有機(jī)化學(xué)(第二版)夏百根黃乾明主編課后答案

1、ch3-ch-ch2-ch2-ch2-ch3 Ch2第二章烷燒作業(yè)參考答案1、共有九種：CH3-CH2-CH2-CH2-CH2-CH2-CH3CH3-CH2-CH-CH2-CH2-CH3CH3CH3-CH-CH-CH2-CH3CH3CH3CH3-CH2-C-CH2-CH3iCH3CH3-CH-CH2-CH-CH31CH3CH3CH3CH3-CCH-CH3CH3Ch3CH3CH3-C-CH2-CH2-CH3CH3CH3-CH2-CH-CH2-CH2CH2-CH32、（1）3-甲基戊烷（2）2,（3）2,2,3,4-四甲基戊烷（6）順-1-甲基-3-乙基環(huán)戊烷（己烷5-二甲基-3,4-二乙基己烷（

2、4）2-甲基-5-乙基庚烷（5）2-甲基-3-環(huán)丁基丁烷7）反-1-甲基-4-乙基環(huán)己烷（8）1-甲基-4-乙基-3-叔丁基環(huán)3、(1)CH3-CH-CH2-CH2-CH3CH3(3)CH2CH31CH3-CH-CH-CH-CH-CH3CH3CH2CH3CH33(2)CH3-C-CH2CH3CH34、(1)CH3CH3CH2-C-CH-CH3CH3(2)CH3CH3CH3CH3-C-CH-CH-CH3CH3-CH-C-CH2-CH3cH3-C-CH2-CH-CH3CH3CH3CH3ch3CH3CH35、（1）錯(cuò)。改為：2,2-二甲基丁烷（2）錯(cuò)。改為：2,2,5-三甲基-4-乙基己烷（3）正確

3、（4）錯(cuò)。改為：2,2-二甲基丁烷6、（1）改為:3-甲基戊烷CH3CH2CHCH2CH3CH3CH(CH3)2yHH3c/、ClCH32,3-二甲基2-氯丁烷ClICH3-CH2-C-CH(CH)2CH3C2H5C2-C3旋轉(zhuǎn):優(yōu)勢構(gòu)象8、（1）CH2cH2cH39、(1)(2)(3)(4)10、B: CH3-CH 2-CH 2-CH 2-CH 3C: CH3-CH-CH2-CH3CH3CH3A：CH3-C-CH31CH311、(4)(1)(2)12、CH3cH2cH3CH3ABr2水A褪色:CH3ACH3cH2cH3(2)CH3-CH-CH2cH3Ic2H5IICH3H2so4CH3-CH

4、C1I.2C/一HC2HH3OSO。士2H3CH3-CH2-C32ICH3OH/H2cH2cH3第三章烯烽炊燒二烯烽習(xí)題參考答案1、（1）2-甲基-4-乙基-3-己烯（2）（Z）-3-甲基-2-戊烯（3）4-甲基-2-丙基-1-戊烯（4）（Z）-4-甲基-3-庚烯（5）2,2-二甲基-5-乙基-3-庚快（6）（E）-3-甲基-2-澳-2-戊烯（7）（2Z,4Z）-3,5-二甲基-2,4-庚二烯（8）3E-2,4-二甲基-1,3-己二烯2、（1）(2)(3)(4)(CH3)2C=C_CH2CH3Cl、.、/CH3.c=c、.CH2=C-CH=CH2CH3H3CHCH3ch2=ch-ch2-ch=

5、ch2H3c、尸3尸、HCH2cH2cH3L,CH3H3C、t=ct=C：、HHH3、Br2CH3-C=C-CH3-CC14CH3(2)CH3CCH-CH3B2/H2O11CH3CH3-C=CH-CH3CH3ICl.CH3CH3-C-CHCH3BrBrCH3CH3-CCH-CH3+OHBrCH3CH3-C-CH-CH3ClICH3CH3-C-CH-CH3BrBr(4)CH3-C=CH-CH3CH3HBr/過氧化物CH3aCH3-C-CH-CH3I1HBrCH3CH3-C=CH-CH3H2SO4.CH3-C一CH2-CH3iCH3OSO3HCH3H2OCH3-C-CH2-CH3OH(6)CH3-

6、q=CH-CH3KMnO4廣CH3-C=OCH3H+CH3+CH3COOHCH3-C=CH-CH3CH3H3%O，CHCH3H3Coo，H2O/ZnCH3-C=OCH3+CH3CHO4、（1）*CH3CH2CCH31ch3ch2c=ch-2+H2O/Hg2,KMnO4/H+Br+H1CH3CH2cch3O-CH3CH2COOH+CO2+Ag(NH3)+CH3cH2C=CH21CNHBr(2mol)BrH3c+HBrH3cH2OCH3-C=CH-CHCH3NaCl/H2OHBr*CH3CH3-CCH2-CH3+IBrCH3CH3-C-CH-CH31ClCH3+CH3-C-CH2-CH3OH(3)

7、CH2-CH=CH2ClCH2=CH-CH=CH 2Cl2CH3-CH=CH2CH2ClWj溫HCl(1mol)-CH3-CH=CH-CH2ClKMnO4/H+CH2=CH-CH=CH 2(1)03(2)H2O/ZnCO2 + 0=C-C=0CH2=CHCH0H2OCHOCH3-CH2-CH3CH2=CH-CH3CH=C-CH3abcKMnO4/H+卜京不褪色b,caAg(NH3)+無IJ白Jbc(2)CH3-CH2-aCH2=CH-CH2-CH2cH3bC三C-CH2-CH2CH3cCH2=CH-CH=CH-CH3dKMnO4/H不褪色褪色vb,c,dAg(NH3)24b,d順丁烯二酸酎Is

8、d,CH、oOHCCHCHCchIII一CH36、(1)CH3CH3C +CH3+CH3-CH-CH2-CH3 + CH3-CH-CH2CH3+ CH2=CHCH2 CH3CHCH3 CH3cH2cH+ CH3H3C-.(3)+ch2+CH 2 O2N2+ch27、用濃H2so48、(1)H3C, j=CH-CH 3H3C(2)CH3cHCH2cH=CH 2CH2CH3CH39、（3）、（4）具有一共軻體系；（2）具有缺電子的p共軻體系;（3）具有多電子的p共軻體系；（1）、（4）具有一共軻體系;10、(A)CH3A(B) CH3-CH2-CH-CH3(C) CH3cH2cH=CH2CH3(A

9、)CH3 HBr(B)CH3cH2cH-CH3 B, (C) CH3cH2CH=CH2 Br11、(A)CH3CH=CHCH(CH 3)2(B) CH3CH2CH=C(CH3)2(C)CH3CH2CH2CH(CH3)212、A:CH 3cH-CH2C=CHCH3B:CH3-C=CH2-CH=CH 2CH 313、CH2=CH CH3Cl2ClBr Br Cl1Br2CH2=CH CH2 *CH2-CH-CH2ch2=ch ch3ClICH2=CH CH2HBr BrClCH3-C-CHCH3C=CH(2)H2c屬于倍半葩H2O 正4(3) OCOOH屬于二葩O屬于倍半菇15、CH3X/C=CH

10、H3c一 ch2CH3一 ch2 c=ch -ch3第四章芳香煌作業(yè)參考答案1、1 , 4-二甲基泰(1)鄰硝基甲苯(2)3-羥基苯磺酸(3)3-甲基-4-氯苯甲酸(5)4-甲基-3-苯基-1-戊烯(6)6-氯-2-蔡酚2、(1)(2)(3)(4)(5)CH3NO2COOHNO2(6)CH=CH2ClSO3HClCH3CH(CH3)2CH2CH3H3coCO0HCl3、(1)COOHCl2.FeCOOHCl(2)CH3CiHNO3ClCH3H2SO4Clno2CH3+O2NCl(3)(9)ClCH(CH3)2Cl2C(CH3)2(4)OCH 3C-CH II OOCH3無水AlCl(CH3CO

11、)2O*3)3KMNOCH2CH3H+OHCOOHCOOH(5)CH2CH=CH21CH2CH3KMNO.H+CH3cH2cH2cH2cl+無水AlCl3CH3CH-CH2CH3CH2CH3HNO3H2sO：CH2CH3KMNOH+-NO2COOHBr2COOHBr4、ClCH3（1）OHNO2CH3Feno2NO2(2)CH3CH31COOHCHCOOHCOOHCOOH5、(1)CH3CH3KMnO4褪色:c不褪色:Br2(H2O)a,c1不褪色：a（2）CH2CH3CH=CHC=CH6、(1)Br2CC14一褪色:b,c.不褪色：aAg(NH3)2.無沉淀：b(2)(3)(4)(5)CH

12、3OHCOOHNHCOCH9、7、(1)無水A1C13CH3BrCH3KMNOh+COOHHNO3COOHNO2H2SO4(2)3Br2CH3AICI3CH3CICHFeBrKMnOBrH+COOHHNO3COOHH2SO4BrNO2(6)A1C13CH3CICH3CH3C1CH3A1C13CH3HNO3CHH2SO4CH3NO2COOHKMnONO2COOHH+8、有芳香性的是：(2),(4),(5),(8)CH3CH2CH310、第五章旋光異構(gòu)作業(yè)參考答案2、對：(6)(7)。錯(cuò)：(1)(2)(3)(4)(5)(8)3、有旋光性的為：(1)(2)(4)(5)4、(1)(2)(：H2BrH

13、-BrCH3CH3Cl2hBri-H1CH3 4(u 一：20HBrH 2Br -3-H(3)COOH 4H3cH3CHC2H5COOH2R ,3S-2,3,4-三羥基丁醛2S ,3R2,3-二澳丁 二酸)注：旋光異構(gòu)體的數(shù)目略。5、(1)R-氟氯澳甲烷(2)S-3-羥基-2-戊酮(3)(4)R-2-氨基-2-苯基乙酸(5)2R,3R-3-氯-2-丁醇1COOHBr-2-HBrH3COOH42R,3S-2,3二澳丁二酸6、(1)都是S-,所以是相同的。(2)分別為：2R,3S-和2s,3R-,所以是對映體關(guān)系(3)分別為：2R,3S-和2R,3R-,所以是非對映體關(guān)系(4)一個(gè)為R-,另一個(gè)為

14、S-,所以是對映體關(guān)系.A:7、8、CH3-CH2-CH-CH-CH 2-CH3OH 0HCC的構(gòu)型為:HHC2H5: 一 OH -OH C2H5OH0HCH3cH2-C-CH=CH2B：CH3cH2-c-CH2cH3Ch3CH3H2OCH3-CH2-CH=CH-CH2-CH3H.CH3-CH2-CH-CH2-CH2-CH3A24OHKMnO4/OHBd第六章鹵代炫習(xí)題參考答案1、（1）2-甲基-1-氯丙烷（伯鹵代烷）（2）2-甲基2-澳丁烷（叔鹵代烷）（3）2,2-二甲基4-澳戊烷（仲鹵代烷）（4）Z-2-甲基-1-澳-2-戊烯（烯丙基型）（5）Z（順）-3-甲基-2-氯-2-戊烯（乙烯型）

15、（6）3-甲基-4-澳-1-丁烯（隔離型鹵代燒）（7）對-氯甲苯（乙烯型）（8）1-苯基-1-澳丙烷（烯丙基型）2、(1)(3)(4)BrBr11CH3-CH-CH-CH3CH3(5)ClCH3CH3-CC-CH2-CH3ClCH3(6)(7)CH=CH-CH2CH=CH-CH2BrClx/H3C、CH3c=cC=CCCC、HQC、ClHHH3、(1)5a62a6abcCl(8)b快2慢褪色：dKMnO4C，d-A不褪色：C(7)CH2=CHClCH3-CH-CH-CH3iiCH3ClaCH3ICH2=CH-C-CH3ClcCH2=CH-CH-CH 3ClCH2=CH-CH-CH 3I4、(1

16、)CH2-CH-CH2CH3 IBr CH 3BrCH3-CH-CH-CH 3 CH3-C-CH2CH3 _CH3 BrCH3C先有黃色沉淀：CH2=CH-CH-CH3I先有白色沉淀：CH2=CH-CH-CH3ClBrICH3-C-CH3CH3-CH2-CH-CH3CH2-CH2-CH2CH3CH3BrBr(2)CH2cH2cH2cH3CH2cH2cH2cH3CH2-CH2-CH2CH3IBrClBrCH3-C-CH2cH3CH3-CH-CH-CH3CH2-CH-CH2CH3CH3CH3BrBrCH35、(1)BrICH3-CH-CH-CH3NaOHCH3CCH-CH3Br2CH3-C-CH-

17、CH3NaOH1 11.CH2=C-CH=CH2CH3CI乙醇，CH3CH3Br乙醇，ICH3(2)(3)小無水乙醍萬二(1)CO2萬飛：,_/CH2Br+MgA1二-CH2MgBr麗O_1_CH2COOHCH-CH3Na0HBr乙醇，_CH=CH2HBr_過氧化物:CH2-CH2一BrCH3ONa一-EL_CH2-CH2OCH3Br(5)CH3NaOH乙醇，_CH3KMnO4OIICH3-C-CH2-CH2-CH2-C-OH6、(1)CH2=CH2Br2NaCNBr-CH2-CH2-Br-而NC-CH2-CH2-CNH2OHOOC-CH2CH2-COOHH+(2)CH3-CH2-qH-CHB

18、r3NaOH:CH3-CH=CH-CH乙醇，3KMnO41ch3COOHH+(3)CH2=CH2(4)ACH3-CH2ClCH3-CH2-CH2cH3CH3-CH2cH2-ClNaOHHCl乙醇CH3-CH=CH2CH3-CH-CH3-ClNH3*-CH3-CH-CH3NH3CH2-CH-CH3IIBrCH3NaOHCH2=C-CH3乙醇，CH3BrHBr廣CH3-C-CH3CH3NaCN乙醇CN*CH3-C-CH3CH3H2OCOOHACH3-C-CH3CH3(6)CH3HBrCH3CH3cCH2-XCH3-CH-CH2Br過氧化物NaCN乙醇CH3ICH3-CH-CH2CN空CH3H+CH

19、3-CH-CH2COOHNaOH - CH3-C=CH-CH3 乙醇，一 CH38、A、CH3CHCH=CH2BrC、 CH2=CH-CH=CH27、CH3-CH-CH-CH3NaOH1 %JCH3Br乙醇，ACH3CCH-CH3HBr1.CH3BKMnOtCH3-C=O+H+CH38、 ChhCH-CHCHzBr11BrBrBCH3-C-CH2-CH31CH3CCH3COOH第七章醇酚醍習(xí)題參考答案1、（1） 4-基-2-己醇（2）2-甲基-2-丙烯基-3-戊烯-1-醇（3）2,4-己二醇（4） 3-環(huán)己烯-1-醇（5）4-苯基-2-戊醇（6）E-5-甲基-4-庚烯-3-醇（7） 4-甲基苯

20、酚（8）對甲氧基苯甲醇（9）苯乙醛（10）1,2-環(huán)氧丁烷2、(1)(2)CH3CH3-C-OH H3CO_CH3. CH20H(6)COOH6OH(3)OH p CH3(5)_ CH20H3、(1)(CH3)3C-OH+HBrSF紜C-Br+“O，、不無水ZnCl23(2)JOH+HCl(儂)-OCl(3)(4)(5)(6)OHICH3-CH-CH 2-CH-CH 3CH3K2Cr2O7A CH3-CH-CH 2-C-CH 3h+Ch 3CH3CH2CH2CH2-OH + SOCl2 CH3CH2CH2CH2-CICH3 OHH2so4CH3-CH-CH-CH 3 1700c濃H2SO4(8

21、)2CH2CH2CH3(9)BrH3C 一 .OH -工 H3c OHBrO+ CH3CH2CH2CH 20HCH2-CH2A1OH OCH(10)C-OHNaO -ONa 4 Ci 二.OH + CH3ICH3CH3CH3-Ch-O-CH3+HI(濃)CHCH3-CH-OH+CH3I4、(1) 1,4-丁二醇正辛醇3-己醇2-甲基-2-戊醇正己烷(2)碳酸鄰甲苯酚水苯甲醇苯甲醛2,4-二硝基苯酚鄰硝基苯酚苯酚鄰甲苯酚尊5、(1)CH3CH2OCH2CH3CH2-CH2CH2CH3CH2-CH2CH2CH3CH2-CH2CH=CH2BrOHOHcdAgNO3(2)(3)OHOHCH2-CH-C

22、H2OHOHOH白卜b無沉淀：a,無沉淀:abAg(NH3)c,Na廠dL無氣體放出：a_褪色：d有氣體放出：c,d生|K2Cr2O7a,b,c不褪色:一變綠快:變綠慢:不變色:Cu(OH)2110H不變色：CH2-CH-CH2顯深監(jiān)色：Oh0H0HOHFeC3不顯色:OH顯紫色:OH(4)6、分子間的氫鍵：（1）、（4）。分子內(nèi)的氫鍵：（2）、（3）7、（1）CH3cH2-CH2-CH20H-HBrCH3cH2-CH2-CH2BrNaCNH3O駐*CH3cH2cH2cH2cNCH3CH2CH2CH2COOHH2SO4CH3cH2-CH2-CH 20H* CH3CH2-CH=CH 2170OC

23、H2SO4h2o*- CH 3cH2fH-CH 3OHCuCH3CH2-C-CH30CH3CH2-CH2-CH2OHH2：4CH3CH2-CH=CH2170OCH2SO4CH3CH2-CH-CH3H2OOHH2SO4-CH3CH=CH-CH3170fbBr2CH3CH-CH-CH3NaOHCH2=CH-CH=CH2BrBrC2H5OH(4)CH3CH2-CH2-CH2OHH2SOCH3CH2-CH=CH2170OCH2SO4O3-O*-CH3CH=CH-CH3CH3CHOH2SO4ACH3CH2-CH-CH3H2OOH10、8、(1)CH3-CH2-CH2OHH2SO4CH3-CH=CH2SO

24、4.CH3-CH-CH3K2Cr2O4CH3COCH31700cH2OH+OH(2)二一OhU二ONa空里二.oc2H5(3)CH3CH2-CH-CH 3ClH2SO4HClCH3CH2-CH2-CH2OHCH3CH2-CH=CH21700cNaCN2CH3CH2-CH-CH3(4)CH3OH1700cCNH2SO4CH3KMnC4H+O*CH3-C-CH2CH2CH2COOH9、HIOH+CH3IOCH3CCH3IA；：“CH3ONO2+AgIC1、(1)(4)2、(1)CO2WOCH3cH2-CH2-CH20HHCl.CH3CH2-CH2-CH2CICH3CH2-CH-CH3ICl第八章醛

25、、酮、酶習(xí)題參考答案2-甲基丙醛3-甲基-2-丁酮(2)4-甲基-2-羥基苯甲醛(3)(5)2,4-己二酮(6)2-甲基5-甲基2一己烯醛4-戊酮-1-醛2-甲基-1,4-環(huán)己二酮(8)水合甲醛(3)ch3-ch2-ch-ch2-choCH3CH3-CH-CH2-C-CH312nCH3OBrC-CH3IIIO(5)(4)CH=N-OHch3-c=n-nh-CH3(6)-NNH-C-NH2O3、(1)OHCuCH3-CH-CH2CH3一CH3-C-CH2CH3HCNOHCNCH3-C-CH2-CH3H2OOHCOOHCH3-C-CH2-CH3O11CH3-C-CH2CH2CH3+O2NH2N-N

26、H-NO2O2NCH3-C=NNH-*H3CH2CH2CNO2無水乙醴CH3CH2CH2CHO+CH3CH2MgBr*OMgBrCH3CH2CH2CH-CH2CH3H2O/H+OH+CH3CH2CH2CH-CH2CH3(4)(CH 3)3CCHOa(CH3)3CCOO-+(CH3)3CCH20H濃OH-CHO+HCHOCH20H+HCOO(6)H2OCH=CHCH3CHOHgSO4H2SO4I2NaOHACI3CH0CHI3+HCOONaOHO (CH3)3C-C-CH3I2OII(CHhMC-C-O-+CHI3NaOH(8)HO-CH2-二2OiCH3CHOHOCH2zo干H+CH3cHjO

27、-(9)OH稀OH-2CH3CH2CHOCH3cH2cH-CH-CHOCH3CH3CH2CH=CrCHOCH3(10)O11C-CH3+(1)無水乙醛CH3MgBr；(2)H2O/H+OHC-CH3CH34、(1) cadb5、(1)(2)abdcCH2=CH2+H2O*H2sO4CH3CH2OHCu*-CH3CHO4稀OH-ACH3-CH=CH-CHOH2CH3-CH2CH2CH20HNi(2)OHCNOHCH3C-HOH-CH3CHCNOHH2O/H+1-CH3-CH-C00HHCHO無水乙醐MgHBrCH3CH=CH2CH3-CH2-CH2Br-CH3-CH2-CH2MgBrh2o2無水

28、乙醴H2OCH3-CH2-CH2-CH2-OMgBrCH3CH2CH2CH20H(4)稀OH-OHCH3CHOCHCH3CHCH2CHOHO-CH2HO-CH2一OHAch3Chch2chOO-CH2CH3CCH2CH一、O-CH2H2OHClOCH3CCH2CHOO-CH2KMnO4O-CH2u+HOHBrCH3CHCH3HB；CH3-CH-CHMg_筑水乙醛MgBrCH3-CH-CH3OHCuCH3CHCH3一八CH3CCH3無水乙醛廣H2O(6)二+CH3CH2-O-X星CH3CH2OHHBrCH3cH2BrNaOHCH3CH2CHCH3H2OOH(8)MgBrCH3-CH-CH3OHC

29、H3、/C-CH-CH3H3CCH3_O二C-CH2cH2cH3H2N-NH2,NaOH一.HOCH；CH2cH2cH2cH3NaCH3cH2cH2cH3CuCH3CH2CCH3二OCH3cH=CH2晅aCH3-CH2-CH2BrH2O2NaOHCl2*CH3cH2cHCH31Cl(1)CH3cH2MgBr/干醛(2)H2OCuOH1CH3cH2c-CH2cH3CH3CH3CH2CH2OH一ACH3-CH2CHOH2O-稀OH-CH3-CH2-CH=C-CHO-AlH4-CH3-CH2-CH=q-CH20HCH3CH36、(1)HCHOCH3CHObOCH3-C-CH3品紅試劑稀H顯紅色：a,

30、b一一，一iI不顯紅色：C，dNaOHd褪色：b不褪色:黃無OC-CH2-CH3(5)(2)CH3CH2cH2cH2cHOCH3C-CH2cH2cH3vCH3cH2-C-CH2cH3CH3cHCH2cH2cH3OHd苯腫b,dI2NaOH一無品紅試劑a,cb .-CHOHO不顯紅色：C(3)O4IC-CH3cFeCl3a,I2bNaOH黃土:bCH3-CH2cHOaI2NaOHOH2NOH7OCH3-CH2-C-CH-CH3CH3H2/NiNOH*CH3-CH2-C-CH-CH3CH3CH3cH2-CH-CH-CH3CH3COONa+CHI3黃OHCH3濃H2SO412/NaOH1rCH3CH

31、3-CH2-CH=C-CH3_(13CH3-CH2CHO+O=CCH3(2)Zn/H2OCH3+1Ag(NH3)2CH3-CH2COONH3Ag8、CH3KMnO4/H+CH3-C-CH2-CH2-CH=C-CH3ACH3（A也可以是：CH3-C=C-CH2CH2CHO）CH3ONCH3-C-CH2-CH2COOHB+CH3-C-CH3OI2/NaOHCH3-C-CH2-CH2COOHNaOOC-CH2CH2-COONaB9、+CHI3OOH1ABZn-HgHClCH2-CH 2-CH3HIOCH2-C-CH3（COH+CH3IOCH3ON-OHCH2-C-CH3CH2-C-CH3OOCH3O

32、CH3OOCH2-C-CH3CH2-C-ONaC潦H*+CHI31黃OCH3OCH3AOHOCH2cH-CH3CH2-C-ONaOH*C+CH|31黃OCH3OCH3B(3)第九章較酸、較酸衍生物及其衍生物作業(yè)參考答案1、(1)4-甲基-3-氯戊酸(2)(E)-2-羥基-3-戊烯酸(3)4-甲基1,3-苯二甲酸(4)4-甲氧基苯乙酰氯2-甲基順丁烯二酸酎(5)苯甲酸苯甲酯(6)-乙基-丁內(nèi)酰胺(8)2R,3S-3-甲基-2-羥基丁二酸單甲酯HO-CH-COOHOIIOII(9)HO-CH-COOHOIIC.NH(1。)CH3-C-CH2-C-OC2H(11)OllHOOC-C-CH2-COOH

33、(12)2、(1)OIIH-C-COOHaCOOHCOOHbHCOOHcCH3COOHdCH=CH-COOHAg(NH3)+一bc一無*Ag:a2,4一二硝基苯脫c無*:cCOOHCOOH1OHcFeC3不褪色：bIICH3-C-COOHCH3-C-CH3褪色：aCH3CH2COOH(3)(4)I2/NaOHO無J：c藍(lán)色石蕊試紙b變紅：a不變色：bCH3-CH2-C-CH2-CH3OCH3-C-CH2CH2CH3OIIOIICH3-C-CH2-C-CH3I2/NaOH無:c,:a,3、(1)丁烯二酸丁二酸丁酸不顯色:顯色：d飽和NaHSO3IbL無*:B(2)2-氟丙酸2-羥基丙酸丙酸2-甲

34、基丙酸(3)乙二酸氯乙酸苯甲酸乙酸丙酸CH=CHCH20HCH2CH2COOH4、(1)CH2cH20HCH2cH20HH2SO4h2o3注：(4)以下答案在下頁(4)(5)OHOHHCNCH3CCH2C1CH3CCH2C1H2O/H+CH3CCH2CIOHCNOHC(X)HCHjCCH2CNE。什CH3CCH2COOHCOOHOHC(X)H?CH3C-COOH濃HzSthCH3COH1) NaOHt (6)2) H+OHaCH?CH：COOH(8)(7)COOHCOOHCOOHO/00C(X)HCOOH(10)2cH3coOC2HsOO5%NnOH()IBH+CMCCH?CONaCH3C-C

35、H3(11)CHKH2c(X)HH-)2C()CH3CH2C(X)NHt-CH3CH2CONH2Hr2+Na()H-CH3ch2nh25.由指定原料合成目標(biāo)產(chǎn)物：(1)CH2-CH2*CH3cH20HCH2-CH2Br2/CCh產(chǎn)-產(chǎn)號BrBrCH2CHHzO/H*CH2CH2CNC(X)HC(X)H(8)2cHicH20H-一CH3CH2CXXCH2CH2CCX)CH2CH3(2) CHKHzOHKzCMA/H.蒸器CH3CHoJt CHaCH-CHCHOh2ch5ch2ch2ch2ohCH3CH2()H曾CH3cHzBr二CHCH2CN上性fCHjCH2coOHCH3cHzcH2cH20HH2SO4-CH3CH2C(X)CH2CH2CH2CH3ch3ch2ch-ch2 曾CHiCHjCHCH3NaCN*CH3CH2CH-CN乙醉Br(4)CH, 12 + NaOH柿 NaOHaCH?電上LCHiCHzCH-C(X)HCH3CH3CHCH3KzCrzO；CH3CCH3OHH,0CH3-C-CHCCH