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碳纖維英文版2第一頁(yè),共21頁(yè)。碳纖維——CarbonFiber第二頁(yè),共21頁(yè)。AbstractofContent
:一、Thestructureandpropertiesofcarbonfiber
二、Preparationofcarbonfiber
三、Theuse,presentsituationanddevelopmentprospectofcarbonfiber
3第三頁(yè),共21頁(yè)。
Carbonfiberbelongtopolymerizationofcarbon,itistheoppositeoforganicsolidshouldbeconvertedto3dcarboncompounds,carbonizationprocessisdifferent,theproductstructureformationisdifferentalso.Carbonfiberandgraphitefiberinthestrengthandelasticmodulushaveverybigdifference,thisismainlyduetothedifferentstructure.Carbonfiberisofsmallalayerofgraphitecrystalofpolycrystalline,carboncontentabout
75-95%;Graphitefiberstructureandgraphitesimilar,carboncontentofupto98-99%,impurities,quiteafew.Thecarboncontentofcarbonfiberandmanufacturingprocessoffibercarbonizationandgraphitizationprocessrelated.carbonfiberstructure第四頁(yè),共21頁(yè)。carbonfibercarbonizationprocess
Organiccompoundsinaninertgasheatingto1000ina1500degrees,allthecarbonatoms(nitrogenandhydrogen,oxygen,etc)willgraduallybedeported,carboncontentgraduallytoincrease,asthecarbonatomsexcluded,andsolidalternatewithinaseries
ofdehydrogenation,cyclization,handinchainsandpolycondensation,chemicalreaction,
formcarbonfiber.5第五頁(yè),共21頁(yè)。
carbonfibergraphitizationprocess
Temperatureto2000a3000degree,tracesofthecarbonatomstocontinuetoruleout,furtherreactionformationfangringplanegraduallytoincrease,thearrangementisneat,sexualorientationsignificantlyincreased,andthe2dalayerofgraphitestructureto3dconversionorderlystructure,formofgraphitefiber,theelasticchessisgreatlyimproved.6第六頁(yè),共21頁(yè)。Thecarbonfiberthree-dimensionalstructureschematicdrawing.7第七頁(yè),共21頁(yè)。Carbonfibermaterialperformance
First,carbonfibermaterialselectricconversionefficiency,saveelectricenergy.Carbonfiberelectrothermalbodyisafullblackbodymaterials,electricheatefficiency
ofconversion30%higherthanmetalfever,electricheatefficiencyabout100%.8第八頁(yè),共21頁(yè)。
Second,carbonfibermaterialsconductiveenergy-savingperformanceisgood,
noimpactonthecurrent.Metalfeverinthestartorclosedcable,becauseofthemetalitselftomaterial,canproduceamomentwhenthemosthighpower,canachievemaximumpowerratingofmorethantwotimes.Atthesametimeinthestart,inacertaintimeinthenottoratedcondition,itspowerwillbeconstantand
continuousgrowth,untiltoratedstate,wouldrestoreratedpower.Carbonfiberheatingcablewithnoimpactcurrent,inthestartofftokeepratedpower,won'tproducethemomentofmaximumpower,sotheenergysavingeffectthanmetal
cable.9第九頁(yè),共21頁(yè)。
Third,carbonfibermaterialswithlongservicelife.Carbonfiberfeverbynon-metallic
materialsforcablecarbonrawmaterials,theycanensurethelifespanoftheheatingelementforonethousand,theprotectivelayerouterinsulationofsiliconerubberandglassQianWeiSiselection,tinplatingcopperwiremultilayerweavesandbecome,thelifecanguaranteeinmorethan50years.Underthesameconditions,theservicelifeof
carbonfiberheatingcablethanmetalcablemuchlonger10第十頁(yè),共21頁(yè)。
Fourth,carbonfibermaterialsbygoodinsulation.Carbonfiberheatingcable
insulationisextremelystrong,itsinsulationfaroutweightherating.Inlaboratory
testsinsulation,heatingcablein80℃undernormaltemperaturedippedintothe0.8%saltwaterforelectricity,insulationresistancefor8550MΩ(standardnot
lessthan500MΩ,insulationintensityexperiment:inthe4500V(AC)1min,frequency50Hzcompression,noflash,leakagecurrentbreakdownthan0.002ma(standardis0.25ma),moreoftheverygoodsecurity.11第十一頁(yè),共21頁(yè)。ThepreparationofCarbonFiber第十二頁(yè),共21頁(yè)。Generallyspeaking,organicfiberareusedtoasarawmaterialtothemanufacturingprocessofcarbonfiber
:Organicfiber
Preoxidationprocessing
Hightemperaturecarbonization
precursorTheconditionsofchoosingtheprecursor:Highstrength,lessimpurities,thefibernumberwell-distributed。Commonlyusedtoascarbonfiberprecursor
:Polyacrylonitrilefibers
、Viscosefiber
、pitchfiber13第十三頁(yè),共21頁(yè)。ViscosefiberPitchPANdifficultcomplexLowrateabundantHighrateeasy14第十四頁(yè),共21頁(yè)。ThepreparationofPAN-CFacrylonitrilecomonomerinitiatorpolymerizationPANspinningPANfiberPreoxidationAirmedium200-300℃CarbonizationInertatmosphere1200-1500℃GraphitizationInertatmosphere2000-3000℃15第十五頁(yè),共21頁(yè)。
preoxidation
200~300℃PANfiberSixmemberedring
oxygen
16第十六頁(yè),共21頁(yè)。Carbonizationprocessofthetransversecross-linkingreaction
400~600℃Removingthehydrogen
600~130℃Removingthe
nitrogen
17第十七頁(yè),共21頁(yè)。TherequirementsofGraphitization
2500-3000℃1tension2Protectivegases
(ArorHe
)3Sealingdevice
(waterormercury
)418第十八頁(yè),共21頁(yè)。Thepurposeofgraphitization:
Amessylayerofgraphitestructure
Similartothegraphitelayeredcrystalstructure
19第十九頁(yè),共21頁(yè)。Thepreparationtechnologyofviscosecarbon
SodiumhydroxideCoagulationbath,
washing,
desulfurization,Ble
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