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Chapter
3Nuclear
Energy
and
ItsEnvironmental
Impact(核能及其環(huán)境影響)3.1
Nuclear
Fission
and
Nuclear
Power(核裂變和核電廠)3.2
Nuclear
Fusion(核聚變)3.1
Nuclear
Fission
and
NuclearPower1. Introduction
to
Nuclear
Fission
andNuclear
PowerNuclear
fission:
nucleus
splits
into
two
daughter
nuclei,with
a
very
large
release
of
energy.Nuclear
power:
any
nuclear
technology
designed
to
extractusable
energy
from
atomic
nuclei
via
controlled
nuclearreactions.the
only
method
in
use
today
is
through
nuclearfission.Nuclear
power
plant
generates
electricity
in
a
mannersimilar
to
a
coal-burning
power
plant.heating
a
fluid
(usually
water)generates
steam
(directly
or
indirectly)drives
turbine
blades
connected
to
a
power
generatorDifference
——
the
method
for
heating
the
water:nuclear
reactions
vs.
coal
combustionIsotopes
–
elements
with
the
same
number
of
protons,different
number
of
neutrons
(and
different
atomic
mass)Example
-
Uranium
(U)
=
92
protons
in
nucleus...238U
(146
neutrons)235U
(143
neutrons)?Radioactivity
and
radioactive
decay
(half-life)Not
all
isotopes
are
stableRadioactive
isotopes
undergo
radioactive
decay
toeventually e
a
stable
nucleusEisxoatomppesle同-位23素8pUroetovne質(zhì)nt子uanlleyuterosn
s中ta子blread2io0a6cPtivbity(l放ea射d性)decay
衰變half-life
半衰期2.
Nuclear
FuelNuclear
fuel
uses
the
isotope
of
uranium,
radioactive235U,
the
only
isotope
of
uranium
that
readily
splits.—
Pure
uranium
ore
is
mostly
composed
of
238U
(only0.7%
235U),
which
does
not
split
readily.—Thus,
most
nuclear
fuel
needs
to
be
concentrated(enriched)
before
it
can
be
used
(3%~4.5%).Nuclear
weapons
require
much
higher
enrichment
in235U>>WEAPON
GRADE
nuclear
material—
enrichment15%~20%
235U.
A
big
step
up
from
preparation
of
reactorfuel.After
enrichment,
the
uranium
is
formed
intoceramic
pellets
which
are
then
encased
in
metalfuel
rods.Bundles
of
rods
are
put
into
a
stainless
steel
reactor vessel.Fuel
rods
remain
in
the
reactor
core,
undergoing fission.At
below1%
the
fuel
is
no
longer
efficient
for
use
in
thereactorpellet
小球encase裝入stainless
steel
不銹鋼vessel
容器For
nuclear
fission:A
neutron
(non-charged particle)
strikes
the
nucleus
of a
235U
atomThis
causes
it
to
split
apart,releasingheat2-3
other
neutrons,
andvarious
kinds
of
fissionproductsThe
released
neutrons
collide with
other
235U
nuclei, repeating
the
process
in
a chain
reaction
(self-supporting)strike
撞擊collide
碰撞Usually,
in
nuclear
reactors,
operators
control
thischain
reaction
so
it
does
not
get
out
of
control.UseControl
rodsRods,
composed
of
either
cadmium
or
boron,
areinserted into
the
core
to
capture
neutronsControl
the
chain
reaction
when
the
reaction
accelerates
too quickly.ModeratorUsed
to
slow
neutrons
and
encourage
more
interaction
with uraniumfuel“Critical
mass”
–
the
amount
of
U
required
tomaintain
a
chain
reaction
in
a
nuclear
reactorGenerally,
completely
out
of
control
reactionswould
lead
to
an
explosion
(as
in
nuclearweapons)Reactor
materials
are
not
concentrated
enough
to
explode.An
out
of
control
chain
reaction
would
lead
to overheating
of
the
core,
causing
the
fuel
rods
and vessel
to
melt“Meltdown”
=
supercritical
mass
-
Chernobyl,
Ukrainereactor
反應(yīng)堆
fuel
rod
燃料棒
control
rod
控制棒
core
堆芯
moderator
慢化劑
shielding
屏蔽Fuel
rods
contain
pellets
of
fuel
for
a
nuclear
reactor
.Control
rods
control
the
chain
reaction.Liquid
water
acts
both
as
a
coolant
and
as
a
moderator.Moderator
slows
down
the
neutrons
to
increase
the
fissionprobability.—the
probability
of
fission
is
maximal
when
the
neutron
energy
is
closeto
the
average
energy
of
the
surroundingmolecules.Breeder
reactor(增殖反應(yīng)堆)Breeder
reactor
extends
the
nuclear
fuel
supply
byconverting
238U
to
239Pu.The
conversion
is plished
by
irradiating
uranium
withneutrons.Efficient
production
of
239Pu
requires
a
“breeder”
reactor,operating
with
fast
neutrons.Surrounding
the
reactor
is
a
blanket
of
ordinary
uranium,
inwhich
the
239Pu
is
bred
by
the
fast
neutrons.The
reactor
fuel
must
be
enriched
to
the
extent
of
15~20percent
with
a
fissionable
isotope,
either
235U
or
239Pu.The
main
difference
with
respect
to
an
ordinary
fissionreactor
is
that
the
water
coolant
is
replaced
by
liquidsodium(鈉).The
sodium
atoms
slow
the
neutron
to
a
much
smallerextent,
while
liquid
sodium
efficiently
carries
away
heatfrom
the
reactor.The
technology
of
the
breeder
reactor
is
farmore
complex
than
that
of
the
ordinary
fissionreactor,
and
the
technology
is
still
beingdeveloped.The
most
formidable
(可怕的)
problem
of
thebreeder
reactor
seems
to
be
associated
with
theplumbing(管道)
of
the
heat
exchanger,
sinceleaksofliquid
sodiumcanbedisastrous(慘重的).ReprocessingThe
235U
in
a
fuel
rod
of
a
pressurized
light
water
reactorcan
not
be
completely
used
up.After
about
a
year,
the
fuel
rods
must
be
replaced
withnew
ones.The
spent
fuel
can
be
reprocessed
by
chemicalextraction
of
the
fission
products,
separation
of
theaccumulated
plutonium(Pu,
钚),and
reconcentration(再濃縮)
of
the
uranium.Uranium:
refabricated
(再加工)into
new
fuel
rods Plutonium:blended
into
MOX
(mixed
uranium-plutonium
oxide,
混合氧化物)fuel
rods.Reprocessing:
the
chemistry
is
straightforward,
but
thetechnology
is
complicated.—The
fuel
rods
are
chopped
up
and
dissolved
in
acid—The
solution
is
subjected
to
successive
solvent
extractionand
ion
exchange
to
separate
the
elements.—Remote
handled
intensely
radioactive
material.StorageSo
far,
there
is
no
way
to
permanently
dispose
of
high-level
radioactivewasteChemical
reactions
cannot
destroy
radioactive
wasteradioactivity
is
a
nuclear
processatomic
nuclei
are
unaffected
by
chemical
reactionsThe
only
choice
is
tostore
the
waste
in
a
place
safe
fromgeological
hazards
(earthquakes,
volcanic
activity,
landslides(山崩),creep(蠕動),floods,
and
seeping
water(滲水))and
human
intervention
(人類干預(yù))allow
them
to
decay
naturally
(over
250,000
years)Many
tons
of
radioactive
materials
haveaccumulated
over
past
decades
and
representproven
hazards
to
humans
and
futuregenerations.High-level
nuclear
waste
needs
to
be
isolated because
high-energy
radiation:Kills
cellsCauses
cancer
and
genetic
mutations(基因突變)Cancause
rapid
death
in
cases
of
high
exposure
levels.Also,
radioactive
decay
produces
heat
and
can damage
crystalline
and
metallic
holding tanks/containers
=
leaks!Two
choicespermanent
disposal
(injection
into
impermeable(不透 水的)
layers)monitored,retrievable(可回收的)
storage
(isolated, safe
storage,but
able
to
pull
out
and
move
until technology
finds
a
better
solution)3.
Change
in
Attitudes
TowardsNuclear
Power1950’s
–
nuclear
power
was
seen
as
the
wave
ofthe
futureClean,
safe,
limitlessSince
1979,
new
concernsPlant
safetyRadioactive
waste
disposalVast
cost
overruns
in
plant
constructionTwo
major
accidents
have
occurred
at
nuclear
powerplants:Three
Mile
Island,
Pennsylvania(1979)Mechanical
and
operator
error
prevented
water
from
cooling
the
coreAllowed
heat
to
build
up
and
partial
meltdown
to
occur.Most
radioactivity
contained
within
the
building,–
small
amount
of
water
with
low-level
radiation
leaked
into
theenvironment.The
building
was
highly
contaminated
but
the
leak
probably
did
littledamage
to
the
environmentBut,
did
damage
the
public
perceptions
of
nuclear
plants
and
theirpotential
hazards.–
Chernobyl,
Ukraine,
1986April26,Siteofthe
most
seriousnuclearaccident
inhistory
1986Due
to
mistakes
and
problems
with
the
cooling
water
system,the
reactor
core
became
supercritical
during
atestexperimentAllowed
temperatures
to
rise
above
3000℃,
causinguranium
fuel
to
completely
melt.Amassive
steam
explosion
occurred
that
(literally)blew
thetop
off
of
the
building.The
graphite
surrounding
the
fuel
rods
ignited
and
burnedfor10
days,
sending
radioactive
gas
into
the
atmosphereThe
fire
was
eventually
put
out
and
the
reactor
core
encasedand
buried
inconcrete.The
plant
design
has
been
criticized
as
being
poor
and
thereare
other
reactors
of
this
same
design
in
Chernobyl
andelsewhere
in
the
former
Soviet
UnionLasting
effects
of
Chernobyl30
people
died
immediately
from
radiation
exposure?
acute
radiation
syndromethousands
died
from
exposure
during
clean-up
operationsmillions
were
exposed
to
high
levels
of
radiationThe
Soviet
governmenthandled
the
crisis
verypoorlyand
delayed
notifying
othercountries
about
the
radiationleak.The
accident
occurred
onSaturdaySwedish
scientists
detected
theradiation
onMonday.The
area
was
evacuatedslowly
and
many
people
wereput
at
riskunnecessarily.Radioactive
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