基礎(chǔ)化學中英文課件 配位化合物

TheCoordinationComplex配位化合物TheCoordinationComplex基礎(chǔ)化學中英文課件配位化合物Notes:cathode

[‘k?θ??d]陰極cathodic[k?‘θ?dik]陰極的cation[‘k?tai?n]陽離子cationic[‘k?tai?nik]陽離子的anode[‘?n??d]陽極anodic[?’n?dik]陽極的anion[‘?nai?n]陰離子anionic[‘?nai?nik]陰離子的Nonionic[‘n?nai?nik]非離子的Notes:cathode

[‘k?θ??d]陰NamesforSomeligandsNamesforSomeligandsWordsandPhrases:instepwisefashion:

inagradualprogressionasifstepbystepprimarily:atfirst;originally;chiefly;mainlyWordsandPhrases:

either---or---:要么---要么---.Thefirstfourcompoundsaresaltlikesubstancesinwhicheitherthecationoranioniscomplex.

Both---and---兩個都---Thefifthcompoundcontainsbothcomplexcationandcomplexanioninsolutionandinthesolid.either---or---:要么---要么---dentate:toothed;edgedwithtoothlikeprojections[uni-;bi-(di-);tri-;tetra-;hexa-;]~dentateconfiguration:arrangementofpartsorelements;thestructuralarrangementofatomsinacompoundormolecule.dentate:toothed;edgedwithtChelate:apolydentateligand,whencoordinatedattwoormorepointstoacentralion,formsaringstructuresuchasillustratedbytheethylenediaminecomplexofcobaltabove.Thistypeofcomplexiscalledachelate.Co(En)3:cobalttriethylenediamineChelate:apolydentateligand,ammonia:NH3氨，氨水Acolorless,pungentgas,extensivelyusedtomanufacturefertilizersandawidevarietyofnitrogen-containingorganicandinorganicchemicals.

ammonium:NH4+

銨TheunivalentchemicalioncomposedofNandH,derivedfromammonia,whosecompoundschemicallyresemblethealkalimetals.

ammonia:NH3氨，氨水a(chǎn)mmine[’?mi:n]:M(NH3)xy+氨絡(luò)合物anyofaclassofinorganiccoordinationcompoundsofammoniaandametallicsalt.---銅氨離子amine[’?min]:R3N

胺anyofagroupoforganiccompoundsofnitrogen,suchasethylamine,C2H5NH2,thatmaybeconsideredammoniaderivativesinwhichoneormorehydrogenatomshavebeenreplacedbyahydrocarbonradical.methylamine:methyl-,amine(甲胺）Ethylenediamine:ethyl-,-ene,di-,amine(乙二胺）ammine[’?mi:n]:M(NH3)xy+氨絡(luò)基礎(chǔ)化學中英文課件配位化合物基礎(chǔ)化學中英文課件配位化合物NamingthecoordinationcompoundsCationsarenamedfirst,anionslast.NamingnegativeligandswiththealphabeticorderUsingRomannumeralsinparenthesestospecifytheoxidationnumberofmetals(ions)Whenacomplexionisnegative,thenameofthecentralelementhas–ateappended.Neutralcomplexesarenamedasiftheywerecations.Uncoordinatedpositiveionisnamedfinally.NamingthecoordinationcompouK[BF4]

Potassiumtetrafluoroborate[Co(H2O)2(NH3)2(CO3)]NO3

配體按照英文拼寫的字母順序排列Diamminediaquacarbonatocobalt(III)nitrate[Ag(NH3)2]Cl

Diamminesilver(I)chlorideK4[Fe(CN)6]

Potassiumhexacyanoferrate(II)[Co(NH3)3(NO2)3]0

Triamminetrinitrocobalt(III)[Cu(NH3)4]SO4

Tetramminecopper(II)sulfatePrinciple:Givingitsnameregardingitasasalt.Usingtheaffixes–ide,-ate,mono-,di-,tri-,tetra-,etc.K[BF4]Pota基礎(chǔ)化學中英文課件配位化合物基礎(chǔ)化學中英文課件配位化合物TheCoordinationComplex配位化合物TheCoordinationComplex基礎(chǔ)化學中英文課件配位化合物Notes:cathode

[‘k?θ??d]陰極cathodic[k?‘θ?dik]陰極的cation[‘k?tai?n]陽離子cationic[‘k?tai?nik]陽離子的anode[‘?n??d]陽極anodic[?’n?dik]陽極的anion[‘?nai?n]陰離子anionic[‘?nai?nik]陰離子的Nonionic[‘n?nai?nik]非離子的Notes:cathode

[‘k?θ??d]陰NamesforSomeligandsNamesforSomeligandsWordsandPhrases:instepwisefashion:

inagradualprogressionasifstepbystepprimarily:atfirst;originally;chiefly;mainlyWordsandPhrases:

either---or---:要么---要么---.Thefirstfourcompoundsaresaltlikesubstancesinwhicheitherthecationoranioniscomplex.

Both---and---兩個都---Thefifthcompoundcontainsbothcomplexcationandcomplexanioninsolutionandinthesolid.either---or---:要么---要么---dentate:toothed;edgedwithtoothlikeprojections[uni-;bi-(di-);tri-;tetra-;hexa-;]~dentateconfiguration:arrangementofpartsorelements;thestructuralarrangementofatomsinacompoundormolecule.dentate:toothed;edgedwithtChelate:apolydentateligand,whencoordinatedattwoormorepointstoacentralion,formsaringstructuresuchasillustratedbytheethylenediaminecomplexofcobaltabove.Thistypeofcomplexiscalledachelate.Co(En)3:cobalttriethylenediamineChelate:apolydentateligand,ammonia:NH3氨，氨水Acolorless,pungentgas,extensivelyusedtomanufacturefertilizersandawidevarietyofnitrogen-containingorganicandinorganicchemicals.

ammonium:NH4+

銨TheunivalentchemicalioncomposedofNandH,derivedfromammonia,whosecompoundschemicallyresemblethealkalimetals.

ammonia:NH3氨，氨水a(chǎn)mmine[’?mi:n]:M(NH3)xy+氨絡(luò)合物anyofaclassofinorganiccoordinationcompoundsofammoniaandametallicsalt.---銅氨離子amine[’?min]:R3N

胺anyofagroupoforganiccompoundsofnitrogen,suchasethylamine,C2H5NH2,thatmaybeconsideredammoniaderivativesinwhichoneormorehydrogenatomshavebeenreplacedbyahydrocarbonradical.methylamine:methyl-,amine(甲胺）Ethylenediamine:ethyl-,-ene,di-,amine(乙二胺）ammine[’?mi:n]:M(NH3)xy+氨絡(luò)基礎(chǔ)化學中英文課件配位化合物基礎(chǔ)化學中英文課件配位化合物NamingthecoordinationcompoundsCationsarenamedfirst,anionslast.NamingnegativeligandswiththealphabeticorderUsingRomannumeralsinparenthesestospecifytheoxidationnumberofmetals(ions)Whenacomplexionisnegative,thenameofthecentralelementhas–ateappended.Neutralcomplexesarenamedasiftheywerecations.