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Materials in Civil
andConstructionEngineering土木工程材料Chapter
2Building SteelIntroductionProperties
of
Building
Steel2.3
Standards
andSelection2.4
Corrosion
and
ProtectionContent2.1Introduction2.1 IntroductionBuildingsteels
arefor
engineeringbuildings,
including
profiledbars,armor
plates,steels
and
steelwires.Buildingsteel
isthematerial
produced
under
strict
technical
conditions,and
ithasthe
following
advantages:high
strength-weightratio,betterplasticity
and
toughness,
flexibleprocessingandthe
propertiesto
bearimpacts
andvibration
loads;the
disadvantages
are:
easy
tobe
corrodedandhighcostofrepairs.Thesecharacteristics
determine
that
steel
isoneof
the
important
materials
needed
by
economicconstruction
departments.
In
construction,
the
steelstructuresconsistedby
steel
invarious
shapeshavehighsecurity
and
light
deadweight,
usedfor
large-spanandhigh-risestructures.
But
though
concretestructureshave
heavydeadweight,theusageof
steel
isdecreased
greatly,
anditcanovercome
the
corrosion
andhighcost
of
repairs
of
steel.
Thus,
steel
iswidely
used
inconcrete
structures.Thischapterfocuses
on
theproperties
of
building
steel
andit
introduces
thestandards
andselection
ofbuilding
steel.
It
simply
introduces
corrosionof
building
steel
and
themeasures
topreventcorrosion.2.1 IntroductionSteel
is
an
alloy
of
iron
with
typically
a
few
percent
of
carbon
to
improve
its
strength
and
fracture
resistancecompared
to
iron.
Many
other
additional
elements
may
be
present
or
added.
Stainless
steels
that
are
corrosion
andoxidation
resistant
need
typically
an
additional
11%
chromium.
Because
of
its
high
tensile
strength
and
low
cost,steel
isused
in
buildings,
infrastructure,
tools,
ships,
trains,cars,
machines,electrical.The
carbon
in
typical
steel
alloys
may
contribute
upto2.14%
ofitsweight.
Varying
the
amount
ofcarbon
andmany
other
alloying
elements,
aswell
as
controlling
their
chemical
andphysical
makeup
inthe
final
steel
(eitherassolute
elements,
oras
precipitated
phases),
slows
the
movement
ofthose
dislocations
that
make
pure
ironductile,
and
thus
controls
andenhances
itsqualities.
These
qualities
include
the
hardness,
quenching
behavior,need
forannealing,
tempering
behavior,
yield
strength,
andtensile
strength
ofthe
resulting
steel.The
increase
insteel's
strength
compared
topure
iron
is
possible
onlyby
reducing
iron'sductility.2.1 IntroductionSteel
wasproducedinblooming
furnaces
forthousands
ofyears,
butits
large-scale,
industrial
use
began
only
after
moreefficient
production
methodsweredevised
inthe
17thcentury,with
the
introduction
of
the
blast
furnaceandproduction
ofcrucible
steel.
This
wasfollowedby
theopen-hearth
furnaceandthen
theBessemer
process
inEnglandinthemid-19thcentury.
With
theinvention
of
the
Bessemer
process,aneweraof
mass-produced
steel
began.Mildsteel
replaced
wrought
iron.HistoryFurther
refinementsinthe
process,such
as
basicoxygen
steelmaking(BOS),
largely
replaced
earliermethodsby
furtherlowering
thecost
ofproduction
andincreasingthequality
ofthefinalproduct.Today,
steelis
oneofthemostcommonmanmade
materials
inthe
world,
with
more
than
1.6billion
tonsproducedannually.Modernsteelis
generallyidentified
byvarious
gradesdefined
byassortedstandardsorganizations.2.1 Introduction2.1.2 Classification1.By
Smelting
ProcessesDuring
smelting,theremovaldegrees
ofimpurities
bydifferent
smelting
methods
arenotthesame,so
thesteelqualities
aredifferent.
Recently,
therearethree
kindsof
steel,
including
Bessemer
steel(converter
steel),Siemens-Martinsteel,
andelectric
steel.BessemerSteelThesmelting
process
of
thissteel
isto
use
themoltenpigiron
as
the
raw
materialwithoutany
fuelandtomake
steel
withair
or
pure
oxygen
being
blownthroughthemolteniron(therawmaterial)from
thebottomorthesidesoftheconverter.Siemens-Martin
SteelUse
solidor
fluid
pig
iron,
ore
orwaste
steelas
theraw
materials
andcoal
gasorheavy
oilasthe
fuelandtoremove
the
impurities
from
theironbyoxidation
withthe
oxygeninoreorwastesteelor
theoxygenbeing
blown
through
the
iron.Electric
SteelTheprocess
of
electric
steelistomake
steel
by
electricheating.
Theheat
source
ishigh-tension
arc,
andthesmelting
temperature
ishighandcan
beadjustedfreely.2.1 IntroductionByPress-workingModesIn
the
process
of
smelting
andingot-casting,
there
will
beuneven
structures,
foams
or
other
defectshappening
to
the
steel,so
the
steel
used
in
industry
should
beprocessed
bypress
to
eliminate
thedefects.
Meanwhile,
there
isrequirement
for
shapes.
Thepress-working
modes
include
hot
workingand
cold
working.Hot-working
steel:
Hot
working
is
to
heat
the
steel
ingot
to
a
certain
temperature
and
toconduct
press-working
to
the
steel
ingot
in
the
plastic
state,
such
as
hot
rolling
and
hot
forging.Cold-working
steel:
Thesteel
is
processed
under
thenormal
temperature2.1 Introduction3.ByChemical
ElementsSteel
Classifications
(GB/T
13304-1991),
the
Chinese
standard,
recommends
two
classificationmethods:
one
is
to
classify
by
chemical
elements,
and
the
other
is
to
classify
by
quality
degrees.
Bychemicalelements,
there
is
non-alloy
steel,
lean-alloy
steel
and
alloy
steel.Non-alloysteel:
thatis
carbonsteel
with
fewalloyelements.Lean-alloy
steel:
that
isthe
steel
with
low
alloyelements.Alloy
steel:
thatisthesteeladded
with
more
alloyelements
to
improve
some
propertiesofthesteel.2.1 IntroductionByQuality
DegreesAccording
to
quality
degrees,
the
steel
can
be
classified
into:
common
steel,
quality
steel
andadvanced
quality
steel.BypurposesThe
steel
can
be
classified
by
purposes,
such
as
construction
steel,
railway
steel,
and
pressure
vesselsteel.
The
construction
steel
can
be
classified
by
purposes
into
the
steel
for
steel
structures
and
that
forconcrete
structures.
At
present,
the
steel
commonly
used
in
constructions
includes
carbon
structuralsteel
and
lean-alloy
andhigh-strength
structural
steel.2.2Properties
ofBuilding
Steel2.2 PropertiesofBuildingSteelThe
essential
properties
of
steels
in
steel
structure
and
reinforced
concrete
in
civilengineering
are:Mechanical
property:
tensile
strength,
impacttoughness,fatigue
strength.Processing
property:
cold
bending
and
welding
property.2.2.1 Mechanical
Properties1.
Tensile
StrengthIt
is
the
most
important
property
of
the
building
steels.
Thetensile
strength
of
construction
steel
includes:
yield
strength,ultimate,
tensile
strength,
and
fatiguestrength.(1)
Low
Carbon
Steel
Stress-strain
Curves
(Figure2.1)Ⅰ-The
elastic
stage,
expressed
by
p
;Ⅱ-Theyield
stage,
expressed
by
s;Ⅲ-Thereinforcement
stage,
expressed
by
b;Ⅳ-The
necking
stage.Figure
2.1Low
carbon
steel
stress-strain
curves2.2 PropertiesofBuildingSteel2)
Strength①
Yield
StrengthAs
shown
in
Figure
2.1,
at
the
yield
stage,
the
corresponding
stress
of
the
highest
point
on
the
hackle
is
calledthe
upper
yield
point
(B);
get
rid
of
theinitial
transient
effect,
thecorresponding
stress
of
the
lowest
point
iscalledthe
lower
yield
point
(B
).
The
Chinese
standard
regulates
that
the
stress
of
the
lower
yield
point
is
the
yieldstrength
of
thesteel,
expressed
by
s.attentionWhen
theactual
stressof
astructurereaches
theyield
point,
there
willbeirretrievable
deformationwhich
isnotallowed
in
constructions.
Thus,
yield
strength
isthemain
base
todeterminetheallowable
stress
of
thesteel.2.2 PropertiesofBuildingSteel②
Ultimate
Tensile
Strength
(Simply
Called
Tensile
Strength)It
is
the
ultimate
tensile
stress
that
the
steel
can
bear
under
the
role
of
tension,
shown
in
Figure
2.1,
the
highestpoint
of
stage
Ⅲ.
s/
b
can
reflect
the
availability
and
safety
of
steel.
The
smaller
theyield
ratio,
the
more
reliablethe
structure
is.
However,
if
the
ratio
istoo
small,the
availableutilization
ratio
ofthe
steel
will
be
toolow,
and
thereasonable
yield
ratio
should
lie
between
0.6-0.75.
Therefore,
the
yield
strength
and
the
tensile
strength
are
themajor
test
indexes
of
themechanical
propertiesof
steel.③
Fatigue
StrengthUnder
the
role
of
alternating
loads,
steel
will
be
damaged
suddenly
when
the
stress
is
far
below
the
yieldstrength,
and
this
damage
is
called
fatigue
failure.
The
value
of
stress
at
which
failure
occurs
is
called
fatiguestrength,
or
fatigue
limit.
The
fatigue
strength
is
the
highest
value
of
the
stress
at
which
the
failure
never
occurs.Generally,
the
biggest
stress
that
the
steel
bears
alternating
loads
for
106-107
times
and
no
failure
occurs
is
calledthefatigue
strength.Thesmaller
theyield
ratioThemorereliable
thestructure
is2.2 PropertiesofBuildingSteel2.PlasticityThe
construction
steel
should
have
good
plasticity.
In
projects,
the
plasticity
of
the
steel
is
usually
expressed
bythe
elongation.
Elongation
refers
to
the
ratio
of
the
increment
of
the
gauge
length
to
the
original
gauge
lengthwhen
thespecimenis
stretched
off,expressed
by
(%),
shown
in
Figure
2.2.
L1
L0L0
100%Plasticity
isan
importanttechnical
property
forsteel.
Thoughthestructures
areused
duringtheelastic
stage,
thepartwherethestressconverges
could
bebeyond
theyield
strength.
Andcertain
plasticity
canguarantee
theredistribution
ofthestress
toavoid
failure
ofstructures.Figure
2.2
Tensile
specimens
of
steel2.2 PropertiesofBuildingSteel3.Impact
DurabilityImpact
durability
refers
to
the
property
that
the
steel
resists
loads
without
being
damaged.
It
is
regulated
thatthe
impact
durability
is
expressed
by
the
work
spent
on
the
unit
area
of
the
damaged
notch
when
the
standardnotched
specimen
is
stricken
by
the
pendulum
of
the
impact
test,
with
the
sign
αK,
and
the
unit
J,
as
shown
inFigure
2.3.The
bigger
αK
is,
the
more
work
will
be
spent
in
damaging
the
specimen,
or
the
more
energy
the
steel
willabsorb
beforegetting
cracked,
and
the
better
the
durability
of
the
steelis.The
impact
durability
of
the
steel
is
related
to
its
chemical
elements,
smelting,
and
processing.
Generally,
Pand
S
contents
in
steel
are
high,
and
impurities
and
the
tiny
cracks
forming
in
smelting
will
lower
the
impactdurability.2.2 PropertiesofBuildingSteelIn
addition,
the
impactdurability
of
the
steelcan
be
influenced
by
temperature
and
time.
At
the
roomtemperature,
the
impactdurability
willdecline
little
with
the
temperature
falling,
andthedamaged
steelstructurereveals
theductile
fracture;
ifthetemperature
falls
into
arange,αk
declines
suddenly,
thesteel
revealsthebrittlefracture,
andthetemperature
is
verylow
when
cold
brittle
fracture
occurs.
In
north,
especially
thecold
places,
thebrittle
fracture
of
the
steelshouldbe
tested
when
the
steelis
used.
The
critical
temperature
ofits
brittle
fractureshould
be
lower
than
thelowesttemperature
oftheplace.
Because
themeasurement
ofthecritical
temperature
iscomplicated,
what
is
regulated
instandards
istheimpact
values
atthenegative
temperature
-20
C
or
-40
C.(a)
specimen
size(b)
test
device(c)
working
principle
of
pendulum
tester1-Pendulum;
2-Specimen;
3-Test-bed;
4-Dial;
5-Needle.Figure
2.3
Thetest
principle
of
impact
durability2.2 PropertiesofBuildingSteel4.RigidityRigidity
is
the
property
to
resist
the
plastic
deformation
when
there
is
a
hard
object
press
into
the
steel
withinthe
partial
volume
of
the
surface,
often
related
to
the
tensile
strength.
Recently,
there
are
various
methods
tomeasure
the
rigidity
of
thesteel,
and
themost
common
one
is
Brinell
hardness,
expressed
by
HB.2.2.2 Process
Properties1.ColdBendingPropertyCold
bending
is
thepropertythat
thesteel
bears
thebending
deformationunder
thenormalconditions.The
cold
bending
is
tested
by
checking
whether
there
are
cracks,
layers,
squamous
drops
and
ruptures
on
thebending
partafter
thespecimen
goes
throughtheregulated
bending.2.2 PropertiesofBuildingSteelGenerally,
it
is
expressed
by
the
ratio
of
the
bending
angle
α
and
the
diameter
of
the
bending
heart
d
to
thethickness
of
thesteel
or
thediameterof
thesteel
a.Figure
2.4
showsthatthebigger
the
bending
angleis,
thesmaller
theratio
of
d
to
a
is,
and
thebetter
thecold
bending
property
is.Coldbending
test
ishelpful
toexpose
some
defects
ofsteel,
such
aspores,impurities
andcracks.
Inwelding,
thebrittleness
of
parts
andjoints
can
befound
bycold
bendingtest,
sothecoldbendingtestis
notonly
theindex
tocheckplasticity
andmachinability,
butalsoan
importantindex
toevaluate
the
welding
quality.Thecold
bending
test
for
thesteelusedinimportant
structures
orthebended
steel
shouldbequalified.Figure
2.4
Cold
bending
test
of
steel2.2 PropertiesofBuildingSteel2.
Weld
AbilityWelding
is
the
major
mode
for
the
combination
of
steel.
The
quality
of
welding
depends
on
the
weldingtechniques,
welding
materials
and
theweldability
of
steel.abilityWeld
ability
refersto
theproperty
that
under
acertain
welding
condition,
there
isnocrackor
hardruptureinor
around
welding
seamsand
themechanical
property
after
welding,
especially
thestrength,
shouldbenotlowerthantheoriginal
one.conditionTheweld
ability
will
decrease,
ifthecarbon
content
ismorethan
0.3%,
or
there
ismore
sulfur,or
theimpurity
content
ishigh,
andthealloy
elements
content
ishigh.materialsThesteel
used
forweldingis
theoxygen
converter
ortheSiemens-Martin
fully-killed
steelwithlower
carbon
content.
Forthehighcarbon
steel
andalloy
steel,
preheating
andheat
treatment
shouldbeadopted
respectively
before
andafterwelding
inorderto
improvethehardbrittleness
ofthesteelafter
welding.2.2 PropertiesofBuildingSteel2.2.3 AffectingFactors
ofProperties1.Influences
of
Chemical
Elements(1)
CarbonCarbon
is
the
major
element
that
determines
the
properties
of
steel.
With
the
increasing
of
carbon
content,
therigidity
and
thestrength
of
steel
willincrease,
and
its
plasticity
and
toughness
willdecrease.If
the
carbon
content
ismore
than
1
%,
the
ultimate
strength
of
the
steel
begins
to
fall.
In
addition,
if
the
carboncontent
is
too
high,
the
brittleness
and
aging
sensitivity
of
the
steel
will
rise,
which
reduce
its
ability
to
resist
thecorrosion
of
the
atmosphere
and
weld
ability.the
rigidity
and
thestrength
of
steel
willincreaseWith
the
increasing
ofcarbon
content2.2 PropertiesofBuildingSteel(2)
Phosphor
and
SulfurPhosphor
is
similar
with
carbon
that
can
improve
the
yield
point
and
bending
strength
of
steel,
lower
itsplasticity
and
toughness,
and
greatly
increase
its
cold
brittleness.
But
the
segregation
of
phosphor
is
serious
andthere
are
cracks
in
welding,
so
phosphor
is
one
of
the
elements
that
can
lower
the
weld
ability
of
steel.
Thus,
incarbon
steel,
the
phosphor
content
should
be
controlled
strictly;
but
in
alloy
steel,
it
can
improve
the
resistance
toatmospheric
corrosion
of
steel,
and
can
also
be
thealloy
element.In
steel,
sulfur
exists
in
the
mode
of
FeS.
FeS
is
a
kind
of
low
melting
compound
that
has
been
melted
whenthe
steel
is
processed
or
welded
in
the
state
of
glowing
red
and
will
lead
to
cracks
inside
the
steel,
called
hotbrittleness.The
hot
brittleness
greatly
reduces
the
process
ability
and
weld
ability
of
steel.
In
addition,
the
segregation
ofsulfur
is
serious
that
can
reduce
the
impact-resistance,
fatigue
strength
and
anti-corrosion
of
steel.
Thus,
the
sulfurcontent
should
also
be
controlled
strictly.2.2 PropertiesofBuildingSteelOxygen
andNitrogenOxygen
and
nitrogen
can
partly
dissolve
in
ferrite
and
most
of
them
exist
in
the
mode
of
compounds.
Thesenon-metals
contain
impurities
that
reduce
the
mechanical
properties
of
steel,
especially
the
toughness
of
steel,
andcan
accelerate
aging
and
lower
weld
ability.
Thus,
the
oxygen
and
nitrogen
should
be
controlled
strictly
in
steel.Silicon
and
ManganeseSilicon
and
manganese
are
the
elements
added
purposely
during
steelmaking
for
deoxygenation
anddesulphurization.
Because
silicon
can
combine
with
oxygen
greatly,
it
can
capture
the
oxygen
in
ferric
oxide
togenerate
silicon
dioxide
and
stay
in
the
steel
slag.
Most
of
the
remaining
silicon
will
dissolve
in
ferrite.
Andwhen
the
content
is
low
(less
than
1%),
it
can
improve
the
strength
of
steel
and
has
little
influence
on
plasticityand
toughness.Combining
force
of
manganese
with
oxygen
and
sulfur
is
higher
than
that
of
iron,
so
manganese
can
changeFeO
and
FeS
into
MnO
and
MnS
respective
19
and
stay
in
the
steel
slag.
And
the
remaining
manganese
dissolvesin
ferrite
and
twiststhecrystal
lattice
to
prevent
slippageand
deformation,
greatly
improving
thestrength
of
steel.concept2.2 PropertiesofBuildingSteel2.Influences
of
Cold
Working
andHeat
Treatment(1)
Cold
WorkingCold
working
is
the
process
that
steel
is
processed
at
the
room
temperature.
The
common
cold
working
modesfor
constructionsteel
include:
cold
stretching,
cold
drawing,cold
rolling,
cold
twisting,
notching.At
the
room
temperature,
beyond
the
elastic
range
of
the
steel,
the
plastic
deformation
strength
and
rigidity
ofthe
steel
have
increased
and
its
plasticity
and
toughness
have
decreased,
which
is
called
cold-workingstrengthening.
It
improvesthestrength
and
the
yield
strength
can
raise
20%-30%
after
cold
working.Within
a
certain
range,
the
bigger
the
cold-working
deformation
is,
the
greater
the
yield
strength
increases,
andthe
more
the
plasticity
and
the
toughness
decrease.2.2 PropertiesofBuildingSteel(2)
Heat
TreatmentSteel
can
be
hardened
or
softened
by
using
heat
treatment;
the
response
ofsteel
to
heat
treatment
depends
on
its
alloy
composition.
The
basic
process
is
toheat
the
steel
to
a
specific
temperature,
hold
the
temperature
for
a
specifiedperiod
of
time,
then
cool
the
material
at
a
specified
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