土壤GSS標(biāo)準(zhǔn)物質(zhì)認(rèn)定證書

1、雨戶國家質(zhì)量監(jiān)督檢驗(yàn)檢疫總局批準(zhǔn)GBW07446 GBW07457標(biāo)準(zhǔn)物質(zhì)認(rèn)定證書土壤成分分析標(biāo)準(zhǔn)物質(zhì)Certified Reference Materials for the ChemicalComposition of soil證書編號定值日期 2009 年3月有效期 年 月認(rèn)定機(jī)構(gòu)：中國地質(zhì)科學(xué)院地球物理地球化學(xué)勘查研究所、概述本系列土壤標(biāo)準(zhǔn)物質(zhì)計12個，主要用于地質(zhì)、地球化學(xué)調(diào)查與礦產(chǎn)普查樣品測試的量 值和質(zhì)量監(jiān)控標(biāo)準(zhǔn)，亦可供其它部門分析類似物質(zhì)使用。二、樣品制備樣品經(jīng)晾干，過0.25mm或1m懶去除雜物，混合，120C烘24h去負(fù)水、滅活，GSS1表 GSS24用高鋁瓷球磨機(jī)研磨至-

2、0.074mm占99如上。GSS25- GSS28采用氣流粉碎至-0.020mm,用高鋁瓷皮磨機(jī)混勻48ho編號采樣地區(qū)編號采樣地區(qū)GSS-17內(nèi)蒙古烏拉特后旗沙化土GSS-23浙江省象山東海灘涂沉積物GSS-18內(nèi)蒙占杭錦后旗鹽堿土GSS-24）、,東省陽江而南海灘涂沉積物GSS-19青海省海晏縣棕漠土GSS-25陜西省洛川黃土GSS-20新疆鄱善鹽堿土GSS-26安徽五河淮河沉積物GSS-21新疆石河子市灰鈣土GSS-27江蘇省張家港長江沉積物GSS-22山東省日照市黃河灘涂沉積物GSS-28湖南省益陽市湘江沉積物三、均勻性和穩(wěn)定性從最小包裝瓶中隨機(jī)抽取24瓶，采用X-射線熒光法對不同含量

3、和性質(zhì)的代表性元素進(jìn) 行雙份分析，用方差分析進(jìn)行檢驗(yàn)，證明樣品均勻性良好，分析最小取樣量為0.1g o經(jīng)穩(wěn)定性考核證明樣品穩(wěn)定性良好。有效期至 2025年。四、認(rèn)定值與不確定度數(shù)據(jù)不少于6組、用準(zhǔn)確方法測試且精度良好為認(rèn)定值；數(shù)據(jù)少（但不少于3組）或精度不符合要求者為參考值，用帶括號數(shù)據(jù)表示。不確定度（U）用公式u 10gn1）?r2 =-2t0.05（n 1）?/八n）2 R/（2?13m）估算，式中Ua, Ub分別為A類和B類標(biāo)準(zhǔn)不確定度估計值，t 為t分布取95%的置信度、自由度為n-1的t列表值，s和n為測試數(shù)據(jù)的標(biāo)準(zhǔn)偏差和數(shù) 據(jù)組數(shù)，R和m為分析方法平均值的極差和參與統(tǒng)計（n2）的方

4、法數(shù)，測試方法單一的用 3 - s/工作不確定度的估計值。五、包裝與儲存樣品以密封良好的玻璃瓶包裝，70g/瓶，用后蓋緊密封保存于陰涼處。六、測試單位國家地質(zhì)實(shí)驗(yàn)測試中心、安徽省地質(zhì)實(shí)驗(yàn)研究所、湖北省地質(zhì)實(shí)驗(yàn)研究所、成都綜合 巖礦測試中心、吉林省地質(zhì)科學(xué)研究所、福建省地質(zhì)礦產(chǎn)實(shí)驗(yàn)室測試中心、核工業(yè)第三研 究所、河南省巖礦測試中心、地球物理地球化學(xué)勘查研究所、中國原子能科學(xué)研究院、陜 西省地質(zhì)礦產(chǎn)實(shí)驗(yàn)研究所、中國科學(xué)院上海硅酸鹽研究所、河北省巖礦測試中心、天津地 質(zhì)礦產(chǎn)研究所。附表定值分析方法兀素分解與曷集萬法測定萬法兀素分解與曷集萬法測定萬法AgDP8 DA1 DMA1 DF1 DFI1AES

5、8 GFAAS2 ICPMS1 AAS1PbDF7 DP6 DFC1XRF5 ICPMS5 ICPES2 AES1 AAS1AsDA10 DP2 DF1AFS8 ICPMS3 XRF1 INAA1PrFU3 DF3 DFI1 DMA1 DFC1ICPMS8 ICPES1BDP8 DFC1AES8 ICPES1RbDP7 DF6XRF6 ICPMS4 ICPES1 AAS1 INAA1BaDF6 DP4 FU2 DFC1ICPMS5 ICPES5 XRF4 INAA1SDP5 FU1 COB2 DH1P XRF5 VOL3 COL1BeDF9 DFC1 DMA1ICPES7 ICPMS4SbDA

6、9 DF2AFS8 ICPMS3BiDA6 DF4 DFC1ICPMS6 AFS5ScDF7 DP2 DMA1ICPMS7 ICPES1 XRF1 INAA1BrDP5 FUP2 FU1XRF5 ICPMS2 IC1SeDA6 DMA1 FU1P AFS9CdDF5 DMA3 DFC1 DFI1 DA1GFAAS4 ICPMS5 ICPES1 AAS1SmDF3 FU3 DFC1 DMA1DFI1 DP1ICPMS9 INAA1CeFU5 DF3 DP2 DFC1 DMA1ICPMS7 ICPES3 XRF1 INAA1SnDP7 DFC1P AES7 ICPMS1ClDP7 FU2XRF7

7、VOL1 IC1SrDF6 DP6 FU3XRF6 ICPMS5 ICPES4CoDF8 DP3 FU2 DMA1 DFC1ICPMS8 ICPES4 XRF2 INAA1TaDF4 FU2 DFC1 DP1ICPMS7 INAA1CrDF6 DP6 DFC1 FU1ICPES5 XRF5 ICPMS3 INAA1TbFU3 DF2 DFC1 DFI1 DP1 DMA1ICPMS8 ICPES1 INAA1CsDF5 DP2 DFC1 DFP1ICPMS6 INAA1 XRF1 AAS1TeDMA2 DF1ICPMS3CuDF10 DP4 DMA1ICPES7 XRF4 ICPMS3 AAS1

8、ThDF7 DP3 FU1ICPMS7 XRF2 INAA1 ICPES1DyDF3 FU3 DFC1 DMA1 DFI1ICPMS8 ICPES1TiDP4 DF3 FUS3 FU2XRF7 ICPES2 COL2 ICPMS1ErDF3 FU3 DFC1 DMA1 DFI1ICPMS8 ICPES1TlDF7 DA1 DFC1 FU1ICPMS9 GFAAS1EuDF3 FU3 DFC1 DP1 DMA1 DFI1ICPMS8 ICPES1 INAA1TmDF4 FU3 DFI1 DFC1ICPMS8 ICPES1FFU8ISE8UDF7 FU1 DFC1 DP1 DA1ICPMS9 IN

9、AA1 LF1GaDP6 DF5 FU1 DFC1ICPMS7 XRF6VDF6 DP2 FU2ICPES5 XRF2 ICPMS3GdDF3 FU3 DFC1 DMA1 DFI1ICPMS9WFU5 DF4 DFC1ICPMS6 POL4GeDA3 DF2 DMA1 FU1 DFC1 DP1AFS7 ICPMS2 XRF1YDP5 DF4 FU3 DFC1 DFI1 DMA1ICPMS8 XRF5 ICPES2HfDF3 DP2 FU1 DFC1ICPMS4 ICPES1 XRF1 INAA1YbFU3 DF2 DFI1 DMA1 DP1ICPMS7 ICPES1 INAA1HgDA9AFS

10、9ZnDF10 DP6ICPES7 XRF5 ICPMS3 INAA1HoDF3 FU3 DFC1 DMA1 DFI1ICPMS8 ICPES1ZrDP5 DF2 FU1 DFC1XRF5 ICPMS4IFU7 DMA1COL5 ICPMS3SiO2FU8 FUS3GR6 XRF3 VOL2InDF5 FU2 DA1 DFC1ICPMS9ALOFU8 DF3 FUS3VOL8 ICPES3 XRF3LaDF4 FU3 DP2 DMA2 DFI1 DFC1ICPMS7 ICPES4 XRF1 INAA1TFezQFU6 DF4 FUS3 DMA1 DP1ICPES5 COL4 XRF3 VOL2

11、 INAA1LiDF9 DMA1ICPES5 ICPMS4 AAS1FeODF3VOL3LuDF3 FU3 DFI1 DMA1 DFC1 DP1ICPMS8 ICPES1 INAA1MgODF6 FU3 FUS3 DMA1ICPES5 VOL3 XRF3 AAS2MnDF7 DP4 FUS2 DMA1 FU1ICPES8 XRF5 AAS1CaODF7 FU3 FUS3 DMA1ICPES6 XRF3 VOL3 AAS2MoDF5 FU4 DP1 DFC1ICPMS7 POL3 AES1NaODF8 FUS3 DMA1 DP1ICPES6 AAS3 XRF3 INAA1NDA9 DMA1VOL

12、10K2ODF8 FUS3 DMA1 DP1ICPES6 AAS3 XRF3 INAA1NbDP6 DF4 FU2 DFC1XRF6 ICPMS6 ICPES1DH7GR7NdDF5 FU2 DFI1 DFC1 DP1ICPMS8 ICPES1 INAA1CODA6VOL6NiDF9 DP3 DFC1 DMA1ICPES6 ICPMS5 XRF3CorgDH7 DA1 DMA1VOL9PDF5 DP4 FU2 FUS2XRF6 ICPES4 COL2 ICPMS1TCDH5 DP1VOL5 XRF1注：分解與富集方法：DF含氫氟酸的混合酸分解，DAi水分解，F(xiàn)U熔融，DPS末法，DM解合酸分解

13、，DFC昆合酸加氫氟酸分解，F(xiàn)US熔片法，DFI堿熔離子交換樹脂富集法，COEB燒法, DHB解法，加P為預(yù)富集； 測定方法：ICPMS?離子體質(zhì)譜法，ICPES等離子體光譜法，XRF X-射線熒光粉末壓片法，AES原子發(fā)射光譜法，AFS原子熒光法，VO喀量法，GRM量法, AAS原子吸收法，GFAASB墨爐原子吸收法，INAA儀器中子活化法，CO冷光光度法，IC離子色譜法，POL催化波極譜法，ISE離子選擇電極法，LF激光熒光法。土壤成分認(rèn)定值與不確定度(10-6)GBW07446(GSS-17)GBW07447(GSS-18)GBW07448 (GSS-19)GBW07449 (GSS-2

14、0)GBW07450 (GSS-21)GBW07451 (GSS-22)Ag0.050 0.0060.066+0.0050.050+0.0050.068 +0.0070.073+0.0030.074+0.006As6.2 0.410.7 +0.57.7 +0.48.7 +0.69.7 +0.47.8 +0.5B24+362+751 + 4143 + 3848+652+7Ba606+12459+9534+14356 17510+4749+14Be1.3 +0.11.7 0.11.7 +0.11.3 +0.11.6 +0.12.1 +0.1Bi0.15 +0.020.25 +0.010.23 +0

15、.010.19 +0.010.25 +0.020.25 +0.02Br0.8 +0.27.2 +1.05.8 +0.76.5 +1.21.5 +0.224+2Cd0.058 +0.0110.15 +0.010.108 +0.0090.108 +0.0110.139+0.0080.065 +0.012Ce25+257 + 257+237+252+281 + 4Cl38+60.78 +0.05 *758+784.0 +0.3 *152+120.51 +0.03 *Co5.0 +0.210.2 +0.39.7 +0.311.3 +0.411.0 +0.311.6 +0. 3Cr25+555+249+

16、243+355+557+3Cs3.0 +0.36.3 +0.38.2 +0.24.2 +0.25.8 +0.45.5 +0.2Cu12.6 +0.619.5 +0.516.0 +0.528+124+118.3 +0.8Dy2.3 +0.24.2 +0.23.8 +0.23.8 +0.34.8 +0.44.6 +0.1Er1.3 +0.12.4 +0.22.2 +0.22.3 +0.22.8 +0.32.6 +0.2Eu0.66 +0.051.06 +0.051.00 +0.050.95 +0.041.13 +0.061.30 +0.03F219+20495+40466+14524+30510+

17、31419+21Ga10.8 +0.513.2 +0.413.4 +0.612.9 +0.715.1 +0.317.4 +0.5Gd2.2 +0.14.4 +0.24.2 +0.23.7 +0.44.7 +0.45.3 +0.2Ge1.11 0.081.21 +0.041.23 +0.050.99 +0.061.24 +0.071.28 +0.07Hf3.8 +0.35.8 +0.36.0 +0.34.3 +0.45.5 +0.27.2 +0.5Hg(0.007)0.015+0.0030.013+0.0030.008 +0.0020.020+0.0020.020+0.002Ho0.46 +0.

18、040.84 +0.060.77 +0.040.80 +0.060.98 +0.090.93 +0.05I0.52 +0.131.4 +0.21.9 +0.21.4 +0.40.73 +0.148.6 +0.7In0.024+0.0030.043 +0.0050.038 +0.0040.042 +0.0050.049+0.0050.051 +0.007La14.0 +0.330+130+119.4 +1.426+144+2Li14.2 +0.832+230+127+228 + 136+1Lu0.24 +0.020.38 +0.0 30.35 +0.020.38+0.030.47 +0.050.

19、43 +0.02Mn309+6529+10518+13667+20700+17755+13Mo0.51 +0.060.61 +0.060.61 +0.053.2 +0.30.68 +0. 070.63 +0.05N(106)273+331030+109(580)460+38438 29Nb6.3 +0.812.6 +0.611.8 +0.38.4 +1.211.4 +0.515.4 +0.6Nd12.4 +0.426+125+118.7 +1.025+ 135+2Ni9.6 +0.625+121+120+228+ 126+1說明：元素符號前帶#含量單位為10: 帶*數(shù)據(jù)含量單位為10一2, “

20、土”后的數(shù)值為不確定度，括號內(nèi)的 數(shù)值為參考值，為信息值。土壤成分認(rèn)定值與不確定度（續(xù)）(10-6)GBW07446 (GSS-17)GBW07447(GSS-18)GBW07448(GSS-19)GBW07449(GSS-20)GBW07450(GSS-21)GBW07451 (GSS-22)P228 14587 + 9505+16706 + 24612+14438+18Pb17.4 +1.120+118.7 +0.913.4 + 1.217+126+2Pr3.2 +0.26.9 +0.36.9 +0.34.7 +0.26.4 +0.59.4 +0.5Rb80+386+295+263+385

21、+2108+4#Re0.0740.250.292.10.240.12S108 14(0.7)*(816)2.70 +0.29 *(167)440+42Sb0.56 +0.070.88 +0.050.58 +0.050.59 +0.031.10 +0.070.50 +0.05Sc5.1 0.59.7 +0.48.7 +0.412.0 +0.411.2 +0.310.4 +0.3Se0.093 +0.0080.12 +0.020.24 +0.030.90 +0.100.084+0.0120.11 +0.02Sm2.4 +0.15.0 +0.24.7 +0.24.0 +0.15.1 +0.26.1

22、+0.3Sn1.3 +0.32.4 +0.42.3 +0.21.8 +0.42.4 +0.32.6 +0.2Sr209+8242+5232+8435+13205+5202+7Ta0.42 +0.080.91 +0.140.88 +0.100.57 +0.080.84 +0.121.1 +0.2Tb0.37 +0.030.74 +0.040.69 +0.030.66 +0.040.80 +0.050.85 +0.03Te(0.03)(0.03)(0.04)(0.04)(0.05)(0.04)Th4.3 +0.39.9 +0.79.7 +0.56.2 +0.48.4 +0. 811.7 +0.9T

23、i%0.191 +0.0050.32 +0.010.30 +0.010.33 +0.030.37 +0.020.38 +0.01Tl0.51 +0.040.55 +0.020.57 +0.060.37 +0.040.51 +0.050.61 +0.05Tm0.23 +0.020.39 +0.030.35 +0.030.38 +0.030.47 +0.040.43 +0.02U1.2 +0.12.3 +0.22.8 +0.25.4 +0.52.0 +0.11.9 +0.2V40+466+560+582+775+369+3W0.7 +0.11.6 +0.11.4 +0.10.9 +0. 21.5

24、+0. 11.5 +0.1Y12.7 +0.823+221+122+327+225+1Yb1.5 +0.12.5 +0.22.2 +0.22.4 +0.33.0 +0.32.8 +0.2Zn29+263+252+261 + 266+359+2Zr134+5204+6209+8153 + 18190+12255+13%SiO278.30 +0.3360.40+0.2666.95+0.2647.28 +0.1 360.30+0.4168.23 +0. 27AlzQ9.65 +0.0910.56+0.0511.02 +0.1010.39 +0.1011.96 +0.0913.89 +0.1 7TFe

25、Q2.07 +0.033.63 +0.053.44 +0.064.12 +0.074.07 +0.064.06 +0.05FeO(0.5)(1.1)(1.4)(0.6)(1.1)(0.6)MgO0.78 +0.082.58 +0.071.69 +0.032.98 +0.1 32.04 +0.041.47 +0.0 6CaO1.83 +0.056.80 +0.104.75 +0.066.48 +0.107.40 +0.091.09 +0.04NaO2.31 +0.043.05 +0.092.16 +0.058.99 +0.2 62.02 +0.042.84 +0.10K2O2.56 +0.032

26、.11 +0.022.29 +0.021.99 +0.052.43 +0.042.97 +0.0 4HLO+(1.2)(2.7)(2.5)(3.2)(3.4)(3.4)CO0.76 +0.134.54 +0.422.92 +0.27(2.2)4.79 +0.25(0.2)Corg(0.1)0.25 +0.051.00 +0.06(0.4)0.34 +0.02(0.3) *TC(0.3)(1.4)1.80 +0.061.03 +0.041.71 +0.10(0.4)土壤成分認(rèn)定值與不確定度(10-6)GBW07452 (GSS-23)GBW07453(GSS-24)GBW07454 (GSS-2

27、5)GBW07455 (GSS-26)GBW07456 (GSS-27)GBW07457 (GSS-28)Ag0.069 0.0050.092 0.0130.070+0.0080.070+0.0040.14 +0.010.13 +0.01As11.8 +0.915.8 +0.912.9 +0.58.9 +0.513.3 + 1.128.5 +2 .0B77+883+754+652+864+780+10Ba441+11340+9495 + 16504+17496+15532+17Be2.3 +0.12.7 +0.21.9 +0.11.9 +0.12.3 +0.13.6 +0.2Bi0.44 +0

28、.030.98 +0.030.32 +0.010.28 +0.010.79 +0.021.53 +0.08Br26+324+22.6 +0.33.0 +0.41.9 +0.21.8 +0.3Cd0.15 +0.020.106+0.0070.175 +0.01 00.14 +0.010.59 +0.040.52 +0.03Ce78+589+371 + 370 582+41074Cl0.63 0.06*0.48 +0.03*61 + 575+971 + 941+6Co16.0 +0.612.4 +0.412.0 +0.511.2 +0.519.0 +0.618.2 +0.5Cr82+462 + 2

29、66+461 +392+494+5Cs9.3 +0.59.8 +0.27.2 +0.36.0 +0.47.7 +0.519.6 +0.7Cu32+128+ 123.6 +1 .019.1 +0.654+238+2Dy5.4 +0.36.1 +0.25.0 +0.44.9 +0.35.7 +0.26.3 +0.4Er3.0 +0.13.5 +0.42.8 +0.32.8 +0.33.2 +0.23.7 +0.2Eu1.4 +0.11.25 +0.041.20 +0.061.21 +0.061.50 +0.051.38 +0.03F665+54524 + 40561 + 43551 + 26650

30、 + 40780+29Ga18.5 +0.418.3 +0.614.9 +0.414.8 +0.517.9 +0.625+1Gd5.8 +0.26.3 +0.25.3 +0.35.3 +0.36.2 +0.36.6 +0.2Ge1.40 0.081.52 +0.091.31 +0.041.30 +0.081.47 +0.081.83 +0.10Hf6.1 +0.410.6 +0.57.0 +0.77.6 +0.27.1 +0.46.4 +0.5Hg0.058 +0.0050.075 +0.0070.043+0.0030.030+0.0030.116 +0.0120.143+0.013Ho1.0

31、8 +0.1 01.22 +0.091.02 +0.080.99 +0.081.13 +0.071.27 +0.08I6.1 0.76.4 +0.51.5 +0.21.1 +0.21.0 +0.21.2 +0.3In0.066+0.0050.088 +0.0100.049 +0.0050.045+0.0060.089+0.0070.122 +0.014La42+244+ 135+ 136+243+ 150+2Li50+155+332+231 + 241 + 266+2Lu0.48 +0.020.59 +0.050.45 +0.040.45 +0.030.50 +0.020.59 +0.04Mn

32、882+18717 + 13632+21561 + 23956 + 370.112 +0.003 *Mo0.65 +0.061.1 +0. 10.72 +0.070.47 +0.060.84 +0.111.18 +0.2 0N600+50617 + 44696+39878+77850+940.143+0.009 *Nb17.4 +0.719.2 +1.014.2 +0.514.9 +0.720+119.6 +1.4Nd36+238+231+134+244+243+2Ni38+124+ 130+ 126+ 143+243+2土壤成分認(rèn)定值與不確定度（續(xù)）(10-6)GBW07452(GSS-23

33、)GBW07453(GSS-24)GBW07454(GSS-25)GBW07455(GSS-26)GBW07456(GSS-27)GBW07457(GSS-28)P675+ 21414+14857+39846+50778 +41493+27Pb28+140+222 + 121 + 241 + 261 + 2Pr9.3 +0.49.8 +0.48.0 +0.58.2 +0.69.8 +0.811.0 +0.3Rb123+5139+595+291 + 4105+3182 + 7#Re0.170.450.080.10.390.22S(420)0.20 0.03*170+22162 + 10254+1

34、2281 + 21Sb0.77+0.051.05 +0.051.13 +0.050.86 +0.061.21 +0.043.6 +0.2Sc13.8 +0.611.7 +0.411.6 +0.410.6 +0.314.2 +0.416.3 +0.4Se0.13 +0.020.20 +0.030.124+0.0170.14 +0.020.29 +0.040.44 +0.05Sm6.6 +0.37.1 +0.25.8 +0.35.8 +0.36.9 +0.37.4 +0.2Sn3.4 +0.36.2 +0.62.9 +0.42.8 +0.24.0 +0.48.7 +1.3Sr154+555+3192+6184+7146+651+3Ta1.3 +0.21.96 +0.191.10 +0.121.12 +0.141.49 +0.141.8 +0.4Tb0.93 +0.051.08 +0.060.86 +0.060.86 +0.051.00 +0.041.11 +0.03Te(0.06)(0.06)(0.05)(0.04)(0.1)(0.1)Th13.5 +0.820.6 +0.911