GB/T 44244-2024質(zhì)子交換膜燃料電池汽車(chē)用氫氣一氧化碳、二氧化碳的測(cè)定氣相色譜法

ICS27.010

CCSF19

中華人民共和國(guó)國(guó)家標(biāo)準(zhǔn)

GB/T44244—2024

質(zhì)子交換膜燃料電池汽車(chē)用氫氣

一氧化碳、二氧化碳的測(cè)定

氣相色譜法

Hydrogenforprotonexchangemembranefuelcellvehicles—Determinationof

carbonmonoxideandcarbondioxide—Gaschromatographymethod

2024?07?24發(fā)布2024?11?01實(shí)施

國(guó)家市場(chǎng)監(jiān)督管理總局

國(guó)家標(biāo)準(zhǔn)化管理委員會(huì)發(fā)布

GB/T44244—2024

目次

前言··························································································································Ⅲ

1范圍·······················································································································1

2規(guī)范性引用文件········································································································1

3術(shù)語(yǔ)和定義··············································································································1

4原理·······················································································································1

5試劑與材料··············································································································2

6儀器與設(shè)備··············································································································2

7試驗(yàn)步驟·················································································································2

8試驗(yàn)數(shù)據(jù)處理···········································································································3

9精密度和正確度········································································································4

10質(zhì)量保證和控制······································································································5

11試驗(yàn)報(bào)告···············································································································5

附錄A（資料性）典型氣相色譜儀氣路流程和操作條件························································6

附錄B（資料性）精密度典型值·······················································································8

參考文獻(xiàn)·····················································································································9

Ⅰ

GB/T44244—2024

前言

本文件按照GB/T1.1—2020《標(biāo)準(zhǔn)化工作導(dǎo)則第1部分：標(biāo)準(zhǔn)化文件的結(jié)構(gòu)和起草規(guī)則》的規(guī)

定起草。

請(qǐng)注意本文件的某些內(nèi)容可能涉及專(zhuān)利。本文件的發(fā)布機(jī)構(gòu)不承擔(dān)識(shí)別專(zhuān)利的責(zé)任。

本文件由全國(guó)氫能標(biāo)準(zhǔn)化技術(shù)委員會(huì)（SAC/TC309）提出并歸口。

本文件起草單位：中石化石油化工科學(xué)研究院有限公司、中國(guó)標(biāo)準(zhǔn)化研究院、廣州能源檢測(cè)研究

院、四川中測(cè)標(biāo)物科技有限公司、北京國(guó)氫中聯(lián)氫能科技研究院有限公司、中國(guó)計(jì)量科學(xué)研究院、中國(guó)

測(cè)試技術(shù)研究院、中石化（大連）石油化工研究院有限公司、中國(guó)石化銷(xiāo)售股份有限公司河北石油分公

司、國(guó)家能源集團(tuán)氫能科技有限責(zé)任公司、北京集思泰科分析技術(shù)有限公司、浙江福立分析儀器有限公

司、安捷倫科技（中國(guó)）有限公司、大連大特氣體有限公司、島津企業(yè)管理（中國(guó)）有限公司、氫跡技術(shù)

（上海）有限公司、中國(guó)科學(xué)院上海應(yīng)用物理研究所、山東能源集團(tuán)煤氣化新材料科技有限公司。

本文件主要起草人：王亞敏、張祎瑋、楊燕梅、徐廣通、秦平、劉季業(yè)、萬(wàn)燕鳴、劉聰敏、胡樹(shù)國(guó)、鄧凡鋒、

杜利鋒、周魯立、薛楊、錢(qián)有、王小偉、趙全友、王浩、李婉、耿朝陽(yáng)、翟明昌、劉安東、王建強(qiáng)、邢濤。

Ⅲ

GB/T44244—2024

質(zhì)子交換膜燃料電池汽車(chē)用氫氣

一氧化碳、二氧化碳的測(cè)定

氣相色譜法

警示：氫氣是一種易燃易爆氣體。本文件不涉及與其應(yīng)用有關(guān)的所有安全問(wèn)題。在使用本文件

前，使用者有責(zé)任制定相應(yīng)的安全和保護(hù)措施，明確其限定的適用范圍，并保證符合國(guó)家有關(guān)法律法

規(guī)、強(qiáng)制性國(guó)家標(biāo)準(zhǔn)的規(guī)定。

1范圍

本文件描述了采用氣相色譜?氦離子化檢測(cè)器測(cè)定質(zhì)子交換膜燃料電池汽車(chē)用氫氣中一氧化碳和

二氧化碳含量的原理、試劑與材料、儀器與設(shè)備、試驗(yàn)步驟、試驗(yàn)數(shù)據(jù)處理、精密度和正確度、質(zhì)量保證

和控制、試驗(yàn)報(bào)告。

本文件適用于質(zhì)子交換膜燃料電池汽車(chē)用氫氣中一氧化碳和二氧化碳含量的測(cè)定，其他用途氫氣

中含量范圍在本文件規(guī)定范圍內(nèi)一氧化碳和二氧化碳含量的測(cè)定參照?qǐng)?zhí)行。

一氧化碳測(cè)定范圍為0.05μmol/mol~10.0μmol/mol；二氧化碳測(cè)定范圍為0.05μmol/mol~

10.0μmol/mol。

2規(guī)范性引用文件

下列文件中的內(nèi)容通過(guò)文中的規(guī)范性引用而構(gòu)成本文件必不可少的條款。其中，注日期的引用文

件，僅該日期對(duì)應(yīng)的版本適用于本文件；不注日期的引用文件，其最新版本（包括所有的修改單）適用于

本文件。

GB/T43306氣體分析采樣導(dǎo)則

GB/T44244質(zhì)子交換膜燃料電池汽車(chē)用氫氣采樣技術(shù)要求

JJF1342標(biāo)準(zhǔn)物質(zhì)研制（生產(chǎn)）機(jī)構(gòu)通用要求

3術(shù)語(yǔ)和定義

本文件沒(méi)有需要界定的術(shù)語(yǔ)和定義。

4原理

將試樣導(dǎo)入配置三閥三柱的氣