2023屆云南省普通高中高三六校第一次聯(lián)考化學(xué)試卷含解析

2023

1.Mttf,

2.aOiMo

3.woBMm?wm$w>

4.T??f>,#Um.

->?&?(§?R1?-Wmfr

#Jtrtt(HjC^C—CH=CHJ)—

CH,üS1

I,+HO

0

l’?'ttiS(HiC=>CH-^-H)—

A.

B.nJWzKOJMW-R^

c.M^?^a<J-<^W2^

2>?^aHTF,

QCaC

A.S.ù->SQ2LCaS04

?>------*

B-Si-g^SiOjjCK*?)^SiCL

infà--

H->0u

G-Fe--^-^FezOsH2O?Fe(OH)3

iO—**

D.NaH2ONaOH(ag)CO^NaHCOs(aq)

3,<)

A.“MMfêtt;B.feKtttt.c.?wmD.

A.H-O-O-HB.CH2CH2

rHT

C.'gOD.NH4Cla<JEè^5￡:H:N=HCl"

LHJ

5.Cu-znO-zrO2?4t^J±C?inMftJWftB+zKlftftfflMS;

(H2-?*H+*H)O()

A.100%

B.

D.*H3CO+H2O->CH3OH+*HO

6.()

tHW^

AH2S04^OffiMCu-ZnJglfeMCu^IE^,jE&±￡￡$^aè

BEfeMCuCl2?

Cosm?^r^rêmjEOMt?o2

DwPH^p^awié.

A.AB.BC.CD.D

7>20i9^4tjRSS#±?^“^fe^,?a?”?)

B.—“?Am”.

c.w?miJWinA#W$A&>t?.S$￡IU?M?BtS?WWfe,A￡?AM±t?

D.f?fminl&S??AlélWH----W?tfnWJ,

8>2019^“HI^WO^“.^?^ftWAoT?üA

?7GMaù^AiE^a<j>()

A.S2>S4^S?^R]M^W

9,|Rj??i^W%W+IWHtinàCu^CuSO4,nr^CuCl^?*Cl-?gjDT:

Cu(s)+Cu2+(aq)2Cu+(aq)\H\—akJ-mol1

Cl-(aq)+Cu+(aq)-=CuCl(s)\Hi=bkJ-mol'1

A.

B.OpH&t?sp(CuCl)ifA

C.RjSàè?iJ￥WitAc(Cu2+),c(Cl-)M^

D.1/2Cu(s)+1/2Cu2+(aq)+C!-(aq)=aCuCI(s)AH=(a+2b)kJ-mol’1

10,()

-12

A.lL0.2molLèüNaHCOi^^HCO3CO3’?^^±_^1^0.2NA

1y

B.H2O2+Ch=2HCl+O2RjS4,SM32gO2,^2NAb^

C.3.6gCON21-8NA

D.WMT,sog^^+^r-a-^W^S^?NA

11,)

A.KOHB.CH3COONH4C.SO2D.CH3COOH

12,^W^*H2SO

^0TWièjm??

CH-,H;S

E<-SOJff}fLCH,?IH?Fe2(SO,),fêift

A.^afê4’Fe2(SO4)3MMMpH^^/h

B.

C.FeSO4

D.H(H2S):n(O2)=2;1

13,i&NA^WO?T?&jEfà?j?()

A.ILlmol’L1NaCIOCIOMgANA

B.78g^WC=C2XMlft|i(@^3NA

C.WWF,14gèN2WWfi￡WWfSONA

D.6.72LNO2^A^MS^è9èT^SA0.2NA

14,êêOJMMWM(^fà,M,

iWM()

A.èJATIW

c.

D.?ifêBa,W@fcO?êm

15,()

A.CO2è<J^T^::6:C:6:B.H-O-CI

c.D.fftiù

U//y

16,???X,Y,Z,WAom,n,rWF,O.lmol-L-’m

O?f?pH=13,lop,±iêWf??4tA?S

A.X<Y<Z<W

B.X,

c.Y<W

D.Y,z,

-,?M(*?&fé5/h?)

17,Bftl:R-CH=CH-O-R'R~CH2CHO+R'OH

^?/?*

A?Wf?f?lCnHi?OoWW?f?&è&T:

43,.

44,_________________________________________________

45,FWmMt?a______________________?

?f?-^FeChMO?Mfe&jS;

(D#T+<4

46,i￡it-&èE-ê-^W^Aife(H3c—(?^HC=CE)ftj-a^iOo

(??M).WmgSSftliiiT!

HBrNaOH?§>ff

H,C=CH,tlpr?CH,CH,Br-------.Il;.(!￡—?.H,CH,OH

3AC4

18,MWMIW%AMW?A,DM!?

200’C,NaOH

Zn(CH3COO)2BWt,￡j-ECH2—?H4-n

?*0CCH3?*

CH3COOH(C4H6O2)

?

OF

02CHCOOH

DQ>—CHO3EJ

Cu/A<>ft^J,350“C

Bfch?A^T^ft^W,AWTH2^W^13O

?DC7HSO,iSFeCh^^^Sfe^Jèo

RiCH—CCOOH+ftO

@R,CHO+R2CH2COOH350rI

R;

W0gLUTln])?:

(1)A^Wft?^?

(2),BO

(3)o

(4)DW:.(WD)^?

(5)￡M@?9ft.^S5S??

(6)

_______________

CH2CH2—O—c—CH=CHCH3

CH3CH2OH>CH3CH200CCH3

19,iWTBWft.1

^TzK:

(2)$0#BN.

(3)S1o

(4)02,___.

(5)

i.W0.0625gMW&,iuà^WiO,M.+

ü.léj^at^inA?SNaOHM^in^,20.00mL0.1008mol-L1f?Wtt;

iii.fflO.lOOOmolL'NaOHNaOH20.32mL.

A.

B.NaOHfêMO&m

C.?w,?JH?

D.??moo?fti

B

20,￡O?MW>iS^%^)^IMmiJ?^?^B0^[(NH4)2SO4-FeSO4-6H2Ol,WWJ^^S

^-￡*MOUS^?70i‘KinAiSfiM^W?,OWI’?fso~6o°cWWtt

O^^WsinAMzK,$iW$Wfe^Mo

(1)??^M50-60°C&2KfêMM.__________

(2)^<BMM<;KMnO4OMftffl<.

____<m.

a.w&M*b.goo?Bcw^mK^w?

(4)?$0WM(NH4)2SO4-FeSO4-6H2OFe^M^Tü:WéW

Un(iiut^)o

MWFe3+M?*W:

?ge$ljFeJ+&??a0.1mg/mLMW'M'M100mL.W(ffiM0.1)mg

[(NH4)Fe(SO4)rl2H2O],inA20.00mL^SMé^TzK?WMMJH.iDà2mol-L’HBrMImL^DImol-L'KSCN

W0.5mL,inzKSe^lOOmLMo

0.2,1.0,3.0,5.0,7.0,10.0?&:mg-L'')M'M?

lOmL,

WMlOOmL,0.590,0.610,

Fe5+^a^mg-L-'o

(6)Wmg^iFn,S2j&250mLigM,lOOmLfitM&Ol'KcmolL'KMnfA

?ftKMnOjOVmL,(ffl^c.V.mf?f?B).

21.

(iWmimtH2SêWWO.TO1200’CTW??,H2Sameniut^so2,#j*&2k

^o

H-S0=0H-Oso2

^/(kJ-mol1)3394984641083

(2)^ijfflNaC!OVH2o2TT&NO.so2?aK-fé

ftf,n(H2O2)/n(NaCIO2).MpHXttJKM?l

-?-SO.ANt*

-*-NO).Mt?

(DM?aMbn(H2O2)/n(NaCIO2)M.ftf?pH>

?Kb+SO2pH?tlifAWifA,WNO?ùA^WEPH>5.5WM#NO

nTfê^SM

2NO2(g)+o3(g)?±N2O5(g)+o2(g),TOiasr,ILw

EF.LWffi^KO't’ia?AImolO32molNO2,

?0~15minv(NO2)=.(f?g2

NO2(iü^w^)

A.

B.

c.NO2

D.iRj^rfS^à1molO3W2molNO2

po,m?Y?Kp=..(#?=MxWM0

(4)a-a?W(K2S2o)nr^^m^^^^?a<jM4t^o

8KHSO4MOJ#^OS,Hü^OI?

#?75:

(Dtfef?BAf?(“ffi”§K“K”)o

??MT,pHApHmO?o~2ZfO

efct?,JüIJWA

1,D

oom,RIWZKOJ,B

1E^;

c.???HMWOf?±m(xù)￡fFS±l#,^vt-2#,CO;

MfiTOftcw,?lttMffl.DW;

[?}

M^ssafe.

2>D

A.-MW^M^Rê^CaSOa,AW;B.ffrMW?

BW;c.Fe-*5H20Fe304,Fe203-*5H20TO&,Fe(0H)3,

CW;D.Na-^H2OR^^NaOH^H2,NaOHflJ?SC02R&￡j￡NaHC03,DIE^;D.

?ffi;FeH20WFeA,Fe203o

3>A

?^zp?fefè&,

LWl

A.MAiEW;

B,MBW;

c>MCW;

D,MDW;

^?Ao

4,A

B.CH2=CH2,i^BW;

C.rteCW;

H

D.NHiClf?ffe^?^:H

:N:H![:C1:1>tt?O5

H

5,A

[Wrl

A.AM?.?.?<,&j&2moiH2O,imoiH.o,#fUl100%,

A^:

B.AS4-?S#,^SiBWWW?+l'alJ?S^fB??,BjE^;

c.AM@t,iRl^M^M+inAOS^TK?cm

D.AOT#,Wf?M?*H3CO.H2O,CH.,OH,*HO,KIM&*J*H3CO+H2O->CH3OH+*HO,

DjEfifti

?&?A.

6,A

A,Zn+H2SO4=ZnSO4+H2?,?&

W±￡?$JIM,AiEifê;

B,^CuChW,^A^WIRJI^?,K?im￡M±A￡EfeT,^TAPHMl^?E

F?,B^TM;

C,O^WF,^f?±^Fe-2e-=Fe2+,2H++2e"=H2?,

D,D^:

A.

L?]

'è’i?lS&o

7,D

[M#T]

A.SfcAe^;

B.i^B^;

D.RTS±??rffl?W&T?,&Dim

r&iaDo

8>B

[mfi

A.&AOh

B.m(Hgs)^xasj&w,msm&

B^;

C.?WülRlWWLWtt.,???MMi&ClEfà;

D.?DjE^;

g￡&B.

9,C

A.fêigM,MWPH^/JSO?c(Ci-)?*,^JTcrf?￡&,&A^;

B.Ksp(CuCl)R^ia?<^,WpH?^,ifcB^s

C.Cu(s)+Cu2+(aq)^=“2Cu+(aq),ifAc(Cu2+),YWlE[n|^^J,fêftc(Cu+)±fA,f?iSCF

(aq)+Cu+(aq)—“CuCI(s)￡^,c(Cr)Mzb>$fcCjE$fé;

D.(?)Cu(s)+Cu2+(aq)-~2Cu+(aq)AHi=akJ-mol'1,(2)CF(aq)+Cu+(aq)-~CuCl(s)AHz=bkJ-mol1,

2+1

fê?X|-+(2)f?:l/2Cu(s)+l/2Cu(aq)+CF(aq)—-CuCl(s)&ùAH=(|-+b)kJ-mol,

?fcJ^Co

10,A

22

A.HCOs’?W't’RW^i^COa",H2CO3,iWS?HCO3-,CO3",H2CO3^W^

^JO.INA,iftAfé?g;

>

B.?H2O2+CI2=2HC1+O2S1S4’,MTG^è-lt?-^O^,SJt^32gM^?gpimoKW,W^2NAb^,

B?E^;

3.6g9

C.CO28g/mol,----;=^mo1’XHHCOWN2W

28g/mol70

9

144-M^F,&—1.8NA4*?^>&ClE￡fê;

D.WST,30g^?<jW&<J*>lmol,-^Z1^^W7^W.BP30gZJ^ft4’m^WM@^7NA,

&DiEfà;

A?

11.D

[Wf]

A.i&FifcA;

C.Wè.^?C:

D.ift&Do

12.D

[Mtlr]

A.?ffigas^Fe2(SO4h-^H2S￡±￡jS:Fe2(SO4)3+H2S=2FeSO4+H2SO4+Si,

4FeSO4+O2+2H2SO4=2Fe2(SO4)3+2H2O,2H2S+O2=2S1+2H2O,nIJOmWll*èTMj^zK,

fêFe2(SO4)3?fê?Mi,SWf?lftpHiOrig*,AO;

B.CH4￡?g*m!lllMBO;

￡c

C.?a?Mj^^té]^FeSO4,OW&SMFeSO4è<jMaù*^,FeSO4,COh

D.?MAWnT^flFe2(S04h>ffiWffiOJ,2H2S+O2=2Si+2H2O,n(H2S):

n(O2)=2:1,DJE^;

?fc'a-SMJtD?

13.C

(MtEl

A.N^,MAoh

B.?BO;

c.CO28g/mol,14g0.5mol,0.5mol

lmolJM^BPNA'?",t&CjEfifê;

D.aDO;

f?i&sC?

14.B

rwm

A.Miè.M?^ktzIC/h,^fgK^J,j&AO;

B.iPà?fiOUtWM?,è?OJ,i^BlE^;

C.ifeM.^OJ,ttCO;

m

15,B

A

A.co2^WcM^2>boMT^4Xt^ffl<TO,W?C*h:6:5c;:6-^

B.aHC1O410H,^W^H-O-C1,BjEf?;

C.ZL^T+M^cgfZfSJM2?4-cMTs?2TH2?fcT?h

^Z^f?bE?IOLcei￡;

D.W9^%f,MWWW,8,8,1,KMT￡fê^M?E??T^@':?ù,Df??;

^'/JJ

t?êSWB?

16,D

[JW1

0.1molL-1mM^WpH=13,jü!jm^-7ü^,jS^NaOH,é?nKffiWWWI?1,

n^jNaCl,NaClMWi!lNaOH,H2#lCl2,p,qWJP>q^H2^Cl2,

Mi&xMx,Y,z,w?T/Hfcf?&^Wfci:X^jHiüM,Y^JOTGM,Z^jNaTGM,W^jClT?ltIg

Jit^o

è^Hfr?T&l:X^HT?:^,Y^IOTG^,Z^jNa7ê^>W^JCITC^O

X<Y<W<Z,?ftA$ti￡;

B.é^?rTO:x^HjélhZ^Na?l?,X,JSTIsJ-?,^B^;

C.Y,w^a<JM4t^^H2o^HCi,WfêMOsaü

M:Y>w,SèC^;

D.Y,Z,W^M-NaCIO,NaCIORTfflTMébAWMéltt,i&DlE?fêo

OD.

-,(M^f?5/h?)

17r

'H3C^D^CH=CH-O-CH2CH2CH3CH3CH2CHO+2Ag(NH3)2OH;:-._?CH3CH2COONH4+

2AgJ,+3NH3+H2O

CH,

èfêMW,ARJS^B^/B,E^B,èBaùW^M*^6o.JüIJB^CH3CH2CH2OH,B^c￡￡flHtM4t

RJS,#f!UCCH3CH2CHO,C—>D^^RjS,JüIJDCH3CH2COONH4?èB.ERA

^BA^f?f?i^H3C^O^CH=CH-0-CH2CH2CH3;OLWEMRH3C-?^-CH2CHO;èEW3WF1ê

<H3C—C=CH),?￡￡-CHOf?M,W￡￡Blftfê￡RJS,

<Jé￡￡iêifWENaOHc^c,

[WJ

43.Af?gHW^tH,C-<>CH=CIIOCH2CH;CH3

1.C-DCH3CH2CHO+2Ag(NH3)2OH__>CH3CH2COONH4+2Agi+3NH3+H2O;

CH3CH2CHO+2Ag(NH3)2OH2,CH3CH2COONH4+2Ag|+3NH3+H2O;

2.?ftteFeCl3MM￡￡SùMJS,

^R?*RJS,?C1M^6<IC^TWWC±S<H]MT,mT4>W4^R]^TOatMlMT,M

/-<CH3

FH3C-0-OH

^CH,

CH,

CH,

46.èH3C-(^-CH2CHO^:-I^—

M^Brzaf?M,

z=xH./^\__

H>C<v-CHjCHO-----—HjC-C>-CH3CH.OHtflTtrH1C-/”\-CH=CH.

?üJMJnrn

81-

CH—CH.\aOH

II?△*

BrBr

H?C-OCHjCHO-^r*H3C-C>-CH2CH2OH^SHJC-O-CH=CH

1,1Z_ù170v

BrBr

-￡-CH2—CH4?+nNaOH—-{7CH2—?Hà+nCH3COONa

18,CH=CHinj^ozIW

n(/VCH=CHC(X)H+-BCH2—CH-J?,

?|*LCH2?HJ?

OHIz=\

OOCCH—CH

Oj/CuCHiCHO

CHJCHJOH—?CHjCHO--------?CHjCOOH——-------<HC(X)H

△△fit-NOM,350C

(A—CIfeCH-OHO

*?<*/△<^-CH2CH2—O—C—CH—CIICFh

[JWtfrl

ATOTH2èüM^13,MA26,X#T^C2H2,

-ECH2—?H-H

TE,^^?^CHSCH-,OCCII3-BC4H6O2,P?^B

-ECH2—?H-}?

CH2=CHOCOCH.?MAfllCH3COOHB;OCCH3S?NaOH?ùzK

O

+(H2-(H+n

M^^Zk^M?ùC^’|';DC7H8O,

OH

CHO,;^m?^CH3COOH￡￡{àl.(a)a<J

-ECH2-?H4-?

E1—CHCOOH,CEF?HC?

O

?yCH2CH2VCCH—CHCH3?

CH3CH=CHCOOH,WMO

O11

<>—CH?CH?—O—C—CH—CHCH.1

[WJ

(1)AC2H2,CH=CH;

(2)M(DCH=CH$nCHJCOOH^MM^TCH2=CHOCOCH3,B^J

CH2=CHOCOCH3,

-ECH2—?H4-?

(3)JxjS@MOCCH3?

O

NaOH?<J?'l’^?S,

“ECHa—?HTJ?+?i.NaOH—*“ECHj—?H-k+nCH3COONa

OCCHaOH

(4)D^0-(’H2OH,??WM1-.2-.2-.2-.1-,DwsmJST

-FCH2—?H-K

(5)M@>CEF^Q)-CH-CHCO’

O

U(CH—CHCWH+-êCHi—CHi

-￡CH2—CHi+nH:O

OH

OOCCH—CH

O

(?jtuz.gr^z.s?^jMmü#//\???,,_

\/CH2CrMHI2OrxCCHTT—CHCH3?

CH3CH=CHCOOH,WIJ

CH?CIh—O—C—CH—CHCH3

Os/CuCHjCHO

CHJCH?OH-——?CHjCHO--*CHC(X)H——:------*CH?CH—CHCWH

△△3-HHtfl.350r

DHsCHjOHO

&?/△

[am

(D?NaOH

Mo(2)?NaOHMZ1B??4’M,(3?H2SO4#??ü^#Tin^>

(OtE^^^iftWcchM^M.(5)

tgJgH2#NiftffiT￡￡M,(6)^o2>Cu(^Ag)>

§￡390'0

#‘%()()’()8=%()()[X———-3—————‘IOIUZ00-0=(N?)u?FW^*OS*H—”HNZ

^[ULU?x[OLU￡(J(J(J+

—MHZSlll‘PiuiOOO=lOu^IOIOOO-lZOOXpTIoiuSOOrO=(”O(jiān)S*H)u‘I<>u?9l0I000

ds?k-WSWWWTO?IMWWWWH‘Ioo?Z￡0Z00’0=IZCOZOOXJ.TIOUIOOOl-0=

(HOBN)u^^‘liuzroz^Wdr^WHOKNHO”N,.TIouiOOOrO&(S)

■NHww?

‘*oYWTiJdaW-M

?feWIYBPO

?O*H9+N8fr=^=*O￡+￡HNt+at’

iO*H9+NHt’^O￡+fHNt+8frNHK?WW(Z)

:q

w'4>w^naY?iwu?S^B‘^i#w?wh$>wq

‘WW±igW^[i$^^W+WWTffid)

[W#]

‘(Nia)uTO^eos*H—+”HNZ

-NazSfWéé‘(HOW#^W?44W

<zoYWTi)da7v

?WMVMi$W4}W&T￡^+iffi(￡)

“WNagfW^W?WW)

‘M^iSjRmwaiike}%wi?w‘MIW^???

□%00-08^t^ê^^Na^?iMS!

WBO^Y?*O^-‘'HNWM?‘WWWWo*H9+Nat<=^*O￡+rHw+afrMWHL?qK6i

'JO?I}^ra±#Watros*H&#(8)<roWW;OW)

OH3—‘WW^WWZ(HO)"3Wfi$w*o^-(Z.)‘±#^(W'O"3

80.00%O

?A.WjBNlWfi?Wfcb,B.?Rt^fflNaOH^mWra

￡W,c.wm,M?

1$?,M?BM,Wt?MsD.

WWW?ê??Miè,

20