2023屆天津河北區(qū)高三第二次調(diào)研化學(xué)試卷含解析

2023

“g?&”

2.±??W￡W^?^.

3.^M?fa,

-,&M(W1HN&WO)

KT^li?z^W?

A.

B.?a&>AMW5?<?1￡W

c.?,

D.ztazs&'mz?,KinAt&fnMM^M,W>?Ws#f?

2.N*R^ftinfê^OcMoT?OW￡?^jEfàa<?

A.SOtt^Mag'f,Wtm?mmm

B.lmolCH4-^ImolCLig^M,ftftfc&Js,&^##T&^NA

C.9.2g^?mttKMn04Mtt.M^￥MW,0.6NA

D.fàlOOmLO.Imol/Lgt^?+è]àCH3C00Na0.01NA

3>)

T&i?.

A

S0?’

2

BS03’

CSOMêso2

WsaSAN^COa-MM+éè^?ù^^,?SA?SaWf?

DH2SO3>H2CO3

KMiAM,W?A^5^ZK+<?￥?*

A.AB.BC.CD.D

4.iM^^WM^NOxWffl?fiNaOHMWifè,WT^J?T^è<J>()

A.x=1.5Bt,R￡j$NaNO2

B.2>x>1.5Bt,^NaNO?^NaNOj

C.x<1.5Bt,

D.x=2Btf,R￡/￡NaNO3

5.MimT,()

A.pHffl^a<J?NH4CI?NH4Al(SO4)2?NH4HSO4^^:NH4W6WMO?>@>?

B.m,

+

C.HAf?fcOSKa=4.93xl0-‘%üPJW?ftJNaA>HA'M-ê-fêf?^:c(Na)>c(HA)>c(A")

++

D.a&?ffira&{4T?1èHF>CH3COOH,NaFCH3COOKc(Na)-c(F)>c(K)

-C(CH3COO)

6>2019^7^10^,±w>

MB?

A.>Fn]W?&&S,IfWSêft

D.CO2^H2O

7,TJiJWlEeèù>

A.

2

B.##0.1mol/LNa2CO3W,CO3’?<JzK^gMOfipHtyi&k

C.M-4Fe3\Cu2\

D.41-iW?aM,

8>T?$4'<i￡W*

????

A.B.(D?4^W?Ti$&TI^-￥ffi

c.2^D.

9,

A.W&?5?B.“i?O±”-Wc.D.

A.AB.BC.CD.I)

10.

A.w.

B.Z.g?Oi>{SJMS^IW

c.

D.SiOiAW#Eète,

11.T?oas*,JTOWW

A.*?w&iKB.

c.??i§TzKD.MM^Tzk

12.TW?>

A.^zKg&f?MM:K<CaB.fcféft:HF>HC1

C.MT￥-fé:Si>ND.WMé:Ca(OH)2>Mg(OH)2

13.CaCO3+2HCl=CaC12+CO2?+H2O^^&ùM^S>()

A.IWg

B.jt&R??

C.

D.M4t&J!^,!xJr?Z

14.AWzK^Riiwm^fè/baaiaMgBn^iim,

??o

?CI2@?JX?CI2

—?àtfê--------------------?Br2--------------?HBr--------------?Br2

3

MD?NaOH

MgBr2___________

—>Mg(OH)2—?-?7kMgCI2-------?Mg

A.Ca(OH)2>fWNaOH

B.w^w?.?.

c.^W@+^JxnT^fflTO-MWizK^M

D.I}lk±???,

15.??H,^Jê^WWWSiDT,

A.

D.

16.()

A.

B.tfi?,WpH=4WB^M?zKW,WimffmSW

C.M4Fe(OH)2(s)+2H2O(l)+O2(g)===4Fe(OH)3(s)^fiTaêg^aff,AH<0

I

D.?-WnT$a<l^ffl^4’M2SO2(g)+O2(g)[ig?>2SO3(g)ià￥W^,

2

C(SO3)

^J,

2

C(SO2)C(O2)

-.^iaS?C?fê5?)

17.M.raa?UT^^:

(i)xCSH8O2,xèü^Wf^?^j=

(2)KHCO3,iraAKHCO3?ùS

(3)MT&RM&f?M(?^)o

(4)BMW?T?!l&ft:

I.FeCb^^^Sfe??

WMiWMfriC:

'OOH

(5).CH2CH0

asg@(?mwffl)

pi_i_rwi

CH3CH2OHyg->CH2-CH2—B-?

wucBrBr

(2)RCHO+HOOCCH2COOH-RCH=CHCOOH

A1o

(2)G—>H;D.

c-WfrJCu(OH)2MMMM^|g:￡.

(4)4t-ê-Ww^E5^|s|^^,WJWnl^?ü^

21:2:1:1:1:1,W?

(5)>R?±^?^,WèCHjCH—CH2#IHOOCCH2COOH^jJMWJ#CH2CH2CH=CHCOOH

m^JSnttPè?^)?o

19.1-Z.MS^fflW^,IèRT^MJèWO￡&￡$iJ￡i-Z.MS3m??nT:

B&:imwsm

?

(’C)(’C)

zkBS?

1-^?144SEW^96’C278°CW^zK

W

1725.5’C267°C

S

ft>kh?g

Z.B46-114.l’C78.5°C

(1)lOOmL?zKZ.^4',iHà5mL

^4't?ffièt*ZiS￥?j^S<_______?

(2).

o)wramwz?zM?!___(&?“fa"uw).?a*_______?

(4)??##

M;?ffl10%WNaOH?§MM?M;?ffl??KM^?^Wiè?iEf?f?t?i#*._________(&?^)o

a.?@?@b.(D?(3)?C.@?(3)?

(5)?fêi-L??Wiwmoma?WIWK.

0f/h

(6)43g,o

?tW1-?i*????

—üJtfct?#*￡t?<4

??/(K?cm-’)0.81.363.1

3t^/t97.27159

1?WA12gjEf?O20mLzK,?7KMT^Hil]à25mL18.4mol-L1H2SO4;^4P

Sa?mM^i^Tinà24gNaBr?

0gT7m?:

ci).

(2)ftSAMWO.

A50mLB100mLC250mL.D500mL.

(3)14’$n>Wà20mL7K^#toà&ù7Ka^,?^éW^ft?fe^/￡K^!±!^M^^g

j￡:?

(4)

5*1K?,U),fffftMH-1X*M<S(L_MMlII

a

?b-%n—?fc—ft.nn?r-LTia~OI>—W^n

OinàOemms5:i,W

_____________?

Wloif?wwg*nrtê-a-<A>(?W,TRD.

abBBCTEzKSi?i^d

(§w?

(5)14.8gjjllj^^

2K“^TKWLLJ^^IIJ^IIJ”,EiItffiftNOx,SO2^A^&WS#&S*WMM5C

1

?SO2(g)+NHrH2O(aq)=NH4HSO3(aq)AHi=akJmol;

1

?NH3-H2O(aq)+NH4HSO3(aq)=(NH4)2SO3(aq)+H2O(l)AH2=bkJ-mol;

1

(3)2(NH4)2SO3(aq)+O2(g)=2(NH4)2SO4(aq)AH3=ckJkJmol.

1

!ü!|R&2SO2(g)+4NH3H2O(aq)+O2(g)=2(NH4)2SO4(aq)+2H2O(l)WAH=kJ-mol

1

2CaCO3(s)+2SO2(g)+O2(g)=2CaSO4(s)+2CO2(g)AH=-681.8kJ-mol

01020304050

021.000.790.600.600.640.64

CO200.420.800.800.880.88

1

?0~10minv(O2)=molf-miiT;K

zb”^‘%$”)o

?30minjs,R&??Jt_____(?W).

A.B.Bà-￡*I$O2

c.D.

1

(3)NOxWW±^ê-T^$^,C(s)+2NO(g)^N2(g)+CO2(g)AH=-34.0kJ-mol,

MNoaWPff?20NO

èSO.lOSOKH?Mê^NO?WMSfl-W^A,;?EHOOKftf,CO2^W?

?1050K.l.lxlO6Paitf,

Kp=[B^l:Wff(P?)=^ftJ&ff(P4)x1^^].

K2CO.4^MCO2,WMX,WMfc|?￡f?K2C03OtS￡,

1,B

[WJ

A,?A^;

ttmfa?M,MB?:

c,m￡MO?WST&￡,TO?O?4g?>B^￡,M&M;Iffm

Mc^;

D,z^z.g^?iwz^,imWBiO??,MDW^.

MB.

2,B

[Wrl

A.^rW$￡TNA4’^'T,W0.5mol0.5molx64g/mol=32g,A

B.^lmolCH4-^ImolCbfg'?’??“MTO,HaitOiO.

Imol,B?e^?

3

C.'Rü5C6H5CH3+6KMnO4+9H2SO4=5C?HsCOOH+3K2SO4+6MnSO4+14H2OnJMImolR

?molffeT,9.2g^Wm*^0.1mol,0.6mol%T,W^W^0.6NA,C?^;

D.[è]100mL0.1inoVLmfê^M4’inàCH3COONa?^MMW^4’tt,

M&t??^zfct?,SilWm

>3100mLx0.1mol/LxNA=0.01NA,D^IE^;

g^?aü4t^?,MW

?w?#:?f?WTi'Kma,Miapiminfê^ot

?mm?WMWW????.?ma.

#aa^3in3gws,

3sD

[WJ

MJgWWttMSêWm.

[WJ

A.afe^fèW^MM,M4>nrtê^W^T,SiWn￡??m$?WiL

B.MWtmrHSO3,iftB

c.AWga^ffla5Wl^?,i&cfé^s

D.&ilàgmWWWW,

<Wf?fê1é3STO?,&DjEfà?

M?D?

LABf]

4>D

Lt?W]

iWJWé^NOxfflONaOHOW.?R^W,NO?NaOHM&?

b2NOx+2NaOH=(2x-3)NaNO3+(5-2x)NaNO2+H2O;

A.x=1.5fft,2x-3=0,^f?Bt^têRêé^NaNO2,i&AiEfà;

B.2>x>1.50t,2x-3#0,5-2x540,lW￡j&NaNü2^NaNOj,?fcBOh

C.xCLStf,m^^#^O2,i^ClE^,

D.^x=2Bt,2x-3=l,NaNO2WNaNO3,i&Dfêig.

ism^D

5,A

A.NH4HSO4i§f?a3$mLNH4Ai(SO4)2^ffi^ra^zK?mL

pHffi^,ü!]NH4CI^NH4AI(SO4)2M+ro^TWzK??Mffi^,?éMWSids

?>?>(3),&AjEfà;

B.TOW?jm&W,apH^IW,M+zk?jfc&M*

R,OO;

1Q-14

C.K=----—----->?,H!lNaA>HA^W:c(HA)

h4.93x10”°a

>c(Na+)>c(A-),f?cfêig;

D.HF>CH3COOH,JülJ^M^zKWMF-<CH3COO”,C(F”)>C(CH3COO”),

+++

ftjNaF-ègCH3COOKMMWWdNa>c(K),nT￡nc(Na)-c(F-)<c(K)-c(CH3COO”)>fàDféi￡;

i&^&A.

L^B?]

HAA-f?zKt?'Ob

6'A

A.AJ^Oh

B.MTnT0M,BW?;

C.CW^;

D.fê*

c

co2;fnH2O;^fiU?/WW±co2?0H2O,

^J^A.

7>C

mtfrl

A.^nMFe^ra,JO^Fe&WW^êOS^ffe?,i&A

et^;

B.##0.1moI/LNa2CO3?§M,zKt?g?i^pH^/Js

2Fe3++Cu=2Fe2++Cu2+,é?fWI§?WW?,

T,Cu2\zn2+ift?Oèf?&?,SfccM;

D.TOf??W￡SfcD^;

[￡?]

8^B

[t?tfrl

A.?<W￡lWT?^>CsHa,&AM;

B.#T^W?T^tê?￥ffi,ttB^;

c.WTW2#mW-?O3±$W2^,i&CM;

D.?^TTOWOIW,?#?+wwé>m?tê,

??J?W.DM.&B.

9sD

[fêiMff]

As^aSJSTft^3e4t,&?A;

B,OTiSB;

CsOJ?.WifcC;

DsfflSJi^Do

10sB

[ftWl

^TM,AW^;

B.^M^XXftzK^^Sa?^tt??oiàa^MSWS^,'?M^R],B^M;

NaHCO3,CJWüh

D.-MMTO^^JiêW,DWiMo

g^i&Bo

IlsD

[W]

A.iSfcA^;

B.fws^gn,MamtF,&B^:

D.MDM;

OM

12>A

[$W1

A.K>Ca>Na>Mg,?^A^iM;

B.#￡JKttF>S,W￡4tWf?aWHF>H2S,i&BlEfà;

c.C'Si|H]±i￡,Wg?MMSsi>c,C'Niwi^ffi,

@C>N,Si>N,i&C?Efà;

D.WCa>Mg,WWCa(OH)2>Mg(OH)2,iftD

?Efà;

OA.

13'A

[Wrl

A.CaCO3^HClMCaCMH2CO3,

?A&:

*fcB/Rfr

A.

14'D

[?]

è^SnT^,MgBn^NaOHR^MM^^NaBr,NaBr,

?+OJxHBr,@4^-^HBrMgCl2

H

M.^?P^H0^?IJMgCl2-6H2O,??HCl^Winj&MgClr?HzO,^XJKi^^zK^lü?zKMgCh,

MgCl?t?Mg,

[WJ

A.Ca(OH)2fWNaOH,&AjEü;

B.WZK+^^M^è,(Sx??mwM^T^m,^B?;

C.^W?x-MWi7Ki§M.SO2+Br2+2H2O=H2SO4+2HBr,HBr,

tt.C1E^;

D.Mg^S^M,T>lk±￡W?&D?m;

i&i&D.

-----fct?,

JM,BlWmOMWII?<JW#Mg^zfcf?W,zKfc$?jMg^MO

^M$lMW^&J?iW,Sjttl>±^ffl<JS?MgCha<j^ü$iJ^M?,

‘t’mtfrf?aS,wmMWAWh'Nacif?^$m￡JK￡$n￡M?i.

15,D

r?wi

A^,Mm?eMWW?MpH^?ù$fe?>4t^4t,^A^;

B^,?^W^MMJMRJS,

c?,￡&Mtt.$JM&&,WW?MMf?c^;

DJ5U&DiEfà;

i!fc&D.

16,C

[jmff]

A,?as,MA^;

B,3taT,WPH=4a<jgt^M^#j5,Oi+M^f?ifcSPêfà,èc(OH-)=^rjTOMMM^&ùM±t

±,MB^?

C,MjS4Fe(OH)2(s)+2H2O(l)4-O2(g)=4Fe(OH)3(s),AS<0,^STIBê^^T,WAH-T?AS<0,01ItWAH<

0,MCIEfà;

DS3

'2ZOZI°L.?rw^jsa<]￥wwa<jjgj^,as?,YWWW,MD^O

c(SO2)c(O2)

Co

HBr?(3)@OOCH

[jmFrl

xCsHsCh,Bx,B

HO—

^D,D't’giW?Wé^E,E>f-Br?-CN?WF,F&WaWfrfc#,jgjlWg.

[W1

(1)?W±WWx

(2)JxMDM^Ff??WHBrinàKHCO3HBr,

^WlHBr;

(3)m??>p)&fi(?)???fiR?,ttt?g&h??@-,

(?"WW*MW?T^J&fhI.FeCI3O^￡

sfesis,^<im^^?w08M(-oocH);

\i;

NaBH42^MW^ZLB,HBr￡￡M&&^

r^B?i

^Feci3M￡&MêM,-a-o&

en—CIKWII

18.cm(S-OCH

<XH

CH—CHC(X)H

ax>n

/

H..C

HllrNaOHHOO'Cu(UH!

CHCHCH,??CH.CHCHIk?CHCHCIKXI-CHCH.CHO-???CH,CHCHCHCWH

iin?coAARtH*A

[fff]

?HO?HO

OH-^(CH?O)

OHOH

CH=CH-^HBr?

HH—CH—COOHHH—CH—COOH’:

BrCHjCH,JMGBrCHjCH;BrCHjCH

HOCHjCHj,HOCHjCHj;HOCHjCHj

OHOH

HH—CH—COOHHH—CH—COOCH7CH2

?HO

,limames

OH

OH

HO—CH=-CH—COOCH2CH2—?J?

CHO

(2)G-*HHOCHjCHj

(KH

CH—CHC(X>H

HOOCCH2COOH

(KH(X’H

CHO

IOCH>

(KH,

CHOC(X)Na

(XII

C(X)Na

-2Cii(OH>.+NaOH—*+CUtO4+3H,O:

(KH,

CH=CH~C00H

(4)*gE(A)s^±<3wfts,

r''OH

OH

EWO>0H,-OH,-CH=CHC00H,-OH,-C(COOH)=CH2,2^-OHW4P>I'HJ.

3ft,l#m^('êL'a'E),(2+3+1)X2-l=llfi>,

(5)$|J&CH3CH2CH=CHCOOH&ffliOS?JMCH3CH=CH2-è5

CH3CH2CH2Br,CH3CH2CH2OH,CH3CH2CHO,

HOOCCH2COOHCH3CH2CH=CHCOOH,

z<IM>H

<H,1H?<H,H“?m<H.<H.H<S,<l>!<H!<l|.<IHIH*1^1-<H.<H3HO—^￡22üCH)(H.<H=OKa>tl’13

??HftWAA?"?-A

y<00H

CHXHOII--"■CHI<H<IGB[-1^<HICH.<H.OH2￡2!-CH,<H/HO—H.-tn=<H<<M>H°

‘MUftWAA?<?A

[^0f]

19.aI-^M

Mit,50%

[WtlTl

(1)?f?i?i-^g&$Ht,

(4)WWS10%WNaOH

?ZK,mowaaMW^HO,??@?,M^a;

(5)uj?^.MTO,?m>sm?t?WLz?*iswèa?,BPI-Z.M

OHO-Cb?

(6)^v\H-SO4AA>1-3^-fej

||JJ+av>V3H------------*|lIJ?Hp’

Jüün(CioH?0)=n(Ci2Hi20)=72g^-144g/mol=0.5mol,Mm(Ci2Hi2O)=0.5molX172g/mol=86g,

(43g-r86g)X100%=50%<>

20.giwg.

2

B2NaBr+2H2SO4(^)==Na2SO4+Br2+2H2O+SO2T3Br2+3COj==5Br+3CO2?+BrO3cb60.2%

LWr]

fe

(3)MWMfe^Br2j?,?r^W^NaBr^TM4t^MJèf

(4)?Br2Wm^<￡Mltf,Br2^Tê>M^2JF.R^,

W??7K;

x100%

(5)?SSC??

[WMl

12g

(2)12giE^^a<]W^=15mL,15mL+20mL+25mL=60mL,?fWl&ffllOOmL

OnQ.8g.cmT

OèA:B;

^'B^TüM^tgnTWtti^B^,2NaBr+2H2SO4(^)==Na2SO4+Br2+2H2O+SO2T;

(4)?Br2WWmBr2^Ta^M4t^?M,5:1

2

BriflJBrO3,3Br2+3CO3==5Br+3CO2T+BrO3;

(gMMTBFOLWL?MzK,c;

?^^?T+zKW^?SWn^,b;

A

H2SO4(^)+NaBr=NaHSO4+HBr?;

12g

CHCHCHOH+HBr—^CHCHCHBr+HO,12glEWf?M=02mo1

322322260<T/mo|'>

fltn(NaBr)=0.2mol,m(NaBr)=0.2moIxl03g/mol=20.6g<24g;^ffif/i(H2SO4)=0.2mol<18.4mol/Lx0.025LsOiW

14.8g

jE?Wfct*?JSOSifc?^10.2mol,0.2molxl23g/mol=24.6g,-^-x100%=60.2%,

60.2%o

[?Btl

2K2a+2b+c0.02iM^BC1050KIWfi?fHft,RjSWinft,NOW^it^:

2

20%440H-4e-=2H20+02?K^2KOI^M^SlMtSMT?OH’-^HCOyRêZ^^CO3'

[t?ffi]

(2)?M^^i+MO2￥^M?;aTOM,?A.

B.?à-?