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1、危險化學(xué)品管理程序hazardous chemical management procedure1、目的 purpose為防止危險化學(xué)品在使用儲存過程中由于泄漏、爆炸、燃燒、腐蝕等原因發(fā)生意外,避免人身傷亡、環(huán)境影響及財產(chǎn)損失,特制定本程序。this procedure is designed to avoid explosion, burning or corrosion of hazardous chemicals while in usage/storage, so as to avoid accidents which can cause personal casualties, en
2、vironmental pollution, and property losses2、范圍scope此程序適用于nrh的危險化學(xué)品管理。the procedure is applicable to hazardous chemical management of nrh 3、定義definition3.1危險化學(xué)品hazardous chemicals 凡具有爆炸、易燃、腐蝕性等性質(zhì),在運輸、儲存和使用過程中,容易造成人身傷亡和財產(chǎn)損毀而需要特別處理的物品,均屬于危險化學(xué)品。常用危險化學(xué)品按其主要特性分為九類:爆炸品;壓縮氣體和液化氣體;易燃液體;易燃固體、自燃物品和遇濕易燃物品;毒害品;放
3、射性物品;氧化劑;腐蝕品;其他類(刺激性或毒性)。 refer to those explosive, inflammable or corrosive goods, which require special care during the process of transportation and storage because they are apt to cause personal casualties and property losses.common hazardous goods are divided into nine categories according to t
4、heir characteristics. they are explosives, compressed air and liquidated gas, inflammable liquids, inflammable solids, spontaneous combustion materials and moisture-ignite inflammables, oxidants and organic peroxides, radioactive substance, noxious materials, and corrosive materials, others (irritan
5、t, harmful).3.2化學(xué)品安全技術(shù)書material safety data sheets (msds) 描述物質(zhì)的物理化學(xué)特性及危害的文件。除此之外包括有如安全使用,貯存,急救,預(yù)防措施等信息。a material safety data sheet (msds) is a document that describes the chemical and physical properties of a substance and identifies health hazards associated with it. other information contained in
6、 an msds includes information regarding safe handling and storage procedures, precautions for use, and first aid procedures.4、職責(zé)responsibility4.1 采購部門負責(zé)purchase department is responsible for4.1.1 選擇符合法規(guī)要求的化學(xué)品供應(yīng)商, 并要求供應(yīng)商提供該化學(xué)品最新的中文版本msds selecting supplier who compliances with legal requirement, obta
7、in the newest chinese material safety sheet data4.2. 各部門 each department is responsible for4.2.1負責(zé)本部門現(xiàn)場儲存化學(xué)品的保管、發(fā)放、使用和廢棄。storage, use and disposal of on site chemical 4.2.2提供工作區(qū)域使用的化學(xué)品培訓(xùn)training on the hazards of any specific chemicals used in their work area4.3 安全辦is responsible for4.3.1 負責(zé)危險化學(xué)品供應(yīng)商
8、資質(zhì)的確認。verifying certificate of chemical suppliers4.3.2負責(zé)協(xié)調(diào)化學(xué)品緊急應(yīng)變計劃演練。conducting the drill for chemical emergency response4.3.3 提供化學(xué)品安全意識培訓(xùn)providing the chemical awareness training 4.3.4 化學(xué)品的購買,使用,貯存及廢棄處理進行管控supervising purchase, use, storage and disposal of chemicals 4.5工程部門負責(zé) me department is resp
9、onsible for4.5.1 危險化學(xué)品倉庫的管理hazardous chemical warehouse management5、程序procedure5.1購買purchase5.1.1采購部門只能向具有相應(yīng)資質(zhì)的供應(yīng)商購買危險化學(xué)品。purchase department shall purchase the dangerous chemical from the chemical suppliers with related chemical permit.危險化學(xué)品生產(chǎn)廠商必須具有危險化學(xué)品生產(chǎn)許可證。the enterprise for chemical manu
10、facture shall hold chemical manufacture license issued by local authorities.危險化學(xué)品經(jīng)營銷售單位經(jīng)營危險化學(xué)品必須具備經(jīng)營許可證。the enterprise for chemical business shall hold chemical business license issued by local authorities.危險化學(xué)品的運輸承運人必須具備危險化學(xué)品運輸資質(zhì)證書,運輸工具為危險化學(xué)品專用運輸工具。the chemical carrier must hold chemi
11、cal transporting permit issued by public security organ and own special chemical transporting containers manufactured by qualified manufacture5.1.2采購部門應(yīng)將危險化學(xué)品供應(yīng)商的供應(yīng)商資質(zhì)相關(guān)證明提交安全辦確認。purchase department shall submit the related certificate provide by chemical supplier to safety council office for record
12、.5.1.3 采購部門須向廠商獲取有效的中文版化學(xué)品安全技術(shù)說明書purchase department shall request the chemical supplier to provide valid msds in chinese. 5.1.4 凡使用或計劃試驗?zāi)撤N新化學(xué)品的部門,必須填寫新化學(xué)品采購申請表,安全辦批準后方可采購。 the department seeking to use or experiment with new chemicals must fill out the new chemical purchasing application form and g
13、et approval by safety office.5.2危險化學(xué)品儲存storage of hazardous chemical 5.2.1危險化學(xué)品儲存原則principle of hazardous chemicals storage 爆炸品不能與起爆藥品、器材一起儲存,避免存放在高溫場所,嚴禁摔、滾、翻、撞和摩擦。explosives shall never be stored with the igniters and ignition equipment. the storage site shall be kept cool. dropping, rollin
14、g, overturning, impacting and rubbing of explosives are not allowed. 壓縮氣體和液體不能與性質(zhì)相抵觸的,盡管都是瓶裝的氣體或物質(zhì)同倉儲存。易燃氣體除惰性氣體外,助燃氣體除不燃氣體和無機毒品外,均不得與其它物品混貯。compressed air and liquidated gases shall not be stored with those materials incompatible in property, even though they are also contained in rums. infl
15、ammable gases, except for inert gases, and combustion assistant gases, except for non-combustion gases and inorganic poisons, shall never be stored with any other materials.易燃液體應(yīng)單獨儲存,遠離火源、熱源、防止靜電危害,鄰近的電氣設(shè)備要整體防靜電。 inflammable liquids shall be stored in separation, away from fire, heat, oxidant
16、s, and oxidized acid. possible harm resulting from static shall be avoided. the electrical appliances in the vicinity shall be installed with anti-explosive device.易燃固體應(yīng)包裝完好,防止火花、烘烤和受潮。inflammable solids shall be kept intact, away from sparkles, heat and moisture.毒害品應(yīng)包裝嚴密完好,單獨隔離存放,遠離火源
17、、熱源、氧化劑、酸類、食品,存放地點應(yīng)通風(fēng)良好toxic materials shall be stored in sealed packing, away from fire, heat, oxidants, acid, and foodstuff. the storing place shall be well ventilated.腐蝕物品容器應(yīng)符合耐腐蝕要求,嚴密不漏。氧化性酸既不能與遇濕易潮物及氧化劑儲存在一起,也不能與堿性腐蝕品儲儲存在一起the containers of corrosive material shall have strong anti-corro
18、sion property and leakage proof. oxidized acid shall be kept away from organic moisture-ignite materials and oxidants. they shall not be stored with alkali corrosives, either.危險化學(xué)品貯存應(yīng)根據(jù)危險品危險特性分區(qū)、分類貯存。hazardous chemical are arranged separately by type to distinguish with others化學(xué)品貯存地應(yīng)存有
19、儲存化學(xué)品的msds以及化學(xué)品清單keep a list of chemicals and available msds in the storage area.危險化學(xué)品專用倉庫/暫存區(qū)內(nèi)禁煙禁火,張貼禁煙標識。placing “no fire” and “no smoking” signs is must at the temporary storage area or chemical warehouse劇毒化學(xué)品以及儲存數(shù)量構(gòu)成重大危險源的其他危險化學(xué)品必須在專用倉庫內(nèi)單獨存放,實行雙人收發(fā)、雙人保管制度。儲存危險化學(xué)品構(gòu)成重大危險源的,由安全辦填寫“重大危
20、險源申報表”向當?shù)毓膊块T和安全生產(chǎn)監(jiān)督管理局備案。hyper-toxic chemicals and other dangerous chemicals that constitute serious hazard sources in quantity must be stored within the specialized warehouses separately, and be subject to the system of double-person receiving and dispatching and double-person safekeeping. safety
21、council office shall report the quantity, places, and management personnel of stored hyper-toxic chemicals and other dangerous chemicals that constitute serious hazard sources to the local public security organ and supervision management bureau of work safety for records.5.2.2 setup of the warehouse
22、 of hazardous chemicals 危險化學(xué)品倉設(shè)置通風(fēng)散熱良好,或有相應(yīng)的通風(fēng)設(shè)備 they must have good ventilation or ventilation devices5.2.2. 設(shè)置安全供電設(shè)施,所使用的電氣設(shè)備必須是防爆型的;they must have safety power supply devices. all electrical appliances must be explosion proof type.5.2.3配備足夠的消防設(shè)備;they must be equipped with adequate fire dis
23、tinguishing devices 5.2.4于門口處設(shè)置警示標志,如易燃品、嚴禁煙火等; warning signs such as “inflammable”, “no smoking”, etc. must be set up in places where they are easily seen.5.2.5需設(shè)置防泄漏裝置及應(yīng)急設(shè)施如洗眼設(shè)施,ppe等 installation of leak-preventing devices and emergency device such as eye wash station, ppe are required. 5.2.6符合供應(yīng)商
24、提供的物料安全數(shù)據(jù)表中所要求的貯存條件。the storage conditions must meet the requirements of the material safety data sheet provided by the chemical suppliers; 5.2.7 良好地接地裝置及防雷設(shè)施with sound grounding device and anti- thunder grounding facilities5.2.3 危險化學(xué)品倉庫的管理management of hazardous chemical warehouse工程部門指定有化學(xué)管理
25、資格的倉庫管理員對危險化學(xué)品倉進行管理。hazardous chemical warehouse shall be managed by the appointed person with qualification certificate from engineering dept. 倉庫管理員要根據(jù)化學(xué)特性對危險化學(xué)品倉中的化學(xué)品分類儲存并分類標識。hazardous chemical shall be stored and label the according to the category and property of chemical by warehouse ke
26、eper倉庫管理員對危險化學(xué)品倉中化學(xué)品列出化學(xué)品清單 the warehouse keeper shall keep the list of hazardous chemical available.倉庫管理員保持危險化學(xué)品倉中化學(xué)品msds的及時更新the warehouse keeper shall updates msds.危險化學(xué)品出入庫,必須進行核查登記。危險化學(xué)品應(yīng)當定期檢查。the dangerous chemicals entry into, and exit from warehouses must be inspected and
27、 registered. the dangerous chemicals shall be inspected at regular intervals such as quantity, label, fire equipment and so on.5.2.4 柴油儲存庫區(qū)的安全要求safety requirements of diesel oil store area. 必須按照相關(guān)規(guī)定設(shè)定防火堤set the fire wall according as national regulation 油罐區(qū)、油泵房和通風(fēng)處的照明燈具、接線盒、開關(guān)等,請選用符合
28、防爆要求的產(chǎn)品,防護等級不應(yīng)低于ip44級the lights, pump, ventilation fan, switch, wire conduit and so forth should be explosion proof, at least ip44 proof level. 油罐儲存區(qū)必須有防雷接地裝置 anti- thunder grounding facilities should be available for the store area 油罐儲存區(qū)必須有防靜電裝置 anti- electrostatic appliance should be
29、 available for the store area 卸油時,汽車油罐車的卸油設(shè)施,應(yīng)設(shè)置與油罐跨接的防靜電接地裝置the vehicle, joint pipe and oil tank should be grounding before discharging the oil. 經(jīng)常檢查與油罐相聯(lián)之接頭是否有“跑,冒,滴,漏”現(xiàn)象,并及時維修。examine if there are seepage and leakage in the joint and other place on a regular basis and replace or mai
30、ntain it well in a timely manner. 維修時用容器接住各易漏點,用過的廢布碎及沾染上柴油的廢置物品請當作危險廢棄物處理。secondary container should be in place while maintaining; rags, glove and other waste contaminated with oil should be treated as hazardous waste.5.3使用usage . 5.3.1 化學(xué)品使用崗位員工在使用化學(xué)品前,應(yīng)熟知安全標簽及安全技術(shù)說明書內(nèi)容,了解接觸的化學(xué)品的特性,選擇適當?shù)膫€人
31、防護用品,掌握事故應(yīng)急處理方法和操作注意事項。the employee who will be exposed to hazardous chemical should know label and msds, property, ppe requirement, emergency handling and safety operation procedure for the chemical to being used before chemical to being used.5.3.2 化學(xué)品使用現(xiàn)場需配備必要的應(yīng)急設(shè)施.如洗眼器等the emergency facilities su
32、ch as eye wash station should be provided in place where the chemical is being used.5.3.3 有毒化學(xué)品作業(yè)場所可能導(dǎo)致職業(yè)病危害的依照職業(yè)健康管理程序?qū)嵤┕芾?。it is likely to suffer from occupation disease due to exposed to toxic chemical ,the corresponding control measures can be found in occupational disease management procedure.5.
33、3.4使用危險化學(xué)品的部門應(yīng)根據(jù)每天兩班的使用量領(lǐng)取化學(xué)品,最多不能超過一天兩班的用量。departments using chemical shall obtain from the chemical warehouse and the chemical warehouse shall provide the hazardous chemicals in the identified quantity for two shifts (one day). the maximum quantity to be obtained and provided shall not exceed that
34、 for two shifts (one day).5.3.5非生產(chǎn)過程直接使用或輔助使用的危險化學(xué)品,使用后剩余的,應(yīng)退回危險化學(xué)品倉庫。the leftovers of the hazardous chemicals in direct or supplement use in non-production process shall be returned to hazardous chemical storehouse.5.3.6 若須在車間儲存危險化學(xué)品,必須控制儲存量,以最少量為原則,設(shè)置防火阻燃和耐腐蝕的專柜或?qū)S萌萜鬟M行儲存且必須指定專人進行管理。the leftovers o
35、f the hazardous chemicals in direct or supplement use in production process, if they need to be stored workshop, must be stored in minimum quantity. dedicated storing cabinets or containers made of fireproof and corrosion proof materials shall be set up in workshop to store hazardous chemicals, and
36、manage by the appointed person.5.3.7 放置在工作場所或正在使用的化學(xué)品,其一次容器及二次容器應(yīng)有明顯的標識,且必須包含化學(xué)品名稱及危險標志。 chemicals that will remain in the workshop are required to have visually labels, chemical name and appropriate hazard warning sign must be included in their labels on the primary and secondary container.5.3.8 盛裝
37、危險化學(xué)品的容器在未凈化處理前,不得更換安全標簽。the label on the container should be replaced before the container is not disposed safely.5.3.9危險化學(xué)品使用部門對使用化學(xué)品清單進行每月更新,并將結(jié)果拷貝給安全辦。 each department using hazardous chemicals shall update chemical list monthly and copy the list to safety council office.5.3.10各部門物料安全數(shù)據(jù)表存放在容易獲得的
38、地方,以保證任何員工在任何時候都可以得到msds。the material safety data sheets will be stored at accessible locations and all employees can access to the msds files at any time.5.3.11使用化學(xué)品部門停止使用某種化學(xué)品時,應(yīng)將停止使用化學(xué)品編號和停止使用時間通知安全辦。the chemical not used by department, it should be noticed safety council office the chemical no.
39、and time.5.3.12安全辦和采購部應(yīng)定期審查可使用的化學(xué)品,從化學(xué)品批準清單中刪除已不再使用的化學(xué)品。safety council office and purchasing department regular inspect the applicable chemical to delete the inapplicable chemical. 5.3.13安全辦定期更新msds目錄中現(xiàn)存的msds。 safety council office will update existing msds in the msds catalog periodical. 5.3.14非日常工
40、作中使用化學(xué)品non-routine tasks using hazardous chemicals員工在非日常工作中使用危險化學(xué)品時應(yīng)首先聯(lián)系其直接主管.其做非日常工作的員工的主管應(yīng)至少提供下列信息給做非日常工作的員工及受化學(xué)品影響的員工.an employee required to perform non-routine work using hazardous chemical should first contact their direct supervisor. each employee s affected by hazardous chemical and these em
41、ployees required to perform non-routine task should be given information on (at a minimum) the following by the supervisor of employees required to perform non-routine task:1) 工作中使用的化學(xué)品及其具體的危害hazardous chemicals needed to perform the task and their specific hazards.2) 應(yīng)當采取的安全措施如工程措施,ppe防護等safety mea
42、sures to be taken e.g. engineering control, personal protective equipment.3) 要使用的化學(xué)品的msdsreview of pertinent msds.4) 應(yīng)急措施review of emergency control procedures.5) 為了確保員工遵守化學(xué)品安全要求,安全主任應(yīng)隨機檢查員工的工作.to ensure required to perform non-routine work using hazardous chemical compliance with chemical safety tr
43、easures, the safety officer will conduct random check of the employees.5.3.15承包商使用化學(xué)品contractor using hazardous chemicals1) me應(yīng)當通知承包商他們在nrh工作期間可能遇到的潛在的危害.包括如獲得化學(xué)品程序,危險化學(xué)品清單及他們要使用的化學(xué)品的msds.me departments must inform outside contractors of the potential hazards which may be encountered during their wo
44、rk at nrh. this includes giving contractor access to the written hazardous chemical procedure, the hazardous chemical inventory, and the msds for these chemicals used. 2) 承包商應(yīng)提供及通知安全辦及me部門他們在工廠工作期間要帶入的化學(xué)品的清單及化學(xué)品的msds.同時也包括提供化學(xué)品的使用及貯存地方.the contractor is expected to inform and provide safety office a
45、nd me department with a chemical inventory and msdss for the materials that will be introduced into the work area in the course of their work at nrh. the contractor must also provide information regarding where chemicals will be used and stored3) 為了確保承包商遵守化學(xué)品安全要求,安全主任應(yīng)隨機檢查承包商的工作.to ensure contractor
46、 compliance with chemical safety treasures, the safety officer will conduct random check of outside contractor work.5.4危險化學(xué)品響應(yīng)hazardous chemicals emergency response 5.4.1 參照應(yīng)急響應(yīng)程序。hazardous chemicals emergence response reference to emergency preparedness and response procedure5.4.2 危險化學(xué)品泄漏演習(xí)至少每年演練一次
47、。chemical spill drill must be conducted at least once a year.5.5廢危險化學(xué)品及其容器的廢棄處理waste hazardous chemical and the container 5.5.1廢危險化學(xué)品及其容器統(tǒng)一作為危險廢物集中收集報廢處理,參考廢物管理程序。 waste hazardous chemical and the container shall be collected and discharged as hazardous waste, reference to waste management procedure.5.6 化學(xué)品培訓(xùn)chemical training 5.6.1接觸化學(xué)品員工每年接受化學(xué)品安全意識培訓(xùn)。the employees exposed to hazardous chemical shall receive chemical awareness training annually.5.6.2 培訓(xùn)內(nèi)容應(yīng)該包括但不局限于下列內(nèi)容:the training contents should include, but not limited to the following:a) 適用的化學(xué)品法律法規(guī)applicable laws and regulation relat
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