工業(yè)有機(jī)廢氣(VOCs)處理方法及設(shè)備

1、創(chuàng)新與品質(zhì)并重ursue innovation and quality環(huán)保與效益同行Care environme nt and ben efit青島華世潔環(huán)?？萍加邢薰?Http:/ E mail:saleshuashijie com cn 通訊地址：青島市經(jīng)濟(jì)技術(shù)開發(fā)區(qū)六盤山路16號(hào) 郵編:266510電話:86頁:86保工程新能源新材料 化工設(shè)備為您提供最佳解決方案Provide the best solution for von幫助您不斷成功Assist you to continuously win05 /Environme

2、ntal Protection EquipmentsP環(huán)保設(shè)備04Structure of Productionfl產(chǎn)端構(gòu)03PartncrsRescarch & Manufacturing Strength我們的合作伙伴研發(fā).制造能力Introduction公司簡(jiǎn)介01Content環(huán)保設(shè)備Environmental Protection Equipments吸附回收（還原性處理方式）Adsorption Recovery吸附概述Introduction to Adsorption活性炭纖維吸附回收設(shè)備ACF Adsorption Recovery Equipments活性炭吸附回收設(shè)備AC

3、 Adsorption Recovery Equipments油氣回收設(shè)備Oil Gas Recovery Equipments吸附濃縮Adsorption Condensation熱氧化處理魚Thermal Oxidation TreatmentTO&CTOT0&CTORTO(RCO)設(shè)備RTO Equipments兩床RTOTwo-bed RTO三床RTOThree-bed RTO旋轉(zhuǎn)式RTORotary RTOPE設(shè)備PE Equipments煤多聯(lián)產(chǎn)Coal Poly-generation化工設(shè)備壓力容器Chemical Equipment-Pressure Vessel公司簡(jiǎn)介Qin

4、gdaoHuashij ie =4島華世潔壞保科技有限公司創(chuàng)建于2001年，是傢依靠自I：研發(fā)、技術(shù)創(chuàng)新發(fā)展起來 自 的高新技術(shù)企業(yè)。公司經(jīng)過名年的發(fā)展逐步形成以環(huán)保設(shè)備為龍頭，新材料、新能源為兩翼，化工設(shè)備為后盾的產(chǎn)業(yè)結(jié)構(gòu)組建了一支從研發(fā)到制作、施工的專業(yè)團(tuán)隊(duì)。專業(yè)有索的隊(duì)伍、認(rèn)其負(fù)責(zé)的態(tài)度、粘益求粘的品丿貞得到了客戶的認(rèn)可，也幫助了我們的發(fā)展。同時(shí)多次獲得國家、當(dāng)?shù)卣姆龀峙c獎(jiǎng)勵(lì).我們秉信“創(chuàng)新與品質(zhì)并重,壞保與效益同行”的理念，從客戶的角度出發(fā),不斷創(chuàng)新、改進(jìn)我們的設(shè)備，不斷滿足客戶的蠱求，不斷幫助客戶成功。愿攜手各方有志之士共同努力,讓中華、出界更加淸潔,讓生活更加美好!公司發(fā)展里程

5、碑2004年9月：公司注冊(cè)成立2005年11月：公司產(chǎn)值超過1000萬2006年3刀：公司逬入:尾“回收項(xiàng)目，并從此占領(lǐng)了R0%的山場(chǎng)份額2007年2月：公祠建立獨(dú)立的研發(fā)中心2007年12月：公司當(dāng)年產(chǎn)值突破1億元2008年6月：公司完成廣東信達(dá)化纖公司年產(chǎn)1000噸高強(qiáng)奇模聚乙烯纖維生產(chǎn)線建設(shè)2008年77J：公司啟動(dòng)用于煤礦乏氣瓦斯節(jié)能減排的RTO的研發(fā)項(xiàng)目2009年3月：公訶啟動(dòng)煤多聯(lián)產(chǎn)中試項(xiàng)目，并在同年11月取得成功2009年II月：公司為|：|東國際電工捉供鋰電池PE隔膜生產(chǎn)配套設(shè)備調(diào)試成功COMPANYi： IntroductionQ July 20083 March 2009

6、November 2009Qingdao Huashijic Environmental Protection Technology CO., I.TD(HSJ), founded in 2004, is a high-tech company relying on its own R&D and technical innovalion. HSJ is now engaged in manufacturing of environmental protcction equipments, chemical equipments, as well as new materials and ne

7、w energy. We have very professional teams that specialize in R&D, manufacturing and projects construction , whose outstanding service, professional skills and high sense of responsibility have won wide recognition from the customers, which in turn facilitate the development of HSJ. HSJ has received

8、grantsand awards from the national and local government for many timesHSJ sticks to the idea of Pursuing Innovation and Quality, Caring Environmental Protection and Economic Returns. We have always, and will continue to make unrelenting eftorts to pursue technical innovation and improve quality of o

9、ur products io meet demands or our customers for their further successHSJ would be happy to work closely with you to make a cleaner world and a better life.DevelopmentQ Feb0 December 2007Q June 2008Q Officially founded by registrationOverall production output exceeded RMB 10 millionEngaged in waste

10、gas recovery in PE industry and took up 80% of themarket share ever since Set up independent R&D centerOverall production output exceeded RMB 100 million Built the production line of high strength and high modulus PE Fiber withan annual output of L000 tons for Guangdong Shinda UHMWPE FiberStarted lh

11、e RTO project for treatment oTcoal-mine gas Started the Coal Poly-generation pilot-scale project and achieved successin November 2009Made and successfully installed the production supporting equipments ofLithium battery PE diaphragm for NITTO DENKO我們的合作伙伴研發(fā)、制造能力中國科學(xué)院山西烘炭化學(xué)研究所 iwn cr om we c*wwamcftP

12、artnersResearch & Manufacturing Strength中國解放軍防化院2HGNCGUOANMTNHEFAN61UNrANGHUAYUAl共同研發(fā)大風(fēng)暈、低濃度有機(jī) 廢氣處理設(shè)備 冇毒冇古氣體防護(hù)共同研發(fā)耐水性蜂窩活性炭共同研發(fā)煤多聯(lián)工藝裝置順酊廢氣處理裝逬液體分離裝亙超為分子屆聚乙烯纖維改性聚乙烯鋰電池隔膜Joint DevelopmentJoint DevelopmentLarge volume and low concentration exhaust organic gas equipment Toxic and harmful gasJoint Develop

13、mentU1 IMWPE fiber modificationPE diaphragm of Lithium batteryWaterproof and honeycomb activated carbon Maleic anhydride exhaust gas process equipment Joint DevelopmentCoal poly-generation lechnology equipmentLiquids separation tcchnology/cqu iprneni研發(fā)團(tuán)隊(duì)博士3人，碩士7人Development team 3 doctors and 7 mast

14、ers實(shí)驗(yàn)室儀器價(jià)值超過1000萬元Laboratorr instruments cost RMB 10 million實(shí)驗(yàn)室面積超過2000 E.多個(gè)項(xiàng)目獲國家、省、市科技專項(xiàng)支持對(duì)外承擔(dān)孑種氣相、液相、固相分析我們的研發(fā)團(tuán)隊(duì)Manufacturing StrengthLaboratory covers over 2000 nrMultiple projects gain the support from suncx province and cityUndertaking the external analysis of gas、liquid, solid productQ3產(chǎn) 業(yè)結(jié)構(gòu) S

15、tructure of ProductionCDM工程CDM project煤礦羽闌緒Vcniilatc methane oxidation of coal mine新材料New materials超過分子量聚乙烯纖維UHMWPE ,聚乙烯鋰電池隔膜UHMWPE, PE Lithium battery diaphragm新能源 N ew energy 1 煤多聯(lián)產(chǎn)項(xiàng)目Coal poly-generation project工業(yè)廢氣治理Industrial waste gas treatment化工設(shè)備Chemical equipment 壓力容器、化工工程Pressure vessel, ch

16、emical projects環(huán)保設(shè)備Environmental protection equipmentsACF/GAC吸附回收設(shè)備，RTO設(shè)備ACI-7GAC adsorption recovery equipments,RTO equipments Care environment and benefit環(huán)保與效益同行環(huán)保工程Environment protection engineering吸附回收(還原性處理方式)吸附概述活性炭纖維吸附回收設(shè)備 活性炭吸附回收設(shè)備油氣回收設(shè)備吸附濃縮熱氧化處理方式TO&CTORTO(RCO)設(shè)備兩床RTO三床RTO旋轉(zhuǎn)式RTOAdsoqlion Re

17、coveryIntroduction to AdsorptionACF Adsorption Recovery EquipmentsAC Adsorption Recovery EquipmentsOil Gas Recovery EquipmentsAdsoqilion CondensationThermal Oxidation TreatmentRTO EquipmentsTwo-bcd RTOThrcc-bcd RTORotary RTOEnvironmental Protection Equipments揮發(fā)性有機(jī) 化合物介紹 VOCs1989年WHO定義VOCs是一組沸點(diǎn)從50C至2

18、60C、來溫卜飽和蒸三壓超過133. 322Ps的易揮發(fā)性化 合物英主要成分為燉類.氣燒類.含鹵燉類、氮燉及硫炷類.低沸點(diǎn)的多環(huán)芳燉類邨。Tlie World Health Organization definition of VOCs in 1989 includes all volatile organic compounds吳宛酣淋宴F8D ncng一 psurenon Equipmcwith boiling temperatures in the range of 50-260C which have a saturated vapor pressure of 133.322 Paor

19、 more in normal ambient temperatures and which is made up of predominantly hydrocarbons, oxygenated h ydroc arbons .halogenated hydrocarbons. niirogcnous hydrocarbon, suit united hydrocarbons and polyaromatic hydrocarbon etcVOCs危害 Environmental&Health Effects含VOCs廢氣未經(jīng)處理排入大氣.在-定條件F會(huì)形成光化學(xué)污染.形響動(dòng)植物生長和人類

20、的健 康.某些有毒YOC廢氣冇致殘.致畸、致癌作用.對(duì)長期暴舉其中的人體造成嚴(yán)啦傷密eVOCs, mostly emitted into the atmosphere as waste gases without treatment, could affect air quality through the fonnation of photochemical pollution. In addition, (hey have negative imp acts on human healih and growth of plantsand animals Some toxic VOCs co

21、uld even induce deformity, disability andPE盈PE EqE.pmHscancer in human population.處理方;去還原法：冷凝.吸收、吸附、膜分離等TreatmentMethods破壞法：接焚饒、盞熱焚燒、催化燃饒.生物分析、光催化等 VOCs recovery: condensation, absorption, adsorption, membrane separation, etc.VOCs conversion: direct incineration, thermal incineration, catalytic comb

22、ustion.biologic analysis, photochemical catalysis, etc.coa- po】y-generc-n處理方法選擇圖Chart for Selection of Treatment MethodsVOCs低濃度屮濃度髙濃度10000ppm不八回枚價(jià)值No recovery “l(fā)uc不其阿收價(jià)值No recovery value具何收價(jià)值Recovery value水洛性低水諧性髙Lou water solubility High water solubility酒性厳吸附AC adsorption牛物遞床Bio-filler生物洗滌塔Biodwncr

23、生物漁濾堪Bio-trickling filter濃縮后再處理Concentration八回收價(jià)值 Recovery value水洱性低水落性高Low water solubility High water solubility焚化爐Ilcai regenerative燭煤焚化CaUlylic點(diǎn)式洗浸塔燃燒塔冷凝何牧ScrubberConbustiunCondensate話性AC tJsorptionchcmjcaEQUipfncnTprcssurc vessel| 吸附概述Introduction to Adsorption*GMa ar c*rvcai|Crbe吸附，十流體與多孔同體接觸吋

24、，流體中菜組分或多個(gè)組分在固體茨而處產(chǎn)生積春 此現(xiàn)彖稱為吸附根據(jù)此特點(diǎn)，可以根據(jù)實(shí)際惜況選用適、勺的吸附劑.回收處理廢氣 中的污染物(VOCs) 達(dá)到循環(huán)利用，保護(hù)環(huán)境的冃的。Adsorption: Adsorption is a separation process in which certain components arc concentrated from a gas onto the surface of a porous solid when the gas comes in contact with the solid. Therefore, certain adsorbent

25、s are selected to treat pollutants (VOCs) in the waste gases for recycle and environmental protection.|變溫吸附工作流程(循環(huán)單元)|Temperature Swing Adsorption Process(Recycling Part)尾r (VOCs )十低混吸附 HiH (水蒸氣、情性氣體)脫附一干燥降溫T*潔凈空氣擔(dān)放冷礙回收利用聒環(huán)話行Exhaux)wvapour.Inert Gi1 A Coudens*tioo RecoveryDryin掘I活性炭吸附器的穿透曲線I Breakth

26、rough curve of AC adsorption希色爰！S旨器的穿詩曲純f AC *4rT尺0住有札化&忱療祭總 Heit of Vocs cccbustionHeat supply hy combuUorchcmjcaEclE.pmcnTprcssurc vesselClean Exhaust Air進(jìn)氣Solvent Laden Air燃燒器BurnerTubular Heat Exchanger 換熱區(qū)燃燒室Primary Combustion Chiinibcr燃燒器Burner薔熱式熱力焚化爐英文名為“RoFjenomti vo ThermalOxidizer故簡(jiǎn)稱為“RTO

27、” 直燃式焚燒爐TO&CTO直燃式焚燒爐（Thermal Oxidizer簡(jiǎn)稱TO通過燃燒來分解有機(jī)廢所有碳氮化合物經(jīng)由適當(dāng)?shù)臏囟葴魰r(shí)間及充分的擾流帑因花而破分解為二氧化嫌及水氣=Direct bum type thennal oxidizer oven decompose organic waste gas by combusiion. All the hydrocarbon experience proper temperature, residence time and sufficient turbulent flow. and convert into CO: and H2O.催化

28、和CatalyzerRTO設(shè)備RTO quipments原理是把冇機(jī)廢氣加熱到76（TC以上.使廢氣中的VGC氣化分解成氣化碳和水氣化產(chǎn) 生的高但氣體流經(jīng)特制的陶瓷蕃熱休.使陶瓷體升溫而女蓄熱此“蓄熱”用丁預(yù)熱 后續(xù)進(jìn)入的有機(jī)廢氣從而節(jié)省廢氣升溫的燃料消耗。曲瓷離熱體分成兩個(gè)（含兩個(gè)） 以上的IX或室.毎個(gè)薔熱室依次經(jīng)歷岳熱放熱清掃等程序，網(wǎng)而復(fù)始.連續(xù)工作。VOCs destmetion in an RTO is achieved by heating the organic waste gas to a temperature, typically over 760 C, where th

29、e VOCs arc oxidized and decomposed into CO: and H:!). The ceramic heat regenerator absorbs and stores heat from the outgoing clean hot gas generated from the oxidation process and delivers the stored heat to the incoming organic waste gas to save use of fuels R)r heating waste gas. Ceramic regerator

30、s are arranged in two sections, where the processes of heat storage heat release and purge occur in sequence repeatedly.兩床RTO設(shè)條的蓄熱材料分為兩個(gè)區(qū)域Heat storage materials in two sections個(gè)證熱區(qū).一個(gè)放熱區(qū)Heat storage section and heat release section投資小.占地面積小Small investment and small space occupation 閥門切換時(shí).系統(tǒng)壓力有波動(dòng)，有廢

31、氣殘留Pressure fluctuate when valve switches and untreated waste gas emitsVOCs凈化效率和熱能|叫收效率均達(dá)95%以上Both VOCs removal and heat recovery efficiency over 95%三床RTO TMd; RTO設(shè)備的蒔熱材料分為v個(gè)區(qū)域Heat storage materials in three sections一個(gè)裕熱區(qū)，一個(gè)放熱區(qū)，一個(gè)吹掃區(qū)Heal storage section, heat release section and purging section 投資較人

32、，宵地面積較大High investment and large area occupation閥門切換時(shí).系統(tǒng)壓力仃波動(dòng)Pressure fluctuate when valve switches處理效率9%以上.熱能回收效率95$以上Removal efficiency of VOCs over 99%. heat efficiency over 95%旋轉(zhuǎn)式RTO3_r ro設(shè)備的器熱材料分為12個(gè)區(qū)域Heat storage materials in twelve sections5個(gè)菩熱區(qū).5個(gè)放熱區(qū),2個(gè)吹扌1區(qū)Five heat storage sections, heat re

33、lease seclions and purge sections 投資適中，占地而積小Moderate investment and small space occupation無閥門切換，系統(tǒng)壓力穩(wěn)定No pressure fluctuation and no valve switch處理效率99%以上.熱能【叫收效率95%以上Removal efficiency of VOCs over 99%. heal efficiency over 95% UHMWPE高強(qiáng)高模聚乙烯纖維新材料New material我們提供的服務(wù)Our services捉供整體解決方案Provide overal

34、l resolvemcnt 項(xiàng)目前期規(guī)劃.設(shè)計(jì)Provide design and plan for project in earlier sxageCl工藝路線選擇：凍膠絲斷點(diǎn)、干燥后斯點(diǎn).干法前紡等Provide various technologies such cis cold col lodion silk breakpoint,dry breakpoini. and dry method for fore-spinning etcCl杠牛產(chǎn)線：前紡系統(tǒng).冷伸系統(tǒng)(町選杼纟種睪取劑Provide main production line: fore-spinning system,

35、stretching system (various extractants choice)Q_ 配套系統(tǒng)：白油分離系統(tǒng)、尾氣回收系統(tǒng)、十氫筑回收系統(tǒng)Provide assorted system: mineral oil separate system, exhaust gas recovery system, decal in recovery system_ UHMWPE纖維后續(xù)UD布力I匸設(shè)備LD cloth process equipment租貨融資服務(wù)Provide renting and financing servicesH PE EquipmentsPE纖維簡(jiǎn)介Introdu

36、ction toPE Fiber201比紀(jì)七I年代后期.以粉末狀超高分了雖聚乙烯為原料，采用個(gè)新的凍膠紡線及超拉伸技術(shù). 制得了超高強(qiáng)奇模的聚乙烯纖維使化學(xué)纖維利化學(xué)纖維I：業(yè)開始了蔚的飛躍。超島分子晴聚 乙烯纖維具有優(yōu)異的物理機(jī)械性能，成為繼碳纖維和芳綸之后出現(xiàn)的第二代髙性能纖維。國附; 上只有荷蘭DSM公司,美國Allied公司，日本東洋紡公司和三井公司.中國的幾家公司形成工業(yè)化規(guī)模的生產(chǎn)。In the late 丨 970s, with the use of powder UHMWPE as the raw material and by adopting the brand new g

37、el spinning and ultrahigh-drawing technology, the ultra high intensity and modulus PE fiber was produced, which has promoted new development in both chemical fiber and chemical fiberindustry. UHMWPE fiber, with its extraordinary physical and mechanical properties, is the third generation highpcribmu

38、mcc fiber after carbon fiber and aramid fiber. Al present, the UHMWPE is only produced in industry by DSM of Netherlands, Allied of US, Toyobo and Mitsui of Japan,and several Chinese companies 主要性能對(duì)照表Contrast of MainCharacteristicsItemUHMWPEKevlar29Kevlar49Carbon HSCarbonHMAbrasive Resistance (Fract

39、ure Cycles) 耐廉性MIOxlO395xld5.7x1020120Bending life (Fracture Cycles) 疲勞壽命240x1037x|(f43x10352Knot Strength (d/den) 結(jié)節(jié)強(qiáng)度10-156-76-700Loop Tenacity (d/den) 鉤接強(qiáng)度12-1810 1210120.70工藝路線Technical Process艸片仲列尾氣何收系統(tǒng) TailGts R&scry Syarmi干嫌空氣冷仲熱鉅 Art I Vdlins H萃取楕 ”七統(tǒng)牽伸機(jī) fiialkr IkAhiia Mtkhiii?口洎阿收系統(tǒng)To Mirw

40、r* OilEnvironmental Prolection EquipmentsPE Equipments滿Chemical fcquipmenL-Prcssurc Vessel i1416WWW.HUASHLnE.COM.(/ 0 牽伸機(jī)Sachi /強(qiáng)度好楕度高無噪音跳動(dòng)小萃取槽High strengthHigh accuracyNo noiseWeak shakeExtraction Tank /密幷性能好，沒右溶劑逸散Excellent soalabi1ity wi th no solvent loss 濃度梯度可實(shí)現(xiàn)幣密控制Fine control of the concentra

41、t ion gradient 可實(shí)現(xiàn)溫度階梯、梢確控制Fine control of the temperature gradient牽伸熱箱/雙風(fēng)道送風(fēng)Double intakes溫度誤杲可控制任以內(nèi)Temperature tolerance within 2X2 保溫效果好.噪音小Good heat preservation and low noise干燥箱三點(diǎn)支撐.齒輪傳動(dòng)Three point support cind gear drive、二級(jí)循環(huán)送風(fēng).降低能耗First and secondary circulating ventilation and lower energy c

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