尼龍66的主要牌號(hào)與性能

1、 尼龍66的主要牌號(hào)與性能01.3.6.1國(guó)產(chǎn)尼龍66的主要性能指標(biāo)國(guó)內(nèi)生產(chǎn)尼龍66的廠(chǎng)家有：黑龍江省尼龍廠(chǎng)、上海塑料制品十八廠(chǎng)、遼陽(yáng)化纖工業(yè)總公司、太原合成纖維廠(chǎng)、神馬集團(tuán)、浙江衢州化工廠(chǎng)、宜興太湖尼龍廠(chǎng)、江蘇海安化工廠(chǎng)。其產(chǎn)品主要用制造各種機(jī)械、汽車(chē)、化工、電子電氣裝置的零部件，特別適合用于高強(qiáng)度或耐磨部件，如各種齒輪、滑輪、輥軸、軸承、泵體中葉輪、風(fēng)箱葉片、高壓密封圈、閥座、墊片、襯套、各種殼體、工具手柄、支撐架、電纜包層、汽車(chē)燈罩等。在電子儀器設(shè)備、繼電器等電氣設(shè)備中制造零件、電梯導(dǎo)軌、建筑裝飾扶手等。在醫(yī)療器械、體育用品和日用品上也有廣泛應(yīng)用，如棒球棒、滑雪板等。也可制成薄膜后與鋁箔

2、等形成復(fù)合膜用于食品包裝，如軟包裝飲料、罐頭等。表01-73列出了幾家企業(yè)的尼龍66產(chǎn)品指標(biāo)。表01-73 國(guó)產(chǎn)尼龍66的性能指標(biāo)項(xiàng)目黑龍江省尼龍廠(chǎng)上海塑料制品十八廠(chǎng)江蘇宜興化工二廠(chǎng)I型II型分子量(1.52)×104(1.52)×104(1.82.2)×104外觀(guān)乳白色，微黃色乳白色，微黃色白色或帶黃色粒乳白至淡黃色相對(duì)密度1.101.151.101.151.101.141.131.15粒度，粒/克,>4040含水量，%，0.30.152粘度比0.403.00>3.00小黑點(diǎn)含量，%，33熔點(diǎn)，238248238248255260脆化溫度，-35-3

3、5馬丁耐熱，5060拉伸強(qiáng)度，MPa657060807080彎曲強(qiáng)度，MPa100（不斷）110（不斷）10012080120彎曲彈性模量，GPa23沖擊強(qiáng)度，kJ/m2缺口無(wú)缺口810601008 12硬度，MPaR118體積電阻率，·cm101410141.830×1015介電常數(shù)（1MHz）1.63成型收縮率，%1.52.201.3.6.2阻燃增強(qiáng)尼龍66的主要性能指標(biāo)目前，國(guó)內(nèi)尚有許多廠(chǎng)家從事改性尼龍66樹(shù)脂的生產(chǎn)。生產(chǎn)阻燃尼龍66和阻燃增強(qiáng)尼龍66的主要廠(chǎng)家有：黑龍江省尼龍廠(chǎng)、黑龍江省化工研究所、上海賽璐珞廠(chǎng)、廣州蓮花山工程塑料廠(chǎng)、江陰市永建化工有限公司等。阻燃尼

4、龍66主要用于低壓電器、機(jī)床電器、廣播電視工業(yè)中，制造各種阻燃零件如調(diào)壓器開(kāi)關(guān)、儀器儀表外殼和電子電氣連接器等；生產(chǎn)玻纖增強(qiáng)尼龍66的主要廠(chǎng)家有：黑龍江省尼龍廠(chǎng)、上海德勝塑料廠(chǎng)、廣州蓮花山工程塑料廠(chǎng)、蘇州塑料一廠(chǎng)等。產(chǎn)品主要應(yīng)用于低壓電器工業(yè)，如交流接觸器底座、線(xiàn)圈骨架、行程開(kāi)關(guān)等各種要求耐火性能的介電零件中。黑龍江省化學(xué)研究所還生產(chǎn)防老化尼龍。其主要指標(biāo)列于表01-74中。表01-74國(guó)產(chǎn)改性尼龍66樹(shù)脂的主要性能指標(biāo)指標(biāo)阻燃尼龍66阻燃增強(qiáng)尼龍66防老化尼龍66玻纖增強(qiáng)尼龍66熔點(diǎn)，245250247250250260相對(duì)密度1.421.451.501.101.151.39吸水率，%<

5、;0.51.0拉伸強(qiáng)度，MPa6012060162彎曲強(qiáng)度，MPa10018090196缺口沖擊強(qiáng)度，kJ/m251059.8熱變形溫度（1.8MPa），6022060220阻燃等級(jí)，UL94V-0V-0體積電阻率，·cm101510131.5×10151014介電常數(shù)<554.4擊穿電壓，kV/mm17172020模后收縮率，%0.51.20.51.00.81.5玻纖含量，%30±230±2彎曲彈性模量，MPa5.4×103耐老化性能，倍>3表面電阻率，101301.3.6.3杜邦公司系列尼龍66產(chǎn)品的基本性能指標(biāo)杜邦公司是主要的

6、尼龍66生產(chǎn)廠(chǎng)家之一，其產(chǎn)品型號(hào)齊全，覆蓋面廣，滿(mǎn)足各行各業(yè)對(duì)尼龍66樹(shù)脂的不同性能要求，見(jiàn)表01-75。表01-75 杜邦公司Zytel®尼龍66樹(shù)脂型號(hào)與用途型號(hào)產(chǎn)品特點(diǎn)用途未增強(qiáng)級(jí)Zytel 101LZytel 101FZytel 103HSLZytel 103FHSZytel 105FZytel EFE1068Zytel 135F增潤(rùn)PA66快速成型熱穩(wěn)定性增潤(rùn)尼龍66快速成型熱穩(wěn)定性尼龍66抗紫外線(xiàn)增潤(rùn)尼龍66核化尼龍66增潤(rùn)成核型尼龍66機(jī)械零件、消費(fèi)品等增韌級(jí)Zytel114BK97Zytel408Zytel450Zytel490抗沖改性PA66增韌PA66增韌PA66

7、增韌PA66具優(yōu)越的韌性和成型性超韌級(jí)ZytelST801超韌PA66杰出的耐沖擊性特制品Zytel122LZytelEFE8073ZytelFN714ZytelFN718抗水解增潤(rùn)PA66增韌PA66擠出級(jí)PA66尼龍合金PA66尼龍合金玻纖增強(qiáng)Zytel70G20HSLZytel70G25HSLZytel70G30HSLZytel70G35HSLZytel70G43HSLZytel70G50HSLZytel70G60HSL20%GF，熱穩(wěn)定性增潤(rùn)PA6625%GF，熱穩(wěn)定性PA6630%GF，熱穩(wěn)定性PA6635%GF，熱穩(wěn)定性PA6643%GF，熱穩(wěn)定性PA6650%GF，熱穩(wěn)定性PA6

8、660%GF，熱穩(wěn)定性PA66抗水解玻纖增強(qiáng)級(jí)Zytel70G25HSLRZytel70G30HSLRZytel70G30HSR225%GF，熱穩(wěn)定性增潤(rùn)抗水解PA6630%GF，熱穩(wěn)定性增潤(rùn)抗水解PA6630%GF，熱穩(wěn)定性增潤(rùn)超高抗水解性能PA66玻纖增強(qiáng)特制品級(jí)Zytel70G33GRAZytel70G35HSLXZytel70G35HSLRA4Zytel70GB40HSLZytelEFE7267Zytel74G20HSLZytel74G30LZytel70G30W玻纖增強(qiáng)增潤(rùn)PA6635%GF，抗熱油脂性PA66高流動(dòng)性玻纖增強(qiáng)PA6640%GF，熱穩(wěn)定性PA66可焊接性玻纖增強(qiáng)PA6

9、620%GF，熱穩(wěn)定性PA66/6共混20%GF，PA66/6共混玻纖增強(qiáng)耐侯性PA66/6共混增韌玻纖增強(qiáng)級(jí)Zytel79G13LZytel80G14Zytel80G25Zytel70G33HS1R13%GF，增韌PA6614%GF，增韌PA6625%GF，增韌PA6635%GF，熱穩(wěn)定性增韌PA66阻燃級(jí)ZytelFR7200V0FZytelFR72G25V0ZytelFR70G25GWZytelFR70G25V0ZytelFR70M30V0ZytelFR70M40GW未增強(qiáng)PA66/6共聚物，UL94V-0(0.5mm)25%GF PA66/6共聚物，UL94V-0(0.5mm)25%G

10、FPA66，熾熱棒850（1mm）25%GF，PA66，UL94V-0(0.5mm)30%礦物增強(qiáng)PA66，UL94V-0(1.6mm)40%礦物增強(qiáng)，熾熱棒960（1.5mm）高粘擠出級(jí)ZytelE40ZytelE42AZytelE50ZytelE51HSBZytelE53高粘PA66（RV=95150）高粘PA66（RV=180310）高粘PA66（RV=240270）熱穩(wěn)定性高粘PA66（RV=240470）高粘PA66（RV=470600）長(zhǎng)條狀、管狀以及其它復(fù)雜成型品擠出用，或用于耐沖擊之成型品杜邦公司Zytel®系列尼龍66的基本性能指標(biāo)、力學(xué)性能指標(biāo)、熱性能指標(biāo)、電性能

11、指標(biāo)分別列于表01-76表01-79中。表01-76杜邦公司Zytel®系列尼龍66的基本性能指標(biāo)密度阻燃性吸水率吸濕率洛氏硬度落球沖擊硬度成型收縮率測(cè)試條件1.6mm23，飽和2350%RHMR流動(dòng)方向標(biāo)準(zhǔn)ISO1183UL94ISO 622039/22039294-4單位g/cm3%MPa%101L,DAM50%RH1.14V-28.52.87959121108160H961/3085 H358/301.3101F,DAM50%RH1.14V-28.52.81.3103HSL,DAM50%RH1.14V-28.52.81.3103FHS,DAM50%RH1.14V-28.52.8

12、1.3105F,DAM1.14V-28.52.81.5EFE1068,DAM50%RH1.14V-28.52.8135F,DAM50%RH1.14V-28.52.787641231160.7408,DAM50%RH1.09HB72.271501151021.5450,DAM50%RH1.08HB72.21.8490,DAM50%RH1.08HB7.12.31.6801,DAM50%RH1.08HB6.72.2112891.7EFE8073,DAM50%RH1.0770G20HSL,DAM50%RH1.29HB6.82.1102851221150.470G35HSL,DAM50%RH1.41HB

13、5.51.7105891251172852030.370G60HSL,DAM50%RH1.70HB3.41.00.270G25HSLR,DAM50%RH1.33HB6.42.00.370GB40HSL,DAM50%RH1.46HB7.31.71.380G14,DAM50%RH1.18HB6.22.01030.4FR7200V0F,DAM50%RH1.19V-06.42.61.2FR72G25V0,DAM50%RH1.49V-04.11.12131060.2E40,DAM50%RH1.142.61.5E42A,DAM50%RH1.14HB8.52.61.5表01-77杜邦公司Zytel®

14、;系列尼龍66的力學(xué)性能指標(biāo)屈服應(yīng)力屈服應(yīng)變斷裂應(yīng)變標(biāo)稱(chēng)斷裂應(yīng)變拉伸模量沖擊強(qiáng)度（無(wú)缺口）缺口沖擊強(qiáng)度測(cè)試條件50mm/min1mm/min23-3023-30標(biāo)準(zhǔn)ISO527-1/2179/1eU180/1A單位MPa%MPakJ/m2kJ/m2101L,DAM50%RH83534.52540>5022>5031001200NBNBNBNB5.411.73.72.7101F,DAM50%RH83534.42540>5018>5031001200NBNBNBNB5.411.73.72.7103HSL,DAM50%RH85534.42540>5018>5031

15、001250NBNBNBNB510.62.83.1103FHS,DAM50%RH85554.42535>5018>5031001350NBNBNBNB510105F,DAM50%RH856052530>5024>503200150045NB555554123EFE1068,DAM50%RH85594.52535>6018>6031001500NBNB511.5135F,DAM50%RH98694.51818>5013>5036002100NBNBNBNB32.8408,DAM50%RH614362655>10035>502200110

16、0NBNBNBNB1920114450,DAM50%RH55405.42450>10028>5022001000NBNBNBNB1770109490,DAM50%RH55405.52950>10033>502100950NBNBNBNB66831716801,DAM50%RH504063840>5060>1002000900NBNBNBNB801002020EFE8073,DAM50%RH52375.53250>10088>1002000950NBNB7593161570G20HSL,DAM50%RH1591032.877200530054695

17、04310118870G35HSL,DAM50%RH2101553.241150089009810088771215101070G60HSL,DAM50%RH2301801.62.1200001500074806058129.587.570G25HSLR,DAM50%RH188115315860063005060604570GB40HSL,DAM50%RH904361350002700304025253.56.52.82.880G14,DAM50%RH110704105100340075758590141977FR7200V0F,DAM50%RH85504203900180050NB65653

18、833FR72G25V0,DAM50%RH1351002.53.5920065005562706191288E40,DAM50%RH85554.42850>5030001200NBNBNBNB5.612.532.2E42A,DAM50%RH8652527>50>5031001200NBNBNBNB5.611.94.34表01-78 杜邦公司Zytel®系列尼龍66的熱學(xué)性能指標(biāo)熔化溫度熱變形溫度維卡軟化點(diǎn)線(xiàn)性熱膨脹系數(shù)測(cè)試條件10K/min0.45MPa1.8MPa50N流動(dòng)方向標(biāo)準(zhǔn)ISO3146C75-1/2306ASTM E831單位E-4 1/K101L262

19、200702381.0101F262200702381.0103HSL262200702381.0103FHS262200702381.0105F262200702391.0EFE1068262700.85135F262210882431.21408262155662091.3245026292652001.6149026285682211.52801262132702131.2EFE80732621956570G20HSL2622602512550.3570G35HSL2622622542560.270G60HSL26226025524870G25HSLR2622622542570.3370

20、GB40HSL2622201152460.680G142622552392400.39FR7200V0F255195752250.78FR72G25V02422412152200.27E40262205722421.0E42A262205722421.0表01-79 杜邦公司Zytel®系列尼龍66的電學(xué)性能指標(biāo)對(duì)比電弧徑跡指數(shù)介電強(qiáng)度表面電阻體積電阻相對(duì)介電率損耗因素測(cè)試條件100Hz1MHz100Hz1MHz標(biāo)準(zhǔn)IEC6011260243-160093600936025060250單位kV/mm·cmE-4101L,DAM50%RH60031.5E12>E15E1

21、6E133.810.93.54802100180750101F,DAM50%RH60051.5E12E12E16E133.810.93.54.614021001801000103HSL,DAM50%RH5253128E12E13E15E123.8133.54755800165700105F,DAM50%RH2731E15E13E15E123.64.6300600135F,DAM50%RH600253.98.73.83.9702400200600408,DAM50%RH60033.5E15E15E15E133.272.93.72001500200500450,DAM50%RH600>E15

22、E12490,DAM50%RH600801,DAM50%RH6003139E15E15E14E133.282.93.680180014055070G20HSL,DAM50%RH400>E15E12>E15E113.94.416070070G35HSL,DAM50%RH400>E15E13E15E114.14.714062070G60HSL,DAM>60070G25HSLR,DAM>E153.67070GB40HSL,DAM425>E154.620080G14,DAM50%RH6003636.5>E15E14E15E123.87.33.53.970180

23、150580FR7200V0F,DAM50%RH5752623E14E14>E15E114.13.8580160FR72G25V0,DAM50%RH3253525>E154.260E40,DAM600E153.9100E42A,DAM50%RH30.5E15E134.310.33.64.2150200024075001.3.6.4 DSM公司的尼龍66樹(shù)脂的基本性能指標(biāo)及用途DSM公司也是世界上著名的尼龍66樹(shù)脂生產(chǎn)商，其尼龍66樹(shù)脂分為Plaslube、Nylatron、Electrafil、Akulon等幾個(gè)系列，在汽車(chē)工業(yè)、電子電氣行業(yè)、消費(fèi)品工業(yè)和機(jī)械制造行業(yè)得到廣泛應(yīng)用。

24、表01-80DSM公司的尼龍66產(chǎn)品系列產(chǎn)品系列組成用途Akulon玻纖增強(qiáng)、增韌Electrafil碳纖維增強(qiáng)NylatronMoS2增潤(rùn)滑、熱穩(wěn)定性拉伸強(qiáng)度、壓縮強(qiáng)度高，表面磨擦低，較高的熱穩(wěn)定性和尺寸穩(wěn)定性，高溫性能優(yōu)良，適合制造耐高溫的部件。PlaslubePTFE增潤(rùn)滑優(yōu)秀的耐磨性能和耐摩擦性能，制造軸承、軸襯、套管的理想材料表01-81DSM公司的尼龍66樹(shù)脂的基本性能力學(xué)性質(zhì)拉伸強(qiáng)度伸長(zhǎng)率拉伸模量撓曲強(qiáng)度撓曲模量沖擊強(qiáng)度(1/8)洛氏硬度壓縮強(qiáng)度剪切強(qiáng)度載荷變形測(cè)試條件缺口無(wú)缺口*單位MPa%GPaMPaMPakJ/m2-MPaMPa%ASTMD638D790D256D785D6

25、95D732D621J-1/101173.05.81765.52.1-J-1/201383.07.22076.93.2E60J-1/301972.510.32769.75.3E65J-1/402143.512.833112.46.3E70J-1/15/MF/251383.510.02149.72.3NY-16/MF/40973.07.21526.92.1J-1/30/HS1862629.54.6J-8/1397564.81384.16.340R115J-8/33134468.32077.68.642R107J-8/431584.0112288.98.4R109M-10161699.54.4NY

26、-85450.0621.738NBR104NY-8/HS4950.0621.738NBR104S223D83701243.01.7D82J-1/CF/101384.07.62076.91.716.8E52124690.3J-1/CF/201933.013.829015.22.721E67172830.20J-1/CF/302482.020.735218.63.227E70200900.15/CF/30/TF/152072.629717.93.8138/CF/30/TF/13/SI/21932.527615.23.8172J-1/CF/402761.828.340721.43.831.5E702

27、0789.60.12GS-512073.031010.34.6R120193GS/GS-HS93101383.41.5R11990NY-1/SI/274451002.8J-1/30/SI/2179232489.33.24.6J-1/30/TF/SI/2162232419.43.8R11950J-1/30/TF/15159-2389.35.3NY-1/TF/15614.3972.82.1基本性質(zhì)密度添加劑含量吸水率線(xiàn)性成型收縮率載荷變形溫度測(cè)試條件水，24hrs平衡1/8試條1/4試條1.8MPa0.45MPa單位-%cm/cmcm/cmASTMD792D570D955D955D645J-1/1

28、01.231.10.005243249J-1/201.301.00.004249254J-1/301.390.90.002252260J-1/401.500.80.001252260J-1/15/MF/251.500.70.002243260NY-16/MF/401.500.060.010221J-1/30/HS1.390.90.002252J-8/131.180.750.0040.007243254J-8/331.320.570.0020.004243257J-8/431.430.600.001243M-10161.39249NY-81.080.80.0200.02866221NY-8/HS1.080.82.02.866221S223D1.141.151.0074221J-1/CF/101.