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HydrochloricAcidElectrolysisby
OxygenDepolarisedCathodes
無(wú)極氧陰極鹽酸電解
Serialnumber:05-3125Yearof
manufacture:2011Issuedate:March2011
Manufacturer:UhdeGmbHFon:+49231547-0Friedrich-Uhde-Str.15
Fax:+49231547-3032D-44141Dortmundinfo.uhde@
Toavoidseriousinjuryordeath,followthesafetyinformation
inthisdocument.
則蠢碼碑解ma腳肥或隔翅占鏟sedtotheoperator.
—L--La/J-T-nn、-r*.mi-J.a,J
ThisltaRfe碗。國(guó)的%acepropertrainingoftheoperating
personnel.Expertoperationsupervisionisabsolutelynecessary.This
hydrochloricacidelectrolysisplantmustbeoperatedbyqualified
Forunderstandingthisoperatingmanual,thefollowingskillsare
required:Danger!危險(xiǎn)
Flammables!可燃物
Readingandund鄲含加雅家招BgM^ubstances
r土工此符號(hào)表示易燃物質(zhì)的危害
1、閱讀和理解英文c,Qg
1sDanger!危險(xiǎn)
Corrosives!腐蝕性物質(zhì)
Readingandundeins神ruding物spi畫鯽硼由麗strun峭Mes
這個(gè)符號(hào)表示腐蝕性物質(zhì)的危害
diagrams(PID)andrite血cessflowdiagrams(PFD)
Acutetoxicity(severe)!劇毒(嚴(yán)重)
2、閱讀和理解管道和儀裱圖sgMKd。i的圖a£(Ff?r^toxicsubstances.
這個(gè)符號(hào)表示劇毒物質(zhì)的危害
Knowingandunderatfi9KtingceatetywidatynMibnJatigWaterial
Thissymbolindicatesenvironmentallyhazardoussubstances,
safetydatasheet聶個(gè)符號(hào)表示環(huán)境有害物質(zhì)
3、知道和了解安全信息牛琳即矍硼表
Thissymbolindicatesanimmediatehealthandsafetyhazardfor
personsnotrelatingtochemicals.Thishazardcanresultin
life-threateninginjuryordeath.Thissymbolisusedforhazards
whicharenotindicatedbymeansofothersymbols.
操作手冊(cè)中的注釋此符號(hào)表示人員的健康和安全不直接與危險(xiǎn)化學(xué)品有關(guān)。這種危險(xiǎn)可能導(dǎo)致
夠跳儺僦畫螭號(hào)用于表示不能由其他符號(hào)來(lái)表示的危害
Thissymbolindicatesahazardfromelectriccurrent.
這個(gè)符號(hào)表示電壓的危害
Handinjuryhazard!手部受傷的危險(xiǎn)
Thissymbolindicatesahandcrushhazard.
這個(gè)符號(hào)表示手部受傷的危害
Sliphazard!滑倒危險(xiǎn)
Thissymbolindicatesasliphazard.
這個(gè)符號(hào)表示滑倒的危害
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AHCLElectrolysisAODC1Notesontheuseoftheoperatingmanual1-2
Tipoverhazard!翻倒危險(xiǎn)!
Thissymbolindicatesatipoverhazardfromtransportoftheinstallation.
A這個(gè)符號(hào)表示安裝運(yùn)輸過程中的翻到危害
Overheadloadshazard!過載危險(xiǎn)
Thissymbolindicatesanoverheadloadshazard.
A這個(gè)符號(hào)表示過載的危害
Explosion!爆炸
Thetextpassagesmarkedwiththissymbolinformyouaboutsituationsentailing
Adangerofexplosion.此標(biāo)志的文字說(shuō)明提醒你將會(huì)導(dǎo)致爆炸的危險(xiǎn)
Harmfulmaterial!有毒物質(zhì)
Thissymbolindicatesdangerfromharmfulmaterial!
A這個(gè)符號(hào)表示有毒物質(zhì)的危害
Hotsurfaces!熱表面
Thissymbolindicatesdangerfromhotsurfaces!
這個(gè)符號(hào)表示熱表面的危害
念
Toxic!有毒
Thissymbolindicatesdangerfromtoxicsubstances.
A這個(gè)符號(hào)表示有毒物質(zhì)的危害
Highlyflammable!高度可燃
Thissymbolindicatesdangerfromhighlyflammablesubstances.
A這個(gè)符號(hào)表示高度可燃物質(zhì)的危害
Corrosivematerial!腐蝕性材料
Thissymbolindicatesdangerfromcorrosivesubstances.
這個(gè)符號(hào)表示腐蝕性物質(zhì)的危害
Doc.-ID-Code:
UDO-VT-DC-00001,Rev.00Code:YantaiJuliOPERATINGMANUAL
UAN:05-3125
AHCLElectrolysisODC1Notesontheuseoftheoperatingmanual1-
1.2Symbolsofpersonalprotectiveequipment
Wearahardhat!佩戴安全帽
Wearafaceshield!佩戴面罩
Wearagasmask!佩戴防毒面具
Wearhearingprotection!佩戴聽力保護(hù)工具
Wearprotectiveglasses!佩戴防護(hù)鏡
Wearprotectivesuitresistanttochemicals!
穿著耐磨耐化學(xué)防護(hù)服
Wearprotectivegloves!佩戴防護(hù)手套
Wearinsulatingboots!Orwearprotectiveboots!Theexactmeaningofthis
signdependsonthecontext.Inthecorrespondingparagraphsitisclearly
definedwhichtypeofbootsisrequired.
穿著絕緣靴!或穿著防護(hù)靴!這個(gè)符號(hào)的確切含義取決于上下文。
在相應(yīng)的段落可以清楚地界定哪類的靴子是必要的
Hardhat,protectiveglasses,protectiveclothingandprotectiveshoeshavetobe
worninsidetheplantallthetime!
在工廠內(nèi)所有的時(shí)間必須配戴安全帽,防護(hù)眼鏡,防護(hù)服和防護(hù)鞋!
Furthermoreemergencyescapemaskhastobecarriedallthetime.
必須隨身攜帶緊急逃生面罩
Doc.-ID-Code:
UDO-VT-DC-00001,Rev.00Code:YantaiJuliOPERATINGMANUAL
UAN:05-3125
AHCLElectrolysisODC1Notesontheuseoftheoperatingmanual1-4
1.3Prohibitivesymbols
Nosmoking!禁止吸煙
Textpassagesnexttothissymbolindicatethatsmokingisprohibitedinthearea.
這個(gè)符號(hào)旁的文字說(shuō)明表示在這個(gè)區(qū)域禁止吸煙
Noaccessforpacemakerwearers!佩戴心臟起搏器的人員禁止入內(nèi)
Textpassagesnexttothissymbolindicatethattheareamustnotbeaccessedby
pacemakerwearers.
Textpassagesnexttothissymbolindicatethattheareamustnotbeaccessedby
personswithmetalimplants.
這個(gè)符號(hào)的文字說(shuō)明表示這個(gè)區(qū)域禁止體內(nèi)有金屬移植物的人員入內(nèi)
1.4Informationsymbol信息符號(hào)
Thetextpassagesmarkedwiththissymbolgivetipsandhints.
Thissymbolindicatesimportantinformationfortheoperatorreadingthemanual.
這個(gè)標(biāo)志的文字說(shuō)明給出提示。
這個(gè)符號(hào)表示操作工需要閱讀手冊(cè)的重要信息
Doc.-ID-Code:
UDO-VT-DC-00001,Rev.00Code:YantaiJuliOPERATINGMANUAL
UAN:05-3125
AHCLElectrolysisODC1Notesontheuseoftheoperatingmanual1-5
1.5Designationandabbreviations名稱和縮寫
Thefollowingabbreviationsareusedinthisoperatingmanual.Theyaredefined
asfollows(inalphabeticalorder):
以下縮寫用于本操作手冊(cè)。它們的定義如下(排名不分先后):
>more/biggerthan更多/大于
MSDSapprox.approximately約Materialsafetydata
sheet材料安全AlAnalysingindicator數(shù)據(jù)表
mtpa6CL.Ba棍呼n用料區(qū)「rent交流電
metrictonnesbaraPressureinbarabsolute絕對(duì)壓力
peryear噸/年bargPressureinbargauge
mtpdCH1channel1通道1
metrictonneschlorine氯氣
perday噸/天DCSDistributedcontrolsystemDCS集散控制系統(tǒng)
NiMHDNnominaldiametre公稱直徑
nickelmetaldepartmentELdepartmentelectrolysis
hydride鍥金屬氫gdiametre直徑
化物DNdiametrenominal公稱直徑
ODCEBElectricalstatus供電狀態(tài)
oxygenEDIElectricalmeasuringdifferenceindicator
depolarisedEPPMotorrunindication電機(jī)運(yùn)行指示
cathodes無(wú)極ESDEmergencyshutdownsystem緊急停車系統(tǒng)
氧陰極FAFlowalarm流量報(bào)警
02FCFailureclosed故障關(guān)閉
oxygen氧氣FLFailurelocked故障鎖定
PEFOFailureopen/Orifice
polyethylene聚FQIFlowcounterindicatoryftfi記錄指示
乙烯FTFlowtransmitter流量變送器
PETFPVFlowcontrolvalvepneumatic氣動(dòng)流量控制閥
polyethyleneGGaseous氣態(tài)
terephthalate聚GNDground地面
對(duì)苯二甲酸乙二
gpigramsperliter克/升
醇酯HCIhydrochloricacid鹽酸
PDIHICHandindicationcontrol手動(dòng)指示控制
PressureHSHandswitch手動(dòng)開關(guān)
differenceHTHightension高張力
indicator壓差指HVHandvalve手動(dòng)閥
示器IPInternationalprotectionrating國(guó)際保護(hù)等級(jí)
PDPVLLiquid液體
Differentialpressurevalve差壓閥
PIPressureindicator壓力指示器
PICPressureindicationcontrol壓力指示控制
PIDPipingandinstrumentdiagram管道和儀表圖
ppbPartsperbillion十億分之一
ppmPartspermillion百萬(wàn)分之一
PPVPressurecontrolvalve(pneumatic)壓力控制閥(氣動(dòng))
PSHPressureswitchhigh高壓力開關(guān)
PSLPressureswitchlow低壓力開關(guān)
PTPressuretransmitting壓力變送
PVPressurevalve壓力閥
__T...transmitter傳感器
SSolid液體
SC_samplingconnection…取樣接口
SPSetpoint設(shè)定點(diǎn)
SPCStored-programcontrol存儲(chǔ)程序控制
TTemperature溫度
Tititanium鈦
TlTemperatureindicator溫度指示器
TICTemperatureindicationcontrol溫度指示控制
TPVTemperaturecontrolledvalve溫度控制閥
TOCTotalorganiccarbon總有機(jī)碳
TONtechnicalordernumber技術(shù)訂單號(hào)
TVTemperaturecontrolledvalve溫度控制閥
TWThermowell熱電偶
UPSUninterruptedpowersupply不間斷電源
VValve閥門
vol.-%percentbyvolume體積百分?jǐn)?shù)
wt.-%percentbyweight重量懺分?jǐn)?shù)
wtWeight重量
xReplacementcharacter替換字符
XVon/offvalve開/關(guān)閥
XEVon/offvalveelectrical電動(dòng)開/關(guān)閥
XPVon/offvalvepneumatic氣動(dòng)開/關(guān)閥
%molemolarpercent摩爾百分?jǐn)?shù)
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UAN:05-3125
AHCLElectrolysisODC1Notesontheuseoftheoperatingmanual1-7
1.5.1Valvesaroundtheelectrolyser電解槽周圍的閥門
Inthismanualcommonabbreviationsareusedforvalvesoftheelectrolysis.Theabbreviations
informaboutthemedium,theactionandtheplacementofthevalve.Forexamplethehandvalve
HCI-fe-FSislocatedatthefeedstation(FS)inafeedpipe(fe)ofthemediumHCLThenumberingof
thevalvesintheplantisindependentfromthisanddiffersfromtheseabbreviations.
在本手冊(cè)中常見的縮寫用于電解閥門??s寫詞告知閥門的介質(zhì),行動(dòng)(作用)和位置。例如,手
動(dòng)閥HCI-fe-FS是位于進(jìn)料站中介質(zhì)為鹽酸的進(jìn)料管道。工廠中閥門的編號(hào)方式是獨(dú)立于這一點(diǎn),
麻而洛”的^后場(chǎng)臍現(xiàn)celectrolyser
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Medium介質(zhì)Function功能Location位置
Labelling標(biāo)簽
AnolyteandChlorine陽(yáng)Anolytecellheader陽(yáng)極液總
A-by-AHby-pass旁路
極液和氯管
A-dr-FSAnolyte陽(yáng)極液drain排放Feedstation進(jìn)料站
A-is-AHAnolyte陽(yáng)極液isolation隔離Anolytecellheader陽(yáng)極液總管
Anolytesampleline陽(yáng)極液取樣
A-is-AS(1-3)Anolyte陽(yáng)極液isolation隔離
管
Air-ve-AH(1-2)Air空氣ventAnolytecellheader陽(yáng)極液總管
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UAN:05-3125
HCLElectrolysisODC1Notesontheuseoftheoperatingmanual1-8
Doc.-ID-Code:
UDO-VT-DC-00001,Rev.00Code:YantaiJuliOPERATINGMANUAL
UAN:05-3125
Doc.-ID-Code:
UDO-VT-DC-00001,Rev.00Code:YantaiJuliOPERATINGMANUAL
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Doc.-ID-Code:
Code:YantaiJuliOPERATINGMANUAL
HRR:*拈夠°°”Rev°。
1.6Validityoftheseinstructions2Technicalinformation
A1Notesontheuseoftheoperatingmanual1-9
2.1CellRoom-Electrolyser,Unit311
槽室-電解槽,311單元
(Processflowdiagrams31401and31402)
(PFD31401和31402)
TheplantisequippedwithbipolarHCIElectrolysersbasedonthe"OxygenDepolarizedCathode"(ODC
technology.
該裝置為復(fù)極HCI電解槽,采用“氧陰極(ODC)”技術(shù)。
EachElectrolyser(V31101A-D)consistsoftworacksholdingthebipolarelementsinafilter-press
configurationbyapressuresystem.Ineachrackoneendanodicandoneendcathodicelementis
2
required.A2.5mactiveareamembraneisplacedtogetherwiththeODCbetweenthecathodicand
anodiccompartments.
每個(gè)單元槽(V31101A-D)由兩個(gè)帶復(fù)極單元槽的槽架組成,并且配備一套壓力系統(tǒng)。每個(gè)槽架包括
一個(gè)末端陽(yáng)極單元槽和一個(gè)末端陰極單元槽。陽(yáng)極室與陰極室之間是一張2.5而的膜
Theanodicchamberisfedwith14wt.-%HCIsolution.Electrochemicaloxidationtakesplaceand
ChlorineisformedwhileHCIisconsumed.AttheoutletoftheanodicchamberHCIisrecoveredtogether
withCl2gasintheElectrolysermanifold.Cl2gasisseparatedfromtheHCIaqueoussolutionand
collectedinthechlorineheader.TheHCIoutletsolutionisroutedtotheAnolyteTank(T31401A/B).A
+-
certainportionofwateraswellasHandClionsaretransferredoverthemembranetothecathodic
compartment.
陽(yáng)極室用14%wt的鹽酸進(jìn)料,發(fā)生電化學(xué)氧化反應(yīng),消耗HCI,生成CI2,陽(yáng)極室出口HCI和CI2同時(shí)
在電解槽歧管收集,CI2從HCI溶液中分離出來(lái),去氯氣總管。鹽酸送至陽(yáng)極液罐(T31401A/B),部
分水及H,和C「透過膜進(jìn)入陰極室
Thecathodicchamberisfedwithoxygentosuppresstheformationofhydrogenatthecathode.The
oxygenisfedinexcessinordertoassureagoodeffiviencyofthereaction.AttheODCtheoxygen
+
reactswithHionscomingfromtheanodicchamberandwaterisformed.TheO2leavingthecathodic
chamberisfedtotheOxygenRecyclingSystem(PFD31502).Theacidicwaterinthecathodic
compartmentistransferredtotheCondensateTank(T31501).
陰極室用氧氣進(jìn)料?,防止陰極生成氫。為了確保高反應(yīng)效率,氧氣進(jìn)料過量。氧氣和H+反應(yīng),
Thepressureintheanodicandcathodiccompartmentsisautomaticallycontrolled.Incaseof
overpressureintheanodicchamber,wetchlorinegasisventedtotheWasteGasUnit(outsideB.L.).
AlsoautomaticcathodicpressurecontroliscarriedoutandoxygengascanbefedtotheWasteGasUnit
(outsideB.L.)incaseofoverpressure.
陽(yáng)極室和陰極室的壓力是自動(dòng)控制的,如果陽(yáng)極室超壓,濕氯氣被排放至廢氣單元(B.L.外),如果
陰極室超壓,氧氣被排放到廢氣單元(B.L.外)
Incaseofmaintenancetheanolytecompartmentisflushedwithdemineralisedwaterseveraltimes.Also
aN2purgeisconnectedtotheanolyteheaderforremovingCl2tracesorforemptyingtheheaderduring
shutdownoftheElectrolyser.______________________________________________________________
Doc.-ID-Code:陽(yáng)極室檢修時(shí),需用脫鹽水沖洗幾次,氮?dú)鉀_洗也車接在陽(yáng)極總管上,停車時(shí)用:長(zhǎng)出去微量的氯氣可
UDO-VT-DC-00雅^避Code:YantaiJuliOPERATINGMANUAL
UAN:05-3125
HCLElectrolysisODC2Technicalinformation
2.2CellWorkshop,Unit312
電解廠房,312單元
IntheCellWorkshopassemblyanddisassemblyofanElectrolyserisprepared.Theelementscanbe
removedfromtheElectrolyserusingtheCellRoomCrane(L31101)inordertocarryoutinspectionor
maintenanceintheCellWorkshop.
在電解廠房中進(jìn)行電解槽的裝配與拆卸,當(dāng)需要進(jìn)行檢查或維護(hù)時(shí),通過行車(L31101)來(lái)移動(dòng)單元
槽
2.3Transformer/Rectifier,Unit313
變壓/整流,313單元
(Processflowdiagram31301)(PFD31301)
2.3.1TransformerandRectifier
整流和變壓
EachElectrolyser(V31101A-D)isconnectedtooneRectifier(V31302A-D).TwoRectifiersare
connectedtooneTransformer(V31303A/B).Withtheuseoftransformersandrectifiersthenecessary
electricityissuppliedtotheElectrolysers.EachElectrolysercanbeseparatedfromtheelectricalsystem
byusingswitches.
每個(gè)電解槽(V31101A-D)連接一個(gè)整流器)(V31102A-D),兩個(gè)整流器連接一個(gè)變壓器
(V31303A/B),整流器和變壓器提供電解槽必須的電流,電解槽通過開關(guān)與電力系統(tǒng)切斷
2.3.2PolarisationRectifierUnit
極化整流器
EachElectrolyserisconnectedtoonePolarisationRectifier(V31101A-D).Thefunctionofthe
PolarisationRectifieristofeedthenecessarycurrenttotheElectrolysersduringstartuporshutdown
phases.
每臺(tái)電解槽連接一臺(tái)極化整流器(V31101A-D),開停車期間,極化整流器提供電解槽必須的電流
Doc.-ID-Code:
UDO-VT-DC-00001,Rev.00Code:YantaiJuliOPERATINGMANUAL
UAN:05-3125
□HCLElectrolysisODC
2.4AnolyteCirculation,Unit314
陽(yáng)極液循環(huán),314單元
TheAnolyteCirculationUnitconsistsoftwo
streets,onestreetservingtwoElectrolysers.
Thereisonecommonsystemfordrainingofan
electrolyser.
(Processflowdiagram31401and31402)
陽(yáng)極液循環(huán)包括兩條路徑,每條路徑服務(wù)兩臺(tái)電
解槽,電解槽排放系統(tǒng)是共用的
ThedepletedHCIleavingtheanodicchamber
flowstotheAnolyteTank(T31401A/B).From
hereitispumpedbacktotheElectrolysersusing
theAnolytePump(P31401A/B).Asmallportion
ofthisstreamissenttotheHCIAbsorptionUnit
outsideB.L.vialevelcontrolintheAnolyteTank.
TheconcentrationoftheHCIwhichisfedtothe
ElectrolysersisadjustedbymixingHCI30wt.-%
fromtheHCIAbsorptionUnitwiththedepleted
HCIcomingfromtheAnolytePump.Thedesired
temperatureisadjustedintheAnolyteHeat
Exchanger(E31401A/B).Coolingwaterisused
forcoolingduringnormaloperation.Thecooling
waterismixedwithlowpressuresteaminthe
SteamJetHeaters(J314014A/B)whenheatingis
required.ChlorinecanbeaddedtotheHCIfeed
solutionforstartoftheElectrolysers.Drainingand
fillingofoneElectrolysercanbedonebyusingthe
CellDrainTank(T31402)andCellDrainPump
(P31402onPFD31501).Demineralisedwater
canbefedtotheAnolyteTankortothe
Electrolysersanolytefeedheaderfor
concentrationdilutionorflushingofthe
Electrolyser.Thisisnormallynecessaryduring
startupandshutdownoftheElectrolysers.The
flowrateofHC114wt.-%toeachElectrolyseris
automaticallycontrolled.
離開陽(yáng)極室的稀鹽酸進(jìn)入陽(yáng)極液罐
(T31401A/B),一小部分通過液位控制送至界
區(qū)外的HCI吸收單元,電解槽進(jìn)料鹽酸的濃度由
來(lái)自鹽酸吸收的30%鹽酸和來(lái)自陽(yáng)極液泵的稀鹽
酸來(lái)調(diào)整。需要的溫度通過陽(yáng)極液換熱器
(E31401A/B),正常運(yùn)行時(shí)用冷卻水冷卻,如
果需要加熱,冷卻水與低壓蒸汽在蒸汽噴射加熱
器(J31401A/B)中混合。電解槽開車時(shí)向進(jìn)料
鹽酸中通入氯氣。電解槽的排液及填充通過槽室
Doc.-ID-Code:排水罐(T31402)/口槽室排水泵(P31402)進(jìn)
UDO-VT-DC-OO4M部漆進(jìn)料至陽(yáng)槌消鱗(秘囪豳槽陽(yáng)極液進(jìn)料OPERATINGMANUAL
UAN:05-3125總管,用于調(diào)整濃度或沖洗電解槽,電解槽開停
軍時(shí)是必須的,進(jìn)料?至E
HCLElectrolysisODC
2.5CondensateSystem,Unit315
陰極液系統(tǒng),315單元
(Processflowdiagram31501and31502)
(PFD31501和31502)
AsmallportionoftheO2gasleavingthe
Electrolyserscathodicchambersispurgedvia
pressurecontroltotheWasteGasUnitoutside
B.L.inordertoavoidtheaccumulationofN2and
othertracepollutantsintheoxygencycle.Mostof
thecathodicoxygencanberecycledusingthe
OxygenRecycleSystem:Hydrogenimpurities
fromtheelectrolysisprocesscanbeoxidised
catalyticallyinthecathodicoxygenstream.
However,theoxygengasmustbepurifiedfor
properoperationofthecatalyst.TracesofHCI
andCl2areabsorbedintheRecycleOxygen
Scrubber(C31501)usingNaOH2wt.-%as
washingliquid.Thecausticconcentrationinthe
circulationloopismaintainedpHcontrolledby
dosingofNaOH20wt.-%tothesuctionsideof
theScrubberCirculationPump(P31502).The
waterbalanceofthescrubberisequalizedby
continuoussprayingofdemineralisedwateron
thedemisterfrombelowwhichwillprevent
crystallisationofsodiumsalts.Excessalkaline
washingliquid,whichmaycontaintracesofNaOH
NaOCIandNaCI,overflowsfromthescrubberto
theAlkalineWaterCollectingVessel(T31503).
TheoxygengasleavingtheRecycleOxygen
ScrubberpassestheRecycleOxygenFilter
(F31501)forremovalofthemajorportionof
NaOH/NaOCI/NaCIaerosolsresultingfromthe
scrubbingstep.Theoxygengasisthen
superheatedinthesteam-operatedRecycle
OxygenHeater(E31501)toavoidcondensationof
watervapourintheHydrogenRemovalReactor
(R31501).TheoxygenenteringtheHydrogen
RemovalReactorpassesfirstaGuardBedto
absorbresidualNaOH/NaOCI/NaCIaerosols.The
downstreamnoblemetalcatalystoxidises
hydrogentowaterreachingtherequiredoutlet
hydrogenconcentration.Thepurifiedoxygen
leavingtheHydrogenRemovalReactoriscooled
downagainintheRecycleOxygenCooler
(E31502)andthenroutedbacktotheOxygen
FeedJetsJ31501A-Dinthecellroom(seePFD
31401/31402).Therecycleoxygenismixedwith
freshoxygenfromoutsideB.L.beforeenteringthe
cathodicchambersoftheelectroivsers.The
HCLElectrolysisODC2Technicalinformation
2.6DescriptionoftheCellRoomSystem
槽室系統(tǒng)介紹
2.6.1ProcessdescriptionoftheCellRoomSystem(Unit311)
槽室系統(tǒng)工藝說(shuō)明(311單元)
ElectrolyserDesign:ThecellroomisdesignedtoproducechlorinefromaHCI14wt.-%solutionusing
2
membraneelectrolysers(V31101A-D)containingbipolarelementswithanactiveareaof2.5mper
membrane.UHDE'sbipolarelementsarecapabletooperateunderveryfastloadchanges,whichareonly
limitedbymaintainingastablechlorineandoxygenpressure.Foreaseofsurveillancemonitoringanddata
processing,eachelementinanelectrolyserisassignedapositionnumber.Theadministrationofthe
TM
elementsisperformedwithUHDE'selementadministrationprogramUhdeAdministrator.
電解槽設(shè)計(jì):電解槽包括含有2.5m,膜的復(fù)極單元槽,通過14%鹽酸來(lái)生產(chǎn)氯氣。Uhde的
復(fù)極單元槽可以在負(fù)荷變化很快的情況下操作,但必須維持恒定氯氣和氧氣壓力。為了便
于監(jiān)控和處理數(shù)據(jù),每個(gè)單元槽分配一個(gè)位置編碼。單元槽的運(yùn)行根據(jù)Uhde單元槽運(yùn)行程
序來(lái)執(zhí)行。
Doc.-ID-Code:
UDO-VT-DC-00001,Rev.00Code:YantaiJuliOPERATINGMANUAL
UAN:05-3125
HCLElectrolysisODC
Electrolysis:Hydrochloricacidandoxygenarefed
totheelements.
電解槽:鹽酸和氧氣進(jìn)料單元槽
Hydrochloricacidwithaconcentrationof14.0
wt.-%flowsintotheanodechamberofthe
elements,wherechlorineisproducedatthe
anode.Theanodeandcathodechambersofthe
elementareisolatedfromeachotherbythe
+
membrane.ThismembraneallowsHionsanda
certainamountofwaterpenetratingintothe
cathodecompartment(about1moleH2Oper
+
moleofH).Depletedhydrochloricacidwitha
concentr
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