建立礦井水化學(xué)數(shù)據(jù)庫技術(shù)標(biāo)準(zhǔn)

礦井水化學(xué)數(shù)據(jù)庫建立方法1范圍本標(biāo)準(zhǔn)規(guī)定了在建立礦井水化學(xué)數(shù)據(jù)庫時對水化學(xué)檢測項(xiàng)目及資料整理的要求、水樣采集處理和項(xiàng)目檢測要求，適用于相關(guān)單位在建立礦井水化學(xué)數(shù)據(jù)庫時參考。2規(guī)范性引用文件下列文件對于本文件的應(yīng)用是必不可少的。凡是注日期的引用文件，僅所注日期的版本適用于本文件。凡是不注日期的引用文件，其最新版本（包括所有的修改單）適用于本文件?！睹旱V安全規(guī)程》（國家安監(jiān)總局令第87號）《煤礦地質(zhì)工作規(guī)定》（安監(jiān)總煤調(diào)〔2013〕135號）《煤礦防治水細(xì)則》（煤安監(jiān)調(diào)查〔2018〕14號）GB／T8538飲用天然礦泉水檢驗(yàn)方法MT／T672煤礦水害防治水化學(xué)分析方法MT／T201煤礦水中氯離子的測定方法MT／T202煤礦水中鈣離子的測定方法MT／T203煤礦水中鈣離子和鎂離子的測定方法MT／T204煤礦水堿度的測定方法MT／T205煤礦水中硫酸根離子的測定方法MT／T206煤礦水硬度的測定方法3水化學(xué)檢測項(xiàng)目及資料整理要求3.1將水質(zhì)分析做為礦井日常水文地質(zhì)基礎(chǔ)性工作及礦井防治水的一種重要手段。目前從煤礦水害防治角度出發(fā)，水化學(xué)分析檢測內(nèi)容可選擇常量離子分析；微量元素分析。3.2水質(zhì)分析按目的、要求不同，可分為簡分析、全分析和專門分析。在對各含水層、已知出水點(diǎn)有充足的水質(zhì)全分析資料，地下水的水質(zhì)特征清楚時，對日常的水質(zhì)監(jiān)測可進(jìn)行簡分析，但必須包括：Na++k+、Ca2+、Mg2+、HCO3-、SO42-、CL-、PH值、耗氧量、總硬度、干涸殘余物及物理性質(zhì)。水質(zhì)全分析和專門分析需要到專業(yè)水質(zhì)檢測中心進(jìn)行，水質(zhì)簡分析可利用水質(zhì)快速檢測分析儀進(jìn)行測試。水化學(xué)檢測項(xiàng)目3.3資料整理要求3.3.1應(yīng)將水樣編號、分析編號、采集地點(diǎn)、時間、含水層、標(biāo)高、出水形式、涌水量、水溫、分析要求、采樣人及備注等記載在送樣單里。3.3.2主要陰陽離子分析結(jié)果用mg／L、meq／L和meq/L％表示?！芀(陽離子meq總量)和∑A(陰離子meq總量)分析結(jié)果應(yīng)接近平衡。4水樣采集4.1各礦應(yīng)建立地下水動態(tài)觀測網(wǎng)，對地表水體、井、泉，井下各出水點(diǎn)及礦井水進(jìn)行日常性觀測，水質(zhì)監(jiān)測按季度進(jìn)行，且每年豐、枯水期各1次，井下出水點(diǎn)水量增大應(yīng)及時加密監(jiān)測。井下所有新增加的出水點(diǎn)必須及時采取水樣進(jìn)行水質(zhì)化驗(yàn)。4.2水源井、地面、井下水文孔施工必須對目的含水層取水樣進(jìn)行水質(zhì)全分析，無水質(zhì)分析資料不得通過終孔驗(yàn)收。4.3采取水樣前，必須將水樣瓶洗滌干凈，并在采樣時用采取水樣的水再次沖洗。水樣采取數(shù)量：簡分析樣：1-1.5L，全分析樣：2.5-3L。5水化學(xué)數(shù)據(jù)庫5.1各礦井必須建立和完善水質(zhì)分析成果臺帳，并實(shí)現(xiàn)計(jì)算機(jī)數(shù)據(jù)庫管理。水質(zhì)化驗(yàn)原始報(bào)告單必須歸檔管理，長期保存。5.2將不同時間充水水源的水質(zhì)數(shù)據(jù)匯總在礦井水化學(xué)數(shù)據(jù)庫表。參照附錄A。5.3將所有的水質(zhì)數(shù)據(jù)進(jìn)行系統(tǒng)性的整理、分析、對比，掌握各種充水水源的水質(zhì)類型及水化學(xué)成分特點(diǎn)，計(jì)算陰陽離子含量及標(biāo)準(zhǔn)值，繪制柱狀圖。參照附錄B。形成不同充水水源的水質(zhì)數(shù)據(jù)庫（即已知充水水源的水質(zhì)樣本），以實(shí)現(xiàn)未知水源的快速、準(zhǔn)確判別。

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礦井水化學(xué)數(shù)據(jù)庫表XX煤礦（填寫地層名稱）水質(zhì)數(shù)據(jù)庫地層名稱水樣地點(diǎn)每升水中含量陽離子陰離子水質(zhì)資料來源K++Na+Ca2+Mg2+Fe3+Fe2+NH4+Al3+合計(jì)Cl-SO42-HCO3-CO32-NO3-NO2-F-合計(jì)毫克毫克毫克毫克毫克平均毫克XX煤礦山西組8#煤層以上頂板水水質(zhì)數(shù)據(jù)庫地層取樣地點(diǎn)每升水中含量陽離子陰離子水質(zhì)資料來源K++Na+Ca2+Mg2+Fe3+Al3+NH4+合計(jì)Cl-SO42-HCO3-CO32-NO3-NO2-合計(jì)山西組8#煤層以上頂板水中頂板水毫克97.20153.3090.600.10.10.1341.40216.20196.90552.200.000.10.336965.40落山水毫克82.97108.0767.370.040.012.3257.06160.07172.05398.550.001.600.97732.27頂板水毫克91.92166.8184.950.020.191.24345.13233.00190.98540.040.000.000.20964.22頂板水毫克142.6651.1830.760.000.001.07225.67152.76107.02237.0620.212.2610529.31。。毫克。。。。。。。。。。。。。。。。。。。。。。。。。。。。。。平均毫克130.3082.5943.280.170.052.36258.75140.15109.08427.976.433.381.47688.49XX煤礦太原組13#煤層以上頂板水水質(zhì)數(shù)據(jù)庫地層取樣地點(diǎn)每升水中含量陽離子陰離子水質(zhì)資料來源K++Na+Ca2+Mg2+Fe3+Al3+NH4+合計(jì)Cl-SO42-HCO3-CO32-NO3-NO2-合計(jì)山西組13#煤層以上頂板水頂板水毫克97.20153.3090.600.10.10.1341.40216.20196.90552.200.000.10.336965.40落山水毫克82.97108.0767.370.040.012.3257.06160.07172.05398.550.001.600.97732.27頂板水毫克91.92166.8184.950.020.191.24345.13233.00190.98540.040.000.000.20964.22頂板水毫克142.6651.1830.760.000.001.07225.67152.76107.02237.0620.212.2610529.31毫克。。。。。。。。。。。。。。。。。。。。。。。。。。。。平均毫克99.80101.3557.080.280.101.18259.79115.58123.20490.640.552.150.05732.17XX煤礦太原組13#煤層底板水水質(zhì)數(shù)據(jù)庫地層取樣地點(diǎn)每升水中含量陽離子陰離子水質(zhì)資料來源K++Na+Ca2+Mg2+Fe3+Al3+NH4+合計(jì)Cl-SO42-HCO3-CO32-NO3-NO2-合計(jì)山西組13#煤層底板水底板水毫克147.80136.3079.600.101.30365.10326.10258.60297.500.001.700.367884.27底板裂隙水毫克97.3383.7559.870.000.091.52242.56111.5583.97520.280.000.440.04716.28材料巷交匯處底板毫克72.25100.2067.280.030.040.12239.92168.42167.32442.060.007.080.11784.99平均毫克105.79106.7568.920.040.070.98282.55202.02169.96419.950.003.070.17795.18XX煤礦礦區(qū)及周邊采空區(qū)水質(zhì)數(shù)據(jù)庫地層取樣地點(diǎn)每升水中含量陽離子陰離子水質(zhì)資料來源K++Na+Ca2+Mg2+Fe3+Al3+NH4+合計(jì)Cl-SO42-HCO3-CO32-NO3-NO2-合計(jì)礦區(qū)及周邊采空區(qū)工作面皮帶機(jī)尾積水毫克126.14133.6056.470.000.190.52316.92259.94247.37205.050.000.230.25712.84工作面涌水（53#點(diǎn)前38米）毫克115.7497.8757.000.000.181.59272.20197.56198.39278.470.004.3217.5696.24工作面舊巷毫克81.7076.4858.470.000.080.56217.29123.2933.75489.990.000.330.07647.43皮帶上山前52米毫克120.88238.1896.580.00450.140.59456.3787.15762.08449.790.000.050.011299.08采區(qū)皮帶上山毫克153.45220.4474.660.020.150.88449.6072.18724.64374.520.000.110.011171.46…………平均值毫克137.73227.52143.740.860.104.07514.03158.25771.68529.360.003.831.511464.62XX煤礦地表水水質(zhì)數(shù)據(jù)庫地層取樣地點(diǎn)每升水中含量陽離子陰離子水質(zhì)資料來源K++Na+Ca2+Mg2+Fe3+Al3+NH4+合計(jì)Cl-SO42-HCO3-CO32-NO3-NO2-合計(jì)地表水嵐漪河水

（地表水）毫克16.9841.8919.660.8579.3813.7023.87188.3710.598.700.13245.36嵐漪河水

（地表水）毫克13.946.115.80.175.91619.218097.50.028231.728嵐漪河水

（地表水）毫克28.838.124.991.833.7103.3115.96258.9嵐漪河水

（地表水）毫克24.4771.0233.120.79129.421.5451.85186.43017.39277.21平均值毫克21.0449.2823.370.5894.2721.2449.56167.686.4011.200.08256.14XX煤礦奧陶系峰峰組灰?guī)r水水質(zhì)數(shù)據(jù)庫地層名稱水樣地點(diǎn)每升水中含量陽離子陰離子水質(zhì)資料來源K++Na+Ca2+Mg2+Fe3+Fe2+NH4+Al3+合計(jì)Cl-SO42-HCO3-CO32-NO3-NO2-F-合計(jì)奧陶系峰峰組灰?guī)r水2403水文孔毫克84.5075.2048.00＜0.1＜0.10.80208.50134.70189.70225.800.001.200.011.00552.41《0204水文孔毫克42.8075.2027.40＜0.1＜0.1＜0.1145.4039.0096.10274.600.0012.000.010.40422.10SK04水文孔毫克83.5096.2031.001.300.100.10212.2037.2076.80503.400.001.300.660.80620.20SK05水文孔毫克102.303.004.90＜0.1＜0.10.30110.5016.0028.8082.4066.0015.000.060.80209.10SK06水文孔毫克208.1022.0018.20＜0.1＜0.10.60249.00234.00168.1045.8012.000.40＜0.0080.40460.70SK07水文孔毫克227.5023.0023.70＜0.1＜0.10.40274.6021.30245.00353.9012.002.300.061.60636.16SK08水文孔毫克116.8019.0014.60＜0.1＜0.10.20150.6051.4093.70204.4018.006.001.200.40375.10………………平均值毫克118.9456.5028.060.220.120.66204.5077.86124.88294.3213.385.380.170.89516.88XX煤礦奧陶系峰峰組加上馬家溝組灰?guī)r水水質(zhì)數(shù)據(jù)庫地層名稱水樣地點(diǎn)每升水中含量陽離子陰離子水質(zhì)資料來源K++Na+Ca2+Mg2+Fe3+Fe2+NH4+Al3+合計(jì)Cl-SO42-HCO3-CO32-NO3-NO2-F-合計(jì)奧陶系峰峰組加上下馬家溝組灰?guī)r水0403水文孔毫克121.40134.3034.00＜0.1＜0.10.50290.20196.70276.20201.400.00＜0.10.021.10675.400204水文孔毫克26.8078.2023.10＜0.1＜0.1＜0.1128.1021.3098.50262.400.007.00＜0.0080.60389.80SK02水文孔毫克84.40131.3045.00＜0.10.100.40261.2092.20156.10482.100.001.60＜0.0081.10733.10SK06水文孔毫克221.6033.1035.30＜0.10.102.30292.40212.70194.50231.906.001.101.221.60649.00SK07水文孔毫克85.4077.2034.00＜0.1＜0.10.10196.7042.5091.30436.300.002.500.040.80573.40SK10水文孔毫克214.3062.1038.90＜0.1＜0.14.00319.30141.80134.50512.600.005.000.011.60795.50平均值毫克125.6586.0335.050.100.101.23248.16117.87158.52354.451.002.880.221.13636.070403水文孔毫克121.40134.3034.00＜0.1＜0.10.50290.20196.70276.20201.400.00＜0.10.021.10675.40…………………平均值毫克125.6586.0335.050.100.101.23248.16117.87158.52354.451.002.880.221.13636.07XX煤礦奧陶系上下馬家溝組灰?guī)r水水質(zhì)數(shù)據(jù)庫地層名稱水樣地點(diǎn)每升水中含量陽離子陰離子水質(zhì)資料來源K++Na+Ca2+Mg2+Fe3+Fe2+NH4+Al3+合計(jì)Cl-SO42-HCO3-CO32-NO3-NO2-F-合計(jì)奧陶系上下馬家溝組灰?guī)r水Xs-3孔毫克32.6681.7427.300.000.220.12142.0423.74136.65251.410.008.210.15420.16Xs-5供井水毫克19.34103.7025.770.070.350.30149.5327.40170.81218.944.975.051.25428.42ZS1井毫克54.50265.5065.70＜0.1＜0.1＜0.1385.7081.50703.60253.200.005.000.051.201044.55ZS2水井毫克92.30165.3053.50＜0.1＜0.1＜0.1311.10239.30295.40247.100.000.000.040.70782.54ZS2水井毫克80.24140.3949.290.100.89270.91124.90254.21245.300.004.050.20628.66ZS3水井毫克63.50122.6038.70＜0.1＜0.1＜0.1224.8088.60255.70279.300.002.900.161.10627.76…………………平均值毫克125.6586.0335.050.100.101.23248.16117.87158.52354.451.002.880.221.13636.07XX煤礦奧陶系上馬家溝組灰?guī)r水水質(zhì)數(shù)據(jù)庫地層名稱水樣地點(diǎn)每升水中含量陽離子陰離子水質(zhì)資料來源K++Na+Ca2+Mg2+Fe3+Fe2+NH4+Al3+合計(jì)Cl-SO42-HCO3-CO32-NO3-NO2-F-合計(jì)奧陶系上馬家溝組灰?guī)r水Xs-3孔毫克26.3890.4827.840.040.220.14145.1063.9982.32266.240.005.790.35418.69Xs-7孔毫克26.8081.2324.010.030.240.20132.5122.5199.61268.020.007.790.20398.13平均值毫克26.5985.8625.930.040.230.17138.8143.2590.97267.130.006.790.28408.41

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陰陽離子含量及標(biāo)準(zhǔn)值柱狀圖XX煤礦（地層水）陰陽離子含量及標(biāo)準(zhǔn)值柱狀圖地層每升水中含量（毫克）陽離子陰離子K++Na+Ca2+Mg2+Fe3+Fe2+NH4+合計(jì)Cl-SO42-HCO3-CO32-NO3-NO2-F-合計(jì)標(biāo)準(zhǔn)值取值范圍XX煤礦山西組8#煤層以上頂板水陰陽離子含量及標(biāo)準(zhǔn)值柱狀圖山西組8#煤層以上頂板水陰陽離子含量標(biāo)準(zhǔn)值及取值范圍每升水中含量（毫克）陽離子陰離子K++Na+Ca2+Mg2+Fe3+Al3+NH4+合計(jì)Cl-SO42-HCO3-CO32-NO3-NO2-合計(jì)標(biāo)準(zhǔn)值130.3082.5943.280.170.052.36258.75140.15109.08427.976.433.381.47688.49取值范圍51.42～296.377.57～166.812.3～90.600～0.80～0.190.1～10.72111.67～345.1315.94～281.299.57～262.28183.52～617.030～42.890～11.180～10266.54～965.4XX煤礦山西組13#煤層以上頂板水陰陽離子含量及標(biāo)準(zhǔn)值柱狀圖太原組13#煤層以上頂板水陰陽離子含量標(biāo)準(zhǔn)值及取值范圍每升水中含量（毫克）陽離子陰離子K++Na+Ca2+Mg2+Fe3+Al3+NH4+合計(jì)Cl-SO42-HCO3-CO32-NO3-NO2-合計(jì)標(biāo)準(zhǔn)值99.80101.3557.080.280.101.18259.79115.58123.20490.640.552.150.05732.17取值范圍71.06～146.3848.89～205.1524.53～93.810～1.920.04～0.170.28～2.43157.87～403.4845.33～256.9450.57～360.47345.25～727.650～17.050.02～6.590.01～0.16451.4～1153.38XX煤礦山西組13#煤層底板水陰陽離子含量及標(biāo)準(zhǔn)值柱狀圖太原組13#煤層底板水陰陽離子含量標(biāo)準(zhǔn)值及取值范圍每升水中含量（毫克）陽離子陰離子K++Na+Ca2+Mg2+Fe3+Al3+NH4+合計(jì)Cl-SO42-HCO3-CO32-NO3-NO2-合計(jì)標(biāo)準(zhǔn)值105.79106.7568.920.040.070.98282.55202.02169.96419.950.003.070.17795.18取值范圍72.25～147.883.75～136.359.87～79.60～0.1０.04～0.090.12～1.52239.92～365.1111.55～326.1083.97～258.6297.5～520.2800.44～7.080.04～0.367716.28～884.27XX煤礦礦區(qū)及周邊采空區(qū)陰陽離子含量及標(biāo)準(zhǔn)值柱狀圖采空區(qū)水陰陽離子含量標(biāo)準(zhǔn)值及取值范圍每升水中含量（毫克）陽離子陰離子K++Na+Ca2+Mg2+Fe3+Al3+NH4+合計(jì)Cl-SO42-HCO3-CO32-NO3-NO2-合計(jì)標(biāo)準(zhǔn)值137.73227.52143.740.860.104.07514.03158.25771.68529.360.003.831.511464.62取值范圍67.6～237.781～545.3837.34～342.82０～4.470～0.190.52～33.89217.29～983.6572.18～259.9433.75～2241.32205.05～840.030.02～10.930.01～17.5647.43～2768.53XX煤礦礦區(qū)地表水陰陽離子含量及標(biāo)準(zhǔn)值柱狀圖地表水陰陽離子含量標(biāo)準(zhǔn)值每升水中含量（毫克）陽離子陰離子K++Na+Ca2+Mg2+NH4+合計(jì)Cl-SO42-HCO3-CO32-NO3-NO2-合計(jì)標(biāo)準(zhǔn)值21.0449.2823.370.5894.2721.2449.56167.686.4011.200.08256.14取值范圍13.9～28.838.1～71.0215.8～33.120.1～0.8575.9～129.413.7～33.719.2～103.3115.9～188.376～10.597.5～17.390.028～0.13231.728～277.21XX煤礦奧陶系峰峰組灰?guī)r水陰陽離子含量及標(biāo)準(zhǔn)值柱狀圖奧陶系峰峰組灰?guī)r水水陰陽離子含量標(biāo)準(zhǔn)值及取值范圍每升水中含量（毫克）陽離子陰離子K++Na+Ca2+Mg2+Fe3+Fe2+NH4+合計(jì)Cl-SO42-HCO3-CO32-NO3-NO2-F-合計(jì)標(biāo)準(zhǔn)值118.9456.5028.060.220.120.66204.5077.86124.88294.3213.385.380.170.89516.88取值范圍42.80～227.503～127.304.90～45.600.10～1.300.10～0.400.10～4.0097.5～304.316.00～234.0026.40～269.0045.80～518.700.00～66.000.10～15.000.008～1.200.20～1.60188.40～853.91XX煤礦奧陶系峰峰組+上馬家溝組灰?guī)r水陰陽離子含量及標(biāo)準(zhǔn)值柱狀圖奧陶系峰峰組+上馬家溝組灰?guī)r水陰陽離子含量標(biāo)準(zhǔn)值及取值范圍每升水中含量（毫克）陽離子陰離子K++Na+Ca2