatecompound金屬指示劑:metallochromeindcator第七章氧化還原滴定法氧化還原滴定法:oxidation-reductiontitration碘量法:iodimetry溴量法:bromimetry]溴量法:brominemethod鈰量法:cerimetry高錳酸鉀法:potassiumpermanganatemethod條件電位:conditionalpotential溴酸鉀法:potassiumbromatemethod硫酸鈰法:ceriumsulphatemethod偏高碘酸:metaperiodicacid高碘酸鹽:periodate亞硝酸鈉法:sodiumnitritemethod重氮化反應(yīng):diazotizationreaction重氮化滴定法:diazotizationtitration亞硝基化反應(yīng):nitrozationreaction亞硝基化滴定法:nitrozationtitration外指示劑:externalindicator外指示劑:outsideindicator重鉻酸鉀法:potassiumdichromatemethod第八章沉淀滴定法沉淀滴定法:precipitationtitration容量滴定法:volumetricprecipitationmethod銀量法:argentometricmethod第九章重量分析法重量分析法:gravimetricanalysis揮發(fā)法:volatilizationmethod引濕水(濕存水):waterofhydroscopicity包埋(藏)水:occludedwater吸入水:waterofimbibition結(jié)晶水:waterofcrystallization組成水:waterofcomposition液-液萃取法:liquid-liquidextration溶劑萃取法:solventextration反萃?。篶ounterextraction分配系數(shù):partitioncoefficient分配比:distributionratio離子對(duì)(離子締合物):ionpair沉淀形式:precipitationforms稱量形式:weighingforms《分析化學(xué)》下冊(cè)儀器分析概述物理分析:physicalanalysis物理化學(xué)分析:physicochemicalanalysis儀器分析:instrumentalanalysis第十章電位法及永停滴定法電化學(xué)分析:electrochemicalanalysis電解法:electrolyticanalysismethod電重量法:electtogravimetry庫(kù)侖法:coulometry庫(kù)侖滴定法:coulometrictitration電導(dǎo)法:conductometry電導(dǎo)分析法:conductometricanalysis電導(dǎo)滴定法:conductometrictitration電位法:potentiometry直接電位法:dirextpotentiometry電位滴定法:potentiometrictitration伏安法:voltammetry極譜法:polarography溶出法:strippingmethod電流滴定法:amperometrictitration化學(xué)雙電層:chemicaldoublelayer相界電位:phaseboundarypotential金屬電極電位:electrodepotential化學(xué)電池:chemicalcell液接界面:liquidjunctionboundary原電池:galvaniccell電解池:electrolyticcell負(fù)極:cathrode正極:anode電池電動(dòng)勢(shì):eletromotiveforce指示電極:indicatorelectrode參比電極:referenceelectroade標(biāo)準(zhǔn)氫電極:standardhydrogenelectrode一級(jí)參比電極:primaryreferenceelectrode飽和甘汞電極:standardcalomelelectrode銀-氯化銀電極:silversilver-chlorideelectrode液接界面:liquidjunctionboundary不對(duì)稱電位:asymmetrypotential表觀PH值:apparentPH復(fù)合PH電極:combinationPHelectrode離子選擇電極:ionselectiveelectrode敏感器:sensor晶體電極:crystallineelectrodes均相膜電極:homogeneousmembranceelectrodes非均相膜電極:heterogeneousmembranceelectrodes非晶體電極:non-crystallineelectrodes剛性基質(zhì)電極:rigidmatrixelectrode流流體載動(dòng)電極:electrodewithamobilecarrier氣敏電極:gassensingelectrodes酶電極:enzymeelectrodes金屬氧化物半導(dǎo)體場(chǎng)效應(yīng)晶體管:MOSFET離子選擇場(chǎng)效應(yīng)管:ISFET總離子強(qiáng)度調(diào)節(jié)緩沖劑:totalionstrengthadjustmentbuffer,TISAB永停滴定法:dead-stoptitration雙電流滴定法(雙安培滴定法):doubleamperometrictitration第十一章
光譜分析法概論普朗克常數(shù):Plankconstant電磁波譜:electromagneticspectrum光譜:spectrum光譜分析法:spectroscopicanalysis原子發(fā)射光譜法:atomicemissionspectroscopy質(zhì)量譜:massspectrum質(zhì)譜法:massspectroscopy,MS第十二章紫外-可見分光光度法紫外-可見分光光度法:ultravioletandvisiblespectrophotometry;UV-vis肩峰:shoulderpeak末端吸收:endabsorbtion生色團(tuán):chromophore助色團(tuán):auxochrome紅移:redshift長(zhǎng)移:bathochromicshift短移:hypsochromicshift藍(lán)(紫)移:blueshift增色效應(yīng)(濃色效應(yīng)):hyperchromiceffect減色效應(yīng)(淡色效應(yīng)):hypochromiceffect強(qiáng)帶:strongband弱帶:weakband吸收帶:absorptionband透光率:transmitance,T吸光度:absorbance譜帶寬度:bandwidth雜散光:straylight噪聲:noise暗噪聲:darknoise散粒噪聲:signalshotnoise閃耀光柵:blazedgrating全息光柵:holographicgraaing光二極管陣列檢測(cè)器:photodiodearraydetector偏最小二乘法:partialleastsquaresmethod,PLS褶合光譜法:convolutionspectrometry褶合變換:convolutiontransform,CT離散小波變換:wavelettransform,WT多尺度細(xì)化分析:multiscaleanalysis供電子取代基:electrondonatinggroup吸電子取代基:electronwith-drawinggroup第十三章熒光分析法熒光:fluorescence熒光分析法:fluorometryX-射線熒光分析法:X-rayfulorometry原子熒光分析法:atomicfluorometry分子熒光分析法:molecularfluorometry振動(dòng)弛豫:vibrationalrelexation內(nèi)轉(zhuǎn)換:internalconversion外轉(zhuǎn)換:externalconversion體系間跨越:intersystemcrossing激發(fā)光譜:excitationspectrum熒光光譜:fluorescencespectrum斯托克斯位移:Stokesshift熒光壽命:fluorescencelifetime熒光效率:fluorescenceefficiency熒光量子產(chǎn)率:fluorescencequantumyield熒光熄滅法:fluorescencequemchingmethod散射光:scatteringlight瑞利光:Reyleithscantteringlight拉曼光:Ramanscatteringlight第十四章紅外分光光度法紅外線:infraredray,IR中紅外吸收光譜:mid-infraredabsorptionspectrum,Mid-IR遠(yuǎn)紅外光譜:Far-IR微波譜:microwavespectrum,MV紅外吸收光譜法:infraredspectroscopy紅外分光光度法:infraredspectrophotometry振動(dòng)形式:modeofvibration伸縮振動(dòng):stretchingvibration對(duì)稱伸縮振動(dòng):symmetricalstretchingvibration不對(duì)稱伸縮振動(dòng):asymmetricalstretchingvibration彎曲振動(dòng):bendingvibration變形振動(dòng):formationvibration面內(nèi)彎曲振動(dòng):in-planebendingvibration,β剪式振動(dòng):scissoringvibration,δ面內(nèi)搖擺振動(dòng):rockingvibration,ρ面外彎曲振動(dòng):out-of-planebendingvibration,γ面外搖擺振動(dòng):waggingvibration,ω蜷曲振動(dòng):twistingvibration,τ對(duì)稱變形振動(dòng):symmetricaldeformationvibration,δs不對(duì)稱變形振動(dòng):asymmetricaldeformationvibration,δas特征吸收峰:charateristicavsorptionband特征頻率:characteristicfrequency相關(guān)吸收峰:correlationabsorptionband雜化影響:hybridizationaffect環(huán)大小效應(yīng):ringsizeeffect吸收峰的強(qiáng)度:intensityofabsorptionband環(huán)折疊振動(dòng):ringprckeringvibration第十五章
原子吸收分光光度法原子光譜法:atomicspectroscopy原子吸收分光光度法:atomicabsorptionspectrophotometry,AAS原子發(fā)射分光光度法:atomicemmsionspectrophotometry,AES原子熒光分光光度法:atomicfluorescencespectrophotometry,AFS第十六章核磁共振波譜法核磁共振:nuclearmagneticresonance,NMR核磁共振波譜:NMRspectrum核磁共振波譜法:NMRspectroscopy掃場(chǎng):sweptfield掃頻:seeptfrequency連續(xù)波核磁共振:continuouswaveNMR,CWNMRFourier變換NMR:PFT-NMR,FT-NMR二維核磁共振譜:2D-NMR質(zhì)子核磁共振譜:protonmagneticresonancespectrum,PMR氫譜:1H-NMR碳-13核磁共振譜:13C-NMRspectrum,13CNMR自旋角動(dòng)量:spinangularmomentum磁旋比:magnetogyricratio磁量子數(shù):magneticquantumnumber,m進(jìn)動(dòng):precession弛豫歷程:relaxationmechanism局部抗磁屏蔽:localdiamagneticshielding屏蔽常數(shù):shieldingconstant化學(xué)位移:chemicalshift國(guó)際純粹與應(yīng)用化學(xué)協(xié)會(huì):IUPAC磁各向異性:magneticanisotropy遠(yuǎn)程屏蔽效應(yīng):longrangeshieldingeffect結(jié)面:nodalplane自旋-自旋偶合:spin-spincoupling自旋-自旋分裂:spin=spinsplitting單峰:singlet,s雙峰:doublet,d三重峰:triplet,t四重峰:quartet五重峰:quintet六重峰:sextet偕偶:geminalcoupling鄰偶:vicinalcoupling遠(yuǎn)程偶合:longrangecoupling磁等價(jià):magneticeqivalence自旋系統(tǒng):spinsystem一級(jí)光譜:firstorderspectrum二級(jí)光譜(二級(jí)圖譜):secondorderspectrumC-H光譜:C-Hcorrelatedspectroscopy,C-HCOSY第十七章質(zhì)譜法質(zhì)譜分析法:massspectrometry質(zhì)譜:massspectrum,MS棒圖:bargraph選擇離子檢測(cè):selectedionmonitoring,SIM直接進(jìn)樣:directprobeinlet,DPI接口:interface氣相色譜-質(zhì)譜聯(lián)用:gaschromatography-massspectrometry,GC-MS高效液相色譜-質(zhì)譜聯(lián)用:highperformanceliquidchromatography-massspectrometry,HPLC-MS電子轟擊離子源:electronimpactsource,EI離子峰:quasi-molecularions化學(xué)離子源:chemicalionizationsource,CI場(chǎng)電離:fieldionization,FI場(chǎng)解析:fielddesorptiion,FD快速原子轟擊離子源:faststombombardment,FAB質(zhì)量分析器:massanalyzer磁質(zhì)譜儀:magnetic-sectormassspectrometer四極桿質(zhì)譜儀(四極質(zhì)譜儀):quadrupolemassspectrometer原子質(zhì)量單位:amu離子豐度:ionabundance相對(duì)豐度(相對(duì)強(qiáng)度):relativeavundance基峰:basepeak質(zhì)量范圍:massrange分辨率:resolution靈敏度:sensitivity信噪比:S/N分子離子:molecularion碎片離子:fragmention同位素離子:isotopicion亞穩(wěn)離子:metastableion亞穩(wěn)峰:metastablepeak母離子:parenion子離子:daughter含奇數(shù)個(gè)電子的離子:oddelectron含偶數(shù)個(gè)電子的離子:eveneletron,EE均裂:homolyticcleavage異裂(非均裂):heterolyticcleavage半均裂:hemi-homolysiscleavage重排:rearragement分子量:MWα-裂解:α-cleavage第十八章
色譜分析法概論色譜法(層析法):chromatography固定相:stationaryphase流動(dòng)相:mobilephase超臨界流體色譜法:SFC高效毛細(xì)管電泳法:highperformancecapillaryelectroporesis,HPEC氣相色譜法:gaschromatography,GC液相色譜法:liquidcromatography,LC超臨界流體色譜法:supercriticalfluidchromatography,SFC氣-固色譜法:GSC氣-液色譜法:GLC液-固色譜法:LSC液-液色譜法:LLC柱色譜法:columnchromatography填充柱:packedcolumn毛細(xì)管柱:capillarycolumn微填充柱:icroborepackedcolumn高效液相色譜法:highperformanceliquidchromatography,HPLC平板色譜法:planar平板色譜法:planechromatography紙色譜法:paperchromatography薄層色譜法:thinlayerchromatography,TLC薄膜色譜法;thiinfilmchomatography毛細(xì)管電泳法:capillaryelectrophoresis,CE分配色譜法:partitionchromatography吸附色譜法:adsorpionchromaography離子交換色譜法:ionexchangechromatography,IEC空間排阻色譜法:stericexclusionchromatography,SEC親和色譜法:affinitychromatography分配系數(shù):distributioncofficient狹義分配系數(shù):partitioncoefficient凝膠色譜法:gelchromatography凝膠滲透色譜法:gelpermeationchromatography,GPC凝膠過濾色譜法:gelfiltrationchromatography,GFC滲透系數(shù):permeationcoefficien;Kp化學(xué)鍵合相色譜法:chemicallybonded-phasechromatography分配系數(shù):distributioncoefficient靛菁綠:indocyanine氣相色譜-傅立葉變換紅外光譜:GC-FTIR第十九章經(jīng)典液相色譜法薄層色譜法:TLC吸附:adsorption活化:activation脫活性:deactivation交聯(lián)度:degreeofcrosslinking交換容量:exchangecapacity薄層板:thinlayerplate展開劑:developingsolvent,developer臨界膠束濃度:criticakmicolleconcentration,CMC相對(duì)比移值:relativeRf,Rr分離度:resolution,R分離數(shù):separationnumber,SN煅石膏:Gypsum羧甲基纖維素鈉:CMC-Na吸收光譜聯(lián)用:TLC-UV薄層色譜-熒光聯(lián)用:TLC-F薄層色譜-紅外吸收光譜聯(lián)用:TLC-IR薄層色譜法:TLC-MS紙色譜法:paperchromatography上行展開:ascendingdevelopment下行法展開:descendingdevelopment雙向展開:twodimensionaldeveloooment第二十章氣相色譜法氣相色譜法:gaschromatography前延峰:leadingpeak拖尾峰:tailingpeak對(duì)稱因子:symmetryfactor,fs保留時(shí)間:retentiontime保留體積:retentionvolume死時(shí)間:deadtime調(diào)整保留時(shí)間:asjustedretentiontime半峰寬:peakwidthathalfheight,W1/2orY1/2峰寬:peakwidth,W等溫線:isotherm理論塔板高度:heightequivalenttoatheoreticalplate化學(xué)鍵合相:chemicallybondedphase丁二酸二乙二醇聚酯:polydiethyleneglycolsuccinate,PDEGS,DEGS高分子多孔微球:GDX苯乙烯:STY乙基乙烯苯:EST二乙烯苯:DVB涂壁毛細(xì)管柱:wallcoatedopentubularcolumn,WCOT載體涂層毛細(xì)管柱:supprotcoatedopentubularcolumn,SCOT熱導(dǎo)檢測(cè)器:thermalconductivitydetector,TCD氫焰離子化檢測(cè)器:hydrogenflameionizationdetector,FID電子捕獲檢測(cè)器:electroncapturedetector,ECD噪聲:noise,N漂移:drift,d靈敏度:sensitivity檢測(cè)限(敏感度):detectability,D,M分離度:resolution歸一化法:normalizationmethod外標(biāo)法:externalstandardization第二十一章高效液相色譜法高效液相色譜法:highperformanceliquidchromatography,HPLC高速液相色譜法:highspeedLC,HSLC高壓液相色譜法:highpressureLC,HPLC高分辨液相色譜法:highresolutionLC,HRLC液固吸附色譜法(液固色譜法):liquid-solidadsorptionchromatography,LSC液液色譜法:liquid-liquidchromatography,LLC正相:normalphase,NP反相:reversedphase,RP化學(xué)鍵合相色譜法:bondedphasechromatography,BPC十八烷基:octadecylselyl,ODS離子對(duì)色譜法:pairedionchromatography,PIC反相離子對(duì)色譜法:RPIC離子抑制色譜法:ionsuppressionchromatography,ISC離子色譜法:ionchromatography,IC手性色譜法:chiralchromatography,CC環(huán)糊精色譜法:cyclodextrinchromatography,CDC膠束色譜法:micellarchromatography,MC親和色譜法:affinitychromatography,AC固定相:stationaryphase化學(xué)鍵合相:chemicallybondephase封尾、封頂、遮蓋:endcapping手性固定相:chiralstationaryphase,CSP恒組成溶劑洗脫:isocraicelution梯度洗脫:gradientelution紫外檢測(cè)器:ultravioletdetector,UVD熒光檢測(cè)器:fluorophotomericdetector,FD電化學(xué)檢測(cè)器:ECD示差折光檢測(cè)器:RID光電二極管檢測(cè)器:photodiodearraydetector,DAD三維光譜-波譜圖:3D-spectrochromatogram蒸發(fā)光散射檢測(cè)器:evaporativelightscatteringdetector,ELSD安培檢測(cè)器:amperedetector,AD高效毛細(xì)管電泳法:highperformancecapillaryelectrophoresis,HPCE淌度:mobility電泳:electrophoresis電滲:electroosmosis動(dòng)力進(jìn)樣:hydrodynamicinjection電動(dòng)進(jìn)樣:electrokineticinjection毛細(xì)管區(qū)帶電泳法:capillaryzoneelectrophoresis,CZE膠束電動(dòng)毛細(xì)管色譜:micellarelectrokineticcapillarychromatography,MECC毛細(xì)管凝膠電泳:capillarygelelectrophoresis,CGE篩分:sieving緒論釋藥系統(tǒng)(drugdeliverysystem,DDS)中國(guó)藥典(ChinesePharmacopoeia,ChP)美國(guó)藥典(TheUnitedStatesPharmacopoeia,USP)美國(guó)國(guó)家處方集(TheNationalFormulary,NF)英國(guó)藥典(BritishPharmacopoeia,BP)歐洲藥典(EuropeanPharmacopoeia,Ph.Eup)國(guó)際藥典(TheInternationalPharmacopoeia,Ph.Int)良好藥品實(shí)驗(yàn)研究規(guī)范(GoodLaboratoryPractice,GLP)良好藥品生產(chǎn)規(guī)范(GoodManufacturePractice,GMP)良好藥品供應(yīng)規(guī)范(GoodSupplyPractice,GSP)良好藥品臨床試驗(yàn)規(guī)范(GoodClinicalPractice,GCP)分析質(zhì)量管理(AnalyticalQualityControl,AQC)第1章藥物的鑒別試驗(yàn)藥物的鑒別試驗(yàn)identificationtest一般鑒別試驗(yàn)generalidentificationtest專屬鑒別試驗(yàn)specificidentificationtest靈敏度sensitivity最低檢出量minimumdetectablequantity最低檢出濃度minimumdetectableconcentration第2章藥物的雜質(zhì)檢查巰基醋酸mercaptoaceticacid古蔡Gutzeit二乙基二硫代氨基甲酸銀siliverdiethyldithio-carbamate硫酸灰分sulphatedash熾灼殘?jiān)黵esidueonignition熱重分析法thermogravimetricanalysis,TGA差示熱分析法differentialthermalanalysis,DTA差示掃描量熱法differentialscanningcalorimetry,DSC堿性酒石酸銅試驗(yàn)Fehling’sreagent異紅紫酸鹽isopurpurate2,3-二氨基萘2,3-diaminonaphthalene4,5-苯并苯硒二唑4,5-benzopiazselenol第三章定量分析樣品前處理與測(cè)定方法的效能指標(biāo)汞齊化法amalgamationmethod氧瓶燃燒法oxygenflaskcombustionmethod葡萄糖醛酸甙glucuronides硫酸酯sulphates血漿plasma血清serum全血wholeblood治療藥物濃度監(jiān)測(cè)therapeuticdrugmonitoring,TDM結(jié)合bound游離free綴合物conjugate液-液提取法liquid-liquidextraction,LLE離子對(duì)試劑ionpairreagent離子對(duì)提取法ionpairextractionmethod反離子counter液-固提取法liquid-solidextractionLSE半自動(dòng)樣品制備系統(tǒng)advancedautomatedsampleprocessor,AASP烷基化alkylations酰基化acylations硅烷化silylations精密度precision標(biāo)準(zhǔn)差standarddeviation,SDorS相對(duì)標(biāo)準(zhǔn)差relativestandarddeviation,RSD變異系數(shù)coefficientofvariation,CV批內(nèi)精密度within-runprecision日內(nèi)精密度within-dayprecision批間精密度between-runprecision日間精密度daytodayprecision準(zhǔn)確度accuracy定量限limitofquantitation,LOQ檢測(cè)限limitofdetection,LOD選擇性selectivity專屬性specificity線性與范圍linearityandrange重現(xiàn)性ruggedness耐用性robustness散布圖scatterdiagram熒光偏振免疫測(cè)定法fluorescencepolarizationimmunoassay,F(xiàn)PIA第4章巴比妥類藥物的分析溴化十六烷基三甲基芐銨cetyltrimethylbenzylammoniumbromide,CTMA氯化四癸基二甲基芐銨Tetradacyldimethybenzylammoniumchloride,TDBA第5章芳酸及其酯類藥物的分析苯甲酸及其鈉鹽benzoicacidandsodiumbenzoate布美他尼bumetanide羥苯乙酯ethylparoben丙磺舒probenecid酚黃乙胺etamsylate第6章胺類藥物的分析第七章雜環(huán)類藥物的分析二硝基氯苯反應(yīng)Vongerichten反應(yīng)戊烯二醛反應(yīng)K?nig反應(yīng)第8章
生物堿類藥物的分析生物堿alkaloids阿片gumopium掃尾劑tailing-suppressingreagent蒂巴因thebaine諾司卡品noscapine競(jìng)爭(zhēng)離子competingions親脂性lipophicity拖尾因子tailingfactor金剛烷adamantane第9章維生素類藥物的分析維生素vitamin去氫維生素Adehydroretinol去水維生素Aanhydroretinol鯨醇kitol三氯化銻反應(yīng)Carr-Price反應(yīng)維生素B1thiaminehydrochloride;鹽酸硫胺2,3,5-三苯基氯化四氮唑2,3,5-triphenyltetrazoliumchlorid,TTC紅四氮唑redtetrazoline,RT藍(lán)四氮唑bluetetrazoline,BT3,3’-二甲基氧苯基-雙-4,4’-(3,5-二苯基)氯化四氮唑{3,3’-dianisole-bis[4,4’-(3,5-dipheny)tetrazoliumchloride]}有色甲……formazan鐵-酚試劑iron-phenolreagent鐵-柯柏試劑iron-Koberreagent第十一章抗生素類藥物的分析6-氨基青霉烷酸6-aminopenicillanicacid,6-APA7-氨基頭孢菌烷酸7-aminocephalosporanicacid,7-ACA氨芐西林ampicillin5-甲基-3-鄰氯苯基-4-異……唑青霉素鈉cloxacillinsodium羥氨芐青霉素amoxicillin氨基糖甙類抗生素aminoglycosidesantibiotics鏈霉素streptomycin麥芽酚maltolN-甲基葡萄糖胺反應(yīng)Elson-Morgan反應(yīng)坂口反應(yīng)Sakaguchi反應(yīng)慶大霉素gentamycin四環(huán)素類tetracyclines4-差向脫水四環(huán)素4-ejpianhydrotetracycline,EATC第十二章藥物制劑分析含量均勻度contentuniformity溶出度dissulution離子對(duì)高效液相色譜法ion-pair,HPLC第十三章生化藥物分析概論第十四章
中藥制劑分析概論超臨界流體萃取supercriticalfluidextraction,SFE過弗羅里Florisil第十五章藥品質(zhì)量標(biāo)準(zhǔn)的制定國(guó)際非專利藥名InternationalNamesforPharmaceuticalSubstances,INN去氧麻黃堿Metamfetaminum國(guó)際理論和應(yīng)用化學(xué)聯(lián)合會(huì)InternationalunionofPureandAppliedChemistry,IUPAC有機(jī)化學(xué)命名原則NomenclatureofOrganicChemistry可待因Codeinum地塞米松Dexamethasonum氯……Chloroquinum青蒿素Artemisininum嗎啡Morphinum苯扎溴銨BenzalkoniiBromidum1-(3,4-二羥苯基)-2-氨基乙醇重酒石酸鹽一水合物[1-(3,4-Dihydroxyphenyl)-2-AminoethanolBitartratemono-hydrate]第十六章藥品質(zhì)量控制中的新方法與新技術(shù)填充柱packedcolumn開管柱opentubularcolumn空心柱capillarycolumn熔融石英開管柱fusedsilicaopentubularcolumn,F(xiàn)SOT高分辨率氣相色譜法highresolutiongaschromatography,HRGC壁涂開管柱wall-coatedopentubularcolumn,WCOT柱固定化相開管柱immobilizedphaseopentubularcolumn,IPOT柱交聯(lián)柱crosslinkingcolumn鍵合相柱bondingphasecolumn不可提取相開管柱nonextractablephaseopentubularcolumn,NPOT柱多孔層開管柱porous-layeropentubularcolumn,PLOT柱擔(dān)體涂漬開管柱support-coatedopentubularcolumn,SCOT柱分流進(jìn)樣splitinjection不分流進(jìn)樣splitlessinjection柱頭進(jìn)樣on-columninjection直接進(jìn)樣directinjection手性分離色譜chiralseparationchromatography,CSC普萘洛爾propranolol沙粒度胺thalidomide測(cè)定對(duì)映體enantiomer手性固定化chiralstationaryphase,CSP手性衍生試劑chiralderivatizationreagent,CDR非對(duì)映異構(gòu)體diastereoisomer,DSTM配基交換型手性添加劑
chiralligand-exchangecomplexes,CLEC手性離子對(duì)絡(luò)合劑chiralionpaircomplex,CIPC環(huán)糊精cyclodextrins,CD葡聚糖sephadex配基交換劑ligandexchanger手性傳荷chargetransfer(R)-N-3,5-二硝基苯甲酰苯基苷氨酸dimitrobenzylphenylglycin;DNBPG三點(diǎn)手性識(shí)別模式three-pointchiralrecognitionmodel噻嗎洛爾thimolol曲洛磷胺trofosfamide乙酰葡萄糖異硫氰酸酯(2,3,4,6-tetra-O-acetyl-β-D-glucopyranosylisothiocyanate,GITC左旋比喹酮L-praziquantel比喹胺praziquanamine苯丙胺phenylpropamine異氰酸-α-萘酯(α-naphthylisocyanae,NI美西律mexiletine氯胺酮ketamine本芴醇benflumelol苯丙醇phenylpropanol烯丙洛爾alprenolol普萘洛爾propranolol氧烯洛爾oxyprenolol麻黃堿ephedrine毛細(xì)管電泳capillaryelectrophoresis,CE毛細(xì)管區(qū)帶電泳capillaryzoneelectrophoresis,CZE膠束動(dòng)電毛細(xì)管色譜mcellarelectrokineticcapillarychromatography,MECC膠束動(dòng)電色譜miccellarelectrokineticchromatography,MEKC環(huán)糊精動(dòng)電色譜cyclodextrinselectrokineticchromatography,CDEKC離子交換動(dòng)電色譜ion-exchangeelectrokineticchromatography,IEEKC微滴乳狀液動(dòng)電色譜microemulsionelectrokineticchromatography,MEEKC毛細(xì)管凝膠電泳capillarygelelectrophoresis,CGE毛細(xì)管等電聚焦capillaryisoelectricfocusing,CIEF毛細(xì)管等速電泳capillaryisotachorphoresis,CITP毛細(xì)管電色譜capillaryelectrochromatography,CEC色譜響應(yīng)函數(shù)chromatographicresponsefunction,CRF色譜優(yōu)化函數(shù)chromatographicoptimizationfunction,COF等級(jí)色譜響應(yīng)函數(shù)hierarchicalchromatographicresponsefunction,HCRF差示分光光度法differencespectrophotometry近紅外光譜nearinfra-redspectrum,NIRS中紅外光譜midinfra-redspectrum,MIRS合譜combinations光譜匹配法spectralmatching匹配指數(shù)matchindex,M.I.主成分分析法principalcomponentregression,PCR人工神經(jīng)網(wǎng)絡(luò)方法artificialneuralnetworks,ANN核磁共振nuclearmagneticresonance,NMR二維NMRtwodimensionalNMR六甲基三硅氧烷hexamethylcyclotrisiloxane吡嗪pyrazine普魯卡因procaine色譜聯(lián)用技術(shù)hyphenatedtechniqueschromatography,HTC接口interface重建色譜圖reconstructivechromatogram命中質(zhì)量系數(shù)hitqualityindex,HQI最小二乘方程序leastsquaresalgothm導(dǎo)數(shù)絕對(duì)值程序absolutederivativealgothm導(dǎo)數(shù)平方程序squarederivativealgothm空心柱opentubularcolumn,OTC總離子流totalioncarrent,TIC選擇性離子監(jiān)測(cè)xelectedionmonitoring,SIM多離子檢測(cè)multipleiondetection,MID質(zhì)量碎片圖譜法massfragmentography冰片borneal川芎嗪tetramethyloyrazine,TMP電子轟擊離子化electronimpactionization,EI化學(xué)離子化chemicalionization,CI場(chǎng)解吸fielddesorption,EI快原子轟擊fastatombombardment,F(xiàn)AB熱噴霧thermospray,TSP電噴霧electrospray,ESP大氣壓離子化atmosphericpressureionization,API粒子束接口particalbeam動(dòng)態(tài)快原子轟擊法FAB離子噴霧接口ISP電子噴霧法ESP大氣壓離子化接口API大氣壓化學(xué)電離APCI串聯(lián)質(zhì)譜MS-MS麗江山慈姑IphigeniaindicaKunthetBenth托非索泮tofisopam色譜字典\術(shù)語(yǔ)大全中文英文色譜圖chromatogram色譜峰chromatographicpeak峰底peakbase峰高h(yuǎn),peakheight峰寬W,peakwidth半高峰寬Wh/2,peakwidthathalfheight峰面積A,peakarea拖尾峰tailingarea前伸峰leadingarea假峰ghostpeak畸峰distortedpeak反峰negativepeak拐點(diǎn)inflectionpoint原點(diǎn)origin斑點(diǎn)spot區(qū)帶zone復(fù)班multiplespot區(qū)帶脫尾zonetailing基線baseline基線漂移baseline
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