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1、05.高分子化學05.1高分子物質(zhì)新序碼漢文名英義名注釋高分子macromolecule, polymer又稱大分子”。超高分子supra polymer天然高分子natural polymer無機高分子inorganic polymer有機高分子organic polymer無機-有機高分子inorganic organic polymer金屬有機聚合物organometallic polymer兀素局分子element polymer局聚物high polymer聚合物polymer低聚物oligomer曾用名齊聚物二聚體dimer三聚體trimer調(diào)聚物telomer預聚物prepoly

2、mer均聚物homopolymer無規(guī)聚合物random polymer無規(guī)卷曲聚合物random coiling polymer頭-頭聚合物head-to-head polymer頭-尾聚合物head-to-tail polymer尾-尾聚合物tail-to-tail polymer反式有規(guī)聚合物transtactic polymer順式啟規(guī)聚合物cistactic polymer規(guī)整聚合物regular polymer非規(guī)整聚合物irregular polymer無規(guī)立構聚合物atactic polymer全同立構聚合物isotactic polymer又稱等規(guī)聚合物”。間同立構聚合物sy

3、ndiotactic polymer又稱間規(guī)聚合物”。雜同立構聚合物heterotactic polymer又稱異規(guī)聚合物”。有規(guī)立構聚合物stereoregular polymer, tactic polymer又稱宥規(guī)聚合物”。蘇型雙全同立構聚合物threo-diisotactic polymer蘇型雙間同立構聚合物threo-disyndiotactic polymer赤型雙全同立構聚合物erythro-diisotactic polymer赤型雙間同立構聚合物erythro-disyndiotactic polymer全向間同等量聚合物equitactic polymer共聚物copo

4、lymer二兀共聚物binary copolymer三元共聚物terpolymer多元聚合物multipolymer序列共聚物sequential copolymer多層共聚物multilayer copolymer多相聚合物multiphase polymer統(tǒng)計結構共聚物statistical copolymer無規(guī)共聚物random copolymer交替共聚物alternating copolymer周期共聚物periodic copolymer梯度共聚物gradient copolymer嵌段共聚物block copolymer又稱“嵌段聚合物(block polymer) 。遞變嵌

5、段共聚物tapered block copolymer兩米嵌段共聚物amphiphilic block copolymer二嵌段共聚物diblock copolymer三嵌段共聚物triblock copolymer多嵌段共聚物segmented copolymer雜聚物heteropolymer恒組分共聚物azeotropic copolymer多組分共聚物multicomponent copolymer單分散聚合物monodisperse polymer, uniform polymer多分散性聚合物polydisperse polymer, non-uniform polymer高分子共

6、混物polyblend, polymer blend聚合物-聚合物配合物polymer-polymer complex聚合物-金屬配合物polymer-metal complex單股聚合物single-strand polymer雙股聚合物double-strand polymer多股聚合物multi-strand polymer鏈型聚合物chain polymer碳鏈聚合物carbon chain polymer雜鏈聚合物heterochain polymer雜環(huán)局分子heterocyclic polymer大劃、聚合物macrocyclic polymer直鏈高分子straight cha

7、in polymer線型聚合物linear polymer體型聚合物three-dimensional polymer又稱“網(wǎng)絡聚合物(network polymer) 、交聯(lián)聚合物(crosslinkedpolymer)”。活性高分子living polymer反應性聚合物reactive polymer極性聚合物polar polymer非極性聚合物non-polar polymer剛性鏈聚合物rigid chain polymer半柔性鏈聚合物semi- flexible chain polymer柔性鏈聚合物flexible chain polymer剛棒局分子rigid rod po

8、lymer棒狀高分子rodlike polymer剛-柔嵌段共聚物rod coil block copolymer樹狀高分子dendrimer, dendritic polymer, tree polymer刷狀聚合物brush polymer線團狀聚合物coiling type polymer花菜狀聚合物cauliflower polymer螺旋形聚合物helical polymer錐形共聚物tapered copolymer梯形聚合物ladder polymer分段梯形聚合物step ladder polymer部分梯形聚合物partial ladder polymer碳環(huán)梯形聚合物car

9、bocyclic ladder polymer梳形聚合物comb polymer星形聚合物star polymer遙爪聚合物telechelic polymer支化聚合物branched polymer超支化聚合物hyperbranched polymer接枝聚合物graft polymer核-殼共聚物core shell copolymer核-殼膠乳聚合物core shell latex polymer手性高分子chiral polymer互穿聚合物網(wǎng)絡interpenetrating polymer networks, IPN半互穿聚合物網(wǎng)絡semi-interpenetrating po

10、lymer network(SIPN)異質(zhì)同晶聚合物polyallomer多晶形聚合物polycrystalline polymer締合聚合物association polymer共軻聚合物conjugated polymer螯合聚合物chelate polymer遠螯聚合物telechelic polymer螯合型離子父換劑chelating ion-exchanger又稱“接枝共聚物(graft copolymer)。螯合型樹脂chelating resin紫膠shellac蠶絲natural silk骨膠原collagen凝膠gel明膠gelatin黃原膠xanthate gum瓊脂ag

11、ar-agar樹膠gum白蛋白albumin脫氧核糖核酸deoxyribonucleic acid (DNA )淀粉amylum , starch直鏈淀粉amylose支鏈淀粉amylopectin甲殼質(zhì)chitin葡聚糖dextran糊精dextrinlignin纖維素cellulose“纖維素a cellulose3纖維素3 cellulose丫纖維素丫 cellulose硝酸纖維素cellulose nitrate胺纖維素amine cellulose乙酸纖維素cellulose acetate甲基纖維素methyl cellulose羥乙基纖維素hydroxyethyl cellulo

12、se較甲基纖維素carboxymethyl cellulose天然橡膠natural rubber三葉橡膠Hevea又稱空膠”。又稱右旋糖酎又稱硝化纖維素俗稱醋酸纖維素杜仲膠Eucommea rubber古塔波膠Gutta percha合成聚合物synthetic polymer加成聚合物addition polymer通用高分子commodity polymer功能高分子functional polymer仿生高分子biomimetic polymer形狀記憶高分子shape-memory polymer類酶高分子enzyme like polymer生物高分子biopolymer生物彈性體

13、bioelastomer生物活性高分子bioactive polymer生物可蝕性高分子bioerodable polymer生物降解高分子biodegradable polymer醫(yī)用高分子medical polymer生物醫(yī)用高分子biomedical polymer局分子約物polymer drug降解性高分子degradable polymer高性能高分子high performance polymer高模量聚合物high modulus polymer特殊性能高分子speciality polymer又稱特種高分子”。智能聚合物intelligent polymer親水聚合物hydr

14、ophilic polymer疏水聚合物hydrophobic polymer西千聚合物amphiphilic polymer吸水性聚合物water absorbent polymer水溶性高分子water soluble polymer大孔聚合物macroporous polymer精細高分子fine polymer3聚合物w-polymer俗稱米花狀聚合物熱解聚合物pyrolytic polymer高熔聚合物dystectic polymer光響應局分子photoresponsive polymer光活性聚合物optical active polymer光敏聚合物photosensitiv

15、e polymer光彈性聚合物photoelastic polymer感光聚合物photopolymer光致發(fā)光聚合物photoluminescence polymer電致發(fā)光聚合物electroluminescent polymer熱敏發(fā)光聚合物thermosensitive luminescence polymer光交聯(lián)聚合物photocrosslinkable polymer光固化聚合物photocureable polymer輻射固化聚合物radiation curable polymer光降解聚合物photodegradable polymer輻射降解聚合物radiation-deg

16、radable polymer光電導聚合物photoconductive polymer導電聚合物conducting polymer超導聚合物superconductive polymer高分子半導體semiconducting polymer電活性聚合物electroactive polymer壓電局分子piezoelectric polymer熱電性高分子pyroelectric polymer電致變色聚合物electrochromic polymer磁性聚合物magnetic polymer超離了導電聚合物super ion-conductive polymer鐵磁聚合物ferroma

17、gnetic polymer鐵電聚合物ferroelectric polymer燒蝕聚合物ablative polymer局分十離十macroion(popcorn polymer )。聚合物駐極體高分子添加劑液晶高分子溶致液晶高分子熱致液晶高分子側(cè)鏈型液晶聚合物主鏈型液晶聚合物高分子催化劑高分子載體高分子試劑離子交聯(lián)聚合物離子交換聚合物離子交換樹脂止離子父換樹脂負離子父換樹脂大網(wǎng)絡樹脂離子聚合物聚電解質(zhì)兩性聚電解質(zhì)聚合物溶劑樹脂熱敏性樹脂天然樹脂熱塑性樹脂熱固性樹脂塑性體燒類樹脂石油樹脂polymer electretpolymeric additiveliquid crystal poly

18、merlyotropic liquid crystalline polymerthermotropic liquid crystalline polymerside chain liquid crystalline polymermain chain liquid crystalline polymerpolymer catalystpolymeric carrier, polymer supportpolymer reactant, polymer reagentionomerion exchange polymerion exchange resincation exchange resi

19、nanion exchange resinmacroreticular resinionic polymerpolyelectrolytepolyampholyte, polyamphoteric electrolytepolymer solventresinthermally sensitive resinnatural resinthermoplastic resinthermosetting resinplastomerhydrocarbon resinpetroleum resin又稱高分子電解質(zhì)(polymer elec-trolyte)。苗樹脂indene resin苯并吠喃-苗樹

20、脂coumarone-indene resin菇烯樹脂terpene resin丙烯睛-.二烯-苯乙烯acrylonitrile-butadiene-styrene resin簡稱“AB劑脂”。樹脂丙烯睛-苯乙烯樹脂acrylonitrile styrene resin (AS)丙烯酸酯類樹脂acrylic resin氟碳樹脂fluorocarbon resin縮醛樹脂acetal resin縮甲醛樹脂methylal resin縮.醛樹脂butyral resin酚醛樹脂phenol-formaldehyde resin, phenolic resin甲階酚醛樹脂resol又叫“可溶酚醛樹脂

21、”。乙階酚醛樹脂resitol又叫“半熔酚醛樹脂”。丙階酚醛樹脂resite又叫不溶不熔酚醛樹脂”??啡渲琭urfural resin糠醛苯酚樹脂furfural phenol resin苯酚醛樹脂phenol ether resin吠喃樹脂furan resin氨基樹脂amino resin月尿醛樹脂urea-formaldehyde resin聚月尿樹脂carbamide resin又叫碳酰胺樹脂”。尿素樹脂urea resin三聚鼠胺樹脂Aminotriazine resin三聚鼠胺-甲醛樹脂melamine-formaldehyde resin, melamineresin聚酯類樹脂

22、polyester resin醇酸樹脂alkyd resin烯丙基樹脂allyl resin有機硅樹脂silicone resin氟樹脂fluoroethylene resin環(huán)氧樹脂epoxy resin脂肪族環(huán)氧樹脂aliphatic epoxy resin雙酚A環(huán)氧樹脂bisphenol A epoxy resin氧化還原樹脂redox resin烯類聚合物vinyl polymer雙烯聚合物diene polymer烯煌共聚物olefine copolymer (OCP)乙烯基聚合物vinyl polymer聚烯煌polyolefin聚乙烯polyethylene超高分子量聚乙烯ult

23、rahigh molecular weight polyethylene,UHMWPE高密度聚乙烯high density polyethylene, HDPE低密度聚乙烯low density polyethylene, LDPE線型低密度聚乙烯linear low density polyethylene, LLDPE超低密度聚乙烯ultra low density polyethylene, ULDPE長支鏈聚乙烯long chain branched polyethylene聚丙烯polypropylene全同立構聚丙烯isotactic polypropylene(iPP )又稱等規(guī)

24、聚丙烯”。聚1-丁烯poly(1-butene)聚異丁烯polyisobutylene聚4-甲基-1-戊烯poly(4-methyl-1-pentene)聚(1-辛烯)poly(1-octene)聚苯乙烯polystyrene局抗沖聚苯乙烯high impact polystyrene, HIPS聚乙快polyacetylene丙烯酸酯類聚合物acrylic polymer10聚丙烯酸poly(acrylic acid)聚丙烯酸鹽polyacrylate聚丙烯酸酯polyacrylate聚甲基內(nèi)烯酸酯polymethacrylate聚甲基內(nèi)烯酸甲酯poly(methyl methacrylat

25、e)乙烯-乙酸乙烯酯共聚物ethylene vinyl acetate copolymer (EVA)聚乳酸poly(lactic acid) , polylactide聚(3氨基丙酸)poly( 3 alanine)又稱尼龍3、聚酰胺3”。聚(3-氨基己酸)poly( w amino caproic acid)又稱尼龍6、聚酰胺6”。聚(8-氨基辛酸)poly(8 amino caprylic acid)又稱尼龍8、聚酰胺8”。聚胱氨酸polycysteine聚谷氨酸poly(glutamic acid)又叫聚2-氨基戊二酸”。聚甘氨酸polyglycine聚丙烯睛polyacrylonit

26、rile聚乙酸乙烯酯poly(vinyl acetate)俗稱“聚醋酸乙烯酯”。聚乙二醇poly(oxyethylene glycol)聚乙烯醇poly(vinyl alcohol)聚乙烯醇縮甲醛poly(vinyl formal)聚乙烯醇縮.醛poly(vinyl butyral)聚氯乙烯poly(vinyl chloride)聚1,2-二氯亞乙烯poly(vinylene chloride)聚偏二氯乙烯poly(vinylidene chloride)又稱聚偏二氯乙烯”。聚氟乙烯poly(vinyl fluoride)聚偏二氟乙烯poly(vinylidene fluoride)又稱聚偏二

27、氟乙烯”。聚三氟氯乙烯poly(chlorotrifluoroethylene), PCTFE11對于環(huán)烯煌的聚合產(chǎn) 物,由于聚合機理的 不同,一種是開環(huán)聚 合,一種是保留環(huán)打 開雙鍵的聚合。聚四氟乙烯聚全氟丙烯聚丁二烯1,4-聚丁烯1,2-聚丁二烯順式-1,4-聚丁二烯反式-1,4-聚丁烯聚環(huán)戊二烯聚異戊二烯1,2-聚異戊二烯3,4-聚異戊二烯順式-1,4-聚異戊二烯反式-1,4-聚異戊二烯聚氯丁二烯開環(huán)聚環(huán)烯燃聚降冰片烯醛類聚合物丙烯醛類聚合物乙快類聚合物丙二烯聚合物二乙快聚合物二烯丙基聚合物偶氮類聚合物氧雜環(huán)丁烷聚合物配位聚合物阻透聚合物氧化性聚合物poly(tetrafluoroeth

28、ylene) poly(perfluoropropene) polybutadiene1,4-polybutadiene1,2-polybutadiene cis-1,4-polybutadiene trans-1,4-polybutadiene polycyclopentadiene polyisoprene1,2-polyisoprene3,4-polyisoprene cis-1,4-polyisoprene trans-1,4-polyisoprene polychloroprene polyalkenamerpolynorbornene aldehyde polymeracrolei

29、n polymer acetylenic polymerallene polymer diacetylene polymerdiallyl polymerazo polymeroxetane polymer coordination polymer barrier polymer oxidative polymer12縮聚物polycondensate共縮聚物intercondensation polymer聚竣酸酯polycarboxylate聚酯polyester脂肪族聚酯aliphatic polyester芳香族聚酯aromatic polyester共聚酯copolyester飽和聚

30、酯saturated polyester不飽和聚酯unsaturated polyester聚對苯一甲酸乙二酯poly(ethylene terephthalate)聚對策一甲酸.二酯poly(tetramethyleneterephthalate),poly(butylene terephthalate)聚對苯一甲酸對苯一酯poly(p-phenylene terephthalate)聚碳酸酯polycarbonate雙酚A聚碳酸酯bisphenol A polycarbonate聚酰胺polyamide聚醛酰胺poly(ether amide)聚己內(nèi)酰胺polycaprolactam聚己二

31、酰己二胺poly(hexamethylene adipamide)聚芳酰胺polyaramide, aromatic polyamide多肽polypeptide聚醒polyether芳香族聚醍poly (aryl ether)共聚醒copolyether嵌段聚醛酯block poly(ester ether)聚甲醛polyoxymethylene, polyformaldehyde低聚甲醛paraformaldehyde又稱多聚甲醛”。共聚甲醛copolyoxymethylene聚環(huán)氧乙烷poly(ethylene oxide)又稱“聚氧化乙烯(polyoxyethylene)。13聚環(huán)氧丙

32、烷聚環(huán)氧氯丙烷聚四氫吠喃聚苯醛聚硫醒聚硫化物聚對亞苯確醛聚對亞聚聚碉聚芳硼聚芳硼酰胺聚醒碉聚一聚醒碉聚酰亞胺聚均苯四酰亞胺-1,4-亞苯聚苯并咪陛聚苯并曝陛聚唾喔咻聚醒酮聚醒醒酮聚醒酮酮聚氨基甲酸酯聚月尿聚醛氨酯聚苯胺苯醍聚合物硅酸鹽聚合物塑料poly(propylene oxide)polyepichlorohydrinpolytetrahydrofuran, polyoxytetramethylenepolyphenylene oxidepolythioetherpolysulfidepoly(p-phenylene sulfide)poly(p-phenylene)polysulfone

33、poly(aryl sulfone) (PAS)aromatic polysulfonamidepoly(ether sulfone)poly(diphenyl ether sulfone)polyimidepoly(pyromellitimido-1,4-phenylene)polybenzimidazolepolybenzothiazolepolyquinoxalinepoly(ether-ketone), PEKpoly(ether-ether-ketone), PEEKpoly(ether-ketone-ketone), PEKKpolyurethanepolyureapoly(eth

34、er-urethane)polyanilinequinone polymersilicate polymer, polysilicateplastic又稱“聚氧化丙烯 (polyoxytrimethyl-ene)又稱聚業(yè)笨醒俗稱聚聚硫醒”。簡稱聚氨酯”。14塑料合金plastic alloy工程塑料engineering plastic增強塑料reinforced plastic纖維增強塑料fiber reinforced plastic自增強聚合物self-reinforcing polymer復合材料composite納米復合材料nanocomposite分子復合材料molecular c

35、omposite原位復合材料in situ composite有機-無機雜化材料organic inorganic hybrid material混雜復合材料hybrid composite橡膠rubber高彈體elastomer又稱彈性體”。合成橡膠synthetic rubber飽和橡膠saturated rubber不飽和橡膠unsaturated rubber氫化橡膠hydrogenated rubber集成橡膠integrated rubber異戊橡膠isoprene rubber苯乙烯-異戊一烯-一styrene isoprene butadiene rubber (SIBR)烯橡

36、膠三元乙丙橡膠ethylene propylene terpolymer, EPT, ethylene又稱“乙丙三元橡propylene diene monomer, EPDM膠”。二兀乙丙橡膠ethylene propylene rubber, EPR, ethylene又稱“乙丙二元橡propylenecopolymer, ethylene propylene膠”。monomer, EPM丁睛橡膠butadiene-acrylonitrile rubber, nitrile rubber氫化丁睛橡膠hydrogenated butadiene-acrylonitrile rubber竣基丁

37、睛橡膠carboxy terminated nitrile rubber順丁橡膠cis-1,4-polybutadiene rubber基橡膠butyl rubber15鹵化基橡膠halogenated butyl rubber苯橡膠styrene butadiene rubber, SBR溶聚.苯橡膠solution polymerized butadiene styrenerubber(SSBR)卜1聚苯橡膠emulsion polymerized butadiene styrenerubber(ESBR)氯丁橡膠chloroprene rubber氯化聚乙烯chlorinated pol

38、yethylene (CPE)氯磺化聚乙烯chlorosulfonated polyethylene csm聚硫橡膠polysulfide rubber丁口比橡膠pyridine butadiene rubber氟橡膠fluororubber, fluoroelastomer氟硅橡膠fluorosilicone rubber氟醍橡膠fluoroether rubber三嗪氟橡膠fluorinated triazine rubber亞硝基氟橡膠nitrosofluoro rubber硅橡膠silicon rubber二甲基硅橡膠dimethyl silicone rubber甲基乙烯基硅橡膠me

39、thylvinyl silicone rubber室溫硫化硅橡膠room temperature vulcanized silicone rubber丙烯酸酯橡膠acrylate rubber聚氨酯橡膠polyurethane rubber氯醛橡膠epichloro-hydrin rubber硫化橡膠vulcanized rubber, vulcanizate粉末橡膠powdered rubber液體橡膠liquid rubber熱塑性彈性體thermoplastic elastomer苯乙烯-一烯-苯乙烯styrene butadiene styrene block copolymer嵌段共

40、聚物(SBS)苯乙烯-一烯-苯乙烯styrene isoprene styrene block copolymer嵌段共聚物(SIS)16撓性聚合物flexomer橡膠改性塑料rubber modified plastics, rubberresin blends纖維fiber天然纖維natural fiber初生纖維as-formed fiber原纖fibril半合成纖維semi-synthetic fiber合成纖維synthetic fiber化學纖維chemical fiber單組分纖維homofiber異質(zhì)復合纖維heterofiber粘膠纖維viscose fiber聚酰胺纖維po

41、lyamide fiber又稱錦綸“、尼龍”。聚芳酰胺纖維aramid fiber又稱芳綸芳香尼龍”。聚酯纖維polyester fiber又稱滌綸”。聚丙烯睛纖維acrylic fiber又稱睛綸”。聚丙烯纖維polypropylene fiber又稱丙綸”。聚乙烯醇纖維polyvinyl alcohol fiber聚乙烯醇縮甲醛纖維formalized PV A fiber又稱維尼綸”。聚氯乙烯纖維polyvinyl chloride fiber又稱氯綸”。聚氨酯彈性纖維polyurethane elastic fiber又稱氨綸”。碳纖維carbon fiber活性碳纖維active c

42、arbon fiber碳化硼纖維boron carbide fiber碳納米管carbon nano-tube全纖維素hollocellulose組合纖維conjugate fiber改性纖維differential fiber俗稱差別纖維”。納米纖維nano-fiber17功能纖維光導纖維激光光纖粘合劑熱熔膠反應性熱熔膠厭氧黏合劑壓敏型黏合劑涂料功能涂料油漆functional fiberphotoconductive fiberlaser fiberadhesivemelt adhesivereactive heat-melting adhesiveanaerobic adhesivepr

43、essure sensitive adhesivecoatingfunctional coatingpaint又稱膠粘劑”。05.2聚合與高分子化學反應1單體2官能度3平均官能度4雙官能基單體5三官能基單體6乙烯基單體71,1-亞乙烯基單體,偏二取代乙烯單體81,2-亞乙烯基單體,1,2-二取代乙烯單體9雙烯單體,二烯單體10極性單體11非極性單體12共軻單體13非共輾單體14活化單體15官能單體monomerfunctionalityaverage functionality bifunctional monomer trifunctional monomer vinyl monomer v

44、inylidene monomervinylene monomerdiene monomerpolar monomernon polar monomerconjugated monomernon conjugated monomer activated monomer functional monomer18161718192021222324252627282930313233343536373839大分子單體環(huán)狀單體共聚單體聚合反應均聚反應低聚反應,齊聚反應(曾用名)調(diào)聚反應自發(fā)聚合預聚合后聚合再聚合鑄塑聚合,澆鑄聚合鏈式聚合烯類聚合,乙烯基聚合雙烯類聚合加成聚合自由基聚合,游離基聚合(曾

45、用名)控制自由基聚合,可控自由基聚合活性自由基聚合原子轉(zhuǎn)移自由基聚合反向原子轉(zhuǎn)移自由基聚合可逆加成斷裂鏈轉(zhuǎn)移氮氧自由基調(diào)控聚合穩(wěn)定自由基聚合macromer, macromonomercyclic monomercomonomerpolymerizationhomopolymerizationoligomerizationtelomerizationspontaneous polymerizationprepolymerizationpost polymerizationrepolymerizationcast polymerizationchain polymerizationvinyl p

46、olymerizationdiene polymerizationaddition polymerizationfree radical polymerization,radical polymerizationcontrolled radical polymerization , CRPliving radical polymerizationatom transfer radical polymerization , ATRPreverse atom transfer radical polymerization , RATRPreversible addition fragmentati

47、on chaintransfer, RAFTnitroxide mediated polymerizationstable free radical polymerization , FRP194041424344454647484950515253545556575859606162636465自由基異構化聚合自由基開環(huán)聚合氧化還原聚合無活性端聚合,死端聚合(曾用名)光致聚合光引發(fā)聚合光敏聚合四中心聚合電荷轉(zhuǎn)移聚合輻射引發(fā)聚合熱聚合電解聚合等離子體聚合易位聚合開環(huán)易位聚合精密聚合環(huán)化聚合拓撲化學聚合平衡聚合離子型聚合輻射離子聚合離子對聚合正離子聚合,陽離子聚合碳正離子聚合假正離子聚合假正離子

48、活性聚合free radical isomerization polymerizationradical ring opening polymerizationredox polymerizationdead end polymerizationphoto polymerizationlight initiated polymerizationphotosensitized polymerizationfour center polymerizationcharge transfer polymerizationradiation initiated polymerizationthermal

49、 polymerizationelectrolytic polymerizationplasma polymerizationmetathesis polymerizationring opening metathesis polymerization , ROMPprecision polymerizationcyclopolymerizationtopochemical polymerizationequilibrium polymerizationionic polymerizationradiation ion polymerizationion pair polymerization

50、cationic polymerizationcarbenium ion polymerization,carbocationic polymerizationpseudo cationic polymerizationpseudo cationic living polymerization20666768697071727374757677787980818283848586878889909192活性正離子聚合負離子聚合,陰離子聚合碳負離子聚合活性負離子聚合負離子環(huán)化聚合負離子電化學聚合負離子異構化聚合陸丙基聚合活性聚合兩性離子聚合齊格勒-納塔聚合配位聚合配位離子聚合配位負離子聚合配位正

51、離子聚合插入聚合定向聚合,立構規(guī)整聚合有規(guī)立構聚合全同立構聚合不對稱誘導聚合不對稱選擇性聚合不對稱立體選擇性聚合對映體不對稱聚合對映體對稱聚合異構化聚合氫轉(zhuǎn)移聚合基團轉(zhuǎn)移聚合living cationic polymerizationanionic polymerizationcarbanionic polymerizationliving anionic polymerizationanionic cyclopolymerizationanionic electrochemical polymerizationanionic isomerization polymerizationallyl

52、ic polymerizationliving polymerizationzwitterion polymerizationZiegler Natta polymerizationcoordination polymerizationcoordinated ionic polymerizationcoordinated anionic polymerizationcoordinated cationic polymerizationinsertion polymerizationstereoregular polymerization, stereospecific polymerizati

53、ontactic polymerizationisospecific polymerizationasymmetric induction polymerizationasymmetric selective polymerizationasymmetric stereoselective polymerizationenantioasymmetric polymerizationenantiosymmetric polymerizationisomerization polymerizationhydrogen transfer polymerizationgroup transfer po

54、lymerization , GTP2193消除聚合elimination polymerization94模板聚合matrixpolymerization,templatepolymerization95插層聚合intercalation polymerization96無催化聚合uncatalyzed polymerization97開劃、聚合ring opening polymerization98活性開劃、聚合living ring opening polymerization99/、死的聚合immortal polymerization100101酶聚合作用聚加成反應,逐步加成聚合(

55、曾用名)enzymatic polymerizationpolyaddition102偶聯(lián)聚合coupling polymerization103序列聚合sequential polymerization104閃發(fā)聚合,俗稱暴聚flash polymerization105氧化聚合oxidative polymerization106氧化偶聯(lián)聚合oxidative coupling polymerization107108109逐步增長1聚合縮聚反應酯交換型聚合step growth polymerization condensation polymerization , polyconden

56、sationtransesterification type polymerization, ester exchange polycondensation110自催化縮聚autocatalytic polycondensation111均相聚合homogeneous polymerization112非均相聚合heterogeneous polymerization113相轉(zhuǎn)化聚合phase inversion polymerization114本體聚合bulk polymerization, mass polymerization115116固相聚合氣相聚合solid phase poly

57、merization gaseous polymerization, gas phase polymerization22117吸附聚合adsorption polymerization118溶液聚合solution polymerization119沉淀聚合precipitation polymerization120淤漿聚合slurry polymerization121懸浮聚合suspension polymerization122反相懸浮聚合reversed phase suspension polymerization123珠狀聚合bead polymerization, pearl

58、 polymerization124分散聚合dispersion polymerization125反相分散聚合inverse dispersion polymerization126種子聚合seeding polymerization127乳液聚合emulsion polymerization128無乳化劑乳液聚合emulsifier free emulsion polymerization129反相乳液聚合inverse emulsion polymerization130微乳液聚合micro emulsion polymerization131連續(xù)聚合continuous polymer

59、ization132半連續(xù)聚合semicontinuous polymerization133分批聚合,間歇聚合batch polymerization134原位聚合in situ polymerization135均相縮聚homopolycondensation136活化縮聚activated polycondensation137熔融縮聚melt phase polycondensation138固相縮聚solid phase polycondensation139體型縮聚three dimensional polycondensation140界面聚合interfacial polyme

60、rization141界面縮聚interfacial polycondensation142環(huán)加成聚合cycloaddition polymerization143環(huán)烯聚合cycloalkene polymerization144環(huán)硅氧烷聚合cyclosiloxane polymerization145引發(fā)劑initiator23146147148149150151152153154155156157158159160161162163164165166167168169170171172173引發(fā)劑活性聚合催化劑自由基引發(fā)劑偶氮類引發(fā)劑2,2偶氮二異丁睛過氧化苯甲酰過硫酸鹽引發(fā)劑復合引發(fā)體系

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