保存到的文件有機習題

1、第八章 醇酚醚習題解答1. (1) 2-丁醇 (2) 1,4-戊二醇 (3) 4-溴-1,2-苯二酚 (4) 3-甲氧基-2-戊醇(5) (E)-4-己烯-2-醇 (6) (E) -2-甲基-1-乙基環(huán)己醇 (7) 乙基異丙基醚 (8) 1-(4-甲基苯基)-1,2-乙二醇 (9) 4-甲基-1-甲氧基-2-戊醇(10)3-甲基-2-環(huán)己烯-1-醇2. (1)HHOCH2CCCH3H(2) H2C = CHCH2O CH2CH2CH2CH3(3) O2N OCH2CH3(4)CH2CHOH(5) CH3CHCHCH3OCH3OCH3(6) CH2CHCH2CH3O(7) CH3CCH2OHCH

2、3CH3(8)OCH3OCH3OHNO2NO2O2N(9)(10)CH2ONO2CHONO2CH2ONO23. (2) (1) (3) 4. (1) (2) (3) (4) 理由略 5.(1)CH2 = CHCH2OH(a)CH3CH2CH2OH (b)CH3CH2CH2Cl (c)Lucass 試劑很快出現(xiàn)混濁(a)加熱后出現(xiàn)混濁(b)加熱也無混濁(c)(2)CH3CH2CH(OH)CH3(a)CH3CH2CH2CH2OH(b)(CH3)3COH (c)Lucas試劑很快出現(xiàn)渾濁者為 (c)幾分鐘出現(xiàn)渾濁者為(a)加熱出現(xiàn)渾濁者為 (b)(3)CH2OH(a)CH2Cl (b)OCH3 (c

3、)AgNO3乙醇放出氣體(a)Na無現(xiàn)象 (c)出現(xiàn)沉淀(b)無現(xiàn)象 (b) 無現(xiàn)象 (c) (4)FeCl36. (1) (CH3)2C = CHCH2CH3(2) OH + CH3CH2I (3) CH3CHCHCH3ClCH3(4) CH2OCCH3OHO(6) Br BrBrOH(5)(7) CH3CH2CH2CH2CH2CH2OMgBr, CH3CH2CH2CH2CH2CH2OH7. (1)CH3CHCH(CH3)2OHH+CH3CHC(CH3)2HBrCH3CH2C(CH3)2BrKOHH2OCH3CH2C(CH3)2OHCH3CHCH2CH3OHSOCl2CH3CHCH2CH3C

4、lNaCNCH3CH2OHCH3CHCH2CH3CNH+H2OCH3CHCH2CH3COOHLiAlH4H2OCH3CH2CHCH2CH3CH3濃硫酸CH3CH2CCH2CH3HBrCH3CH2Br(CH3)2NaOH/C2H5OHCH3CHC(CH3)2 (2)H+(3) CH3CH2CH2OH CH3CH2CH2Cl CH3CH2CH2CNNaCNPCl CH3CH2CH2COOHHOH乙醇9.(1)乙醚中含有少量乙醇，可先用固體CaCl2，除去少量乙醇，再蒸餾即可。(2) CH3CH2CH2CH2OH CH3CH2CH = CH2 CH3CH2CHCH3BrHBrH2SO4 CH3CH2CHCH3 CH3COOCHCH2CH3NaOHHOHCH3COOHH+，CH3OH8. (1) (CH3)3COH (CH3)3CCl (CH3)3CMgCl (CH3)3CCH2CH2OMgCl (CH3)3CCH2CH2OHPCl3Mg干醚O干醚H2OH+(3) 先用NaOH與苯酚生成酚鹽后分液（環(huán)己醇不溶于NaOH溶液）。(CH3)2CHCHCH3濃H2SO4(CH3)2CH = CHCH3(C)O3Zn/H2OCH3CH3C=O + CH3CHOOH10.(CH3)2CHCHCH3BrHO