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1、abo2,7,8-trioxabicyclo3.2.1octyl ac acetyl acbz 4-azidobenzyloxycarbonyl ace -chloroethoxycarbonylachmb 2-acetoxy-4-methoxybenzyl acm acetamidomethyl ad 1-adamantyl adoc 1-adamantyloxycarbonyl adpoc 1-(1-adamantyl)-1-methylethoxycarbonyl aibn2,2-azobis(2-methylpropionitrile) or azobisisobutyronitril
2、e all allyl allocalloxycarbonyl als allylsulfonyl amb 2-(acetoxymethyl)benzoyl an 4-methoxyphenyl or anisyl anpe 2-(4-acetyl-2-nitrophenyl)ethyl aoc allyloxycarbonyl p-aom p-anisyloxymrthyl or (4-methoxyphenoxy)methyl ar aryl 芳香基atp adenosine 5-triphosphate 三磷酸腺苷atpaseadenosinetriphosphatase atp酶azb
3、p-azidobenzyl bam benzamidomethyl bba butane-2,3-bisacetalbbnp-bromobenzyl 9-bbn 9-borabicyclo3.3.1nonane bdms biphenyldimethylsilylbdt1,3-benzodithiolan-2-yl bic5-benzisoxazolymethoxycarbonylbmpc2,4-dimethylthiophenoxycarbonyl bmpm1,1-bis(4-methoxyphenyl)-1-pyrenylmethylbmsborane-methyl sulfide bnb
4、enzyl boct-butylcarbonyl bombenzyloxymethyl bop benzotriazol-1-yloxytris(dimethylamino) phosphonium hexafluorophosphate bop-cl n,n-bis(2-oxo-3-oxazolidinyl)phosphinicbp boiling pointbpoc 1-methyl-1-(4-biphenyl)ethoxycarbonylbpy 2,2-bipyridyl bsa bistrimethylsilyl acetamide btbenzotriazo-1-yl or 1-be
5、nzotriazolyl btba benzyltributylammonium chloride bu butyl s-bu sec-butyl t-butert-butyl bum t-butoxymethyl t-bumeoc 1-(3,5-di-t-butylphenyl)-1-methylethoxycarbonyl bz benzoyl cam carboxyamidomethylcamp adenosine cyclic 3,5-phosphatecan cerium(iv) ammonium nitrate cbz benzyloxycarbonyl cd circular d
6、ichrosimcdi 1,1-carbonyldiimidazole cee 1-(2-chloroethoxy)ethyl ci chemical ionization (in ms) configuration interaction (in mo theory)cidnp chemically induced dynamic nuclear polarizationcm centmetercmpi2-chloro-1-methylpyridium chloride cndo complete neglect of differential overlapcoc cinnamyloxyc
7、arbonyl cod 1,5-cyclooctadiene cosy correlation spectroscopycotcyclooctatetrenecpcyclopentadienyl cptr4,4,4”-tris(4,5-dichlorophthalimido)riphenylmethylcsa camphorsulfonic acid ctmp1-(2-chloro-4-methyl)phenyl-4-methoxypiperidin-4-yl cys cysteine chemical shift in ppmddaydabco1,4-diazabicyclo2.2.2oct
8、ane dam di(4-methoxyphenyl)methyl dastdiethylaminosulfurtrifluoride db-t-boc 1,1-dmethyl-2,2-dibromoethoxycarbonyldbd-tmoc 2,7-di-t-butyl9-(10,10-dioxo-10,10,10,10-tetrahydrothioxanthyl)methy lcarbonyldbn 1,5-diazabicyclo4.3.0non-5enedbu1,8-diazabicyclo5.4.0undec-7-ene dccdicyclohexylcarbodiimide dc
9、mmedichloromethylammonium chloride ddq 2,3-dichloro-5,6-dicyano-1,4-benzoquinone dead diethylazodicarboxylatedeips diethylisopropylsilyl dept distortionless enhancement by polarization transferdg diacyl glyceroldiad diisopropyl azodicarboxylate dibah dibaldiisobutylalumium hydride dim2-(1,3-dithiany
10、l)methyldipea diisopropylethylamine dipt diisopropyl tartrate dmac dimethylacetamide dmad diethyl acetylenedicarboxylate dmap 4-dimethylaminopyridine dme dimethoxyethane dmf n,n-dimethylformamide dmips dimethylisopropylsilyl dmoc dithianylmethoxycarbonyl dmpdimethylpropane dmp dimethylphosphinyl dmp
11、m3,4-dimethoxybenzyl dmpu 1,3-dimethyl-3,4,5,6-tetrhydro-2(1h)-pyrimidinone dmsdimethyl sulfate dmso dimethyl sulfoxide or methyl sulfoxide dmt dimethoxytrityl dmtr di(p-methoxyphenyl)phenylmethyl dnadeoxyribonucleic aciddnbp,p-dinitrobenzhyrryldnmbs4-(4,8-dimethoxynaphthylmethyl)benzenesulfonyl dnp
12、2,4-dinitrophenyl dobzp-(dihydroxyboryl)benzyloxycarbonyl dpmdiphenylmethyl dpmsdiphenylmethylsilyl dppdiphenylphosphinyl dppadiphenylphosphoryl azide dppe2-(diphenylphosphino)ethyl dppm (diphenyl-4-pyridyl)methyl dptdiphenylthiophosphinyl dtbms di-t-butylsilylene dts dithiasuccinimidyl e1 unimolecu
13、lar eliminatione2bimolecular eliminationed50dose that is effective in 50% of test subjectsedc1-ethyl-3-(3-dimethylaminopropyl)carbodiimideedta ethylenediaminetetraacetic acid ee 1-ethoxyethyl eeenantiomeric excessei electron impact (in ms)esrelectron spin resonanceet ethyl fabfast atom bombardment (
14、in ms)fcm-nr2n-ferrocenylmethylfd fieldfield distortion (in ms)fgfounctional groupfidflame ionization detection or free induced decay (in nmr)fm 9-fluorenylmethyl fmoc9-fluorenylmethylcarbamate fp 5ftfoutier transformg gramgc gas chromatographygtpguanosine 5-triphosphate gumguaiacolmethylhhourhca he
15、xachloroacetone hexhexyl hmds1,11,3,3,3-hexamethyldisilazanehmohuckel molecular orbitalhmpa hexamethylphosphoramide hmpt hexamethylphosphoroustriamide hobt1-hydroxybenzotriazole homo highest occupied molecular orbitalhplchigh performance liquid chromatographyhrmshigh-resolution mass spectrumhirradia
16、tion with lighthzhertzhzhomobenzyloxycarbonylicr ion cyclotron resonanceidtr 3-(imidazole-1-ylmethyl)-4,4”-dimethoxytriphenylmethyl im imidazole-1-yl or 1-imidazolyl imds 2,6dimethoxy-4-methylbenzenesulfonyl indoincomplete neglect of differential overlapipionization potentialipaoc 1-isopropylallylox
17、ycarbonyl ipdms isopropyldimethylsilyl ir infraredj coupling constant (in nmr)k kilokapa potassium 3-aminopropylamide khmdspotassium bis(trimethylsilyl)amide or potassium hexamrthyldisilane l triphenylphosphine ligand or literlah lithium aluminum hydride lcao linear combination of atomic orbitalslda
18、 lithium diisopropylamide ldbb 4,4-di-tert-butyybiphenyl ylidelev levulinoyl levslevulinoyldithioacetal ester 4,4-(ethylenedithio)pentanoyllfer linear free energy relationshiplica lithium isopropylcyclohexylamide lhmds lithium bis(trimethylsilyl)amide or lithium hexamrthyldisilane lta lead tetraacet
19、ate ltmp lithium 2,2,6,6-tetramethylpiperididelumo lowest unoccupied molecular orbital microm multiple (spectral), meter, millim moles per liter or megamadmethylaluminum bis(2,6-di-t-butyl-4-methylphenoxidembe1-methyl-1-benzyloxyethyl mbf 2,3,3a,4,5,6,7,7a-octahydro-7,8,8-trimethyl-4,7-methanobenzof
20、uran2-yl mbsp-methoxybenzenesulfonyl mcpbam-chloroperbenzoic acid mds 2,6-dimethyl-4-methoxybenzenesulfonyl mem -methoxyethoxymethylmeozp-methoxybenzyloxycarbonyl mes mesityl 2,4,6-trimethylphenyl mhz megahertzminminutemindo modified intermediate neglect of differential overlapmm millimoles per lite
21、rmmtr p-methoxyphenyldiphenylmethyl mom methoxymethyl mooph oxodiperoxymolybdenum(pyridine) hexamethylphosphoramidemoz p-methoxybenzyloxycarbonyl mp melting pointmpmp-methoxyphenylmethyl or p-methoxybenzyl mps p-methoxyphenylsufonyl mpt dimethylthiophosphinyl mrnamessenger rnamsmethanesulfonyl or me
22、syl msmass spectrometrymsamethanesulfonic acid msib4-(methylsulfinyl)benzyl msz4-methylsulfinylbenzyloxycarbonyl mtb2,4,6-trimethoxybenzenesufonyl mte2,3,5,6-tetramethyl-4-methoxybenzenesulfonyl mthp4-methoxytetrahydropyranyl mtm methylthiomethyl mtmb 4-(methylthiomethoxy)butyryl mtmeco2-(methylthio
23、methoxy)ethoxycarbonyl mtmt2-(methylthiomethoxymethyl)benzoxy mtpc4-methylthiophenoxycarbonyl mtr 2,3,6-trimethyl-4-methoxybenzenesulfonyl mts 2,3,6-trimethylbenzenesulfonyl(mesitylenesulfonyl) m/z mass to charge ratio (in ms)nnaonad nicotinamide adenine dinucleotidenadhreduced nadnba n-bromoacetami
24、de nbs n-bromosuccinimide ncs n-chlorosuccinimide ni(acac)2 nickel acetylacetonatenis n-iodosuccinimide niraney nickelnmm n-methyl morpholine nmrnuclear magnetic resonance noc4-nitrocinnamyloxycarbonyl noe nuclear overhauser effectnoesy nuclear overhauser effect spectroscopynps 2-nitrophenylsulfenyl
25、 npys 3-nitro-2-pyridinesulfenyl nu nucleophileodoptical densityonb o-nitrobenzyl ord optical rotary dispersionot oven temperaturepada potassium azodicarboxylate pcc pyridinium chlorochromate pdc pyridinium dichromate pdcl2(tpp)2dichlorobistris(2-methylphenyl)phosphinepalladium pd2(dba)3 tris(dibenz
26、ylideneacetone)dipalladium pe photoelectronpeoc 2-phosphonioethoxycarbonyl or 2-(triphenylphosphonio)ethoxycarbonyl pet 2-(2-pyridyl)ethyl pg protective groupph phenyl phen1,10-phenanthroline phenoc 4-methoxyphenacyloxycarbonyl phth phthaloyl pixyl 9-(9-phenyl)xanthenylpmb p-methoxybenzyl pmbmp-meth
27、oxybenzoxymethyl pmc 2,2,5,7,8-pentamethylchroman-6-sulfonyl pme pentamethylbenzenesulfonyl pmsp-methylbenzylsulfonyl pnb p-nitrobenzoyl pnbspp-nitrobenzenesulfonyl peroxide pom 4-pentenyloxymethyl or pivaloxymethyl ppapolyphosphoric acid (多聚磷酸)ppepolyphosphate ester (聚磷酸酯)ppm parts per mollionppoc
28、2-triphenylphosphonioisopropoxycarbonylppts pyridinium p-to;uenesulfonatepr propyli-pr isopropylpsec 2-(phenylsulfonyl)ethoxycarbonyl ptmphenylthiomethyl ptc phase-transfer catalysispv pivaloyl pypyridine pyoc 2-(2- and 4-pyridyl)ethoxycarbonylq quartetrf retention factorrrna ribosomal rnart room te
29、mperatures singlet or secondscm s-carboxymethylsulfenyl scmcl methoxycarbonylsulfenyl chloride sem trimethylsilylmeyhoxyethylses -trimethylsilylethanesulfonylset single electron transfersmom (phenyldimethylsilyl)methoxymethyl sn1unimolecular nucleophilic substitutionsn2bimolecular nucleophilic subst
30、itutionsn nucleophilic substitution with allylic rearrangementsnm s-(n-methyl-n-phenylcarbamoyl)sulfenylstabase 1,1,4,4-tetramethyldisilyl azacyclopentane su succinimidyl t triplettacm trimethylacetamidomethyl tbaftetrabutylammonium fluoride tbai tetrabutylammonium iodide tbdms t-butyldimethylsilyl
31、tbdpst-butyldiphenylsilyl tbdstetra-t-butoxydisiloxane-1,3-diylidene tbhp t-butyl hydroperoxide tbmps t-butylmethoxyphenylsilyl tbstributylsilane tbscltert-butyldimethylsilyl chloride tbtr 4,4-4”-tris(benzyloxy)triphenylmethyl tcboc 1,1-dimethyl-2,2,2-trichloroethoxycarbonyl tcne tetracyanoethylene
32、tcnq 7,7,8,8-tetracyanoquinodimethane tcroc 2-(trifluoromethyl)-6-chromonylmethylene carbonyltcrom 2-(trifluoromethyl)-6-chromonylmethylene tds thexyl dimethylsilyl teatriethylamine teab tetraethylammonium bromide tebac benzyltriethylammonium chloride tebbstebbstedatriethylene diamine teoc2-(trimethylsilyl)ethoxycarbony
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