20%吡唑醚菌酯種子處理劑Accelero dx

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20%吡唑醚菌酯種子處理劑（Accelerodx

MONSANTOCOMPANYPage:1of8AcceleronDX-109FungicideSeedTreatmentVersion:2.0Effectivedate:18-June-2010MONSANTOCOMPANYSafetyDataSheetCommercialProduct1.Substance/preparationandcompanyidentificationProductNameAcceleronDX-109FungicideSeedTreatmentSubstancenumber:000000213893Molecularformula:C19H18ClN3O4Molecularweight:387.82g/molChemicalfamily:strobilurineSynonyms:pyraclostrobinEPARegistrationNo.7969-266-524CompanyMONSANTOCOMPANY,800N.LindberghBlvd.,St.Louis,MO,63167Telephone:800-332-3111,Fax:314-694-5557E-mail:TS-SAFETYDATASHEET@DOMINO.MONSANTO.COMEmergencynumbersFORCHEMICALEMERGENCY,SPILLLEAK,FIRE,EXPOSURE,ORACCIDENTCallCHEMTREC-DayorNight:1-800-424-9300tollfreeinthecontinentalU.S.,PuertoRico,Canada,orVirginIslands.Forcallsoriginatingelsewhere:703-527-3887(collectcallsaccepted).FORMEDICALEMERGENCY-DayorNight:+1(314)694-4000(collectcallsaccepted).2.HazardsIdentificationEmergencyoverviewCAUTION:HARMFULIFSWALLOWED.HARMFULIFABSORBEDTHROUGHSKIN.Causeseyeirritation.KEEPOUTOFREACHOFCHILDREN.KEEPOUTOFREACHOFDOMESTICANIMALS.Avoidcontactwiththeskin,eyesandclothing.SeeProductLabelforadditionalprecautionarystatements.Stateofmatter:liquidColour:off-whiteOdour:fruityPotentialhealtheffectsPrimaryroutesofexposure:Routesofentryforsolidsandliquidsincludeeyeandskincontact,ingestionandinhalation.Routesofentryforgasesincludeinhalationandeyecontact.Skincontactmaybearouteofentryforliquifiedgases.Acutetoxicity:Slightlytoxicaftersingleingestion.Relativelynontoxicaftershort-terminhalation.Relativelynontoxicaftershort-termskincontact.Irritation/corrosion:Maycausemoderateirritationtotheskin.Maycauseslightbuttemporaryirritationtotheeyes.Sensitization:Skinsensitizingeffectswerenotobservedinanimalstudies.PotentialenvironmentaleffectsMONSANTOCOMPANYPage:2of8AcceleronDX-109FungicideSeedTreatmentVersion:2.0Effectivedate:18-June-2010Aquatictoxicity:Verytoxic(acuteeffect)toaquaticorganisms.Terrestrialtoxicity:Withhighprobabilitynotacutelyharmfultoterrestrialorganisms.Degradation/environmentalfate:Notreadilybiodegradable(byOECDcriteria).3.Composition/InformationonIngredientsCASNumberContent(W/W)175013-18-0Chemicalname=20.4%Pyraclostrobin56-81-5=11.0%glycerol108-88-3=0.1%Toluene=70.0%Proprietaryingredients4.First-AidMeasuresGeneraladvice:Firstaidprovidersshouldwearpersonalprotectiveequipmenttopreventexposure.Removecontaminatedclothing.Movepersontofreshair.Ifpersonisnotbreathing,call911orambulance,thengiveartificialrespiration,preferablymouth-to-mouthifpossible.Callapoisoncontrolcenterorphysicianfortreatmentadvice.Havetheproductcontainerorlabelwithyouwhencallingapoisoncontrolcenterordoctororgoingfortreatment.Ifinhaled:Removetheaffectedindividualintofreshairandkeepthepersoncalm.Ifonskin:Rinseskinimmediatelywithplentyofwaterfor15-20minutes.Ifineyes:Holdeyesopenandrinseslowlyandgentlywithwaterfor15to20minutes.Removecontactlenses,ifpresent,afterfirst5minutes,thencontinuerinsing.Ifswallowed:Neverinducevomitingorgiveanythingbymouthifthevictimisunconsciousorhavingconvulsions.Donotinducevomiting.Havepersonsipaglassofwaterifabletoswallow.Antidote:NotetophysicianNoknownspecificantidote.Treatment:Treatsymptomatically.5.Fire-FightingMeasuresFlashpoint:100C(ASTMD93)Non-flammable.Autoignition:425C(Directive92/69/EEC,A.15)Flammability:notself-ignitingSuitableextinguishingmedia:foam,dryextinguishingmedia,carbondioxide,watersprayHazardsduringfire-fighting:carbonmonoxide,carbondioxide,nitrogendioxide,nitrogenoxide,Hydrogenchloride,halogenatedhydrocarbons,Hydrocarbons,Ifproductisheatedabovedecompositiontemperature,toxicvapourswillbereleased.Thesubstances/groupsofsubstancesmentionedcanbereleasediftheproductisinvolvedinafire.Protectiveequipmentforfire-fighting:Firefightersshouldbeequippedwithself-containedbreathingapparatusandturn-outgear.MONSANTOCOMPANYPage:3of8AcceleronDX-109FungicideSeedTreatmentVersion:2.0Effectivedate:18-June-2010Furtherinformation:Evacuateareaofallunnecessarypersonnel.Containcontaminatedwater/firefightingwater.Donotallowtoenterdrainsorwaterways.6.AccidentalreleasemeasuresPersonalprecautions:Takeappropriateprotectivemeasures.Cleararea.Shutoffsourceofleakonlyundersafeconditions.Extinguishsourcesofignitionnearbyanddownwind.Ensureadequateventilation.Wearsuitablepersonalprotectiveclothingandequipment.Environmentalprecautions:Donotdischargeintothesubsoil/soil.Donotdischargeintodrains/surfacewaters/groundwater.Containcontaminatedwater/firefightingwater.Cleanup:Dikespillage.Pickupwithsuitableabsorbentmaterial.Placeintosuitablecontainersforreuseordisposalinalicensedfacility.Spilledsubstance/productshouldberecoveredandappliedaccordingtolabelrateswheneverpossible.Ifapplicationofspilledsubstance/productisnotpossible,thenspillsshouldbecontained,solidified,andplacedinsuitablecontainersfordisposal.Afterdecontamination,spillareacanbewashedwithwater.Collectwashwaterforapproveddisposal.7.HandlingandStorageGeneraladvice:HandlingRECOMMENDATIONSAREFORMANUFACTURING,COMMERCIALBLENDING,ANDPACKAGINGWORKERS.PESTICIDEAPPLICATORSWORKERSmustrefertotheProductLabelandDirectionsforUseattachedtotheproductforAgriculturalUseRequirementsinaccordancewiththeEPAWorkerProtectionStandard40CFRpart170.Ensureadequateventilation.Providegoodventilationofworkingarea(localexhaustventilationifnecessary).Keepawayfromsourcesofignition-Nosmoking.Keepcontainertightlysealed.Protectcontentsfromtheeffectsoflight.Protectagainstheat.Protectfromair.Handleandopencontainerwithcare.Donotopenuntilreadytouse.Oncecontainerisopened,contentshouldbeusedassoonaspossible.Avoidaerosolformation.Avoiddustformation.Providemeansforcontrollingleaksandspills.Donotreturnresiduestothestoragecontainers.Followlabelwarningsevenaftercontainerisemptied.Thesubstance/productmaybehandledonlybyappropriatelytrainedpersonnel.Avoidalldirectcontactwiththesubstance/product.Avoidcontactwiththeskin,eyesandclothing.Avoidinhalationofdusts/mists/vapours.Wearsuitablepersonalprotectiveclothingandequipment.Protectionagainstfireandexplosion:Therelevantfireprotectionmeasuresshouldbenoted.Fireextinguishersshouldbekepthandy.Avoidallsourcesofignition:heat,sparks,openflame.Sourcesofignitionshouldbekeptwellclear.Avoidextremeheat.Keepawayfromoxidizablesubstances.Electricalequipmentshouldconformtonationalelectriccode.Groundalltransferequipmentproperlytopreventelectrostaticdischarge.Electrostaticdischargemaycauseignition.Generaladvice:StorageKeeponlyintheoriginalcontainerinacool,dry,well-ventilatedplaceawayfromignitionsources,heatorflame.Protectcontainersfromphysicaldamage.Protectagainstcontamination.Theauthoritypermitsandstorageregulationsmustbeobserved.Storageincompatibility:Generaladvice:Segregatefromincompatiblesubstances.Segregatefromfoodsandanimalfeeds.Segregatefromtextilesandsimilarmaterials.TemperaturetoleranceProtectfromtemperaturesbelow:0CChangesinthepropertiesoftheproductmayoccurifsubstance/productisstoredbelowindicatedtemperatureforextendedperiodsoftime.Protectfromtemperaturesabove:40CMONSANTOCOMPANYPage:4of8AcceleronDX-109FungicideSeedTreatmentVersion:2.0Effectivedate:18-June-2010Changesinthepropertiesoftheproductmayoccurifsubstance/productisstoredaboveindicatedtemperatureforextendedperiodsoftime.8.ExposureControlsandPersonalProtectionUsersofapesticidalproductshouldrefertotheproductlabelforpersonalprotectiveequipmentrequirements.glycerolComponentswithworkplacecontrolparametersOSHAPEL5mg/m3Respirablefraction;PEL15mg/m3Totaldust;ACGIHTWAvalue10mg/m3Mist;TolueneOSHATWAvalue200ppm;CLV300ppm;max.conc.500ppm;ACGIHTWAvalue20ppm;Adviceonsystemdesign:Wheneverpossible,engineeringcontrolsshouldbeusedtominimizetheneedforpersonalprotectiveequipment.RECOMMENDATIONSFORMANUFACTURING,COMMERCIALBLENDING,ANDPACKAGINGWORKERS:PersonalprotectiveequipmentRespiratoryprotection:Wearrespiratoryprotectionifventilationisinadequate.WearaNIOSH-certified(orequivalent)organicvapour/particulaterespirator.Forsituationswheretheairborneconcentrationsmayexceedthelevelforwhichanairpurifyingrespiratoriseffective,orwherethelevelsareunknownorImmediatelyDangeroustoLifeorHealth(IDLH),useNIOSH-certifiedfullfacepiecepressuredemandself-containedbreathingapparatus(SCBA)orafullfacepiecepressuredemandsupplied-airrespirator(SAR)withescapeprovisions.Handprotection:Chemicalresistantprotectivegloves,Protectivegloveselectionmustbebasedontheuser’sassessmentoftheworkplacehazards.Eyeprotection:Safetyglasseswithside-shields.Tightlyfittingsafetygoggles(chemicalgoggles).Wearfaceshieldifsplashinghazardexists.Bodyprotection:Bodyprotectionmustbechosendependingonactivityandpossibleexposure,e.g.headprotection,apron,protectiveboots,chemical-protectionsuit.Generalsafetyandhygienemeasures:Wearlongsleevedworkshirtandlongworkpantsinadditiontootherstatedpersonalprotectiveequipment.Workplaceshouldbeequippedwithashowerandaneyewash.Handleinaccordancewithgoodindustrialhygieneandsafetypractice.Personalprotectiveequipmentshouldbedecontaminatedpriortoreuse.Glovesmustbeinspectedregularlyandpriortoeachuse.Replaceifnecessary(e.g.pinholeleaks).Takeoffimmediatelyallcontaminatedclothing.Storeworkclothingseparately.Handsand/orfaceshouldbewashedbeforebreaksandattheendoftheshift.Noeating,drinking,smokingortobaccouseattheplaceofwork.Keepawayfromfood,drinkandanimalfeedingstuffs.9.PhysicalandChemicalPropertiesForm:liquid,viscousOdour:fruityColour:off-whitepHvalue:approx.7.3(1%(m),22C)(assuspension)Freezingpoint:approx.0C(1,013.3hPa)Informationappliestothesolvent.Boilingpoint:approx.100C(1,013.3hPa)Informationappliestothesolvent.Vapourpressure:23.3hPa(20C)Informationappliestothesolvent.Density:approx.1.09g/cm3(20C)Viscosity,dynamic:approx.58mPa.s(20C)MONSANTOCOMPANYPage:5of8AcceleronDX-109FungicideSeedTreatmentVersion:2.0Effectivedate:18-June-2010Solubilityinwater:dispersibleMolarmass:387.82g/mol10.StabilityandReactivityConditionstoavoid:Avoidallsourcesofignition:heat,sparks,openflame.Avoidextremetemperatures.Avoidprolongedexposuretoextremeheat.Avoidcontamination.Avoidelectro-staticdischarge.Avoidprolongedstorage.Substancestoavoid:strongoxidizingagentsHazardousreactions:Theproductischemicallystable.Hazardouspolymerizationwillnotoccur.Nohazardousreactionsifstoredandhandledasprescribed/indicated.Decompositionproducts:Nohazardousdecompositionproductsifstoredandhandledasprescribed/indicated.,Prolongedthermalloadingcanresultinproductsofdegradationbeinggivenoff.Thermaldecomposition:165CPossiblethermaldecompositionproducts:carbonmonoxide,carbondioxide,nitrogendioxide,nitrogenoxide,Hydrogenchloride,halogenatedhydrocarbons,HydrocarbonsStableatambienttemperature.Ifproductisheatedabovedecompositiontemperaturetoxicvapoursmaybereleased.Ifproductisheatedabovedecompositiontemperaturehazardousfumesmaybereleased.Corrosiontometals:Corrosiveeffectstometalarenotanticipated.Oxidizingproperties:Notanoxidizer.11.ToxicologicalinformationAcutetoxicityOral:Typeofvalue:LD50Species:rat(female)Value:approx.2,000mg/kgInhalation:Typeofvalue:LC50Species:rat(male/female)Value:5.3mg/l(OECDGuideline403)Exposuretime:4hDermal:Typeofvalue:LD50Species:rat(male/female)Value:5,000mg/kgIrritation/corrosionSkin:Species:rabbitResult:moderatelyirritatingEye:Species:rabbitResult:Minimallyirritating.MONSANTOCOMPANYPage:6of8AcceleronDX-109FungicideSeedTreatmentVersion:2.0Effectivedate:18-June-2010Sensitization:modifiedBuehlertestSpecies:guineapigResult:Skinsensitizingeffectswerenotobservedinanimalstudies.GenetictoxicityInformationon:pyraclostrobinNomutageniceffectwasfoundinvarioustestswithmicroorganismsandmammaliancellculture.CarcinogenicityInformationon:pyraclostrobinInlong-termstudiesinratsandmiceinwhichthesubstancewasgivenbyfeed,acarcinogeniceffectwasnotobserved.ReproductivetoxicityInformationon:pyraclostrobinTheresultsofanimalstudiesgavenoindicationofafertilityimpairingeffect.Development:Informationon:pyraclostrobinNoindicationsofadevelopmentaltoxic/teratogeniceffectwereseeninanimalstudies.Informationon:TolueneIndicationsofpossibledevelopmentaltoxicity/teratogenicitywereseeninanimalstudies.12.EcologicalInformationFishInformationon:pyraclostrobinAcute:Cyprinuscarpio/LC50(96h):0.0121-0.0258mg/lLepomismacrochirus/LC50(96h):0.0196-0.0335mg/lOncorhynchusmykiss/LC50(96h):0.00616mg/lAquaticinvertebratesInformationon:pyraclostrobinAcute:Daphniamagna/EC50(48h):0.016mg/lAquaticplantsInformationon:pyraclostrobinToxicitytoaquaticplants:greenalgae/EC50(96h):0.843mg/lNon-MammalsInformationon:pyraclostrobinOtherterrestrialnon-mammals:bobwhitequail/LD50:2,000mg/kgbobwhitequail:mallardduck/LC50:5,000ppmMONSANTOCOMPANYPage:7of8AcceleronDX-109FungicideSeedTreatmentVersion:2.0Effectivedate:18-June-2010Honeybee/LD50:100ug/beeDegradability/PersistenceBiological/AbiologicalDegradationEvaluation:Notreadilybiodegradable(byOECDcriteria).BioaccumulationInformationon:pyraclostrobinBecauseofthen-octanol/waterdistributioncoefficient(logPow)accumulationinorganismsispossible.Otheradverseeffects:Theecologicaldatagivenarethoseoftheactiveingredient.Donotreleaseuntreatedintonaturalwaters.13.DisposalconsiderationsWastedisposalofsubstance:Pesticidewastesareregulated.Improperdisposalofexcesspesticide,spraymixorrinsateisaviolationoffederallaw.Ifpesticidewastescannotbedisposedofaccordingtolabelinstructions,contacttheStatePesticideorEnvironmentalControlAgencyortheHazardousWasterepresentativeatthenearestEPARegionalOfficeforguidance.Containerdisposal:Rinsethoroughlyatleastthreetimes(triplerinse)inaccordancewithEPArecommendations.Consultstateorlocaldisposalauthoritiesforapprovedalternativeproceduressuchascontainerrecycling.Recommendcrushing,puncturingorothermeanstopreventunauthorizeduseofusedcontainers.RCRA:ThisproductisnotregulatedbyRCRA.14.TransportInformationReferenceBillofLading15.RegulatoryInformationFederalRegulationsRegistrationstatus:CropProtectionTSCA,USreleased/exemptChemicalTSCA,USblocked/notlistedOSHAhazardcategory:Chronictargetorganeffectsreported;ACGIHTLVestablishedEPCRA311/312(Hazardcategories):Acute;ChronicStateregulationsStateRTKCASNumberMA,PAChemicalname56-81-5glycerolMONSANTOCOMPANYPage:8of8AcceleronDX-109FungicideSeedTreatmentVersion:2.0Effectivedate:18-June-2010MA,NJ,PA108-88-3Toluene16.OtherInformationRefertoproductlabelforEPAregistrationnumber.Recommendeduse:fungicideNFPAHazardcodes:Heal