海洋環(huán)境中銹層下碳鋼腐蝕行為的研究進展

1、 1,1,1,21.,266100;2.,110015:,.:;:TG172.5:A:10026495(201101009306Research Progress on Corrosion of Carbon Steels Under Rust Layerin Marine EnvironmentZHENG Ying-ying1,ZOU Yan1,WANG Jia1,21.College of Chemistry and Chemical Engineering,Ocean University of China,Qingdao266100;2.State Key Laboratory for

2、 Corrosion and Protection,Shenyang110015Abstract:Resaerch activities and progress on corrosion of carbon steel covered with rust layerin recent years were summarized,in particular,on the physicochemical properties of the rust,theelectrochemical characteristics of corrosion of steels beneath rust lay

3、er and the relations betweenrust and evolution of corrosion process Several inuencing factors on corrosion behavior of steelswere analyzed,and the trends of research in thiseld were also postulatedKey words:carbon steel;corrosion behavior;rust layer;marine environment,.,.,.,.,.94231:9596231:9798

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7、;Ä Æ . ܱ à 1 Melchers R E. Eect on marine immersion corrosion of carbon content of low alloy steels J. Corros. Sci., 2003, 45(11: 2609. 2 Melchers R E, Jerey R. Early corrosion of mild steel in seawater J. Corros. Sci., 2005, 47 (7: 1678. 3 Pineau S, Sabot R, Quillet L. For

8、mation of the Fe(IIIII hydroxysulphate green rust during marine corrosion of steel associated to molecular detection of dissimilatory sulphite-reductaseJ. Corros. Sci., 2008, 50(4: 1099. 4 Evans U R, Taylor C A J. Mechanism of atmospheric rusting J. Corros. Sci. 1972, 12(3: 227. 5 Stratmann M, Bohne

9、nkamp K, Engell H J. An electrochemical study of phase - transition in rust layers J. Corros. Sci., 1983, 23(9: 969. 6 Ma Y T, Li Y, Wang F H. The eect of -FeOOH on the corrosion behavior of low carbon steel exposed in tropic marine environmentJ. Mater. Chem. Phys., 2008, 112(3: 844. 7 14 15 16 

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11、Ú J. ¤ « , 2001, 13(2: 81 ÆÁ J. 8 ÙÂÌ, ²¤. Ï Ô¾¼ Ì Â ¤ « , 2000, 12(6: 315. 9 Ñ , ÙÂÌ, Ý . ̼§Ô¾¼ Ì J. § ÆÁ, 2002, (4: 14. ¸, 

12、0;Õ Ò. Ì ´Ì²Ì¼Ô¾¼ 10 ÖÑÒ, ´ º J. ÂÆ ¤ ­, 2007, 27(6: 321 11 Dillmann Ph, Mazaudier F, Hoerl´ S. Advances in undere standing atmospheric corrosion of iron. I. Rust characterisation of ancient ferr

13、ous artefacts exposed to indoor atmospheric corrosion J. Corros. Sci., 2004, 46(6: 1401. 12 Deliyanni E A, Bakoyannakis D N, Zouboulis A I, et al. Akagan´ite-type -FeO(OH nanocrystals: preparation e 27 28 29 30 31 and characterizationJ. Microporous Mesoporous Mater., 2001, 42(1: 49. Ohtsuka T,

14、Komatsu T. Enhancement of electric conductivity of the rust layer by adsorption of water J. Corros. Sci., 2005, 47(10: 2571. Hoerl´ S, Mazaudier F, Dillmann Ph, et al. Advances e in understanding atmospheric corrosion of iron.II. Mechanistic modelling of wet-dry cycles J. Corros. Sci., 2004, 46

15、(6: 1431. Qu D Y. Application of a.c. impedance technique to the study of the proton diusion process in the porous MnO2 electrode J. Electrochim. Acta, 2003, 48 (12: 1675. Memet J B, Girault P, Sabot R, et al. Electrochemical impedance spectroscopy of a free-standing oxide lm J. Electrochim. Acta, 2

16、002, 47(7: 1043. , , . J , 2006, 18(4: 269. , , . J. , 2001, 37(02: 193. Lair V, Antony H, Legrand L, et al. Electrochemical reduction of ferric corrosion products and evaluation of galvanic coupling with iron J. Corros. Sci, 2006, 48(8: 2050. Nishimura T, Katayama H, Noda K. Electrochemical behavio

17、r of rust formed on carbon steel in a wet/dry environment containing chloride ionsJ. Corrosion, 2000, 56(9: 935. . M. : , 1989: 164. Allam I M, Arlow J S, Saricimen H. Initial stages of atmospheric corrosion of steel in the Arabian GulfJ. Corros. Sci., 1991, 32(4: 417. , , . J. , 2006, 28(4: 6. Melc

18、hers R E. Eect of small compositional changes on marine immersion corrosion of low alloy steels J. Corros. Sci., 2004, 46(7: 1669. , , . 3 J. , 2002, 23(7: 288. Refait Ph, Memet J B, Bon C, et al. Formation of the Fe(II-Fe(III hydroxysulphate green rust during marine corrosion of steelJ. Corros. Sci

19、., 2003, 45(4: 833. Ona-Nguema G, Abdelmoula M, Jorand F, et al. Iron (II, III hydroxycarbonate green rust formation and stabilization from lepidocrocite bioreductionJ. Environ. Sci. Technol., 2002, 36(1, 16. , , . J. , 2007, 28(1: 17. . M. : , 1984: 230. Liu H, Wei Y, Sun Y H. The formation mechanism from ferrihydrite to hematite when Fe (II used as a catalyst J. J. Mol. Catal. A: Chem., 2005, 226(1: 135. Refait Ph, Abdelmoula M, G´nin J M R. Mechanisms of e formation and structure of g