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WhatisTankCleaning
什么是洗艙Revised1stMar20051COMGroup,TMWhatisTankCleaning
什么是洗艙ReCompanyObjectivesofTankCleaningDeliver“CleanonboardCargoes”andprovideprofessionalservicestomeetcustomers’requirements.ContinuouslyimproveourTankCleaningprocessestoincreaseefficiencyandcustomersatisfaction.Ensurethatresourcesandtrainingarereviewedtomeetcustomers’requirements.Asacompany,wearecommittedtocontinuousimprovementinthequalityofallourservicesandoperations.Wearealsocommittedtocontinuousimprovementandenhancementofourrelationshipswithcustomers,shareholders,employeesandpartners.Compliancewithsafety,healthandenvironmentallegislationandregulationscontinuouslyimprovingthesafetyandhealthpreventingpollution;systematicallyidentifyingrisksfromouractivitieswhetherarisingfromfacilities,equipmentorpeople;controllingidentifiedrisksbyensuringthatappropriateresourcesareavailableforbothplanningandoperations;Revised1stDec20042COMGroup,TMCompanyObjectivesofTankCleTankCleaningEquipments相關(guān)洗艙設(shè)備Revised1stDec20043COMGroup,TMTankCleaningEquipments相關(guān)洗艙設(shè)備TankCleaningMachineTherearetwo(2)typesofgreasetypeandnon-greasetypewhichcanbefoundfrommaker‘sinstructionbook.Chemicaltankersgenerallyusenon-greasetype.Knowingwatercapacity&cycletimeoftankcleaningmachineagainstthewaterpressureisveryusefultocarryouteffectivetankcleaning.有兩種洗艙設(shè)備。知道水的容量,洗艙設(shè)備循環(huán)時間,以及水壓力是非常有用的ThisisasampleofT/CmachinewhichisusedforchemicaltankersofDWT10,000foryourguidance.Lowwaterpressureisusedforvolatilecargo,orpreventingdamageofcoatingincaseofaggressivecargo.低水壓用于易揮發(fā)貨物,或者在裝了對涂層有刺激貨物后為了保護(hù)涂層。Highwaterpressureisusedfornon-volatilecargo,highviscositycargoorvegetable&animaloil.高水壓用于不揮發(fā)貨物,高粘度貨物或者植物油,動物油。
120oUP180oDN270oUP360oRevised1stDec20044COMGroup,TMTankCleaningMachineTherearTankCleaningHeater
洗艙加熱器
Ithastobemaintainedwellandtoconductcleaningoftheheaterbychemicalcleanerevery6monthssoastogetgoodtemperatureduringtankcleaning.每六個月使用化學(xué)清洗劑清洗,進(jìn)行維護(hù),從而保證洗艙達(dá)到理想的溫度Revised1stDec20045COMGroup,TMTankCleaningHeater
洗艙加熱器ItFactorstobeconsideredfortankcleaning洗艙時應(yīng)考慮的因素Revised1stDec20046COMGroup,TMFactorstobeconsideredfortPropertyofCargo
a)Aggressivecargo(MEK,Methanol)
刺激性貨物(丁酮,甲醇等) Suchcargomakescoatingofcargotanksoftenanddamaged.Beforetankcleaning,Itisrequiredtotakecuringtimebyventilationuntiltankcoatingrecoveredtotheoriginalcondition.Lowwaterpressureoflessthan6kg/cm2shouldbeappliedduringbutterworthing.
該貨物使涂層軟化以及遭到損壞,在洗艙前,需要通風(fēng)使涂層愈合,在洗艙時水壓小于6公斤/平方厘米b)Viscosityofcargo(Lubadd,OLOA270
)
高粘度貨物 Viscosityistheinternalresistancecreatedinfluidssuchaswater,oilandgaswhenthesematerialsflow.Strengthorrateofviscosityis,inprinciple,shownas(mPa.s)at20C.Viscosityisaffectedbytemperatureand/orpressure.Viscosityofliquiddecreasesastemperaturerises.液體的粘度隨著溫度的升高而減少。 Thereforehighertemperatureandhighpressureofwashingmachinecanmakeiteasytoremovecargoresidueincargotank.SuchcargotanksarerequiredtodotankcleaningbyhightemperatureandsettingT/Cmachineswithalotofstepaccordingtotheheightofcargotank.提高水溫以及壓力來除去殘余貨物Revised1stDec20047COMGroup,TMPropertyofCargoa)AggressivPropertyofCargoc)Solidityofcargo(FattyAlcohol,PalmOil)易凝結(jié)(固化)物質(zhì)Everycargohasitsmeltingpointwhichisthetemperaturethattheabsorptionofheatenergycausesthemoleculestomovemorefreely,breakingupthesolidstructure.Onthecontrary,freezingpointisthetemperatureatwhichcrystallizationbegins.Thetemperatureoftankcleaningwaterdependsonmeltingpointofcargo.SuchcargotanksarerequiredtodotankcleaningbyhightemperatureandsettingT/Cmachineswithalotofstepaccordingtotheheightofcargotank每種貨物都有相應(yīng)的溶點(diǎn)(凝固點(diǎn)),提高水溫,根據(jù)貨艙高度來采取多步驟。d)Corrosive(AceticAcid,CausticSoda)
腐蝕性(冰醋酸,液堿)Liquidswhichcorrodenormalconstructionalmaterialssuchassteel&coatingatanexcessiverate.ThosecargotanksarerequiredtodoT/Cbyabundantwaterimmediatelyassoonascompletionunloadingcargo.TheT/Cwatershouldbedischargeddirectlyintoseathroughflexiblehoseorpipelineinordertoavoiddamagetocoating.Sloppingtoothercargotankisnotrecommended.完貨后立即需要使用大量的水清洗,直接通過軟管或者管線排入海中,不建議將洗艙污水放在別的貨倉中。Revised1stDec20048COMGroup,TMPropertyofCargoc)SolidityoPropertyofCargoe)Vaporpressure(Methanol,Acetone)蒸氣壓(甲醇,丙酮) Thepressureexertedbythevaporabovetheliquidatagiventemperature.Itisexpressedasabsolutepressure.ThecargowithhighvaporpressurecanbedoneT/Cbysimplemethodonlyonestepofmachinebecausethereisnoresidueonthewallbutonlybottomandshortesttimewhichcanremoveresidueremainedonbottom.在液體表面上蒸氣產(chǎn)生的壓力。使用壓力表示。高蒸氣壓的貨物可以僅僅使用非常簡單方式和少量的步驟來進(jìn)行洗艙,因為艙壁沒有殘留物,僅僅在艙底才有殘留物,使用最少的時間就可以將殘留物除去。 DuringtheinitialstagesofT/C,lowtemperatureoftankcleaningwaterisrequiredinordertoavoidexplosionbyflammablevapor.Cargoresiduesofsubstanceswithavaporpressuregreaterthan5kpa(equaledto37.5mmMg)at20Cmayberemovedfromacargotankbyventilation.在洗艙初期,必須使用低溫水洗艙,避免可燃蒸氣爆炸。在20度時當(dāng)殘留物的物質(zhì)的蒸氣壓力大于5KPa(等于37.5mmMg),可以僅用通風(fēng)來除去殘留物。Revised1stDec20049COMGroup,TMPropertyofCargoe)VaporpresPropertyofCargof)
Staticelectricity(Benzene)
靜電(苯)Cleanoilsare,ingeneral,accumulatorsofstaticelectricitybecauseoftheirlowconductivityanditisrequiredfollowingprecautionsbefore/during/aftertankcleaninginordertoavoidexplosion:通常來說,清油由于不導(dǎo)電的特征從而使其容易聚集電荷,在洗艙中需要下列步驟來避免爆炸。·
Beforewashing,thetankbottomshouldbeflushedwithwaterandstripped.在洗艙前,艙底必須加水沖洗,并且泵出?!?/p>
Beforewashing,thetankshouldbeventilatedtoreducethegasconcentrationofthe atmosphereto10%orlessofthelowerflammablelimit.在洗艙前,艙內(nèi)必須通風(fēng),致使氣體濃度在10%以下或者爆炸極限下限?!?/p>
Ifportablewashingmachinesareused,allhoseconnectionsshouldbemadeupandtestedfor electricalcontinuitybeforethewashingmachineisintroducedintothetank.如果使用移動洗艙機(jī),所有管線應(yīng)該系牢,并且接地,對導(dǎo)電性進(jìn)行測試,之后才能開始洗艙?!?/p>
Connectionsshouldnotbebrokenuntilafterthemachinehasbeenremovedfromthetank,在整個機(jī)器完全移出貨艙后才能將給連接口拆開?!?/p>
Todrainthehoseacouplingmaybepartiallyopenedandthenre-tightenedbeforethe machineisremoved
,為了濾干管線接頭,·
Re-circulatedwashwatershouldnotbeusedfortankcleaning·
Steamshouldnotbeinjectedintothetank
蒸氣不允許進(jìn)入艙內(nèi)·
Washwaterdoesnotexceed60C
洗艙水不允許超過60度·
Thetotalwaterthroughputpercargotankshouldbekeptaslowaspracticableandmustinno caseexceed180m3/h
各艙進(jìn)水速度要保持盡量低速,不能超過180立方/小時Equipmentshouldbebondedandsecurelyearthedtotheshipbeforeintroductionintothetankandremainsoeartheduntilremoved設(shè)備必須綁扎住并且在進(jìn)入貨艙前接地,直到移開設(shè)備。Revised1stDec200410COMGroup,TMPropertyofCargof)
StatiPropertyofCargog)
Solubilityinwater(MEG,IPA,Acetone,Methanol,)水溶性物質(zhì)Thecargowhichiscompletelysolubleinwaterisveryeasytoremovetheresidueincargotankbyonlywash-waterwithoutusinganydetergentorchemicalsolvent.Solubilityinwaterofsomecargodependsontemperature.Phenoliscompletelysolubleinwaterat66C.此類貨物能夠完全融于水,可以不加清潔劑或化學(xué)溶劑而僅用水就可以除去殘留物。但有些貨物的可溶性是和水溫有關(guān)系,苯酚在66度時完全溶于水。h)
Dryoil(Fishoil,Linseedoil,Saffloweroil,Soyabeanoiletc.,)干油類Itistheoilexceeding130iniodinevalue.T/CofDrycargotankhastobedoneassoonascompletionunloadingcargo.IfnotavailabletodoT/Cimmediately,pre-washisrequired.T/Cofsuchcargohastousehighpressuredcoldwaterwithalotofstepofmachineinordertoavoidcargoresiduesincargotanktobecomesticky.Suchcargocannotcompletelyremoveresiduesincargotankbyonlypre-washingbutrequiredtousedetergentorchemicalsolvent.Sloppingtoothercargotankisnotrecommended.(Nondryingoil<IV100,Semidrying=IV100-130)
含碘值大于130的油類,在卸完貨后立即進(jìn)行洗艙。如果無法立即洗艙,必須進(jìn)行預(yù)洗。洗艙必須使用高壓冷水采取多種步驟進(jìn)行,從而防止殘留物粘在艙壁上。如果僅僅預(yù)洗的話是無法出去殘留物,而必須要加入洗滌劑和化學(xué)溶劑。不建議將洗艙水放在另外的貨倉中。Revised1stDec200411COMGroup,TMPropertyofCargog)
SolubilityPropertyofCargoi)
Reaction(SM,MMA)
化學(xué)反應(yīng)(苯乙烯,甲基丙烯酸甲酯)ThetendencyofachemicaltoreactwithitselforwithotheroutsideinfluencesuchasOxygenorheat,usuallyresultinginpolymerizationordecompositionwherebythemoleculesofacompoundcanbemadetolinktogetherintoalargerunitcontaininganythingfromtwotothousandsofmolecules.
這類貨有自己反應(yīng)或和外界物質(zhì),比如空氣,熱量等進(jìn)行反應(yīng)的趨勢,通常會因為兩個或成千上萬個分子之間聯(lián)結(jié)成為大的物質(zhì)從而導(dǎo)致聚合或分解 T/Cofreactioncargotankhastobedoneassoonascompletionunloadingcargo.IfnotavailabletodoT/Cimmediately,pre-washisrequired.T/Cofsuchcargohastousehighpressuredcoldwaterwithalotofstepofmachineinordertoavoidbeingpolymerized.這類貨必須在完貨后立即進(jìn)行洗艙。如果無法洗艙,則必須進(jìn)行預(yù)洗。洗艙時要使用高壓冷水采取多種步驟來洗艙,從而避免聚合。Revised1stDec200412COMGroup,TMPropertyofCargoi)
Reaction(PropertyofCargoj)
Smell(2-EH,DINP,Octanol)
氣味(辛醇,Dinp) Thosecargoesremainstrongsmellincargotankforalongtime.Machinewashbycoldwaterfirstandthenwarmandhotwater,detergent,steamingandfanning(repeatedly)arerequired.這類貨長時間保留非常強(qiáng)烈的氣味。用熱水,洗滌劑,蒸氣和風(fēng)扇進(jìn)行洗艙。Revised1stDec200413COMGroup,TMPropertyofCargoj)
Smell(2-EHChemicalReaction(貨物相容表).Revised1stDec200414COMGroup,TMChemicalReaction(貨物相容表).ReviWhatisStaticElectricity?Everythingweseeismadeupoftinylittlepartscalledatoms.Theatomsaremadeofevensmallerparts.Thesearecalledprotons質(zhì)子,electrons電子
andneutrons中子.Theyareverydifferentfromeachotherinmanyways.Onewaytheyaredifferentistheir"charge."Protonshaveapositive(+)charge.Electronshaveanegative(-)charge.Neutronshavenocharge.Usually,atomshavethesamenumberofelectronsandprotons.Thentheatomhasnocharge,itis"neutral."Butifyourubthingstogether,electronscanmovefromoneatomtoanother.Someatomsgetextraelectrons.Theyhaveanegativecharge.Otheratomsloseelectrons.Theyhaveapositivecharge.Whenchargesareseparatedlikethis,itiscalledstaticelectricity.Iftwothingshavedifferentcharges,theyattract,orpulltowardseachother.Iftwothingshavethesamecharge,theyrepel,orpushawayfromeachother.StaticElectricitycausesFIRE
靜電導(dǎo)致火災(zāi).StaticElectricity
靜電Revised1stDec200415COMGroup,TMStaticElectricity靜電Revised1Surroundingcargotanks
周圍的貨艙
WhenmakingaT/Cplan,surroundingcargotanksshouldbetakenintoconsideration.Somecargoescanbeaffectedbyhightemperatureofhotwaterbutterworthingorsteaming.DonotstartT/Cuntilthecargohasbeenfullydischarged.Iftherewerealotofemptycargotankstobecleaned,placethepriorityonthepolymerizingcargoordrycargotanks.當(dāng)洗艙的時候必須要考慮周圍的貨艙。有些貨容易被隔壁的貨艙熱水洗艙產(chǎn)生的高溫而受到反應(yīng)。這種情況下,必須要隔壁的艙卸完貨后在進(jìn)行洗艙。如果有很多艙需要清洗,易聚合的物質(zhì)或干貨艙優(yōu)先進(jìn)行清洗。Revised1stDec200416COMGroup,TMSurroundingcargotanks周圍的貨艙 Typeofcoating(Epoxy/Zinc/SUS)涂層的種類Zinccoatingtank鍍鋅涂層
isnotaggressiveagainstchemicalcargoandcaneasilyremoveresidue&smellincargotankcomparingwithEpoxycoatingtank.TheeasiesttankcoatingtodotankcleaningisSUSwhichdoesnottakemuchtankcleaningtimecomparedwithotherEpoxyorZinccoatedtank.
和環(huán)氧涂層相比,鍍鋅涂層更加不受化學(xué)品的影響,更加容易清洗。最容易清洗的涂層是不銹鋼。
WithintheTMFleet,mostofthevesselsareequippedwithSUS316stainlesssteel.SUS316alloywithlowCcontent.Resistanttointer-granularcorrosionandGrade316alsohasexcellentcorrosionresistanceinawiderangeofChemicals.EpoxyStainlessSteelZincRevised1stDec200417COMGroup,TMTypeofcoating(Epoxy/Zinc/SUROUGING(鐵紅粉)-ADISCOLORATIONOF
STAINLESSSTEELSURFACESRougingisathinfilm,usuallyreddish-brownorgoldenincolor,ofironoxideorhydroxide,typicallyonstainlesssteels.Thecontrastbetweenthisfilmandshinymetalaccentuatesthisaestheticsproblem.Therougefilmtypicallywipesoffeasilywithalightcloth(Figure1),butitreformswhiletheprocessfluidisincontactwiththestainlesssteel.Asstated,rougeisferricoxide(i.e.,rust)三氧化二鐵(也就是鐵銹),butthefilmmaycontainnotonlyironbutalsochromiumandnickelcompoundsinvariousforms,andhencethefilmmayvaryincolorandtenacity(Figure2).Stainlesssteelis"stainless"owingtothefactthatthealloyformsathin,protective,tenacious,transparentoxidefilmthatprotectsitagainstdestructivecorrosivespeciesinaqueoussolutions.Thisfilmiscomposedofchromiumoxide,andissaidtomakethesteel"passive"againstcorrosion.Theexactnatureofthisfilmisacontinuingsubjectofdebate,andinfactitsexactstructureandnaturemayvary,dependingonanumberofvariables.Figure1.-Rougewipeseasilyoffthestainlesssteelsubstrate,butwillreform
Figure2.-Rougingcomesinmanycolorsdegreesoftenacity.Revised1stDec200418COMGroup,TMROUGING(鐵紅粉)-ADISCOLORATIONPittingofStainlessSteelAnotherprocess,whichismoredamaging,isthecreationandpropagationofpits.Non-metallicinclusions,suchassulfides,oxides,etc.,areaninherentresultofalloyproduction.Theyaredispersedthroughoutthemetalandarehighlysusceptibletoattackbyaggressiveenvironments.另外的一個過程,更加嚴(yán)重的損壞,就是凹點(diǎn)的產(chǎn)生和擴(kuò)大。合金里面包含了非金屬物質(zhì),比如硫化物,氧化物等,這是合金固有的性質(zhì)。他們散布在整個金屬中,并且受到刺激的環(huán)境的影響。Typicallytheseinclusionsaredissolvedinaparticularsolutionorenvironmentandleaveamicro-voidbehind.Thisvoidbecomesanoccludedcellwheresolutionchemistrycanbedifferentfromthebulksolution.通常這些包含物在特定的方式或環(huán)境下溶解掉,留下微小的空洞。Ifthestainlesssteeldoesnotreadilyre-passivate,thencorrosionattackwithinthevoidcanpropagate.Thecorrosionproductswithinthenowformedpitspilloutontothebulkmetalsurfaceproducinglocalizedrougingorrustblooms(Figure3).Afterapitinitiates,propagationofthepitmayoccurandprogressesuntilathrough-wallpenetrationoccurs.Alternately,ifthepitheals,theactivityceasesandnopropagationoccurs.
Figure3.-Rougeorrustbloomsidentifypitsites.Revised1stDec200419COMGroup,TMPittingofStainlessSteelAnotPassivationofStainlessSteelWhatispassivation?鈍化AccordingtoASTMA380,passivationis"theremovalofexogenousironorironcompoundsfromthesurfaceofstainlesssteelbymeansofachemicaldissolution,mosttypicallybyatreatmentwithanacidsolutionthatwillremovethesurfacecontamination,butwillnotsignificantlyaffectthestainlesssteelitself."Inaddition,italsodescribespassivationas"thechemicaltreatmentofstainlesssteelwithamildoxidant,suchasanitricacidsolution,forthepurposeofenhancingthespontaneousformationoftheprotectivepassivefilm."Itisalsoknownthatthetheprotectivepassivefilmformsveryrapidlyinmostenvironmentsthatarenotactivelyreducing.Exposuretomoistairwillprovidethispassivationwithinamatterofminutes,andthefilmwillthickenwithtime.ProcedureforPassivation:鈍化方式1)NitricAcid20%withFreshWatersolution,circulationbutterworth,3hrs.(3butterworthmachines,3steps)20%硝酸溶劑,循環(huán)沖洗,3小時(3個機(jī)器,3個步驟)2)Freshwaterbutterworth,30min.
淡水沖洗,30分鐘。3)Dryingthetanks,5hrs.
使貨艙干燥,5小時。Revised1stDec200420COMGroup,TMPassivationofStainlessSteelPassivation1.Precleaningbyseaorfreshwaterdependsoncurrentcargoes.2.Freshwaterwashingforthetankswashedbyseawaterandallseawaterdrainintanksmustbepumpedoutbeforemakingsolution.3.Picklingby30%nitricsolution3hrskeepmaximumtrimandlisttomakegoodstrippingadvantage.4.Keep3hrsforpassivation5.Freshwaterrinsingtilltheacidityistobe7atmanifold6.Wait1or2hrsbeforesteaming7.Steaming2-3hrs8.Dryingandmopping.Howtomakesolution?:Notes1.trytopassivationasmanyaspossiblebyonesolution2.leavetwotankswhichwereloadedphosphoricacidpreviouslytomakecompareinthefuture.3.takeapicturebeforeandafterpassivationbutitmustbesamelocation.4.keeprecordallhappeningswhilepassivation5.passivationtankbytankisrecommended.7.keeptheenoughstockoffreshwater.Revised1stDec200421COMGroup,TMPassivation1.PrecleaningbyHowtodilution如何稀釋
Ex)When3000Litersof30%solutionismadeusingby60%concentrationofNitricAcid.Athere,“A”standsfor60%Nitricacid,and“B”standsforFreshwater.Then,1500LofFreshwaterand1500Lof60%ofNitricAcidwillmake3000Lsolutionof30%Revised1stDec200422COMGroup,TMHowtodilution如何稀釋
Ex)When3BeforepassivationRevised1stDec200423COMGroup,TMBeforepassivationRevised1stAfterpassivationRevised1stDec200424COMGroup,TMAfterpassivationRevised1stDTankCoatingPropertiesTankCoatingProperty性質(zhì)Detergent洗滌劑EpoxyNormallyvegetable&animaloils,andnon-aggressivecargoesaresuitable.Highfattyacid&aggressivecargoesareunsuitable通常動植物油,非刺激性貨物,高脂肪酸或刺激貨物不適合Alkalis,weakacid,neutral堿類,弱酸,中性ZincChemicalcargoesaresuitable.AcidsorAlkalisarenotsuitable.TheirsuitabilityislimitedtoproductsinthepH-rangebetween5.5to9.0一般化學(xué)貨物適合,酸堿不適合,適用于ph值在5.5-9之間的貨物.neutral中性StainlesssteelVegetableoils,Chemicalbutsomecargosuchasaceticaciddependonkindofstainlesssteel植物油,化工品,但是化工品如冰醋酸需要看不銹鋼的等級.Norestrictionbutalkalisdetergentcanberesultedtowhiteresidueonbulkheads沒有限制,但是堿性洗滌劑可以導(dǎo)致艙壁上白色殘留物Revised1stDec200425COMGroup,TMTankCoatingPropertiesTankCoKinds&Quantityofdetergent
GenerallyHighertemperatureofdetergentismoreeffective.ButsomeAlkalinedetergentcanremainwhiteresidueonthewallofcargotank.Theconcentrationofdetergentagainstwatershouldfollowmaker’srecommendationwhichismentionedinthedatasheet.通常溫度越高,洗滌劑就越有效.但是有些堿性洗滌劑能夠保留白色的殘留物.洗滌劑的濃度大小必須要根據(jù)制造商的建議.Lowconcentrationofdetergentisnoteffectiveforcleaning.低濃度的洗滌劑對洗艙沒有效果.Highconcentrationisnotpreferablebecauseofremainingwhitepowderonthewallortakinglongtimeforrinsing.高濃度的洗滌劑也不可取,因為遺留的白色粉末需要更長的時間清洗.Mixingdifferentdetergentwitheachotherisnotrecommended不建議不同的洗滌劑混合使用.Revised1stDec200426COMGroup,TMKinds&QuantityofdetergentDetergentcompatibilityChartwithTankCoatingKindofdetergent&chemicalEpoxyZincSUSTemp.againstdetergentAlkalinedetergent(B2,CausticSoda)SuitableUnsuitableSuitablebutremainswhitepowderonsurfaceMax.50CDuetowhitepowderNeutraldetergentSuitableSuitableSuitableMax.70CAcidascleaningmaterials(rustremover,phosphoricacid)Limitedaccordingtothematerialofcoating&coatingcondition.ItcanacceleratecoatingdamageUnsuitableSuitable30Cisnormal.Dependonconcentrationofacid&lastcargoMaxTemperatureagainstcoating80C70CNolimitationbutcoatingofsurroundingcargotanksandballasttankshouldbeconsidered
Revised1stDec200427COMGroup,TMDetergentcompatibilityChartStructureofcargotankNormallycentertankdoesn’thavemuchstructures(Stiffeners)whichcreatedifficultyfortankcleaning,buthoweverwingtankshavestructuressuchaswebframeandlongitudinalbeamwhichcanbeobstructedtodotankcleaningbyT/Cmachines.Thereforeheightofmachinehastobetakenintoconsiderationnottohaveshadowareaandeverystep(drop)hastobeadjustedtheheightofmachineperiodically.Tankcleaningtimeofwingtankisrequiredlongerthancentertank.Revised1stDec200428COMGroup,TMStructureofcargotankNormallMARPOLRegulation
MARPOLAnnex-1&2regulationssuchasspecialarea&limitationaboutdisposaloftankcleaningwatershouldbetakenintoconsideration.ForfurtherdetailsrefertoGuidanceofCargoRecordBookwhichprovidedbycompanyandMARPOLPublication.(SEESEPARATEDDATA)Revised1stDec200429COMGroup,TMMARPOLRegulation MARPOLAnnexOilDischargeMonitoringSystem(ODME)Revised1stDec200430COMGroup,TMOilDischargeMonitoringSysteItemstobeconsideredfortankcleaningplanning洗艙時需要考慮的事情Watersolubilityanditstemperature
水溶性和溫度Polymerization
聚合性Meltingpoint=Freezingpoint
溶點(diǎn)=凝固點(diǎn)Boilingpoint
沸點(diǎn)Aggressiveness=Penetrating
刺激性=穿透性Staticelectricity
靜電Vaporpressure
蒸氣壓PollutionCategory
污染類別TankCoating
貨艙的涂層Inhibitor
阻聚劑Nextcargo
下一票貨Revised1stDec200431COMGroup,TMItemstobeconsideredfortanCapacityofButterworthHeaterCapacityofButterworthHeaterdependsondesignedcapacity,seatemperature,&maintenanceofButterworthHeater.洗艙加溫器的能力取決于設(shè)計能力,海水溫度和維護(hù).Revised1stDec200432COMGroup,TMCapacityofButterworthHeaterNumbersoftankcleaningmachinetobeusedduringtankcleaning如何決定洗艙時洗艙機(jī)數(shù)量Itisdecidedaccordingtocapacityoftankcleaningpump,powerpack&butterworthheaterandpropertyofcargo.
由洗艙泵的能力,功率,加溫器和貨物的性質(zhì)決定的.
Ifcapacityoftankcleaningpumpis150m3,thenumberofT/Cmachinewillbe15018=about8.
如果洗艙泵的能力是150立方,那么洗艙設(shè)備的數(shù)量是150÷18=8(大約) Where:18isselectedfromtableoftankcleaningmachinementioned.18是根據(jù)所選用的洗艙設(shè)備所提到而決定的.However,thenumberofT/CmachinemaybelimitedbythecapacityofpowerpacksbecausenumbersofcargotankstobecleanedhavetoincludeandcapacityofbutterworthheaterincaseofT/Cofcargohadhighmeltingpointinwinterseason.但是決定洗艙設(shè)備數(shù)量并不僅僅局限于功率大小,還決定于加溫器的能力,特別在冬季洗艙時,貨物的溶點(diǎn)大于水溫.Revised1stDec200433COMGroup,TMNumbersoftankcleaningmachiNextcargo
下一票貨Cleaningofcargotankdependsonnextcargoifitislowergrade,samegradeorhighergradethanlastcargo.洗艙還決定下一票貨是否比上票貨等級低,同等或者高等級.Revised1stDec200434COMGroup,TMNextcargo下一票貨CleaningofcarManpowerTankcleaningplanhastobereasonablymadetomeetcapacityandmanpowerofvessel’screw.
洗艙計劃還必須根據(jù)船員的能力以及勞動力來決定.Revised1stDec200435COMGroup,TMManpowerTankcleaningplanhasStep(Drop)ofmachineStep(Drop)ofmachinedependsonpropertyoflastcargo,structureofcargotank,andnextcargo.步驟(下垂)根據(jù)上票貨的性質(zhì),貨艙結(jié)構(gòu)和下票貨來決定.3metersRevised1stDec200436COMGroup,TMStep(Drop)ofmachineStep(DroKindoftankcleaningwater洗艙水的種類Therearetwo(2)kindsoftankcleaningwateri.e.freshwaterandseawater.SomecargoessuchasCausticSodaorAcidsmakeareactionwithseawater.有兩種洗艙水,淡水和海水.有些貨可以和海水反應(yīng),如燒堿或酸.Itisrecommendedtousefreshwateratfollowingcases:下列情況下建議用淡水洗艙i)makingdetergentsolutionwithwater
使用洗滌劑.ii)lastcargoiscausticsodaoracids
上票貨是燒堿或酸.iii)nextcargoissensitiveagainstchloride(MEG,Methanoletc.,)下票貨對氯離子敏感.Revised1stDec200437COMGroup,TMKindoftankcleaningwater洗艙水PropertyofCargoTemp.(C)
Pressure(bar.)
T/CprocedureBWmachineCuring
BWcleaning
Detergent
SteamforNo.Step(drop)1.SolubleinwaterN/ANormalN/A(exceptmolasses)YesNoremovechlorideHalfoftotalnosminimumdrop2.Highvaporpressure(volatile)WithinLELMinimumEpoxytankGasfreeorafewminuteBWNoRemovesmellHalfoftotalnosOnedrop3.SolidifyHottemp.Max.N/AYesDependonnextcargoEmulsifyMax.Max.(everystep)4.HighviscosityHottemp.Max.N/AYesDependonnextcargoReduceviscosityMax.Max.5.PolymerColdMax.N/AYesDependonnextcargoSmellMax.Max.6.DryColdMax.N/AYesYes
Max.Max.7.Non-volatile)Warm&hatMax.DependoncargoYesDependoncargoSmellMax.Max.1+2(Acetone)ColdMin.EpoxytankGasfree&BWNoSmellMin.Onedrop1+3(Phenol)HotNormalN/AYesNoSmellNormal2-3drops1+4(TEA)HotNormalN/AYesNoSmellNormal2-3drops1+5ColdNormalN/AYesNoSmellNormal2-3drops1+6ColdNormalN/AYesNo
Normal2-3drops1+7(MEG)ColdMinN/AYesNoChlorideMin.2dropsRevised1stDec200438COMGroup,TMPropertyofCargoTemp.PressurePreparationfortankcleaning
Revised1stDec200439COMGroup,TMPreparationfortankcleaningTankcleaningplantobeprovidedaccordingly
只作相應(yīng)的洗艙計劃a)Time,Drops,Temperature,foreachcargotank時間,次數(shù),溫度b)Sequenceofhoseconnectiontomanifolds,軟管接Manifold的順序c)Rotationofcargotank,洗艙的先后d)Watchkeeping,監(jiān)視洗艙e)
Ballastcontrolforadjustinglist&trim
壓載艙調(diào)整船舶傾斜(前后,左右)f)Name&quantityofDetergent
洗滌劑的名稱和數(shù)量Revised1stDec200440COMGroup,TMTankcleaningplantobeprovi
Explaintheplantocrew&theplantobepostedatCCRwithsignatureofcrew
向船員講解洗艙計劃并且將船員簽字的計劃貼在CCR上
Revised1stDec200441COMGroup,TM
Explaintheplantocrew&thFollowingstobepreparedinadvance
下面事項必須要提前準(zhǔn)備a)Butterworthmanholes
洗艙孔b)PVvalves(toavoidconfusionwithcargoloadedtanks)PV閥c)
Lineupvalves(toavoidconfusionwithcargoloadedtanks)卸貨閥d)
ManifoldsamplingflangesManifold樣品法蘭e)LetprepareDrainHoseatspilltank
f)Standbytankcleaningpump&cargopump
準(zhǔn)備好洗艙泵和貨泵g)Don'topenflangesofAircocksoncargopumpstackanddraincocksbecausecargomightleaked.h)FlangesofAircockstobeopenedonlyafterconfirmedthatcleanwaterisbeingdischarged.
Revised1stDec200442COMGroup,TMFollowingstobepreparedinaPre-cleaningWhendischargedpolymerizeordrycargo,thetankisrequiredtocarryoutpre-cleaningassoonascompletionofcargodischargeandaftergotdrycertificatefromcargosurveyor.ThesameprecautionsasPre-washatportarerequired.當(dāng)卸完易聚合貨物或干貨后,貨艙必須在拿到干艙證書后立即進(jìn)行預(yù)洗。當(dāng)然也要按照港口規(guī)則。Revised1stDec200443COMGroup,TMPre-cleaningWhendischargedpoBWCleaning(MainTankCleaning)6.1)
IncaseofPolymerizecargo,heatingcoilincargotank&cofferdamofcargopumptobeblownouttoavoidcargointheCargoLinestopolymerize.對于聚合物的洗艙,在貨艙中的加熱管和貨泵的隔艙中必須吹管吹干凈。防止貨物在貨管中聚合。6.2)
WhendischargingCategoryIII/cleantankwashingintotheSeathroughCargoManifold,allowsufficientlengthofCargoHose/HosetobelowereddowntoShip-sidetopreventdamagingofShip’shullpaint.(DuetoswingingofHoseincontactwithShipHull)Ifapplicable,don'tusecargohose6.3)
AssoonasthePumpstarts,thecleaningwateristobeconfirmedifitisbeingdischargedproperly.當(dāng)泵機(jī)開始時,必須馬上確認(rèn)干凈的水是否正確進(jìn)入。6.4)
Whendischargingsimultaneouslytankcleaning
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