附錄2能量平衡計算書

1、目錄1.1總述11.2熱量的原理和準則11.3熱量任務11.4熱量. 21.4.1Claus 硫磺回收工段能量. 21.4.2SCOT 尾氣處理工段能量. 121.4.3碳捕集工段能量. 251.5總結301.1 總述700 萬立方米/年含硫廢氣處理副產(chǎn) 3 萬噸硫磺項目，在全工藝段中伴隨著物料從一系或單元進入另一系或單元，在發(fā)生質量傳遞的同時也伴隨著能量的消耗、和轉化。其中的能量變換數(shù)量關系可以從能量求得，對于新設計的車間，可以由此確定設備的熱負荷。再根據(jù)設備的熱負荷大小、所處理物料的性質及工藝要求選擇恰當?shù)脑O備?？傊ㄟ^下述能量，可以為后續(xù)設計工作中提高熱量的利用率，降低能耗提供主要依據(jù)

2、。1.2 熱量的原理和準則工程依據(jù)化工設計中關于熱量的基本和要求，遵循基與實際工藝相結合的原則，進行熱量書的編制。其中一個主要依據(jù)是能量平衡方程： = + 其中，表示輸入設備熱量的總和； 表示輸出設備熱量的總和； 表示損失熱量的總和。對于連續(xù)系統(tǒng)：Q + W = 其中，Q 設備的熱負荷。W 輸入系統(tǒng)的機械能。 離開設備的各物料焓之和。 進入設備的各物料焓之和。在進行全廠熱量時，是以單元設備為基本，考慮由機械能轉換、化學反應和單純的物理變化帶來的熱量變化。最終對全工藝段進行系統(tǒng)級的熱量平衡計算，進而用于指導節(jié)能降耗設計工作。1.3 熱量任務在進行硫磺回收資源化裝置的熱量中，主要通過定量計算完成下

3、述基本任務：確定工藝單元中物料輸送機械（如泵）所需要的功率，以便于進行設備的設計和選型；確定精餾等單元操作中所需要的熱量或冷量以及傳遞速率，計算換熱設備的尺寸，確定加熱劑和冷卻劑的消耗量，為后續(xù)設計中比如供汽、供冷、供水等專業(yè)提供設備條件；確定為保持一定反應溫度所需移除或者加入的熱傳遞速率，指導反應器的設計和選型；提高熱量集成度，充分利用余熱，提高能量利用率，降低能耗；最終計算出總需求能量和能量的費用，并由此確定工藝過程在經(jīng)濟上的可行性。1.4 熱量1.4.1 Claus 硫磺回收工段能量1.4.1.1 反應器（R-0101R-0104）表 1-1 燃燒爐（R-0101）物流焓變計算表INOU

4、TUnitsS0102S0103S0104PhaseVaporVaporVaporTemperatureC38.99364701115.319Prerebar666Molar Vapor Fraction111Mass Flowskg/hr7816.4187998.6715815.09Volume Flowcum/hr849.43711291.6249126.494Molar Enlpykcal/mol-44.70530.276961-19.0133Mass Enlpykcal/kg-1161.499.599897-569.198Molar Entropycal/mol-K4.112535-1

5、.5984814.76172表 1-2 燃燒爐（R-0101）能量表表 1-3 一級 Claus 反應器（R-0102）物流焓變計算表INOUTUnitsS0108S0109PhaseVaporVaporTemperatureC250336.2259Prerebar5.75.7Molar Vapor Fraction11Volume Flowcum/hr3352.7413845.373Mass Flowskg/hr14353.3814353.38Molar Enlpykcal/mol-31.2104-31.7911Mass Enlpykcal/kg-961.607-961.607Molar E

6、ntropycal/mol-K3.0897253.381664Mass Entropycal/gm-K0.0951960.102287Molar Densitykmol/cum0.1319020.112904Mass Densitykg/cum4.2810893.732637Enlpy FlowGcal/hr-13.8023-13.8023HinGcal/hr-13.8023Q( Gcal/hr)W(Gcal/hr)Hin( Gcal/hr)Hout( Gcal/hr)Error00-9.00191-9.001918.43099E-11Mass Entropycal/gm-K0.106848-

7、0.055410.441919Molar Densitykmol/cum0.2390740.2146490.051877Mass Densitykg/cum9.201886.1927231.732877Enlpy FlowGcal/hr-9.07870.076786-9.00191HinGcal/hr-9.00191HoutGcal/hr-9.00191表 1-4 一級 Claus 反應器（R-0102）能量表表 1-5二級 Claus 反應器（R-0103）物流焓變計算表表 1-6 二級 Claus 反應器（R-0103）能量表Q( Gcal/hr)W(Gcal/hr)Hin( Gcal/h

8、r)Hout( Gcal/hr)Error00-14.3824-14.3824-8.03E-15INOUTUnitsS0112S0113PhaseVaporVaporTemperatureC230233.0798Prerebar5.65.6Molar Vapor Fraction11Mass Flowskg/hr12519.0112519.01Volume Flowcum/hr3154.5573172.53Molar Enlpykcal/mol-33.8524-33.8709Mass Enlpykcal/kg-1148.85-1148.85Molar Entropycal/mol-K0.543

9、190.549211Mass Entropycal/gm-K0.0184340.018628Molar Densitykmol/cum0.134680.133844Mass Densitykg/cum3.9685463.946064Enlpy FlowGcal/hr-14.3824-14.3824HinGcal/hr-14.3824HoutGcal/hr-14.3824Q( Gcal/hr)W(Gcal/hr)Hin( Gcal/hr)Hout( Gcal/hr)Error00-13.8023-13.80232.83E-15HoutGcal/hr-13.80231.4.1.2換熱器（E-010

10、1E-0106）表 1-7廢熱鍋爐（E-0101）物流焓變計算表表 1-8 廢熱鍋爐（E-0101）能量表表 1-9 一級硫冷凝器（E-0102）物流焓變計算表UnitsS0105S0106PhaseVaporMixedTemperatureC350140Q( Gcal/hr)W(Gcal/hr)Hin( Gcal/hr)Hout( Gcal/hr)Error00-35.2923-35.29234.64E-09INOUTUnitsS0104S0301S0105S0302PhaseVaporLiquidVaporVaporTemperatureC1115.319210350450.0349Pre

11、rebar6405.945Molar Vapor Fraction1011Mass Flowskg/hr15815.097298.15515815.097298.155Volume Flowcum/hr9126.4948.5403813934.798513.3606Molar Enlpykcal/mol-19.0133-64.8972-29.4489-54.4238Mass Enlpykcal/kg-569.198-3602.34-837.477-3020.98Molar Entropycal/mol-K14.76172-30.13525.504018-10.8984Mass Entropyc

12、al/gm-K0.441919-1.672760.156525-0.60495Molar Densitykmol/cum0.05187747.434550.1143020.789132Enlpy FlowGcal/hr-9.00191-26.2904-13.2448-22.0476HinGcal/hr-35.2923HoutGcal/hr-35.2923表 1-10 一級硫冷凝器（E-0102）能量表表 1-11 一級加熱器（E-0103）物流焓變計算表UnitsS0107S0304S0108S0305PhaseVaporVaporVaporLiquidTemperatureC139.9998

13、450.0349250224.1288Prerebar5.8455.745Molar Vapor Fraction1110Mass Flowskg/hr14353.38738.626514353.384738.6265Volume Flowcum/hr2580.46551.955833352.74140.882568Molar Enlpykcal/mol-32.1627-54.4238-31.21043-64.6182Mass Enlpykcal/kg-990.727-3020.98-961.6073-3586.85Molar Entropycal/mol-K1.029077-10.89843

14、.0897251-29.5713Q( Gcal/hr)W(Gcal/hr)Hin( Gcal/hr)Hout( Gcal/hr)Error-0.9703574910-14.2151-14.21510.0682623152Prerebar5.95.8Molar Vapor Fraction10.984671Mass Flowskg/hr15815.0915815.09Volume Flowcum/hr3934.7982583.518Molar Enlpykcal/mol-29.4489-31.6582Mass Enlpykcal/kg-837.477-898.833Molar Entropyca

15、l/mol-K5.5040181.247226Mass Entropycal/gm-K0.1565250.035411Molar Densitykmol/cum0.1143020.173801Enlpy FlowGcal/hr-13.2448-14.2151HinGcal/hr-14.2151HoutGcal/hr-14.2151表 1-12 一級加熱器（E-0103）能量表表 1-13 燃燒爐（R-0101）物流焓變計算表UnitsS0111S0307S0112S0308PhaseVaporVaporVaporLiquidTemperatureC120450.0349230226.745Pr

16、erebar5.6455.644.9Molar Vapor Fraction1110Mass Flowskg/hr12519.01684.580612519.01684.5806Volume Flowcum/hr2446.52648.154183154.5570.821432Molar Enlpykcal/mol-34.7624-54.4238-33.8524-64.566Mass Enlpykcal/kg-1179.63-3020.98-1148.85-3583.96Molar Entropycal/mol-K-1.48994-10.89840.54319-29.4666Mass Entro

17、pycal/gm-K-0.05056-0.604950.018434-1.63564Molar Densitykmol/cum0.1736430.7891320.1346846.26068Mass Densitykg/cum5.11705414.216433.968546833.3991Enlpy FlowGcal/hr-14.7678-2.0681-14.3824-2.45351HinGcal/hr-16.8359HoutGcal/hr-16.8359Q( Gcal/hr)W(Gcal/hr)Hin( Gcal/hr)Hout( Gcal/hr)Error00-16.4517-16.4517

18、2.01E-09Mass Entropycal/gm-K0.031699-0.604950.0951958-1.64146Molar Densitykmol/cum0.171340.7891320.131902346.45533Mass Densitykg/cum5.56232414.216434.2810889836.9058Enlpy FlowGcal/hr-14.2203-2.23138-13.80232-2.64934HinGcal/hr-16.4517HoutGcal/hr-16.4517表 1-14 二級加熱器（E-0105）能量表1.4.1.3氣液分離器（F-0101F-0103

19、）表 1-15氣液分離器（F-0101）能量表表 1-16 氣液分離器（F-0101）物流焓變計算表Q( Gcal/hr)W(Gcal/hr)Hin( Gcal/hr)Hout( Gcal/hr)ErrorINOUTUnitsS0106S0107S0115PhaseMixedVaporLiquidTemperatureC140139.9998139.9998Prerebar5.85.85.8Molar Vapor Fraction0.98467110Mass Flowskg/hr15815.0914353.381461.704Volume Flowcum/hr2583.5182580.4653

20、.050653Molar Enlpykcal/mol-31.6582-32.16270.749606Mass Enlpykcal/kg-898.833-990.7273.52995Molar Entropycal/mol-K1.2472261.02907715.25922Mass Entropycal/gm-K0.0354110.0316990.071857Molar Densitykmol/cum0.1738010.171342.256327Mass Densitykg/cum6.1215335.562324479.1445Enlpy FlowGcal/hr-14.2151-14.22030

21、.00516HinGcal/hr-14.2151HoutGcal/hr-14.2151Q( Gcal/hr)W(Gcal/hr)Hin( Gcal/hr)Hout( Gcal/hr)Error00-16.8359-16.83592.15E-09表 1-17氣液分離器（F-0101）物流焓變計算表表 1-18 氣液分離器（F-0102）能量表Q( Gcal/hr)W(Gcal/hr)Hin( Gcal/hr)Hout( Gcal/hr)Error00-14.7777-14.77771.38E-10INOUTUnitsS0110S0111S0116PhaseMixedVaporLiquidTemp

22、eratureC120120120Prerebar5.65.65.6Molar Vapor Fraction0.97994510Mass Flowskg/hr14353.3812519.011834.378Volume Flowcum/hr2450.1672446.5263.641208Molar Enlpykcal/mol-34.0881-34.7624-1.13985Mass Enlpykcal/kg-1029.56-1179.63-5.40251Molar Entropycal/mol-K-1.22931-1.4899411.50588Mass Entropycal/gm-K-0.037

23、13-0.050560.054534Molar Densitykmol/cum0.1769330.1736432.387769Mass Densitykg/cum5.8581245.117054503.783Enlpy FlowGcal/hr-14.7777-14.7678-0.00991HinGcal/hr-14.7777HoutGcal/hr-14.777700-14.2151-14.21511.01E-07表 1-19氣液分離器（F-0103）物流焓變計算表表 1-20 氣液分離器（F-0103）能量表1.4.1.4 混合器（M-0101M-0102）表 1-21 混合器（M-0101）

24、物流焓變計算表UnitsS0101S0236S0102PhaseVaporVaporVaporTemperatureC38.838.0000438.99364Q( Gcal/hr)W(Gcal/hr)Hin( Gcal/hr)Hout( Gcal/hr)Error00-14.8233-14.8233-9.46E-10INOUTUnitsS0114S0117S0122PhaseMixedLiquidVaporTemperatureC110110110Prerebar5.55.55.5Molar Vapor Fraction0.99838801Mass Flowskg/hr12519.01142.

25、910212376.1Volume Flowcum/hr2421.3440.277222421.067Molar Enlpykcal/mol-34.9128-2.46745-34.9652Mass Enlpykcal/kg-1184.06-11.8179-1197.6Molar Entropycal/mol-K-1.770349.6085-1.78871Mass Entropycal/gm-K-0.060040.04602-0.06127Molar Densitykmol/cum0.1753492.4690470.175086Mass Densitykg/cum5.170272515.5122

26、5.111836Enlpy FlowGcal/hr-14.8233-0.00169-14.8216HinGcal/hr-14.8233HoutGcal/hr-14.8233表 1-22 混合器（M-0101）能量表表 1-23 混合器（M-0102）物流焓變計算表UnitsS0115S0116S0117S0118PhaseLiquidLiquidLiquidMixedTemperatureC139.9998120110128.3471Prerebar5.85.65.55.5Molar Vapor Fraction0000.006733Molar Enlpykcal/mol0.749606-1.

27、13985-2.46745-0.3964Mass Enlpykcal/kg3.52995-5.40251-11.8179-1.87247Molar Entropycal/mol-K15.2592211.505889.608513.06445Mass Entropycal/gm-K0.0718570.0545340.046020.061713Enlpy FlowGcal/hr0.00516-0.00991-0.00169-0.00644Mass Flowskg/hr1461.7041834.378142.91023438.992Q( Gcal/hr)W(Gcal/hr)Hin( Gcal/hr)

28、Hout( Gcal/hr)Error00-9.07866-9.07873.95E-06Prerebar616Molar Vapor Fraction111Mass Flowskg/hr7588.473227.93367816.418Volume Flowcum/hr820.44176.0123849.4371Molar Enlpykcal/mol-45.8857-10.8854-44.7053Mass Enlpykcal/kg-1186.55-327.095-1161.49Molar Entropycal/mol-K3.9898619.7434614.112535Mass Entropyca

29、l/gm-K0.1031730.292780.106848Enlpy FlowGcal/hr-9.00411-0.07456-9.0787HinGcal/hr-9.07866HoutGcal/hr-9.07866表 1-24 混合器（M-0102）能量表1.4.2 SCOT 尾氣處理工段能量1.4.2.1 反應器（R-0201R-0202）表 1-25 SCOT 加氫反應器（R-0201）物流焓變計算表INOUTUnitsS0203S0204PhaseVaporVaporTemperatureC220234.074Prerebar5.55.5Molar Vapor Fraction11Mass

30、 Flowskg/hr12394.2412394.58Volume Flowcum/hr3207.6993295.66Molar Enlpykcal/mol-33.3307-33.3856Mass Enlpykcal/kg-1164.13-1164.1Molar Entropycal/mol-K0.4549340.689224Mass Entropycal/gm-K0.0158890.024032Enlpy FlowGcal/hr-14.4285-14.4285HinGcal/hr-14.4285HoutGcal/hr-14.4285Q( Gcal/hr)W(Gcal/hr)Hin( Gcal

31、/hr)Hout( Gcal/hr)Error00-0.00644-0.006441.36E-06Volume Flowcum/hr3.0506533.6412080.277227.613169HinGcal/hr-0.00644HoutGcal/hr-0.00644表 1-26 SCOT 加氫反應器（R-0201）能量表表 1-27尾氣燃燒爐（R-0202）物流焓變計算表表 1-28 尾氣燃燒爐（R-0201）能量表Q( Gcal/hr)W(Gcal/hr)Hin( Gcal/hr)Hout( Gcal/hr)Error00-8.87892-8.878922.34E-13INOUTUnits

32、S0233S0234S0235PhaseMixedVaporVaporTemperatureC35.1011925150.7067Prerebar4.911.01325Molar Vapor Fraction0.99999911Mass Flowskg/hr10235.48571.142510806.62Volume Flowcum/hr1657.49490.517811682.38Molar Enlpykcal/mol-27.8475-0.00161-26.4254Mass Enlpykcal/kg-867.462-0.05572-821.619Molar Entropycal/mol-K-

33、1.360591.0423024.066841Mass Entropycal/gm-K-0.042380.0361280.126446Enlpy FlowGcal/hr-8.87889-3.18E-05-8.87892HinGcal/hr-8.87892HoutGcal/hr-8.87892Q( Gcal/hr)W(Gcal/hr)Hin( Gcal/hr)Hout( Gcal/hr)Error00-14.4285-14.42851.23E-161.4.2.2換熱器（E-0201E-0207）表 1-29加氫預熱器（E-0201）物流焓變計算表表 1-30 加氫預熱器（E-0201）能量表表

34、1-31 加氫產(chǎn)物冷卻器（E-0202）物流焓變計算表UnitsS0204S0205PhaseVaporVaporTemperatureC234.074120Prerebar5.55.4Q( Gcal/hr)W(Gcal/hr)Hin( Gcal/hr)Hout( Gcal/hr)Error00-16.9444-16.94442.37E-09UnitsS0202S0309S0203S0310PhaseMixedVaporVaporLiquidTemperatureC108.596450.0349220229.5719Prerebar5.5455.544.9Molar Vapor Fractio

35、n0.999875110Mass Flowskg/hr12394.24702.595912394.24702.5959Volume Flowcum/hr2464.14249.42143207.6990.846949Molar Enlpykcal/mol-34.2393-54.4238-33.3307-64.5094Mass Enlpykcal/kg-1195.87-3020.98-1164.13-3580.82Molar Entropycal/mol-K-1.63268-10.89840.454934-29.3537Mass Entropycal/gm-K-0.05702-0.604950.0

36、15889-1.62938Molar Densitykmol/cum0.1756760.7891320.13495446.04765Mass Densitykg/cum5.02983914.216433.863903829.5613Enlpy FlowGcal/hr-14.8219-2.12253-14.4285-2.51587HinGcal/hr-16.9444HoutGcal/hr-16.9444表 1-32 加氫產(chǎn)物冷卻器（E-0202）能量表表 1-33 氨冷器（E-0203）物流焓變計算表UnitsS0208S0209PhaseMixedMixedTemperatureC70.591

37、910Prerebar2.92.8Molar Vapor Fraction0.0055930.003158Mass Flowskg/hr18537.8818537.88Volume Flowcum/hr74.4888345.1473Molar Enlpykcal/mol-67.5258-68.6293Mass Enlpykcal/kg-3720.5-3781.3Molar Entropycal/mol-K-36.1758-39.7072Q( Gcal/hr)W(Gcal/hr)Hin( Gcal/hr)Hout( Gcal/hr)Error00-14.4285-14.8270.026871Mo

38、lar Vapor Fraction11Mass Flowskg/hr12394.5812394.58Volume Flowcum/hr3295.662595.479Molar Enlpykcal/mol-33.3856-34.3074Mass Enlpykcal/kg-1164.1-1196.25Molar Entropycal/mol-K0.689224-1.33824Mass Entropycal/gm-K0.024032-0.04666Molar Densitykmol/cum0.1311360.166512Mass Densitykg/cum3.7608794.77545Enlpy

39、FlowGcal/hr-14.4285-14.827HinGcal/hr-14.827HoutGcal/hr-14.827表 1-34 氨冷器（E-0203）能量表表 1-35 吸收冷卻器（E-0207）物流焓變計算表UnitsS0231S0232PhaseLiquidLiquidTemperatureC52.732524.73Prerebar11Molar Vapor Fraction00Mass Flowskg/hr5272.845272.84Volume Flowcum/hr5.352185.273579Molar Enlpykcal/mol-71.1853-71.8032Mass En

40、lpykcal/kg-2834.91-2859.52Molar Entropycal/mol-K-49.636-51.7243Mass Entropycal/gm-K-1.97672-2.05989Molar Densitykmol/cum39.2340639.81882Mass Densitykg/cum985.1763999.8599Enlpy FlowGcal/hr-14.948-15.0778HinGcal/hr-15.0778HoutGcal/hr-15.0778Q( Gcal/hr)W(Gcal/hr)Hin( Gcal/hr)Hout( Gcal/hr)Error00-68.97

41、02-70.09720.016079Mass Entropycal/gm-K-1.9932-2.18777Molar Densitykmol/cum13.7119922.62347Mass Densitykg/cum248.8679410.6087Enlpy FlowGcal/hr-68.9702-70.0972HinGcal/hr-70.0972HoutGcal/hr-70.0972表 1-36 吸收冷卻器（E-0207）能量表1.4.2.3氣液分離器（F-0201F-0202）表 1-37氣液分離器（F-0201）物流焓變計算表表 1-38 氣液分離器（F-0201）能量表Q( Gcal/

42、hr)W(Gcal/hr)Hin( Gcal/hr)Hout( Gcal/hr)Error00-10.1544-10.15441.15E-09INOUTUnitsS0215S0217S0219PhaseMixedLiquidVaporTemperatureC404039.999998Prerebar555Molar Vapor Fraction0.9506401Molar Enlpykcal/mol-29.5478-68.0485-27.54872Mass Enlpykcal/kg-941.266-3773.6-858.6128Molar Entropycal/mol-K-2.77606-38

43、.0679-0.94362Mass Entropycal/gm-K-0.08843-2.11104-0.02941Molar Densitykmol/cum0.20326354.944320.1932657Mass Densitykg/cum6.380749990.7996.2009585Enlpy FlowGcal/hr-10.1544-1.1543-9.000095HinGcal/hr-10.1544HoutGcal/hr-10.1544Q( Gcal/hr)W(Gcal/hr)Hin( Gcal/hr)Hout( Gcal/hr)Error-0.1297397880-14.948-15.

44、07780.008605表 1-39氣液分離器（F-0202）物流焓變計算表表 1-40 氣液分離器（F-0202）能量表1.4.2.4 混合器（M-0201M-0204）表 1-41 混合器（M-0201）物流焓變計算表INOUTUnitsS0122S0201S0202PhaseVaporVaporMixedTemperatureC11020108.596Q( Gcal/hr)W(Gcal/hr)Hin( Gcal/hr)Hout( Gcal/hr)Error00-0.69686-0.69686-2.88E-08INOUTUnitsS0224S0225S0236PhaseMixedLiqui

45、dVaporTemperatureC3838.0000438.00004Prerebar111Molar Vapor Fraction0.42807101Mass Flowskg/hr392.9743165.0408227.9336Volume Flowcum/hr176.17850.166303176.0123Molar Enlpykcal/mol-43.5537-68.0048-10.8854Mass Enlpykcal/kg-1773.29-3770.6-327.095Molar Entropycal/mol-K-17.6523-38.15719.743461Mass Entropyca

46、l/gm-K-0.71871-2.115660.29278Molar Densitykmol/cum0.09081755.02540.038913Mass Densitykg/cum2.230546992.4131.294987Enlpy FlowGcal/hr-0.69686-0.6223-0.07456HinGcal/hr-0.69686HoutGcal/hr-0.69686表 1-42 混合器（M-0201）能量表表 1-43 吸收劑混合器（M-0204）物流焓變計算表INOUTUnitsS0225S0229S0230S0231PhaseLiquidLiquidLiquidLiquidT

47、emperatureC38.0000454.510292552.7325Prerebar11.111Molar Vapor Fraction0000Mass Flowskg/hr165.04084870.496237.30395272.84Volume Flowcum/hr0.1663034.9479190.2380925.35218Molar Enlpykcal/mol-68.0048-71.29-72.1806-71.1853Q( Gcal/hr)W(Gcal/hr)Hin( Gcal/hr)Hout( Gcal/hr)Error00-14.8219-14.82192.19E-09Prer

48、ebar5.585.5Molar Vapor Fraction110.999875Molar Enlpykcal/mol-34.9652-0.03418-34.2393Mass Enlpykcal/kg-1197.6-16.9577-1195.87Molar Entropycal/mol-K-1.78871-4.21855-1.63268Mass Entropycal/gm-K-0.06127-2.09266-0.05702Molar Densitykmol/cum0.1750860.328290.175676Mass Densitykg/cum5.1118360.6617945.029839

49、Enlpy FlowGcal/hr-14.8216-0.00031-14.8219Mass Flowskg/hr12376.118.1429212394.24Volume Flowcum/hr2421.06727.414772464.142HinGcal/hr-14.8219HoutGcal/hr-14.8219表 1-44 吸收劑混合器（M-0204）能量表1.4.2.5 泵（P-0201P-0202）表 1-45 冷卻水循環(huán)泵（P-0201）物流焓變計算表INOUTUnitsS0206S0207PhaseLiquidLiquidTemperatureC70.6662171.82172Pre

50、rebar1.153Molar Vapor Fraction00Mass Flowskg/hr20149.8620149.86Volume Flowcum/hr20.9429920.95488Molar Enlpykcal/mol-67.5268-67.5261Mass Enlpykcal/kg-3720.55-3720.5Molar Entropycal/mol-K-36.1535-36.1919Mass Entropycal/gm-K-1.99197-1.99408Molar Densitykmol/cum53.0108652.98061Mass Densitykg/cum962.1293

51、961.5836Enlpy FlowGcal/hr-74.9686-74.9676Q( Gcal/hr)W(Gcal/hr)Hin( Gcal/hr)Hout( Gcal/hr)Error00-14.9481-14.948-7.37E-07Mass Enlpykcal/kg-3770.6-2806.72-2762.91-2834.91Molar Entropycal/mol-K-38.1571-50.0048-53.7183-49.636Mass Entropycal/gm-K-2.11566-1.96871-2.05622-1.97672Enlpy FlowGcal/hr-0.6223-13

52、.6701-0.65565-14.948HinGcal/hr-14.9481HoutGcal/hr-14.9481表 1-46 冷卻水循環(huán)泵（P-0201）能量表表 1-47 吸收進料泵（P-0202）物流焓變計算表INOUTUnitsS0232S0220PhaseLiquidLiquidTemperatureC24.7324.78403Prerebar15Molar Vapor Fraction00Mass Flowskg/hr5272.845272.84Volume Flowcum/hr5.2735795.273071Molar Enlpykcal/mol-71.8032-71.8005M

53、ass Enlpykcal/kg-2859.52-2859.41Molar Entropycal/mol-K-51.7243-51.7211Mass Entropycal/gm-K-2.05989-2.05976Molar Densitykmol/cum39.8188239.82265Mass Densitykg/cum999.8599999.9562Enlpy FlowGcal/hr-15.0778-15.0772HinGcal/hr-15.0778HoutGcal/hr-15.0772Q( Gcal/hr)W(Gcal/hr)Hin( Gcal/hr)Hout( Gcal/hr)Error

54、00.001029-74.9686-74.9676-1.36E-05HinGcal/hr-74.9686HoutGcal/hr-74.9676表 1-48 吸收進料泵（P-0202）能量表1.4.2.6壓縮機（C-0201）表 1-49尾氣壓縮機（C-0201）物流焓變計算表表 1-50 尾氣壓縮機（C-0201）能量表Q( Gcal/hr)W(Gcal/hr)Hin( Gcal/hr)Hout( Gcal/hr)Error00.52875-9.97571-9.44696-0.053INOUTUnitsS0212S0213PhaseVaporVaporTemperatureC39.814082

55、34.9494Prerebar1.155Molar Vapor Fraction11Mass Flowskg/hr10788.0210788.02Volume Flowcum/hr7761.7162901.587Molar Enlpykcal/mol-29.0278-27.4892Mass Enlpykcal/kg-924.703-875.69Molar Entropycal/mol-K1.7032732.598498Mass Entropycal/gm-K0.0542590.082777Molar Densitykmol/cum0.0442760.118439Mass Densitykg/c

56、um1.3899023.717973Enlpy FlowGcal/hr-9.97571-9.44696HinGcal/hr-9.97571HoutGcal/hr-9.44696Q( Gcal/hr)W(Gcal/hr)Hin( Gcal/hr)Hout( Gcal/hr)Error00.00056-15.0778-15.0772-3.71E-051.4.2.7塔（T-0201 T-0203）表 1-51急冷塔（T-0201）物流焓變計算表表 1-52 急冷塔（T-0201）能量表表 1-53 吸收塔（T-0202）物流焓變計算表INOUTUnitsS0219S0220S0221S0233Pha

57、seVaporLiquidLiquidMixedTemperatureC4024.7840343.4188435.101192Q( Gcal/hr)W(Gcal/hr)Hin( Gcal/hr)Hout( Gcal/hr)Error00-84.9445-84.9443-2.16E-06INOUTUnitsS0205S0211S0207S0212PhaseVaporMixedLiquidVaporTemperatureC1209.83113671.821715439.81408Prerebar5.4231.15Molar Vapor Fraction10.00380801Mass Flowskg

58、/hr12394.5818543.3120149.86510788.02Volume Flowcum/hr2595.47963.6778320.95487617761.716Molar Enlpykcal/mol-34.3074-68.6292-67.526072-29.0278Mass Enlpykcal/kg-1196.25-3781.28-3720.5005-924.703Molar Entropycal/mol-K-1.33824-39.7038-36.1919471.703273Mass Entropycal/gm-K-0.04666-2.18757-1.99407650.05425

59、9Enlpy FlowGcal/hr-14.827-70.1175-74.967583-9.97571HinGcal/hr-84.9445HoutGcal/hr-84.9443表 1-54 吸收塔（T-0202）能量表表 1-55 再生塔（T-0203）物流焓變計算表INOUTUnitsS0219S0220S0221S0233PhaseVaporLiquidLiquidMixedTemperatureC4024.7840343.4188435.101192Prerebar5554.9Molar Vapor Fraction1000.9999985Mass Flowskg/hr10482.135

60、272.845519.81210235.475Volume Flowcum/hr1690.4065.2730715.8034681657.4904Molar Enlpykcal/mol-27.5487-71.8005-69.7679-27.84751Mass Enlpykcal/kg-858.613-2859.41-2753.68-867.4622Molar Entropycal/mol-K-0.94362-51.7211-49.0198-1.360593Q( Gcal/hr)W(Gcal/hr)Hin( Gcal/hr)Hout( Gcal/hr)Error00-24.0773-24.078