科勒恩茂金屬

1、Pigments & Additives DivisionMarketing Specialties BusinessSlide 15/30/2022科萊恩有限公司Licocene 茂金屬催化聚烯烴茂金屬催化聚烯烴Slide 2Marketing Specialties BusinessMS Formulators1.Licocene introduction2.Licocene product range3.Licocene properties4. Licocene compatibilities5. Licocene applications5/30/20221. 研究和發(fā)展研究

2、和發(fā)展 茂金屬催化劑是聚烯烴聚合物工業(yè)中的一種全新發(fā)展方向.關(guān)于茂金屬催化劑的第一篇專(zhuān)利出現(xiàn)在上世紀(jì)80年代,但直到最近5年,這方面的研究才急劇增多,并在技術(shù)上,逐步成熟.作為聚烯烴類(lèi)蠟工業(yè)領(lǐng)域的全球領(lǐng)導(dǎo)者,科萊恩立刻意識(shí)到茂金屬催化劑的重要性,并投入了大量的資金.目前,擁有多項(xiàng)專(zhuān)利技術(shù)和產(chǎn)品.科萊恩采用的技術(shù)是C3/C2技術(shù).Slide 3Marketing Specialties BusinessMS Formulators1.Licocene introduction2.Licocene product range3.Licocene properties4. Licocene comp

3、atibilities5. Licocene applications5/30/20221. 聚烯烴的聚合工藝聚烯烴的聚合工藝齊格勒法齊格勒法 n低壓n可形成共聚物 LD法高壓設(shè)備和維護(hù)費(fèi)用相對(duì)便宜 茂金屬法茂金屬法低壓可對(duì)產(chǎn)品進(jìn)行設(shè)計(jì)控制可形成共聚物Slide 4Marketing Specialties BusinessMS Formulators1.Licocene introduction2.Licocene product range3.Licocene properties4. Licocene compatibilities5. Licocene applications5/30

4、/20221.茂金屬催化劑的特性茂金屬催化劑的特性催化劑分子鏈茂金屬催化劑茂金屬催化劑齊格勒齊格勒-納塔催化劑納塔催化劑n 分子鏈排列規(guī)整n 分子量分布窄n 熔融峰較窄Slide 5Marketing Specialties BusinessMS Formulators1.Licocene introduction2.Licocene product range3.Licocene properties4. Licocene compatibilities5. Licocene applications5/30/2022 PP 1602滴點(diǎn)滴點(diǎn)/軟化點(diǎn)軟化點(diǎn) vs. 熔融粘度熔融粘度PEPP

5、PP 1302 PP 1502PP 6102 Licocene PP1.Licocene 聚烯烴的產(chǎn)品性能聚烯烴的產(chǎn)品性能內(nèi)聚力內(nèi)聚力 PP 2602PP 4202 PP 3502結(jié)晶度結(jié)晶度Slide 6Marketing Specialties BusinessMS Formulators1.Licocene introduction2.Licocene product range3.Licocene properties4. Licocene compatibilities5. Licocene applications04.05.2005Licocene 產(chǎn)品系列產(chǎn)品系列- 非接枝型非

6、接枝型 -TP Licocene .特性特性物理形態(tài)粘度滴點(diǎn)針刺入深針刺入深度度密度主要應(yīng)用mPa.sC0,1mmg/cm3PE 4201低粘度,高結(jié)晶度,較硬顆粒或粉末6012810,97EPS; 可微粉化 (=Ceridust 3610); 熱熔膠PE 3401中等粘度,中等結(jié)晶度顆粒550111ca. 30,93護(hù)理產(chǎn)品 PP 6102低粘度,高結(jié)晶度,相對(duì)低的熔點(diǎn).谷狀顆粒6014510,90色母料, 熱熔膠TP Ceridust 6050 M 微細(xì)粉末, d50 = 9 m60145 提高附著力,內(nèi)聚力 和其他性能,如開(kāi)放時(shí)間, 固化時(shí)間Licocene在粘合劑和密封膠上的應(yīng)用在粘合

7、劑和密封膠上的應(yīng)用Slide 8Marketing Specialties BusinessMS Formulators1.Licocene introduction2.Licocene product range3.Licocene properties4. Licocene compatibilities5. Licocene applications04.05.2005Licocene 產(chǎn)品系列產(chǎn)品系列- 接枝型接枝型 -Licocene .接枝官能團(tuán)接枝官能團(tuán)接枝度接枝度粘度粘度滴點(diǎn)滴點(diǎn)酸值酸值物理狀態(tài)物理狀態(tài)產(chǎn)品狀態(tài)產(chǎn)品狀態(tài)主要應(yīng)用主要應(yīng)用mPa.sCmgKOH/g已商業(yè)化已商業(yè)化P

8、E MA 4221 TP中等中等10012317谷狀顆粒谷狀顆粒偶聯(lián)劑偶聯(lián)劑相容劑相容劑, PE MA 4351 TP馬來(lái)酸酐接枝馬來(lái)酸酐接枝高高30012342已正式生產(chǎn)已正式生產(chǎn)熱熔膠熱熔膠, 乳液乳液PP MA 6252 TPPP MA 7452 TP高高1008001401604042顆粒顆粒相容劑相容劑乳液乳液熱熔膠熱熔膠PE SI 3361 TP硅烷接枝硅烷接枝高高150115-顆粒顆粒已正式生產(chǎn)已正式生產(chǎn)偶聯(lián)劑偶聯(lián)劑PP SI 3262 TP硅烷接枝硅烷接枝高高60115-密封裝在密封裝在桶中桶中已正式生產(chǎn)已正式生產(chǎn)熱熔膠熱熔膠偶聯(lián)劑偶聯(lián)劑在實(shí)驗(yàn)中在實(shí)驗(yàn)中PP MA 1332馬來(lái)

9、酸酐接枝馬來(lái)酸酐接枝中等中等3508018密封裝在密封裝在桶中桶中實(shí)驗(yàn)實(shí)可提實(shí)驗(yàn)實(shí)可提供樣品供樣品鞋護(hù)理鞋護(hù)理 膠粘劑膠粘劑,乳液乳液PP MA 1452高高5008540膠粘劑膠粘劑乳液乳液PE ST 4361苯乙烯接枝苯乙烯接枝高高80120-塑料處理塑料處理, 膠粘劑膠粘劑PE OX 4241氧化氧化低低6012017小顆粒小顆粒塑料處理塑料處理,PE OX 3441氧化氧化高高30010017乳液乳液*) 測(cè)試溫度.: PE 140C, PP 170CSlide 9Marketing Specialties BusinessMS Formulators1.Licocene introd

10、uction2.Licocene product range3.Licocene properties4. Licocene compatibilities5. Licocene applications5/30/2022 L I C O C E N E S 3. Licocene 代表什么代表什么? Low Viscosity & long open time低粘度,長(zhǎng)開(kāi)放時(shí)間 Increased adhesion提高附著力 Chemical resistance & Colourless耐化學(xué)腐蝕無(wú)色 Odourless無(wú)氣味 Cohesive內(nèi)聚力 Excellent t

11、hermal stability優(yōu)秀的熱穩(wěn)定性 Narrow molecular weight distribution窄分子量分布 Enhancer促進(jìn)劑 Solvent resistant耐溶劑Slide 10Marketing Specialties BusinessMS Formulators1.Licocene introduction2.Licocene product range3.Licocene properties4. Licocene compatibilities5. Licocene applications5/30/20223. Licocene在膠粘劑和密封膠上的

12、應(yīng)用在膠粘劑和密封膠上的應(yīng)用 優(yōu)秀的熱穩(wěn)定性能 無(wú)氣味 無(wú)凝膠 無(wú)碳化 無(wú)色 減少終端客戶(hù)的停機(jī)檢修次數(shù) 節(jié)約時(shí)間 提高產(chǎn)量 降低保養(yǎng)費(fèi)用支鏈少, 沒(méi)有不飽和鍵 或沒(méi)有不穩(wěn)定的官能團(tuán), 因此具有以下性能加入 0,5% Sanduvor PR 31穩(wěn)定劑Slide 11Marketing Specialties BusinessMS Formulators1.Licocene introduction2.Licocene product range3.Licocene properties4. Licocene compatibilities5. Licocene applications5/3

13、0/20223. Licocene在膠粘劑和密封膠上的應(yīng)用在膠粘劑和密封膠上的應(yīng)用Licocene vs APAO vs C2/C8 茂金屬聚烯烴茂金屬聚烯烴10 N/mm 9 N/mm 8 N/mm 7 N/mm 6 N/mm 5 N/mm 4 N/mm 3 N/mm 2 N/mm 1 N/mm 0 N/mmSlide 12Marketing Specialties BusinessMS Formulators1.Licocene introduction2.Licocene product range3.Licocene properties4. Licocene compatibilit

14、ies5. Licocene applications5/30/20223. Licocene在膠粘劑和密封膠上的應(yīng)用在膠粘劑和密封膠上的應(yīng)用應(yīng)用溫度低: 加熱和冷卻時(shí)間短,導(dǎo)致更高的生產(chǎn)效率更低的能源成本Slide 13Marketing Specialties BusinessMS Formulators1.Licocene introduction2.Licocene product range3.Licocene properties4. Licocene compatibilities5. Licocene applications5/30/2022表面張力表面張力 值值基材基材 m

15、N/m玻璃玻璃300PA 647,5PVC45,2PS42PE31-39鋁鋁33-35PP28-30= (dG/dA) T,p3. Licocene在膠粘劑和密封膠上的應(yīng)用在膠粘劑和密封膠上的應(yīng)用表面能的比較表面能的比較浸潤(rùn)浸潤(rùn) : dG 01 - 2 01 = PP ; 2 = PE ABA: C2/C8 茂金屬催化聚烯烴B: Licocene PP * 在沒(méi)有處理的聚丙烯膜上在沒(méi)有處理的聚丙烯膜上Slide 14Marketing Specialties BusinessMS Formulators1.Licocene introduction2.Licocene product rang

16、e3.Licocene properties4. Licocene compatibilities5. Licocene applications5/30/2022有機(jī)揮發(fā)物有機(jī)揮發(fā)物(VOC)* *170C/敞開(kāi)容器敞開(kāi)容器/ 氧氣氧氣% 失重3. Licocene在膠粘劑和密封膠上的應(yīng)用在膠粘劑和密封膠上的應(yīng)用Slide 15Marketing Specialties BusinessMS Formulators1.Licocene introduction2.Licocene product range3.Licocene properties4. Licocene compatibil

17、ities5. Licocene applications5/30/2022 3.日本室內(nèi)空氣污染的標(biāo)準(zhǔn)日本室內(nèi)空氣污染的標(biāo)準(zhǔn)室內(nèi)的濃度標(biāo)準(zhǔn)室內(nèi)的濃度標(biāo)準(zhǔn)有害揮發(fā)性化學(xué)成分有害揮發(fā)性化學(xué)成分濃度濃度資料資料甲醛100m/m3(0.08ppm)1997.6.13甲苯260m/m3(0.07ppm)2000.6.26二甲苯870m/m3(0.20ppm)2000.6.26二氯苯240m/m3(0.04ppm)2000.6.26乙基苯3800m/m3(0.88ppm)2000.12.15苯乙烯220m/m3(0.03ppm)2000.12.15氯吡磷1m/m3(0.07pp)2000.12.15鄰苯

18、二甲酸酯類(lèi)220m/m3(0.02ppm)2000.12.15十四烷類(lèi)化合物330m/m3(0.04ppm)200.7.5鄰苯二乙酸酯類(lèi)120m/m3(7.6pp)2001.7.5二嗪磷 0.29mg/m3(0.02ppb）2001.7.5乙醛48m/m3(0.03ppm)2002.1.22 總的有機(jī)揮發(fā)物(TVOC)目標(biāo)值 400mm/m32000.12.15Slide 16Marketing Specialties BusinessMS Formulators1.Licocene introduction2.Licocene product range3.Licocene properti

19、es4. Licocene compatibilities5. Licocene applications5/30/2022 g/m3. 日本室內(nèi)空氣污染標(biāo)準(zhǔn)日本室內(nèi)空氣污染標(biāo)準(zhǔn)/十四烷類(lèi)化合物十四烷類(lèi)化合物g/mSlide 17Marketing Specialties BusinessMS Formulators1.Licocene introduction2.Licocene product range3.Licocene properties4. Licocene compatibilities5. Licocene applications5/30/20223. Licocene在膠

20、粘劑和密封膠上的應(yīng)用在膠粘劑和密封膠上的應(yīng)用 Licocene PP 1602 DSCLicocene 顯示出優(yōu)異的冷卻過(guò)程DSC Tc 37CDSC Tm 75C37C75CSlide 18Marketing Specialties BusinessMS Formulators1.Licocene introduction2.Licocene product range3.Licocene properties4. Licocene compatibilities5. Licocene applications5/30/20224. Licocene在膠粘劑和密封膠上的應(yīng)用在膠粘劑和密封膠上

21、的應(yīng)用Slide 19Marketing Specialties BusinessMS Formulators1.Licocene introduction2.Licocene product range3.Licocene properties4. Licocene compatibilities5. Licocene applications5/30/20224. Licocene在膠粘劑和密封膠上的應(yīng)用在膠粘劑和密封膠上的應(yīng)用Licocene 和脂肪烴類(lèi)樹(shù)脂和脂肪烴類(lèi)樹(shù)脂,松香樹(shù)脂等增粘樹(shù)脂松香樹(shù)脂等增粘樹(shù)脂,有較有較好的相容性好的相容性,如如: Regalite R range (11

22、25, 1100,1010, .) (伊士曼) Eastotac range (115W, 110, .) (伊士曼) Escorez ( 53xx; 54xx series)(?？松? Regalite R9100 (伊士曼) Sukurez SU 90,200, (南韓) Arkon M100 (陶氏)Abitol E (伊士曼) Plastolyn R1140 (伊士曼) Foralyn 5020 (伊士曼)Foralyn 110/90 (伊士曼)Slide 20Marketing Specialties BusinessMS Formulators1.Licocene introduc

23、tion2.Licocene product range3.Licocene properties4. Licocene compatibilities5. Licocene applications5/30/20224. Licocene在膠粘劑和密封膠上的應(yīng)用在膠粘劑和密封膠上的應(yīng)用Licocene 和以下的聚合物有較好的相容性和以下的聚合物有較好的相容性 : APAO (如: Vestoplast 系列) SEBS (如: Kraton G-1657) 少量的 ( 沒(méi)有反滲= 可用更薄的無(wú)紡布PE膜和無(wú)紡布粘接的剝離強(qiáng)度膜和無(wú)紡布粘接的剝離強(qiáng)度 grams5. Licocene在膠粘劑和

24、密封膠上的應(yīng)用在膠粘劑和密封膠上的應(yīng)用Slide 29Marketing Specialties BusinessMS Formulators1.Licocene introduction2.Licocene product range3.Licocene properties4. Licocene compatibilities5. Licocene applications5/30/2022 基于Licocene PP 1602的配方有以下優(yōu)點(diǎn): 1. 和SIS,SBS相比,上膠量可以更少 2. 沒(méi)有壓敏性 = 可以用更薄的無(wú)紡布3. 不含SIS4. 配方不含油 grams5. Licoc

25、ene在膠粘劑和密封膠上的應(yīng)用在膠粘劑和密封膠上的應(yīng)用Slide 30Marketing Specialties BusinessMS Formulators1.Licocene introduction2.Licocene product range3.Licocene properties4. Licocene compatibilities5. Licocene applications5/30/20225. Licocene在膠粘劑和密封膠上的應(yīng)用在膠粘劑和密封膠上的應(yīng)用如如:紡織品和紡織品的復(fù)合紡織品和膜的復(fù)合紡織品和海綿類(lèi)材料的復(fù)合Licocene用于紡織品的涂布和復(fù)合用于紡織品的

26、涂布和復(fù)合Slide 31Marketing Specialties BusinessMS Formulators1.Licocene introduction2.Licocene product range3.Licocene properties4. Licocene compatibilities5. Licocene applications5/30/2022有以下的膠粘劑有以下的膠粘劑:-反應(yīng)型的反應(yīng)型的PU熱熔膠熱熔膠-反應(yīng)型的反應(yīng)型的PU溶劑膠溶劑膠-水性橡膠水性橡膠, .-熱塑型熱熔膠熱塑型熱熔膠5. Licocene在膠粘劑和密封膠上的應(yīng)用在膠粘劑和密封膠上的應(yīng)用什么類(lèi)型的膠

27、粘劑適合應(yīng)用于紡織品的復(fù)合呢?Slide 32Marketing Specialties BusinessMS Formulators1.Licocene introduction2.Licocene product range3.Licocene properties4. Licocene compatibilities5. Licocene applications5/30/2022防護(hù)服防護(hù)服運(yùn)動(dòng)服運(yùn)動(dòng)服典型的終端應(yīng)用典型的終端應(yīng)用:5. Licocene在膠粘劑和密封膠上的應(yīng)用在膠粘劑和密封膠上的應(yīng)用Slide 33Marketing Specialties BusinessMS Fo

28、rmulators1.Licocene introduction2.Licocene product range3.Licocene properties4. Licocene compatibilities5. Licocene applications5/30/2022典型的終端應(yīng)用典型的終端應(yīng)用:5. Licocene在膠粘劑和密封膠上的應(yīng)用在膠粘劑和密封膠上的應(yīng)用醫(yī)療行業(yè)醫(yī)療行業(yè) 醫(yī)院用的床墊罩 手術(shù)衣 Slide 34Marketing Specialties BusinessMS Formulators1.Licocene introduction2.Licocene produc

29、t range3.Licocene properties4. Licocene compatibilities5. Licocene applications5/30/2022汽車(chē)行業(yè)汽車(chē)行業(yè)座椅汽車(chē)門(mén)內(nèi)的面板典型的終端應(yīng)用典型的終端應(yīng)用:5. Licocene在膠粘劑和密封膠上的應(yīng)用在膠粘劑和密封膠上的應(yīng)用Slide 35Marketing Specialties BusinessMS Formulators1.Licocene introduction2.Licocene product range3.Licocene properties4. Licocene compatibiliti

30、es5. Licocene applications5/30/2022女性?xún)?nèi)衣女性?xún)?nèi)衣:內(nèi)衣罩杯的制造典型的終端應(yīng)用典型的終端應(yīng)用:5. Licocene在膠粘劑和密封膠上的應(yīng)用在膠粘劑和密封膠上的應(yīng)用Slide 36Marketing Specialties BusinessMS Formulators1.Licocene introduction2.Licocene product range3.Licocene properties4. Licocene compatibilities5. Licocene applications5/30/2022上膠方式上膠方式:輪轉(zhuǎn)凹版上膠輪轉(zhuǎn)凹版

31、上膠:絲網(wǎng)上膠絲網(wǎng)上膠:槽膜涂布槽膜涂布:5. Licocene在膠粘劑和密封膠上的應(yīng)用在膠粘劑和密封膠上的應(yīng)用Slide 37Marketing Specialties BusinessMS Formulators1.Licocene introduction2.Licocene product range3.Licocene properties4. Licocene compatibilities5. Licocene applications5/30/2022上膠方式上膠方式:滾輪上膠滾輪上膠:噴膠噴膠:5. Licocene在膠粘劑和密封膠上的應(yīng)用在膠粘劑和密封膠上的應(yīng)用Slide

32、38Marketing Specialties BusinessMS Formulators1.Licocene introduction2.Licocene product range3.Licocene properties4. Licocene compatibilities5. Licocene applications5/30/2022復(fù)合用熱熔膠復(fù)合用熱熔膠:目前正在使用目前正在使用:-壓敏性熱熔膠壓敏性熱熔膠-EVA基的熱熔膠基的熱熔膠-APAO基的熱熔膠基的熱熔膠(如如: 床墊的被套床墊的被套)5. Licocene在膠粘劑和密封膠上的應(yīng)用在膠粘劑和密封膠上的應(yīng)用Slide 3

33、9Marketing Specialties BusinessMS Formulators1.Licocene introduction2.Licocene product range3.Licocene properties4. Licocene compatibilities5. Licocene applications5/30/2022Licocene在紡織品的涂布和復(fù)合上的應(yīng)用在紡織品的涂布和復(fù)合上的應(yīng)用 1.Licocene PP 2602 對(duì)許多纖維類(lèi)的材料有著優(yōu)異的粘附力對(duì)許多纖維類(lèi)的材料有著優(yōu)異的粘附力,同時(shí)同時(shí)由于其內(nèi)聚力好由于其內(nèi)聚力好,因此因此,其膠耗可以減少其膠耗可以

34、減少50% .2.當(dāng)當(dāng)Licocene的上膠量為的上膠量為10g/m2時(shí)時(shí),其剝離強(qiáng)度和上膠量為其剝離強(qiáng)度和上膠量為 26 g/m 的的EVA熱熔膠相當(dāng)熱熔膠相當(dāng)5. Licocene在膠粘劑和密封膠上的應(yīng)用在膠粘劑和密封膠上的應(yīng)用Slide 40Marketing Specialties BusinessMS Formulators1.Licocene introduction2.Licocene product range3.Licocene properties4. Licocene compatibilities5. Licocene applications5/30/2022Lico

35、cene在紡織品的涂布和復(fù)合上的應(yīng)用在紡織品的涂布和復(fù)合上的應(yīng)用對(duì)紡織品上的應(yīng)用對(duì)紡織品上的應(yīng)用,如涂布如涂布,復(fù)合復(fù)合,增強(qiáng)增強(qiáng), Licocene是一種很好的選擇是一種很好的選擇5. Licocene在膠粘劑和密封膠上的應(yīng)用在膠粘劑和密封膠上的應(yīng)用Slide 41Marketing Specialties BusinessMS Formulators1.Licocene introduction2.Licocene product range3.Licocene properties4. Licocene compatibilities5. Licocene applications5/3

36、0/2022應(yīng)用應(yīng)用 Licocene的兩種不同方法的兩種不同方法 1. 熔融后涂布熔融后涂布 : 相應(yīng)產(chǎn)品相應(yīng)產(chǎn)品100%的的Licocene PP 2602,無(wú)需配方無(wú)需配方2. 粉末應(yīng)用粉末應(yīng)用: 相應(yīng)產(chǎn)品相應(yīng)產(chǎn)品 Licocene PP 1602 pwdLicocene PP 2602 pwd也是也是100% Licocene,無(wú)需配方無(wú)需配方5. Licocene在膠粘劑和密封膠上的應(yīng)用在膠粘劑和密封膠上的應(yīng)用Slide 42Marketing Specialties BusinessMS Formulators1.Licocene introduction2.Licocene pr

37、oduct range3.Licocene properties4. Licocene compatibilities5. Licocene applications5/30/2022應(yīng)用應(yīng)用 Licocene兩種不同方法兩種不同方法1. 熔融后涂布熔融后涂布: 2. 粉末應(yīng)用粉末應(yīng)用- 設(shè)備成本高設(shè)備成本高 - 設(shè)備成本低設(shè)備成本低- 膠的成本相對(duì)較低膠的成本相對(duì)較低 - 粉末的成本較高粉末的成本較高 - 速度可達(dá)到速度可達(dá)到 60m/min - 速度一般只有速度一般只有 10 m/min- 上膠量低上膠量低 - 上膠量高上膠量高 ( 30-45g/m) ( 12-30g/m)5. Lico

38、cene在膠粘劑和密封膠上的應(yīng)用在膠粘劑和密封膠上的應(yīng)用Slide 43Marketing Specialties BusinessMS Formulators1.Licocene introduction2.Licocene product range3.Licocene properties4. Licocene compatibilities5. Licocene applications5/30/20225. Licocene在膠粘劑和密封膠上的應(yīng)用在膠粘劑和密封膠上的應(yīng)用壓敏膠配方壓敏膠配方 Ba W368/112:不含SIS的 壓敏膠配方不含油 的壓敏膠配方針對(duì)多功能的壓敏膠應(yīng)用,

39、如標(biāo)簽,基于 Licocene PP A 330Slide 44Marketing Specialties BusinessMS Formulators1.Licocene introduction2.Licocene product range3.Licocene properties4. Licocene compatibilities5. Licocene applications5/30/20225. Licocene在膠粘劑和密封膠上的應(yīng)用在膠粘劑和密封膠上的應(yīng)用熱熔壓敏膠配方熱熔壓敏膠配方: BaW 368/112Licocene PPA 33030%Kraton G 165720%Foral 85E35%Regalite 710015%Slide 45Marketing Specialties BusinessMS Formulators1.Licocene introduction2.Licocene pr