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1、呋喃樹脂液msds 報(bào)告(化學(xué)品安全技術(shù)說明書)furan resin liquid msds report(material safety data sheet)發(fā)布時(shí)間: 2010-09-29date of issue: september 29, 2010第一部分:化學(xué)品名稱part 1: chemical name化學(xué)品中文名稱:呋喃樹脂液chinese name: 呋喃樹脂液化學(xué)品英文名稱: furan resin liquidenglish name: furan resin liquid主要成份:糠醇(c5h6。2)、糠醛(c6h4。2)及其高聚物main ingredients
2、: furfuryl alcohol (c 5h6o2), furfural (c 6h4o2) and their high polymers.第二部分:成分/ 組成信息part 2: composition/information on ingredients有害物成分:糠醇(c5h6。2)、糠醛(c6h4。2)及其高聚物harmful ingredients: furfuryl alcohol (c5h6o2), furfural (c 6h 4o2) and their high polymers.第三部分:危險(xiǎn)性概述part 3: hazards summarizing危險(xiǎn)性類別:d
3、angerousness classification:健康危害:本品有弱刺激作用,可引起皮膚和上呼吸道輕度不適health hazards: this product has the weak irritating effect and may induce mild discomfort of skin and upper respiratory tract.環(huán)境危害:對(duì)環(huán)境有危害,對(duì)水體可造成污染。environment hazards: this product may cause environmental damage, and especially may cause water
4、 pollution.燃爆危險(xiǎn):本品可燃。fire and explosion hazards: this product is flammable.第四部分:急救措施part 4: first aid measures皮膚接觸:脫去污染的衣著,用肥皂水和清水徹底沖洗皮膚。skin exposure: take off the polluted clothes, and flush thoroughly skin with soap water and clean water.眼睛接觸:提起眼瞼,用流動(dòng)清水或生理鹽水沖洗。就醫(yī)。eye contact: raise eyelid, flush
5、with fluid clean water or normal sodium and go to a doctor.吸入:迅速脫離現(xiàn)場(chǎng)至空氣新鮮處。保持呼吸道通暢。inhaled: leave the scene quickly to fresh air and keep respiratory tracts unobstructed. 食入:飲足量溫水,催吐。就醫(yī)。swallowed: drink enough warm water to induce vomiting and seek medical advice.第五部分:消防措施part 5: fire fighting measu
6、res危險(xiǎn)特性:遇明火、高熱可燃。hazard characteristics: it is flammable in case of open fire and high heat.有害燃燒產(chǎn)物:一氧化碳、二氧化碳hazardous combustion products: co, co 2.滅火方法: 將容器從火場(chǎng)移至空曠處。 處在火場(chǎng)中的容器若已變色或從安全泄壓裝置中產(chǎn)生滅火劑:泡沫、二氧化碳、干粉、砂土。用水滅火無(wú)效,有害燃燒產(chǎn)物:一氧化碳、二氧化碳。extinguishing method: transfer the containers from the scene of fire
7、 to open space. if the containers in the fireground have changed colors or generate extinguishant from the safety relief device, use foam, co 2, dry powder and sand to extinguish the fire. if trying to extinguish the fire with water, it will be ineffective. hazardous combustion products: co, co 2.第六
8、部分:泄漏應(yīng)急處理part 6: accidental release measures應(yīng)急處理:隔離泄漏污染區(qū),限制出入。切斷火源。建議應(yīng)急處理人員戴防塵口罩。不要直接接觸泄漏物。小量泄漏:收集于干燥、潔凈、有蓋的容器中。大量泄漏:收集回收或運(yùn)至廢物處理場(chǎng)所處置。emergency measures: isolate the contaminated areas of leakage and restrict access. it is advised the emergency personnel should wear dust mask and should not contact t
9、he leakage directly. in case of small amount of leakage, collect it in a dry and clean container with lid. in case of large amount of leakage, collect and recycle it or transport it to a waste treatment plant for disposal.第七部分:操作處置與儲(chǔ)存part 7: handling and storage操作注意事項(xiàng): 操作人員應(yīng)經(jīng)過專門培訓(xùn), 嚴(yán)格遵守操作規(guī)程。 建議操作人員佩
10、戴 (口罩) , 遠(yuǎn)離火種、 熱源,工作場(chǎng)所嚴(yán)禁吸煙。使用通風(fēng)系統(tǒng)和設(shè)備。 避免與氧化劑 接觸。 配備相應(yīng)品種和數(shù)量的消防器材及泄漏應(yīng)急處理設(shè)備。 倒空的容器可 能殘留有害物。handling notes: all handling personnel should be specially trained, and should be in strict accordance with the handling rules. it is recommended all handling personnel wear masks and stay away from fire and heat
11、. it is strictly prohibited to smoke at work. use ventilating system and equipment. keep the chemicals away from any oxidant. provide relevant types and quantity of firefighting equipment and leakage emergency equipment. there may be residual hazards in any emptied container.儲(chǔ)存注意事項(xiàng):儲(chǔ)存于陰涼、通風(fēng)的庫(kù)房。遠(yuǎn)離火種、
12、熱源。防止陽(yáng)光直射。包裝密封。應(yīng)與氧化劑、 食用化學(xué)品分開存放, 切忌混儲(chǔ)。 配備相應(yīng)品種和數(shù)量的消防器 材。儲(chǔ)區(qū)應(yīng)備有合適的材料收容泄漏物。storage notes: store it in cool, ventilated storehouse. keep away from fire and heat. avoid direct sunlight. the packaging should be well sealed. separate it from oxidant and food chemicals, and no mixed storage is allowed. provi
13、de relevant types and quantity of firefighting equipment. the storage area should be provided with stuff suitable for containing leakage.第八部分:接觸控制/個(gè)體防護(hù)part 8: exposure control/personal protection 職業(yè)接觸限值:未制定標(biāo)準(zhǔn)professional exposure limits: not regulated.中國(guó) mac(mg/m 3):未制定標(biāo)準(zhǔn)china mac (mg/m 3): not regu
14、lated.前蘇聯(lián) mac(mg/m 3):未制定標(biāo)準(zhǔn)former soviet union mac (mg/m 3): not regulated.監(jiān)測(cè)方法:嚴(yán)加密閉,提供充分的局部排風(fēng)。monitoring methodology: be strictly airtight and provide full local exhaust.呼吸系統(tǒng)防護(hù):口罩respiratory system protection: respirators眼睛防護(hù):護(hù)目鏡eye protection: goggles其他防護(hù):工作現(xiàn)場(chǎng)禁止吸煙、進(jìn)食和飲水。工作完畢,淋浴更衣。保持良好的衛(wèi)生習(xí)慣other pr
15、otections: no smoking, feeding and drinking at work. take a shower and change clothes after work. maintain good health habits.第九部分:理化特性part 9: physical and chemical properties 主要成分:糠醇、糠醛及其高聚物main ingredients: furfuryl alcohol, furfural and their high polymers.外觀與性狀:棕褐色液體appearance and properties: br
16、own liquidph: 6.57沸點(diǎn)(c): 161.7171boiling point ( c): 161.7 171相對(duì)密度 (水=1) : 1.19relative density (water=1): 1.19相對(duì)蒸氣密度(空氣=1) :無(wú)資料relative vapor density (air=1): no useful information available up to date.飽和蒸氣壓(kpa) :無(wú)資料saturation vapor pressure (kpa): no useful information available up to date.燃燒熱 (k
17、j/mol) :無(wú)資料combustion heat: no useful information available up to date.閃點(diǎn)( ):無(wú)資料flash point ( ): no useful information available up to date.引燃溫度 ( ) : 392ignition temperature ( ): 392 溶解性:無(wú)資料dissolubility: no useful information available up to date.主要用途:適宜用作耐水性膠黏劑、防腐蝕膠泥、襯里、浸漬液、玻璃鋼。main application:
18、suitable to be used as water-resisting adhesive, anti-corrosion mastic, lining, impregnant and glass fiber reinforced plastics.第十部分:穩(wěn)定性和反應(yīng)活性part 10: stability and reactivity熱分解及要避免的情況:如果按照規(guī)則使用則不會(huì)分解thermal decomposition and conditions to avoid: no decomposition will occur if used in accordance with t
19、he rules.危險(xiǎn)的反應(yīng):未有已知危險(xiǎn)反應(yīng)hazardous reaction: none.危險(xiǎn)的分解產(chǎn)品:未有已知危險(xiǎn)分解產(chǎn)品hazardous decomposition products: none.第十一部分:毒理學(xué)資料part 11: toxicological information糠醇(c5h6。2)、糠醛(c6h4。2)及其高聚物furfuryl alcohol (c 5h6o2), furfural (c 6h4o2) and their high polymers主要的刺激性影響:main irritating effects:皮膚:刺激皮膚的粘膜skin: it ha
20、s irritating effect on skin mucous membrane.眼睛:eye:致敏作用:沒有已知的至敏影響sensitization: none.該產(chǎn)品顯示以下危險(xiǎn):刺激性的this product has following hazards: irritation.第十二部分:生態(tài)學(xué)資料part 12: ecological information生態(tài)毒性的影響:該物質(zhì)對(duì)環(huán)境有危害,應(yīng)特別注意對(duì)水體的污染ecotoxicity effect: this product is harmful to environment and special attention sh
21、ould be paid to its water pollution.第十三部分:廢棄處置part 13: disposal information廢棄處置方法:在能利用的地方重復(fù)使用容器或在規(guī)定場(chǎng)所集中處理waste disposal method: reuse containers where applicable or dispose of them in a centralized way in a place as required.廢棄注意事項(xiàng):不能將該產(chǎn)品與普通垃圾一起丟棄,不要讓該產(chǎn)品接觸污水系統(tǒng)disposal considerations: this product sh
22、ould not be discarded together with general refuse and should be kept away from sewage system.第十四部分:運(yùn)輸信息part 14: transport information危險(xiǎn)貨物編號(hào): 90code of dangerous goods: 90un 編號(hào): 3082un no.: 3082包裝標(biāo)志: ii ipacking mark: ii i包裝類別:packing group:包裝方法:螺紋口玻璃瓶、鐵蓋壓口玻璃瓶、塑料瓶或金屬桶(罐)外普通木箱;螺紋口玻璃瓶、塑料瓶或鍍錫薄鋼板桶(罐)。pa
23、cking method: thread screw neck vial, gland vial, plastic bottle or metal drum (can) enclosed by common wooden case; thread screw neck vial, plastic bottle or tinned steel sheet drum (can)運(yùn)輸注意事項(xiàng):運(yùn)輸前應(yīng)先檢查包裝容器是否完整、密封,運(yùn)輸過程中要確保容器不泄漏、不倒塌、不墜落、不損壞。嚴(yán)禁與酸類、氧化劑、食品及食品添加劑混運(yùn)。運(yùn)輸時(shí)運(yùn)輸車輛應(yīng)配備相應(yīng)品種和數(shù)量的消防器材及泄漏應(yīng)急處理設(shè)備。 運(yùn) 輸途中應(yīng)
24、防曝曬、雨淋,防高溫。caution during transport: check first whether packing containers are complete and sealed before transport, and make sure no leakage, collapse, fall and damage occur to containers during transport. transport vehicles should be provided with relevant types and quantity of firefighting equipment and accidental release
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