鋁粉MSDS（安全技術(shù)說明書）

1、鋁粉安全技術(shù)說明書Material Safety Data Sheet of Aluminum Powder第一部分 化學品及企業(yè)標識Section 1: Chemical product and company identification1、 化學品中文名：鋁粉；鋁銀粉；Chinese name of the chemical product: aluminum powder; aluminum metallic powder.商品名： 微細球形鋁粉、高純球形鋁粉Commercial product name: Fine Spherical Aluminum PowderHigh-puri

2、ty spherical aluminum powder英文名：fine spherical aluminum powder、high-purity spherical aluminum powderEnglish Name: fine spherical aluminum powder、high-purity spherical aluminum powder2、 企業(yè)名稱： Company name: 地 址： Address: 郵 編： Post Code: 電 話： Telephone NO.: 第二部分 成分/組成信息Section 2: Composition / informat

3、ion on ingredients主要成分：鋁含量99.70%Main content: Al99.70%CAS號：7429-90-5CAS No.: 7429-90-5相關(guān)于分子質(zhì)量：26.98Molecular Weight: 26.98分子式：ALChemical Formula: AL化學類別：金屬粉體Chemical Type: Metallic Powder第三部分 危險性概述Section 3: Hazards Overview危險性類別：第4.3類 遇濕易燃品Dangerous cargo grade: 4.3 Combustieles in the damp侵入途徑：吸入、

4、皮膚接觸Inhalation methods: Inhalation、skin contact健康危害：本品在肺中沉積，易引起鋁肺。關(guān)于皮膚黏膜具有刺激性。Health Hazard: Pulmonary fibrosis from chronic inhalation has been reported, Causes irritation to eyes and respiratory tract, may affect lungs, May cause skin irritation.環(huán)境危害：無資料Environmental Hazard: N/A燃爆危險：1、可與水、化學品發(fā)生反映，

5、產(chǎn)生易爆炸的氣體。Explosion conditions: 1. Reacts with water、some acids and caustic solutions to produce hydrogen. 2、易燃，與空氣混合能形成爆炸性混合物 2. Flammable Solid, Dust may form flammable or explosive mixture with air.第四部分 急救措施Section 4: First Aid Measures: 皮膚接觸：用肥皂水及清水徹底沖洗皮膚 Skin Contact: Wash exposed area with soap

6、 and water. Get medical advice if irritation develops. 眼睛接觸：用大量流動清水或生理鹽水徹底沖洗，嚴重時洗后就醫(yī)。 Eye Contact: Immediately flush eyes with plenty of water for at least 15 minutes, lifting upper and lower eyelids occasionally. Get medical attention. 吸 入：迅速脫離現(xiàn)場至空氣新鮮處。Inhalation: Remove to fresh air. If not breath

7、ing, give artificial respiration. If breathing is difficult, give oxygen. Get medical attention. 食 入：飲足量溫水，催吐，就醫(yī)。Ingestion: Give several glasses of water to drink to dilute. If large amounts were swallowed, get medical advice. 第五部分 消防措施Section 5: Fire Fighting Measures危險特性：1、與空氣混合能形成爆炸性混合物；Dangerous

8、 Property: 1. Fine dust dispersed in air in sufficient concentrations, and in the presence of an ignition source is a potential dust explosion hazard.2、 遇水或潮濕空氣可能會引起燃燒； May cause flame when meeting water or damp air, when the temperature is high3、 與氧化劑會發(fā)生反映，遇明火、高熱易引起燃燒；Reacts with oxidizer，may foam

9、explosion with the flame、high heat.4、 與酸、堿發(fā)生反映，生成易燃燒爆炸氣體；Reacts with acids and caustic solutions to release of flammable hydrogen gas有害燃燒產(chǎn)物：三氧化二鋁Hazardous Combustion product: Al2O3滅火方法及滅火劑：使用干燥惰性顆粒狀物質(zhì)（如干砂）石棉被等滅火材料，輕輕圍蓋；避免揚起粉塵；僅能適合D類滅火器Fire-fighting measures and extinguishing media: The use of inert

10、dry granular material (sand Rugan) fire-fighting materials such as asbestos were gently covered in circle; up to avoid dust; only for Class D fire extinguisher滅火注意事項及措施：消防人員穿戴全身消防防護服；不能使用水溶性和二氧化碳類的滅火器；嚴禁用水滅火； Fire-fighting comments and measures: Fire-fighters must wear Fire-fighting protective cloth

11、es. Water and carbon dioxide kind extinguishers are forbidden.第六部分 泄漏應(yīng)急處理 Section 6: Accidental Release Measures 應(yīng)急行動：隔離泄漏污染區(qū)，限制出入;切斷泄漏污染區(qū)火源、水源 Emergency action: Segregate the area of lead or spill, remove the sources of ignition and water from the polluted area. 應(yīng)急人員防護：應(yīng)急人員配戴防塵面具、建議穿隔熱服、使用防爆工具 Pers

12、onnel protective measurements: wear dust-proof mask, heat-proof clothes and use the explosion prevention tools and equipments. 環(huán)保措施、消除方法：避免揚塵、用潔凈的鏟子收集于干燥、潔凈、密封的容器中 Environmental protective measurements: avoid powder flying, collect the Pick up spill for recovery or disposal and place in a closed con

13、tainer.第七部分 操作處治與儲存Section 7: Handling and storage: 操作處治注意事項：操作人員必需經(jīng)過專門培訓，嚴格遵守操作規(guī)程。建議操作人員佩戴自吸過濾式防塵口罩，戴化學安全防護眼鏡,穿防靜電工作服。遠離火種、熱源，工作場所嚴禁吸煙。使用防爆型的通風系統(tǒng)和設(shè)備，避免粉塵揚起，避免與氧化劑、酸、堿類接觸。搬運時要輕裝輕卸，防止包裝及容器損壞。配備相應(yīng)品種和數(shù)量的消防器材及泄漏應(yīng)急處理設(shè)備。倒空的容器可能殘留有害物。 Handling: Operators must pass special trade, obey the operating rules. S

14、uggest operators wear filter-type dust-proof respirator, chemical safe goggles, static-free working clothes. Far away from sources of ignition and heat and smoking is not allowed in working area. Apply explosion prevention ventilation system and equipment. Avoid power flying and contact with oxidant

15、, acids and alkalis. Load and unload slightly and protect package from breaking out. Prepare the related suitable extinguisher with full quantity and accidental release handling devices. It may leave harmful materials in emptied out containers. 儲存注意事項：儲存于干燥、通風的庫房。遠離火種、熱源；庫房內(nèi)濕度不大于85%。包裝密封。應(yīng)于氧化劑、酸、堿類分

16、開存放，切忌混儲。與門窗間距大于1米。采用防爆型照明、通風設(shè)施。不宜久存，以免變質(zhì)。配備相應(yīng)的品種和數(shù)量的消防器材；儲區(qū)應(yīng)備有合適的材料收集收容泄漏物。Storage: Store in day and ventilated warehouse. Be far away from sources of ignition and heat. Humidity of the warehouse should max 85%. Stored in separated place against oxidant, acids and alkalis and shouldnt be swapped. U

17、se explosion prevention ventilation and lighting devices. Be not stored in long time to avoid out of date. Prepare the related suitable extinguisher with full quantity; There are suitable containers to pick up the leaking powder. 第八部分 暴露控制/人體防護Section 8: Exposure controls / personal protection中國MAC（

18、mg/m3）：未制定標準China MAC（mg/m3）：NO Standard前蘇聯(lián)MAC（mg/m3）：2ALTe former Soviet Union MAC（mg/m3）：2AL美國TLV-TWA：未制定標準 TLVTN:ACGIH 10mg/m3粉塵，5mg/m3焊接煙霧USA TLV-TWA：NO Standard TLVTN:ACGIH 10mg/m3dust/ 5mg/m3 welding smoke美國TLV-STEL：未制定標準 TLVWN：未制定標準USA TLV-STEL：NO Standard TLVWN：NO Standard監(jiān)測方法： 工程控制：密閉操作，加強通

19、風。提供淋浴和安全設(shè)備。Project Control: Operation in a closed devise, be well ventilated in the workshop. Supply the shower and safety devise. 呼吸系統(tǒng)防護：可能接觸其粉塵時，必需佩戴自吸過濾式防塵口罩。必要時，佩戴空氣呼吸器。Respiratory tract protection: must wear protective mask when contacting the powder, if necessary, wear air-purifying respirato

20、rs眼睛防護：戴化學安全防護眼鏡。Eye Protection: Use chemical safety goggles.身體防護：穿防靜電工作服。Body protection: wear antistatic working clothes.手防護：戴防靜電作業(yè)防護手套。Hands protection: wear antistatic gloves.其他防護：工作場所禁止吸煙、進食和飲水，飯前要洗手。工作完畢，淋浴更衣。注意個人清潔衛(wèi)生。實行就業(yè)前和定期體檢，防止塵肺。Additional information: No smoking, eating and drinking in t

21、he workshop, wash the hands before eating. Wash thoroughly and change the clothing after handling. Do physical examination regularly if contacting the powder with a long time.第九部分 理化特性Section 9: Physical /chemical properties 外觀與性狀：銀灰色粉狀顆粒 Appearance: Fine, silver-gray powder. 沸點（）：2467 Boiling point

22、（）: 2467 熔點（）：680Melting point （）: 660 相關(guān)于密度（水=1）：1.40（振實） Relative density: 1.40 (Tap density) 相關(guān)于蒸汽密度（空氣=1）：無資料 Relative density of steam (air=1): No Data 飽和蒸汽壓（KPa）：0.13（1284） Saturated vapor pressure: 0.13 (1284) 燃燒熱（kJ/mol）：822.9 Burning hot: 822.9 臨界溫度（）：無意義 Critical temperature (): Meaningles

23、s 臨界壓力（MPa）：無意義 Critical press (MPa): meaningless 閃 點：無資料Flash point: No Data 辛醇/水分配系數(shù)：無資料 octanol/water partion coefficient：No Data引燃溫度（）：700Ignition Temperature (): 700 爆炸上限；無資料 Explosion max limit: No Data爆炸下限：40g/m3Explosion min limit: 40g/ m3溶解性：與水、乙醇反映，不溶于其它有機溶劑Solubility: react with water and

24、 ethanol, insoluble in other organic solvents. 主要用途：金屬顏料、化工催化、火藥、耐火材料等 Mainly applications: metal pigment, chemical catalyst, powder and refractory material and so on. 其他理化性質(zhì)：微米級顆料，不含有機物，無放射性、侵蝕性，最小點火能15mg。 Other chemical and physical properties: microns grade powder, no organic, no radioactive and

25、corrosive, min ignition heat 15mg.第十部分 穩(wěn)定性和反映活性Section 10 Stability and Reactivity穩(wěn)定性：穩(wěn)定 Stability: Stable聚合危害：不能發(fā)生Hazardous Polymerization: Will not occur.避免接觸條件：火種、熱源、潮濕空氣Avoid contact: fire, heat and humid air.Conditions to Avoid: flames, heat, moisture禁忌物：水、酸、堿、強氧化劑Taboo: water, acids, alkalis a

26、nd strong oxidant. 燃燒產(chǎn)物：氧化鋁Combustion product: Al2O3第十一部分 毒理學資料Section 11 Toxicological Information 急性毒性：LD50：無資料 LC50：無資料Acute toxicity: LD50: No DataLC50: No Data 刺激性：關(guān)于眼睛輕度刺激 Irritation: light stimulate to eyes 致敏性：無資料Allergenicity: No Data 亞急性和慢性毒性：無資料 Sub-acute and chronic toxicity: No Data 致突變

27、性：無資料 Mutagenicity: No Data 致畸性：無資料 Teratogenicity: No Data 致癌性：無資料 Carcinogenicity: No Data第十二部分 生態(tài)學資料Section 12 Ecological Data 生物效應(yīng)：該物質(zhì)關(guān)于環(huán)境有危害，關(guān)于哺乳動物應(yīng)給予特別注意。Biological effect: This substance is harmful to environment，please pay special attention to mammal. 生物降解性：無資料Biodegradable: No Data 非生物降解性：無

28、資料Non-biodegradable: No Data生物富集：無資料Bioconcentration: No Data 環(huán)境遷移：無資料Environmental migration: No Data第十三部分 廢棄處理Section 13 Waste Disposal 廢氣物性質(zhì)：不屬于危險廢棄物Waste characters: not belong to hazardous waste廢棄方法：除之前應(yīng)參閱國家和地方有關(guān)法規(guī)。若可能回收使用，也可安全掩埋法處治Waste: must follow the laws of the Country and location before

29、dispose it. If can recycling, also can bury safety.廢棄注意事項：建議操作人員佩戴自吸過濾式防塵口罩。 Disposal attentions: Suggest the operator wear self-priming and filter to dust mask.第十四部分 運輸信息Section 14 Transport Data 危險貨物編號：43013Dangerous goods Code: 43013 UN編號：1396UN No: 1396 包裝標志：遇濕易燃品 Packing mark: Easy to flame mat

30、erial meet met.包裝類別：II類包裝 052Packing Group: II包裝方法：裝入雙層敷膜編織袋，內(nèi)襯雙層HDPE袋密封；或裝入0.5毫米厚的鐵桶中，內(nèi)襯HDPE袋密封。Packing: put into the double-coated bags, sealing with double-coated HDPE (High Density Polyethylene) bags in inner. Or put into the steel drums, 0.5mm thick, with double-coated HDPE bags sealing.運輸注意事項：

31、鐵路運輸應(yīng)嚴格依照鐵道部危險貨物運輸規(guī)則中的危險貨物配裝表進行配裝。鐵路運輸時禁止溜放。起運時包裝要完整，裝載應(yīng)穩(wěn)妥。運輸進程中要確保容器不泄漏、不倒塌、不墜落、不損壞。嚴禁與氧化劑、酸、堿類等混裝混運。運輸時運輸車輛應(yīng)配備相應(yīng)品種和數(shù)量的消防器材及泄露應(yīng)急處理設(shè)備。運輸途中應(yīng)防曝曬、防雨淋，防高溫，防拋灑泄露，中途停留應(yīng)遠離火種、熱源。運輸用車、船必需干燥，并且有良好的防雨設(shè)施。車輛運輸完畢應(yīng)進行徹底清掃。Attentions: Railway transportation should be strictly accordance with the Ministry of Railways

32、 the Transportation of Dangerous Goods Rules in the distribution of dangerous goods loaded table for compatibility. It is ban to put away when the goods on railway transportation. It should be packing well when shipment, loading should be safe. During the shipment, must ensure the containers no leak

33、ing, no collapsing, not falling, no damage. It is strictly prohibited shipping mix with oxidizer, acids, bases, etc. Transportation vehicles should be equipped with the corresponding variety and quantity of the leak and fire equipment and emergency equipment. During the transport should anti-exposure, anti-rain, anti-high-temperature, anti-leaking and throwing and sprinkling , and it should stop away from fire and heat. The vehicles and vessels must be