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藥物分析專(zhuān)業(yè)詞匯緒論釋藥系統(tǒng)( drugdeliverysystem,DDS)中國(guó)藥典( ChinesePharmacopoeia,ChP)美國(guó)藥典(TheUnitedStatesPharmacopoeia,USP)美國(guó)國(guó)家處方集(TheNationalFormulary,NF)英國(guó)藥典(BritishPharmacopoeia,BP)歐洲藥典(EuropeanPharmacopoeia,Ph.Eup)國(guó)際藥典(TheInternationalPharmacopoeia,Ph.Int)良好藥品實(shí)驗(yàn)研究規(guī)范(GoodLaboratoryPractice,GLP)良好藥品生產(chǎn)規(guī)范 (GoodManufacturePractice,GMP)良好藥品供應(yīng)規(guī)范 (GoodSupplyPractice,GSP)良好藥品臨床試驗(yàn)規(guī)范 (GoodClinicalPractice,GCP)分析質(zhì)量管理 (AnalyticalQualityControl,AQC)第1章藥物的鑒別試驗(yàn)藥物的鑒別試驗(yàn) identificationtest一般鑒別試驗(yàn) generalidentificationtest專(zhuān)屬鑒別試驗(yàn) specificidentificationtest靈敏度sensitivity最低檢出量 minimumdetectablequantity最低檢出濃度 minimumdetectableconcentration第2章藥物的雜質(zhì)檢查巰基醋酸mercaptoaceticacid古蔡Gutzeit二乙基二硫代氨基甲酸銀 siliverdiethyldithio-carbamate硫酸灰分sulphatedash熾灼殘?jiān)黵esidueonignition熱重分析法 thermogravimetricanalysis,TGA差示熱分析法 differentialthermalanalysis,DTA差示掃描量熱法 differentialscanningcalorimetry,DSC堿性酒石酸銅試驗(yàn) Fehling’sreagent異紅紫酸鹽 isopurpurate2,3-二氨基萘2,3-diaminonaphthalene4,5-苯并苯硒二唑 4,5-benzopiazselenol第三章定量分析樣品前處理與測(cè)定方法的效能指標(biāo)汞齊化法amalgamationmethod氧瓶燃燒法 oxygenflaskcombustionmethod葡萄糖醛酸甙 glucuronides硫酸酯sulphates血漿plasma血清serum全血wholeblood治療藥物濃度監(jiān)測(cè)therapeuticdrugmonitoring,TDM結(jié)合bound游離free綴合物 conjugate液-液提取法 liquid-liquidextraction,LLE離子對(duì)試劑ionpairreagent離子對(duì)提取法 ionpairextractionmethod反離子 counter液-固提取法 liquid-solidextractionLSE半自動(dòng)樣品制備系統(tǒng) advancedautomatedsampleprocessor,AASP烷基化 alkylations酰基化 acylations硅烷化 silylations精密度 precision標(biāo)準(zhǔn)差 standarddeviation,SDorS相對(duì)標(biāo)準(zhǔn)差relativestandarddeviation,RSD變異系數(shù)coefficientofvariation,CV批內(nèi)精密度 within-runprecision日內(nèi)精密度 within-dayprecision批間精密度 between-runprecision日間精密度 daytodayprecision準(zhǔn)確度 accuracy定量限 limitofquantitation,LOQ檢測(cè)限 limitofdetection,LOD選擇性 selectivity專(zhuān)屬性 specificity線性與范圍 linearityandrange重現(xiàn)性 ruggedness耐用性 robustness散布圖 scatterdiagram熒光偏振免疫測(cè)定法 fluorescencepolarizationimmunoassay,F(xiàn)PIA第4章巴比妥類(lèi)藥物的分析溴化十六烷基三甲基芐銨 cetyltrimethylbenzylammoniumbromide,CTMA氯化四癸基二甲基芐銨 Tetradacyldimethybenzylammonium chloride,TDBA第5章芳酸及其酯類(lèi)藥物的分析苯甲酸及其鈉鹽 benzoicacidandsodiumbenzoate布美他尼 bumetanide羥苯乙酯 ethylparoben丙磺舒probenecid酚黃乙胺 etamsylate第6章胺類(lèi)藥物的分析第七章雜環(huán)類(lèi)藥物的分析二硝基氯苯反應(yīng)Vongerichten反應(yīng)戊烯二醛反應(yīng)K?nig反應(yīng)第8章生物堿類(lèi)藥物的分析生物堿 alkaloids阿片gumopium掃尾劑 tailing-suppressing reagent蒂巴因 thebaine諾司卡品 noscapine競(jìng)爭(zhēng)離子 competingions親脂性 lipophicity拖尾因子tailingfactor金剛烷 adamantane第9章維生素類(lèi)藥物的分析維生素 vitamin去氫維生素 Adehydroretinol去水維生素 Aanhydroretinol鯨醇kitol三氯化銻反應(yīng)Carr-Price反應(yīng)維生素B1thiaminehydrochloride;鹽酸硫胺TTC2,3,5-三苯基氯化四氮唑 2,3,5-triphenyltetrazoliumchloridTTC紅四氮唑 redtetrazoline,RT藍(lán)四氮唑 bluetetrazoline,BT3,3’-二甲基氧苯基-雙-4,4’-(3,5-二苯基)氯化四氮唑{3,3’-dianisole-bis[4,4’-(3,5-dipheny)tetrazoliumchloride]}有色甲 formazan鐵-酚試劑 iron-phenolreagent鐵-柯柏試劑 iron-Koberreagent第十一章 抗生素類(lèi)藥物的分析氨基青霉烷酸 6-aminopenicillanicacid,6-APA氨基頭孢菌烷酸 7-aminocephalosporanicacid,7-ACA氨芐西林ampicillin5-甲基-3-鄰氯苯基-4-異 口坐青霉素鈉cloxacillinsodium羥氨芐青霉素amoxicillin氨基糖甙類(lèi)抗生素 aminoglycosidesantibiotics鏈霉素 streptomycin麥芽酚 maltolN-甲基葡萄糖胺反應(yīng)Elson-Morgan反應(yīng)坂口反應(yīng) Sakaguchi 反應(yīng)慶大霉素 gentamycin四環(huán)素類(lèi) tetracyclines4-差向脫水四環(huán)素 4-ejpianhydrotetracycline,EATC第十二章藥物制劑分析含量均勻度 contentuniformity溶出度dissulution離子對(duì)高效液相色譜法 ion-pair,HPLC第十三章生化藥物分析概論第十四章 中藥制劑分析概論超臨界流體萃取 supercriticalfluidextraction,SFE過(guò)弗羅里 Florisil第十五章 藥品質(zhì)量標(biāo)準(zhǔn)的制定國(guó)際非專(zhuān)利藥名InternationalNamesforPharmaceuticalSubstancesINN去氧麻黃堿 Metamfetaminum國(guó)際理論和應(yīng)用化學(xué)聯(lián)合會(huì) InternationalUnionofPureandAppliedChemistry,IUPAC有機(jī)化學(xué)命名原則NomenclatureofOrganicChemistry可待因Codeinum地塞米松Dexamethasonum氯 Chloroquinum青蒿素 Artemisininum嗎啡Morphinum苯扎溴銨BenzalkoniiBromidum1-(3,4-二羥苯基)-2-氨基乙醇重酒石酸鹽一水合物[1-(3,4-Dihydroxyphenyl)-2-AminoethanolBitartratemono-hydrate]第十六章藥品質(zhì)量控制中的新方法與新技術(shù)填充柱 packedcolumn開(kāi)管柱 opentubularcolumn空心柱 capillarycolumn熔融石英開(kāi)管柱 fusedsilicaopentubularcolumn,F(xiàn)SOT高分辨率氣相色譜法 highresolutiongaschromatography,HRGC壁涂開(kāi)管柱 wall-coatedopentubularcolumn,WCOT柱固定化相開(kāi)管柱 immobilizedphaseopentubularcolumn ,IPOT柱交聯(lián)柱 crosslinkingcolumn鍵合相柱bondingphasecolumn不可提取相開(kāi)管柱 nonextractablephaseopentubularcolumn,NPOT柱多孔層開(kāi)管柱 porous-layeropentubularcolumn,PLOT柱擔(dān)體涂漬開(kāi)管柱 support-coatedopentubularcolumn,SCOT柱分流進(jìn)樣 splitinjection不分流進(jìn)樣 splitlessinjection柱頭進(jìn)樣 on-columninjection直接進(jìn)樣 directinjection手性分離色譜 chiralseparationchromatography , CSC普萘洛爾 propranolol沙粒度胺 thalidomide測(cè)定對(duì)映體 enantiomer手性固定化 chiralstationaryphase,CSP手性衍生試劑 chiralderivatizationreagent ,CDR非對(duì)映異構(gòu)體 diastereoisomer,DSTM配基交換型手性添加劑chiralligand-exchangecomplexes,CLEC手性離子對(duì)絡(luò)合劑chiralionpaircomplex,CIPC環(huán)糊精cyclodextrins,CD葡聚糖 sephadex配基交換劑ligandexchanger手性傳荷chargetransfer(R)-N-3,5-二硝基苯甲酰苯基苷氨酸 dimitrobenzylphenylglycin;DNBPG三點(diǎn)手性識(shí)別模式 three-pointchiralrecognitionmodel噻嗎洛爾thimololtrofosfamide乙酰葡萄糖異硫氰酸酯(2,3,4,6-tetra-O-acetyl-伊D-glucopyranosylisothiocyanate,GITC左旋比喹酮 L-praziquantel比喹胺 praziquanamine苯丙胺 phenylpropamine異氟酸-a-蔡酯(a-naphthylisocyanae,NI美西律 mexiletine氯胺酮 ketamine本芴醇 benflumelol苯丙醇 phenylpropanol烯丙洛爾 alprenolol普萘洛爾 propranolol氧烯洛爾 oxyprenolol麻黃堿 ephedrine毛細(xì)管電泳 capillaryelectrophoresis ,CE毛細(xì)管區(qū)帶電泳 capillaryzoneelectrophoresis,CZE膠束動(dòng)電毛細(xì)管色譜 mcellarelectrokineticcapillarychromatography ,MECC膠束動(dòng)電色譜 miccellarelectrokineticchromatography,MEKC環(huán)糊精動(dòng)電色譜 cyclodextrinselectrokineticchromatography,CDEKC離子交換動(dòng)電色譜 ion-exchangeelectrokineticchromatography,IEEKC微滴乳狀液動(dòng)電色譜 microemulsionelectrokineticchromatography ,MEEKC毛細(xì)管凝膠電泳 capillarygelelectrophoresis,CGE毛細(xì)管等電聚焦capillaryisoelectricfocusing,CIEF毛細(xì)管等速電泳 capillaryisotachorphoresis,CITP毛細(xì)管電色譜 capillaryelectrochromatography,CEC色譜響應(yīng)函數(shù) chromatographicresponsefunction,CRF色譜優(yōu)化函數(shù) chromatographicoptimizationfunction,COF等級(jí)色譜響應(yīng)函數(shù) hierarchicalchromatographicresponsefunctionHCRF差示分光光度法 differencespectrophotometry近紅外光譜 nearinfra-redspectrum,NIRS中紅外光譜 midinfra-redspectrum ,MIRS合譜combinations光譜匹配法 spectralmatching匹配指數(shù)matchindex,M.I.主成分分析法 principalcomponentregression,PCR人工神經(jīng)網(wǎng)絡(luò)方法artificialneuralnetworks,ANN核磁共振nuclearmagneticresonance,NMR二維NMRtwodimensionalNMR六甲基三硅氧烷 hexamethylcyclotrisiloxane吡嗪pyrazine普魯卡因procaine色譜聯(lián)用技術(shù) hyphenatedtechniqueschromatography ,HTC接口interface重建色譜圖 reconstructivechromatogram命中質(zhì)量系數(shù) hitqualityindex,HQI最小二乘方程序leastsquaresalgothm導(dǎo)數(shù)絕對(duì)值程序absolutederivativealgothm導(dǎo)數(shù)平方程序 squarederivativealgothm空心柱opentubularcolumn,OTC總離子流totalioncarrent,TIC選擇性離子監(jiān)測(cè) xelectedionmonitoring ,SIM多離子檢測(cè)multipleiondetection,MID質(zhì)量碎片圖譜法 massfragmentography冰片borneal川芎嗪tetramethyloyrazine,TMP電子轟擊離子化 electronimpactionization,EI化學(xué)離子化 chemicalionization,CI場(chǎng)解吸 fielddesorption ,EI快原子轟擊 fastatombombardment,F(xiàn)AB熱噴霧 thermospray, TSP電噴霧 electrospray, ESP大氣壓離子化atmosphericpressureionization,API粒子束接口particalbeam動(dòng)態(tài)快原子轟擊法 FAB離子噴霧接口ISP電子噴霧法 ESP大氣壓離子化接口API大氣壓化學(xué)電離 APCI串聯(lián)質(zhì)譜 MS-MS麗江山慈姑 IphigeniaindicaKunthetBenth托非索泮 tofisopam儀器常用詞匯玻璃漏斗Glassfunnellongstem試管testtubetesttubebrushtesttubeholdertesttuberack蒸發(fā)皿 evaporatingdishsmall燒杯beaker錐形瓶 Erlenmeyer量筒 gradcylinder洗瓶 plasticwashbottle勺皿casserole,smallstopperedflask分液漏斗separaloryfunnelwaterbath/oilbathstrringbarmagneticstirrer冷凝器 condenserBallastbottle圓頸燒瓶 Round-buttomflask試劑瓶 reagentbottles托盤(pán)天平 platformbalance 臺(tái)秤0.1g托盤(pán)pan指針刻度表 pointerandscalecrossbeamsandslidingweights游碼分析天平 two-pan/single-pananalyticalbalance滴定管 burette glass bead(basic) nozzle移液管 pipette 胖肚 elongated glassbulb洗耳球 rubber suctionbulb玻棒 glassrod玻璃活塞 stopcock容量瓶 pyknowmeterflasks比重瓶 (one-mark)volumetricflasks胖肚吸管 one-markpipette刻度吸管 graduatedpipettesClass“A”highergradeClass”B”lowergradeMlmillilitreEx—thepipettehasbeenadjustedtodeliveritsindicatedcapacityEx+15swaitingtime摘自(1).6-32. E4735.ISOInternationalOrgnizationForStandardizationLab.GlasswareandRelatedApparatus.第一章緒論分析化學(xué): analyticalchemistry定性分析: qualitativeanalysis定量分析: quantitativeanalysis物理分析: physicalanalysis物理化學(xué)分析:physico-chemicalanalysis儀器分析法:instrumentalanalysis流動(dòng)注射分析法:flowinjectionanalysis ;FIA順序注射分析法:sequenticalinjectionanalysis;SIA化學(xué)計(jì)量學(xué): chemometrics第二章誤差的分析數(shù)據(jù)處理絕對(duì)誤差: absoluteerror相對(duì)誤差: relativeerror系統(tǒng)誤差: systematicerror可定誤差: determinateerror隨機(jī)誤差:accidentalerror不可定誤差:indeterminateerror準(zhǔn)確度: accuracy精確度: precision偏差:debiation,d平均偏差:averagedebiation相對(duì)平均偏差: relativeaveragedebiation標(biāo)準(zhǔn)偏差(標(biāo)準(zhǔn)差):standerddeviation;S相對(duì)標(biāo)準(zhǔn)偏差: relatibestandarddeviation;RSD變異系數(shù): coefficientofvariation誤差傳遞: propagationoferror有效數(shù)字: significantfigure置信水平: confidencelevel顯著性水平:levelofsignificance合并標(biāo)準(zhǔn)偏差(組合標(biāo)準(zhǔn)差):pooledstandarddebiation舍棄商:rejectionquotient;Q化學(xué)定量分析第三章滴定分析概論滴定分析法:titrametricanalysis滴定:titration容量分析法 :volumetricanalysis化學(xué)計(jì)量點(diǎn): stoichiometricpoint等當(dāng)點(diǎn):equivalentpoint電荷平衡: chargebalance電荷平衡式: chargebalanceequation質(zhì)量平衡: massbalance物料平衡:materialbalance質(zhì)量平衡式: massbalanceequation第四章酸堿滴定法酸堿滴定法: acid-basetitrations質(zhì)子自遞反應(yīng): autoprotolysisreaction質(zhì)子自遞常數(shù): autoprotolysisconstant質(zhì)子條件式 :protonbalanceequation酸堿指示劑: acid-baseindicator指示劑常數(shù): indicatorconstant變色范圍: colourchangeinterval混合指示劑: mixedindicator雙指示劑滴定法:doubleindicatortitration第五章非水滴定法非水滴定法:nonaqueoustitrations質(zhì)子溶劑: protonicsolvent酸性溶劑: acidsolvent堿性溶劑: basicsolvent兩性溶劑:amphototericsolvent無(wú)質(zhì)子溶劑: aproticsolvent均化效應(yīng): differentiating effect區(qū)分性溶劑: differentiatingsolvent離子化:ionization離解: dissociation結(jié)晶紫:crystalviolet茶酚苯甲醇:-naphthalphenolbenzylalcohol奎哪啶紅:quinadinered百里酚藍(lán):thymolblue偶氮紫: azoviolet溴酚藍(lán): bromophenolblue第六章配位滴定法配位滴定法:compleximetry乙二胺四乙酸:ethylenediaminetetraaceticacid,EDTA螯合物:chelatecompound金屬指示劑:metallochromeindcator第七章氧化還原滴定法氧化還原滴定法:oxidation-reductiontitration碘量法: iodimetry溴量法: bromimetry]溴量法: brominemethod鈰量法: cerimetry高錳酸鉀法:potassiumpermanganatemethod條件電位: conditionalpotential溴酸鉀法: potassiumbromatemethod硫酸鈰法: ceriumsulphatemethod偏高碘酸: metaperiodicacid高碘酸鹽: periodate亞硝酸鈉法: sodiumnitritemethod重氮化反應(yīng): diazotizationreaction重氮化滴定法: diazotizationtitration亞硝基化反應(yīng):nitrozationreaction亞硝基化滴定法:nitrozationtitration外指示劑:externalindicator外指示劑:outsideindicator重鉻酸鉀法: potassiumdichromatemethod第八章沉淀滴定法沉淀滴定法: precipitationtitration容量滴定法: volumetricprecipitationmethod銀量法:argentometricmethod第九章重量分析法重量分析法:gravimetricanalysis揮發(fā)法:volatilizationmethod引濕水(濕存水):waterofhydroscopicity包埋 (藏)水:occludedwater吸入水: waterofimbibition結(jié)晶水: waterofcrystallization組成水: waterofcomposition液-液萃取法:liquid-liquidextration溶劑萃取法:solventextration反萃?。篶ounterextraction分配系數(shù):partitioncoefficient分配比: distributionratio離子對(duì)(離子締合物):ionpair沉淀形式: precipitationforms稱(chēng)量形式: weighingforms《分析化學(xué)》下冊(cè)儀器分析概述物理分析:physicalanalysis物理化學(xué)分析:physicochemicalanalysis儀器分析:instrumentalanalysis第十章電位法及永停滴定法電化學(xué)分析:electrochemicalanalysis電解法:electrolyticanalysismethod電重量法:electtogravimetry庫(kù)侖法: coulometry庫(kù)侖滴定法: coulometrictitration電導(dǎo)法: conductometry電導(dǎo)分析法: conductometricanalysis電導(dǎo)滴定法: conductometrictitration電位法: potentiometry直接電位法: dirextpotentiometry電位滴定法: potentiometrictitration伏安法: voltammetry極譜法: polarography溶出法: strippingmethod電流滴定法: amperometrictitration化學(xué)雙電層: chemicaldoublelayer相界電位: phaseboundarypotential金屬電極電位:electrodepotential化學(xué)電池: chemicalcell液接界面: liquidjunctionboundary原電池: galvaniccell電解池: electrolyticcell負(fù)極:cathrode正極:anode電池電動(dòng)勢(shì): eletromotiveforce指示電極: indicatorelectrode參比電極: referenceelectroade標(biāo)準(zhǔn)氫電極: standardhydrogenelectrode一級(jí)參比電極: primaryreferenceelectrode飽和甘汞電極: standardcalomelelectrode銀-氯化銀電極:silversilver-chlorideelectrode液接界面:liquidjunctionboundary不對(duì)稱(chēng)電位:asymmetrypotential表觀 PH值:apparentPH復(fù)合 PH電極:combinationPHelectrode離子選擇電極:ionselectiveelectrode敏感器: sensor晶體電極 :crystallineelectrodes均相膜電極: homogeneousmembranceelectrodes非均相膜電極: heterogeneousmembranceelectrodes非晶體電極: non-crystallineelectrodes剛性基質(zhì)電極: rigidmatrixelectrode流流體載動(dòng)電極:electrodewithamobilecarrier氣敏電極:gassensingelectrodes酶電極: enzymeelectrodes金屬氧化物半導(dǎo)體場(chǎng)效應(yīng)晶體管:MOSFET離子選擇場(chǎng)效應(yīng)管:ISFET總離子強(qiáng)度調(diào)節(jié)緩沖劑:totalionstrengthadjustmentbuffer,TISAB永停滴定法: dead-stoptitration雙電流滴定法(雙安培滴定法):doubleamperometrictitration第十一章光譜分析法概論普朗克常數(shù): Plankconstant電磁波譜: electromagneticspectrum光譜: spectrum光譜分析法:spectroscopicanalysis原子發(fā)射光譜法:atomicemissionspectroscopy質(zhì)量譜: mass spectrum質(zhì)譜法: mass spectroscopy,MS第十二章 紫外-可見(jiàn)分光光度法紫外-可見(jiàn)分光光度法:ultravioletandvisiblespectrophotometry;UV-vis肩峰: shoulderpeak末端吸收:endabsorbtion生色團(tuán): chromophore助色團(tuán): auxochrome紅移: redshift長(zhǎng)移: bathochromicshift短移: hypsochromicshift藍(lán)(紫)移:blueshift增色效應(yīng)(濃色效應(yīng)): hyperchromiceffect減色效應(yīng)(淡色效應(yīng)): hypochromiceffect強(qiáng)帶: strongband弱帶: weakband吸收帶: absorptionband透光率: transmitance,T吸光度:absorbance譜帶寬度:bandwidth雜散光: straylight噪聲:noise暗噪聲: darknoise散粒噪聲: signalshotnoise閃耀光柵: blazedgrating全息光柵: holographicgraaing光二極管陣列檢測(cè)器:photodiodearraydetector偏最小二乘法:partialleastsquaresmethod,PLS褶合光譜法: convolutionspectrometry褶合變換:convolutiontransform,CT離散小波變換: wavelettransform,WT多尺度細(xì)化分析:multiscaleanalysis供電子取代基: electrondonatinggroup吸電子取代基: electronwith-drawinggroup第十三章熒光分析法熒光:fluorescence熒光分析法:fluorometryX-射線熒光分析法:X-rayfulorometry原子熒光分析法: atomicfluorometry分子熒光分析法: molecularfluorometry振動(dòng)弛豫:vibrationalrelexation內(nèi)轉(zhuǎn)換: internalconversion外轉(zhuǎn)換: externalconversion體系間跨越:intersystemcrossing激發(fā)光譜: excitationspectrum熒光光譜: fluorescencespectrum斯托克斯位移: Stokesshift熒光壽命: fluorescencelifetime熒光效率: fluorescenceefficiency熒光量子產(chǎn)率: fluorescencequantumyield熒光熄滅法:fluorescencequemchingmethod散射光: scatteringlight瑞利光: Reyleithscantteringlight拉曼光: Ramanscatteringlight第十四章紅外分光光度法紅外線: infraredray,IR中紅外吸收光譜:mid-infraredabsorptionspectrum,Mid-IR遠(yuǎn)紅外光譜:Far-IR微波譜: microwavespectrum,MV紅外吸收光譜法: infraredspectroscopy紅外分光光度法: infraredspectrophotometry振動(dòng)形式: modeofvibration伸縮振動(dòng): stretchingvibration對(duì)稱(chēng)伸縮振動(dòng): symmetricalstretchingvibration不對(duì)稱(chēng)伸縮振動(dòng):asymmetricalstretchingvibration彎曲振動(dòng): bendingvibration變形振動(dòng): formationvibration面內(nèi)彎曲振動(dòng):in-planebendingvibration,0剪式振動(dòng):scissoringvibration, 6面內(nèi)搖擺振動(dòng):rockingvibration,面外彎曲振動(dòng):out-of-planebendingvibration,面外搖擺振動(dòng): waggingvibration,⑴蜷曲振動(dòng): twistingvibration, r對(duì)稱(chēng)變形振動(dòng): symmetricaldeformationvibration, 6s不對(duì)稱(chēng)變形振動(dòng):asymmetricaldeformationvibration,6as特征吸收峰 :charateristicavsorptionband特征頻率: characteristicfrequency相關(guān)吸收峰:correlationabsorptionband雜化影響: hybridizationaffect環(huán)大小效應(yīng):ringsizeeffect吸收峰的強(qiáng)度:intensityofabsorptionband環(huán)折疊振動(dòng): ringprckeringvibration第十五章原子吸收分光光度法原子光譜法: atomicspectroscopy原子吸收分光光度法: atomicabsorptionspectrophotometry,AAS原子發(fā)射分光光度法: atomicemmsionspectrophotometry,AES原子熒光分光光度法: atomicfluorescencespectrophotometry,AFS第十六章核磁共振波譜法核磁共振:nuclearmagneticresonance,NMR核磁共振波譜:NMRspectrum核磁共振波譜法:NMRspectroscopy掃場(chǎng): sweptfield掃頻: seeptfrequency連續(xù)波核磁共振: continuouswaveNMR,CWNMRFourier變換NMR:PFT-NMR,FT-NMR二維核磁共振譜: 2D-NMR質(zhì)子核磁共振譜:protonmagneticresonancespectrum,PMR氫譜:1H-NMR碳-13核磁共振譜:13C-NMRspectrum,13CNMR自旋角動(dòng)量:spinangularmomentum磁旋比: magnetogyricratio磁量子數(shù):magneticquantumnumber,m進(jìn)動(dòng): precession弛豫歷程: relaxationmechanism局部抗磁屏蔽:localdiamagneticshielding屏蔽常數(shù): shieldingconstant化學(xué)位移: chemicalshift國(guó)際純粹與應(yīng)用化學(xué)協(xié)會(huì):IUPAC磁各向異性: magneticanisotropy遠(yuǎn)程屏蔽效應(yīng):longrangeshieldingeffect結(jié)面: nodalplane自旋-自旋偶合: spin-spincoupling自旋-自旋分裂: spin=spinsplitting單峰: singlet,s雙峰: doublet,d三重峰: triplet,t四重峰: quartet五重峰: quintet六重峰: sextet偕偶: geminalcoupling鄰偶: vicinalcoupling遠(yuǎn)程偶合:longrangecoupling磁等價(jià): magneticeqivalence自旋系統(tǒng): spinsystem一級(jí)光譜: firstorderspectrum二級(jí)光譜(二級(jí)圖譜):secondorderspectrumC-H光譜: C-Hcorrelatedspectroscopy,C-HCOSY第十七章質(zhì)譜法質(zhì)譜分析法:massspectrometry質(zhì)譜: massspectrum,MS棒圖: bargraph選擇離子檢測(cè):selectedionmonitoring,SIM直接進(jìn)樣:directprobeinlet,DPI接口:interface氣相色譜-質(zhì)譜聯(lián)用:gaschromatography-massspectrometry,GC-MS高效液相色譜-質(zhì)譜聯(lián)用:highperformanceliquidchromatography-massspectrometry,HPLC-MS電子轟擊離子源:electronimpactsource,EI離子峰: quasi-molecularions化學(xué)離子源: chemicalionizationsource,CI場(chǎng)電離: fieldionization,FI場(chǎng)解析: fielddesorptiion,FD快速原子轟擊離子源:faststombombardment,FAB質(zhì)量分析器: massanalyzer磁質(zhì)譜儀: magnetic-sectormassspectrometer四極桿質(zhì)譜儀(四極質(zhì)譜儀):quadrupolemassspectrometer原子質(zhì)量單位 :amuionabundance相對(duì)豐度(相對(duì)強(qiáng)度 ):relativeavundance基峰: basepeak質(zhì)量范圍:massrange分辨率: resolution靈敏度: sensitivity信噪比: S/N分子離子: molecularion碎片離子: fragmention同位素離子:isotopicion亞穩(wěn)離子: metastableion亞穩(wěn)峰: metastablepeak母離子: parenion子離子: daughter含奇數(shù)個(gè)電子的離子: oddelectron含偶數(shù)個(gè)電子的離子: eveneletron,EE均裂:homolyticcleavage異裂(非均裂):heterolyticcleavage半均裂:hemi-homolysiscleavage重排:rearragement分子量: MWa一裂解:a-cleavage第十八章 色譜分析法概論色譜法(層析法): chromatography固定相: stationaryphase流動(dòng)相: mobilephase超臨界流體色譜法: SFC高效毛細(xì)管電泳法: highperformancecapillaryelectroporesis,HPEC氣相色譜法: gaschromatography,GC液相色譜法: liquidcromatography,LC超臨界流體色譜法: supercriticalfluidchromatography,SFCTOC\o"1-5"\h\z氣-固色譜法: GSC氣-液色譜法: GLC液-固色譜法: LSC液-液色譜法: LLC柱色譜法: columnchromatography填充柱:packedcolumn毛細(xì)管柱: capillarycolumn微填充柱: icroborepackedcolumn高效液相色譜法:highperformanceliquidchromatography,HPLC平板色譜法: planar平板色譜法: planechromatography紙色譜法: paperchromatography薄層色譜法:thinlayerchromatography,TLC薄膜色譜法 ;thiinfilmchomatography毛細(xì)管電泳法:capillaryelectrophoresis,CE分配色譜法: partitionchromatography吸附色譜法: adsorpionchromaography離子交換色譜法: ionexchangechromatography,IEC空間排阻色譜法: stericexclusionchromatography,SEC親和色譜法:affinitychromatography分配系數(shù): distributioncofficient狹義分配系數(shù):partitioncoefficient凝膠色譜法:gelchromatography凝膠滲透色譜法: gelpermeationchromatography,GPC凝膠過(guò)濾色譜法: gelfiltrationchromatography,GFC滲透系數(shù): permeationcoefficien;Kp化學(xué)鍵合相色譜法:chemicallybonded-phasechromatography分配系數(shù): distributioncoefficient靛菁綠:indocyanine氣相色譜-傅立葉變換紅外光譜:GC-FTIR第十九章 經(jīng)典液相色譜法薄層色譜法:TLC吸附: adsorption活化: activation脫活性: deactivation交聯(lián)度: degreeofcross linking交換容量: exchangecapacity薄層板: thinlayerplate展開(kāi)劑: developingsolvent ,developer臨界膠束濃度:criticakmicolleconcentration,CMC相對(duì)比移值:relativeRf,Rr分離度:resolution,R分離數(shù): separationnumber,SN煅石膏: Gypsum羧甲基纖維素鈉:CMC-Na吸收光譜聯(lián)用:TLC-UV薄層色譜-熒光聯(lián)用:TLC-F薄層色譜-紅外吸收光譜聯(lián)用:TLC-IR薄層色譜法: TLC-MS紙色譜法: paperchromatography上行展開(kāi): ascendingdevelopment下行法展開(kāi): descendingdevelopment雙向展開(kāi): twodimensionaldeveloooment第二十章氣相色譜法氣相色譜法: gaschromatography前延峰: leadingpeak拖尾峰: tailingpeak對(duì)稱(chēng)因子: symmetr
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