分析化學(xué)授課綱要

1、分析化學(xué)授課綱要授課節(jié)次:第_1_週上課課程主題: The Nature of Analytical Chemistry講授目的:定量分析的分類及方法授課綱要: The Role of Analytical Chemistry Quantitative Analytical Methods A Typical Quantitative Analysis Choosing a Method Acquiring the Sample Processing the Sample Eliminating Interference Calibrating and Measuring Concentrat

2、ion Calculating ResultsIntegral Role for Chemical Analysis: Feedback Control System分析化學(xué)授課綱要授課節(jié)次:第_2_週上課課程主題: Calculations Used in Analytical Chemistry講授目的: 定量分析濃度之單位與表示法，化學(xué)之計(jì)量關(guān)係授課綱要:Some Important Units of Measurement SI Units The Distinction Between Mass and Weight The mole The milimole Calculating

3、 the Amount of a Substance in Moles or MillimolesSolutions and Their Concentrations Concentration of Solutions Density and Specific Gravity of SolutionsChemical Stoichiometry Empirical Formulas and Molecular Formulas Stiochiometric Calculations 分析化學(xué)授課綱要授課節(jié)次:第_3_週上課課程主題: Errors in Chemical Analyses講授

4、目的: 平均值及真值、精密度及準(zhǔn)確度、誤差之種類及來源授課綱要: Some Important Terms The mean and Median Precision Accuracy Types of Errors in Experimental DataSystematic Errors Sources of Systematic Errors The Effect of Systematic Errors on Analytical Results Detection of Systematic Instrument and Personal Errors Detection of Sy

5、stematic Method Errors 分析化學(xué)授課綱要授課節(jié)次:第_4_週上課課程主題: Random Errors in Chemical Analysis講授目的: 隨機(jī)誤差的性質(zhì)、統(tǒng)計(jì)處理、結(jié)果計(jì)算的標(biāo)準(zhǔn)偏差、數(shù)據(jù)的記錄授課綱要: The Nature of Random Errors Random Error SourceDistribution of Experimental Results Statistical Treatment of Random Error Samples and Populations Properties of Gaussian Curve Th

6、e Sample Standard Deviation: A measure of Precision Reliability of s as a Measure of Precision Variance and other Measures of PrecisionStandard Deviation of Calculated Results Standard Deviation of a Sum or Difference Standard Deviation of a Product or Quotient Standard Deviations in Exponential Cal

7、culations Standard Deviations of Logarithms and AntilogarithmsReporting Computed Data Significant Figures Significant Figures in Numerical Computations Rounding Data Expressing Results of Chemical Computations 分析化學(xué)授課綱要授課節(jié)次:第_5_週上課課程主題: Statistical Data Treatment and Evaluation講授目的:統(tǒng)計(jì)應(yīng)用於數(shù)據(jù)的處理評(píng)估授課綱要:

8、Confidence Intervals Finding the Confidence Interval When Is Known or s Is a Good Estimate of Finding the Confidence Interval When Is Unknown Statistical Aids to Hypothesis Testing Comparing an Experimental Mean with a Known ValueComparison of Two Experimental MeansErrors in Hypothesis TestingCompar

9、ison of Precision Analysis of Variance ANOVA ConceptsSingle-Factor ANOVADetermining Which Results FifferDetection of Cross Errors The Q Test Other Statistical TestsRecommendations for Treating Outliers 分析化學(xué)授課綱要授課節(jié)次:第_6_週上課課程主題: Sampling, Standardization, and Calibration講授目的:採(cǎi)樣、校正與分析品質(zhì)的保證與控管授課綱要: Ana

10、lytical Samples and MehtodsTypes of Samples and MethodsReal SamplesSampling and Sample HandlingSampling UncertaintiesThe Gross SampleNumber of Laboratory Samples Standardization and Calibration External Standard Calibration Minimizing Errors in Analytical ProceduresFigures of Merit for Analytical Me

11、thods Sensitivity and Detection Limit Linear Dynamic Range Quality Assurance of Analytical Results 分析化學(xué)授課綱要授課節(jié)次:第_7_週上課課程主題: Aqueous Solutions and Chemical Equilibria講授目的:水溶液化學(xué)組成、化學(xué)平衡、緩衝溶液授課綱要:The Chemical Composition of Aqueous SolutionsClassifying Solutions of ElectrolytesAmphiprotic SpeciesChemic

12、al Equilibrium Types of Equilibrium Constants Encountered in Analytical Chemistry Applying Acid-Base Dissociation Constants Buffer Solutions Calculation of the pH of Buffer Solutions Properties of Buffer Solutions 分析化學(xué)授課綱要授課節(jié)次:第_8_週上課課程主題: Effect of Electrolytes on Chemical Equilibria講授目的:電解質(zhì)對(duì)平衡的效應(yīng)、

13、活性係數(shù)授課綱要: The Effect of Electrolytes on Chemical Equilibria The Effect of Ionic Charges on Equilibria The Effect of Ionic StrengthBuffer CoefficientsProperties of Activity CoefficientsThe Debye-Hückel EquationEquilibrium Calculation Using Activity Coefficients 分析化學(xué)授課綱要授課節(jié)次:第_9_週上課課程主題: 期中考講授目的:

14、 期中評(píng)量授課綱要:分析化學(xué)授課綱要授課節(jié)次:第_10_週上課課程主題: Solving Equibrium Calculation for Complex System講授目的:複雜系統(tǒng)的平衡計(jì)算及應(yīng)用授課綱要:Solving Multiple-Equilibrium Problems by a Systematic Method Mass-Balance Equations Charge-Balance Equation Steps for Solving Problems Involving Several Equilibria Using Approximations to Solve

15、 Equilibrium Calculations Use of Computer Programs to Solve Multiple-Equilibrium ProblemsCalculating Solubilities by the Systematic Method The Solubility of Metal Hydroxides The Effect of pH on Solubility The Effect of Undissociated Solutes on Precipitation Calculations The Solubility of Precipitate

16、s in The Presence of Complexing AgentsSeparation of Ions by Control of the Concentration of the Precipitating Agent Calculation of the Feasibility of Separations Sulfide Separations 分析化學(xué)授課綱要授課節(jié)次:第_11_週上課課程主題: Gravimetric Methods of Analysis講授目的:重量分析法原理及應(yīng)用授課綱要:Precipitation Gravimetry Properties of P

17、recipitates and Precipitating Reagents Particle Size and Filterability of Precipitates Colloidal Precipitates Crystalline Precipitates CoprecipitationPrecipitation from Homogeneous Solution Drying and Ignition of PrecipitatesCalculation of Results from Gravimetric DataApplications of Gravimetric Met

18、hods Inorganic Precipitating Agents Reducing Agents Organic Precipitating Agents Organic Functional Group Analysis Volatilization Gravimetry分析化學(xué)授課綱要授課節(jié)次:第_12_週上課課程主題: Titrimetric Methods; Precipitation Titrimetry講授目的:容量及重量滴定法、沉澱滴定法原理及應(yīng)用授課綱要: Some Terms Used in Volumeric Titrimetry Equivalence Points

19、 and End Points Primary StandardsStandard SolutionsVolumetric Calculations Some Useful Algebraic Relationships Calculating the Molarity of Standard Solutions Treating Titration DataGravimetric Titrimetry Calculations Associated with Weight Titrations Advantages of Weight TitrationsTitration Curves i

20、n Titrimetric MethodsTypes of Titration CurvesConcentration Changes during TitrationsPrecipitation Titrimetry Precipitation Titration Curves Involving Silver Ion Titration Curves for Mixtures of Anions Indicators for Argentometric Titrations Applications of Standard Silver Nitrate Solutions分析化學(xué)授課綱要授

21、課節(jié)次:第_13_週上課課程主題: Principles of Neutralization Titration講授目的:酸鹼中和滴定理論及滴定曲線授課綱要: Solutions and Indicators for Acid/Base Titrations Standard Solutions Acid/Base Indicators Titration of Strong Acids and Strong Bases Titrating a Strong Acid with a Strong Base Titrating a Strong Base with a Strong Acid T

22、itration Curves for Weak Acids The Effect of Concentration The Effect of Reaction Completeness Choosing an Indicator: The Feasibility of Titration Titration Curves for Weak Bases The Composition of Solutions During Acid/Base Titrations 分析化學(xué)授課綱要授課節(jié)次:第_14_週上課課程主題: Titration Curves for Complex Acid/Bas

23、e Systems Application of Neutralization Titrations講授目的: 複雜酸鹼系統(tǒng)及酸鹼滴定的應(yīng)用授課綱要: Mixtures of Strong and Weak Acids or Strong and Weak BasesPolyfunctional Acids and Bases The Phosphoric Acid System The Carbon Dioxide Carbonic SystemBuffer Solutions Involving Polyprotic AcidsCalculation of the pH of Soluti

24、ons of NaHATitration Curves for Polyfunctional Acids and BasesTitration Curves for Amphiprotic SpeciesReagents for Neutralization Titrations Preparation of Standard Acid and Base Solutions The Standardization of Acids and BasesTypical Applications of Neutralization Titrations Elemental Analysis The

25、Determination of Inorganic Substances The Determination of Organic Functional Groups The Determination of Salts分析化學(xué)授課綱要授課節(jié)次:第_15_週上課課程主題: Complexation Reaction and Titrations講授目的:錯(cuò)合物生成滴定原理及應(yīng)用授課綱要: The Formation of Complexes Complexation Equilibria The Formation of Insoluble Species Ligands That Can

26、ProtonateTitrations with Inorganic Complexing AgentsOrganic Complexing AgentsAminocarboxylic Acid Titrations Ethylenediaminetetraacetic Acid (EDTA) Complexes of EDTA and Metal Ions Equilibrium Calculations Involving EDTA EDTA Titration Curves The Effect of Other Complexing Agents on EDTA Titration Curves Indicators for EDTA Titrations Titratio