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1、標(biāo)準(zhǔn)電極電勢StandardElectrodePotentials序號(No.)電極過程(Electrodeprocess)E/V1Ag+eAg0.79962Ag2+eAg+1.9803AgBr+eAg+Br-0.07134AgBrO3+eAg+BrO3-0.5465AgCl+eAg+Cl-0.2226AgCN+eAg+CN-0.0177Ag2CO3+2e2Ag+CO32-0.4708Ag2c2O4+2e2Ag+C2O42-0.4659Ag2CrO4+2e2Ag+CrO42-0.44710AgF+eAg+F-0.77911Ag4Fe(CN)6+4e4Ag+Fe(CN)64-0.14812Agl
2、+eAg+I-0.15213AgIO3+eAg+IO3-0.35414Ag2MoO4+2e2Ag+MoO42-0.45715Ag(NH3)2+eAg+2NH30.37316AgNO2+eAg+NO2-0.56417Ag2O+H2O+2e2Ag+2OH-0.342182AgO+H2O+2eAg2O+2OH-0.60719Ag2S+2e2Ag+S2-0.69120Ag2S+2H+2e2Ag+H2s-0.036621AgSCN+eAg+SCN-0.089522Ag2SeO4+2e2Ag+SeO42-0.36323Ag2SO4+2e2Ag+SO42-0.65424Ag2WO4+2e2Ag+WO42-0
3、.46625Al3+3eAl-1.66226AlF63-+3eA1+6F-2.06927Al(OH)3+3eA1+3OH-2.3128AlO2-+2H2O+3eA1+4OH-2.3529Am3+3eAm-2.04830Am4+eAm3+2.6031AmO22+4H+3eAm3+2H2O1.7532As+3H+3eAsH3-0.60833As+3H2O+3eAsH3+3OH-1.3734As2O3+6H+6e2As+3H2O0.23435HAsO2+3H+3eAs+2H2O0.24836AsO2-+2H2O+3eAs+4OH-0.6837H3AsO4+2H+2eHAsO2+2H2O0.56038
4、AsO43-+2H2O+2eAsO2-+4OH-0.7139AsS2-+3eAs+2S2-0.7540AsS43-+2eAsS2-+2S2-0.6041Au+eAu1.69242Au3+3eAu1.49843Au3+2eAu+1.40144AuBr2-+eAu+2Br-0.95945AuBr4-+3eAu+4Br-0.85446AuCl2-+eAu+2Cl-1.1547AuCl4-+3eAu+4Cl-1.00248Au+eAu+-0.5049Au(SCN)4-+3eAu+4SCN-0.6650Au(OH)3+3H+3eAu+3H2O1.4551BF4-+3eB+4F-1.0452H2BO3-+
5、H2O+3eB+4OH-1.7953B(OH)3+7H+8eBH4-+3H2O-.048154Ba2+2eBa-2.91255Ba(OH)2+2eBa+2OH-2.9956Be2+2eBe-1.84757Be2O32-+3H2O+4e2Be+6OH-2.6358Bi+eBi0.559Bi3+3eBi0.30860BiCl4-+3eBi+4Cl-0.1661BiOCl+2H+3eBi+Cl-+H2O0.1662Bi2O3+3H2O+6e2Bi+6OH-0.4663Bi2O4+4H+2e2BiO+2H2O1.59364Bi2O4+H2O+2eBi2O3+2OH-0.5665Br2(水溶液,aq)+
6、2e2Br-1.08766Br2(液體)+2e2Br-1.06667BrO-+H2O+2eBr-+2OH0.76168BrO3-+6H+6eBr-+3H2O1.42369BrO3-+3H2O+6eBr-+6OH-0.61702BrO3-+12H+10eBr2+6H2O1.48271HBrO+H+2eBr-+H2O1.331722HBrO+2H+2eBr2(水溶液,aq)+2H2O1.57473CH30H+2H+2eCH4+H2O0.5974HCHO+2H+2eCH30H0.1975CH3cOOH+2H+2eCH3cHO+H2O-0.1276(CN)2+2H+2e2HCN0.37377(CNS)
7、2+2e2CNS-0.7778CO2+2H+2eCO+H2O-0.1279CO2+2H+2eHCOOH-0.19980Ca2+2eCa-2.86881Ca(OH)2+2eCa+2OH-3.0282Cd2+2eCd-0.40383Cd2+2eCd(H)-0.35284Cd(CN)42-+2eCd+4CN-1.0985CdO+H2O+2eCd+2OH-0.78386CdS+2eCd+S2-1.1787CdSO4+2eCd+SO42-0.24688Ce3+3eCe-2.33689Ce3+3eCe(H)-1.43790CeO2+4H+eCe3+2H2O1.491Cl2(HB)+2e2Cl-1.3589
8、2ClO-+H2O+2eCl-+2OH-0.8993HClO+H+2eCl-+H2O1.482942HClO+2H+2eCl2+2H2O1.61195ClO2-+2H2O+4eCl-+4OH-0.76962ClO3-+12H+10eCl2+6H2O1.4797ClO3-+6H+6eCl-+3H2O1.45198ClO3-+3H2O+6eCl-+6OH-0.6299ClO4-+8H+8eCl-+4H2O1.381002ClO4-+16H+14eCl2+8H2O1.39101Cm3+3eCm-2.04102Co2+2eCo-0.28Co3+eCo2+1.808103Co(NH3)63+eCo(NH
9、3)62+0.108104Co(NH3)62+2eCo+6NH3-0.43105Co(OH)2+2eCo+2OH-0.73106Co(OH)3+eCo(OH)2+OH-0.17107Cr2+2eCr-0.913108Cr3+eCr2+-0.407109Cr3+3eCr-0.744110Cr(CN)63-+eCr(CN)64-1.28111Cr(OH)3+3eCr+3OH-1.48112Cr2O72-+14H+6e2Cr3+7H2O1.232113CrO2-+2H2O+3eCr+4OH-1.2114HCrO4-+7H+3eCr3+4H2O1.350115CrO42-+4H2O+3eCr(OH)3
10、+5OH-0.13116Cs+eCs-2.92117Cu+eCu0.521118Cu2+2eCu0.342Cu2+eCu+0.17119Cu2+2eCu(H)0.345120Cu2+Br-+eCuBr0.66121Cu2+Cl-+eCuCl0.57122Cu2+I-+eCui0.86123Cu2+2CN-+eCu(CN)2-1.103124CuBr2-+eCu+2Br-0.05125CuCl2-+eCu+2Cl-0.19126CuI2-+eCu+2I-0.00127Cu2O+H2O+2e2Cu+2OH-0.360128Cu(OH)2+2eCu+2OH-0.2221292Cu(OH)2+2eCu
11、2O+2OH-+H2O-0.080130CuS+2eCu+S2-0.70131CuSCN+eCu+SCN-0.27132Dy2+2eDy-2.2133Dy3+3eDy-2.295134Er2+2eEr-2.0135Er3+3eEr-2.331136Es2+2eEs-2.23137Es3+3eEs-1.91138Eu2+2eEu-2.812139Eu3+3eEu-1.991140F2+2H+2e2HF3.053141F2O+2H+4eH2O+2F-2.153142Fe2+2eFe-0.447143Fe3+3eFe-0.037Fe3+eFe2+0.680.771*144Fe(CN)63-+eFe(
12、CN)64-0.358145Fe(CN)64-+2eFe+6CN-1.5146FeF63-+eFe2+6F-0.4147Fe(OH)2+2eFe+2OH-0.877148Fe(OH)3+eFe(OH)2+OH-0.56149Fe3O4+8H+2e3Fe2+4H2O1.23150Fm3+3eFm-1.89151Fr+eFr-2.9152Ga3+3eGa-0.549153H2GaO3-+H2O+3eGa+4OH-1.29154Gd3+3eGd-2.279155Ge2+2eGe0.24156Ge4+2eGe2+0.0157GeO2+2H+2eGeO(棕色)+H2O-0.118158GeO2+2H+2
13、eGeO(黃色)+H2O-0.273159H2GeO3+4H+4eGe+3H2O-0.1821602H+2eH.20.0000161H2+2e2H-2.251622H2O+2eH2+2OH-0.8277163Hf4+4eHf-1.55164Hg2+2eHg0.851165Hg22+2e2Hg0.7971662Hg2+2eHg22+0.920167Hg2Br2+22Hg+2Br-0.1392168HgBr/-+2Hg+4Br-0.21169Hg2Cl2+22Hg+2Cl-0.26811702HgCl2+2Hg2C12+2C1-0.63171Hg2CrO4+22Hg+CrO42-0.54172Hg
14、工+22Hg+2I-0.0405173Hg2O+H2O+22Hg+2OH-0.123174HgO+H2O+2Hg+2OH-0.0977175HgS(紅色)+2Hg+S2-0.70176HgS(黑色)+2Hg+S2-0.67177Hg2(SCN)2+22Hg+2SCN-0.22178Hg2SO4+22Hg+SO42-0.613179Ho2+2Ho-2.1180Ho3+3Ho-2.33181I2+22I-0.5355182I3-+23I-0.5361832IBr+2I2+2Br-1.02184ICN+2I-+CN-0.301852HIO+2H+2I2+2H2O1.439186HIO+H+2I-+H
15、2O0.987187IO-+H2O+2I-+2OH-0.4851882IO3-+12H+10I2+6H2O1.195189IO3-+6H+6I-+3H2O1.085190IO3-+2H2O+4IO-+4OH-0.15191IO3-+3H2O+6I-+6OH-0.261922IO3-+6H2O+10I2+12OH-0.21193H5IO6+H+2IO3-+3H2O1.601194In+In-0.14195In3+3In-0.338196In(OH)3+3In+3OH-0.99197Ir3+3Ir1.156198IrBr62-+IrBr63-0.99199IrC162-+IrCl63-0.8672
16、00K+K-2.931201La3+3La-2.379202La(OH)3+3La+3OH-2.90203Li+Li-3.040204Lr3+3Lr-1.96205Lu3+3Lu-2.28206Md2+2Md-2.40207Md3+3Md-1.65208Mg2+2Mg-2.372209Mg(OH)2+2Mg+2OH-2.690210Mn2+2Mn-1.185211Mn3+3Mn1.542212MnO2+4H+2Mn2+2H2O1.224213MnO4-+4H+3MnO2+2H2O1.679214MnO4-+8H+5Mn2+4H2O1.507215MnO4-+2H2O+3MnO2+4OH-0.5
17、95216Mn(OH)2+2Mn+2OH-1.56217Mo3+3Mo-0.200218MoO/-+4H2O+6Mo+8OH-1.05219N2+2H2O+6H+62NH40H0.0922202NH30H+H+2N2H5+2H2O1.422212NO+H2O+2N2O+2OH-0.762222HNO2+4H+4N2O+3H2O1.297223NO3-+3H+2HNO2+H2O0.934224NO3-+H2O+2NO2-+2OH-0.012252NO3-+2H2O+2N2O4+4OH-0.85226Na+Na-2.713227Nb3+3Nb-1.099228NbO2+4H+4Nb+2H2O-0.
18、690229Nb2O5+10H+102Nb+5H2O-0.644230Nd2+2Nd-2.1231Nd3+3Nd-2.323232Ni2+2Ni-0.257233NiCO3+2Ni+CO32-0.45234Ni(OH)2+2Ni+2OH-0.72235NiO2+4H+2Ni2+2H2O1.678236No2+2No-2.50237No3+3No-1.20238Np3+3Np-1.856239NpO2+H2O+H+Np(OH)3-0.962240O2+4H+42H2O1.229241O2+2H2O+44OH-0.401242O3+H2O+2O2+2OH-1.24243Os2+2Os0.85244
19、OsCl63-+Os2+6C1-0.4245OsO2+2H2O+4Os+4OH-0.15246OsO4+8H+8Os+4H2O0.838247OsO4+4H+4OsO2+2H2O1.02248P+3H2O+3PH3(g)+3OH-0.87249H2PO2-+P+2OH-1.82250H3PO3+2H+2H3PO2+H2O-0.499251H3PO3+3H+3P+3H2O-0.454252H3PO4+2H+2H3PO3+H2O-0.276253PO43-+2H2O+2eHPO32-+3OH-1.05254Pa3+3ePa-1.34255Pa4+4ePa-1.49256Pb2+2ePb-0.126
20、257Pb2+2ePb(H)-0.121258PbBr2+2ePb+2Br-0.284259PbCl2+2ePb+2Cl-0.268260PbCO3+2ePb+CO32-0.506261PbF+2ePb+2F-2-0.344262PbI2+2ePb+2I-0.365263PbO+H2O+2ePb+2OH-0.580264PbO+4H+2ePb+H2O0.25265PbO2+4H+2ePb2+2H2O1.455266HPbO2-+H2O+2ePb+3OH-0.537267PbO2+SO/-+4H+2ePbSO4+2H2O1.691268PbSO4+2ePb+SO42-0.359269Pd2+2e
21、Pd0.915270PdBr2-+2ePd+4Br-40.6271PdO2+H2O+2ePdO+2OH-0.73272Pd(OH)2+2ePd+2OH-0.07273Pm2+2ePm-2.20274Pm3+3ePm-2.30275Po4+4ePo0.76276Pr2+2ePr-2.0277Pr3+3ePr-2.353278Pt2+2ePt1.18279PtCl62-+2ePtCl42-+2Cl-0.68280Pt(OH)2+2ePt+2OH-0.14281PtO2+4H+4ePt+2H2O1.00282PtS+2ePt+S2-0.83283Pu3+3ePu-2.031284Pu5+ePu4+1
22、.099285Ra2+2eRa-2.8286Rb+eRb-2.98287Re3+3eRe0.300288ReO2+4H+4eRe+2H2O0.251289ReO4-+4H+3eReO2+2H2O0.510290ReO4-+4H2O+7eRe+8OH-0.584291Rh2+2eRh0.600292Rh3+3eRh0.758293Ru2+2eRu0.455294RuO2+4H+2eRu2+2H2O1.120295RuO4+6H+4eRu(OH)22+2H2O1.40296S+2eS2-0.476297S+2H+2eH2s(水溶液,aq)0.142298S2O62-+4H+2e2H2SO30.56
23、42992SO32-+3H2O+4eS2O32-+6OH-0.5713002SO32-+2H2O+2eS2O/-+4OH-1.12301SO42-+H2O+2eSO32-+2OH-0.93302Sb+3H+3eSbH3-0.510303Sb2O3+6H+6e2Sb+3H2O0.152304Sb2O5+6H+4e2SbO+3H2O0.581305SbO3-+H2O+2eSbO2-+2OH-0.59306Sc3+3eSc-2.077307Sc(OH)3+3eSc+3OH-2.6308Se+2eSe2-0.924309Se+2H+2eH2Se(水溶液,aq)-0.399310H2SeO3+4H+4e
24、Se+3H2O-0.74311SeO32-+3H2O+4eSe+6OH-0.366312SeO42-+H2O+2eSeO32-+2OH-0.05313Si+4H+4eSiH4(氣體)0.102314Si+4H2O+4eSiH4+4OH-0.73315SiF2-+4eSi+6F-_6-1.24316SiO2+4H+4eSi+2H2O-0.857317SiO32-+3H2O+4eSi+6OH-1.697318Sm2+2eSm-2.68319Sm3+3eSm-2.304320Sn2+2eSn-0.138321Sn4+2eSn2+0.151322SnCl42-+2eSn+4Cl-(1mol/LHCl)-0.19323SnF2-+4eSn+6F-6-0.25324Sn(OH)3-+3H+2eSn2+3H2O0.142325SnO2+4H+4eSn+2H2O-0.117326Sn(OH)62-+2eHSnO2-+3OH-+H2O-0.93327Sr2+2eSr-2.899328Sr2+2eSr(H)-1.793329Sr(OH)2+2eSr+2OH-2.88330Ta3+3
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