附表二物料平衡計算書

1、目錄物料平衡計算書11.1 總論11.2 物料的原理和準則21.3 總項目核算21.3.1 工段介紹31.3.2 脫硫工段的物料.31.3.3 脫氫反應工段的物料461.3.4 產(chǎn)品分離精制工段物料. 521.4 總結138致知物料平衡計算書1.1 總論本流程共分為三個工段，分別是脫硫工段、反應工段、產(chǎn)品分離精制工段。因為國內(nèi)來自石油煉廠的副產(chǎn)物丙烷純度較低，配為液化石油氣時純度約為95%。且含硫量較高，其中硫化氫占總硫含量的 90%，硫醇和羰基硫占有機硫的90%，一方面是純度為 95%的丙烷不能滿足Oleflex 工藝的要求，另一方面是較高的硫含量會對產(chǎn)品質(zhì)量產(chǎn)生影響，所以必須對丙烷進行處理

2、，即增加了脫硫工段。在羰基硫水解塔中，原料從塔底進入，脫硫劑水溶液從塔頂進入，在塔中逆流接觸，在塔的填料層，在以氧化鉀為活性組分，氧化鋁和二氧化鈦為復合型載體的作用下，水解為二氧化硫和，同時被脫硫劑水溶液吸收，丙烷從塔頂排出，富硫的脫硫劑水溶液從塔底排除，到脫硫劑再生工段，從而達到脫羰基硫的目的。從羰基硫水解塔排除的丙烷從塔底進入水洗塔，水洗用水為 0.4MPa下壓入空氣的含氧水，含氧水從塔頂進入，逆流接觸，除去丙烷中殘留的脫硫劑，丙烷從塔頂排除，水洗用水從塔底排除。在硫醇氧化塔中，丙烷從塔底進入，在塔的填料層，在以磺化酞菁鈷為活性組分，活性炭為載體的催化劑的作用下，硫醇氧化為二硫化物，為液態(tài)

3、，從塔底排除，丙烷從塔頂排除。在精餾塔中，塔底溫度為 90，壓力 8 atm，塔頂為 65 ，壓力位 7.5 atm，從而脫出丙烷中含有的 C4 組分，和少量殘留的二硫化物成分。塔頂排除高純度的丙烷，摩爾分數(shù)大于 97%，總硫含量小于 1.2 g/g。塔底排除C4 組分。反應工段所用的反應器是徑向移動床反應器。產(chǎn)品分離精制工段是將來自反應器的溫度為 600反應氣加入急冷塔中，用 30的公用工程冷卻水將反應氣降溫至 300，原因是 600的反應氣在金屬管道中時會發(fā)生裂解，而 300的反應氣的不會發(fā)生裂解，而且 300以下的熱量可以被進一步充分地利用，之后進入一級換熱器，加熱新鮮丙烷、循環(huán)丙烷以及

4、循環(huán)氫，達到一定溫度以后，致知1進入二級換熱器，用 30冷卻水降溫至室溫，這是來自急冷塔的水會冷凝下來，經(jīng)過之后的氣液分離罐可以將反應氣分離出來，縮機中，為了之后的分離效果，壓縮機出口壓力為 1.1MPa，再進入干燥器中，目的是除去殘留的水分，防止在深冷分離裝置中溫度降低導致水結冰，堵塞管道、對儀器造成損壞，從深冷分離裝置分離出的輕組分主要是氫氣、甲烷等、乙烷等，經(jīng)過磨分離，可以將氫氣高純度地分離出來，一部分作為循環(huán)氫返回反應氣器作催化劑稀釋劑防止催化劑結焦，另一部分返回總廠作為產(chǎn)品出售；從深冷分離裝置分離出的重組分主要是未反應的丙烷、產(chǎn)物丙烯以及副產(chǎn)物丙炔，為了得到的產(chǎn)品丙烯，將丙炔經(jīng)過選擇

5、性加氫裝置轉化成丙烯，在此過程中要控制合適的氫炔比、溫度等參數(shù)，為了除去過量的氫氣，反應氣進入脫乙烷塔中，從塔底出來的丙烷和丙烯經(jīng)過 PP 分離塔進行分離，最終塔頂?shù)玫教幎紴榇笥?99.6%的聚合級丙烯，塔底得到純度大于 97%的丙烷，直接返回反應器進行反應。1.2 物料的原理和準則物料是以質(zhì)量守恒定律為基礎，對物料平衡進行的計算。物料平衡是指“在時間內(nèi)進入系統(tǒng)的全部物料質(zhì)量必定等于離開該系統(tǒng)的全部物料質(zhì)量再加上損失掉的和積累起來的物科質(zhì)量”。進行物料系。對于已經(jīng)達到穩(wěn)定的體系，通常滿足以下關系：時，先必須確定的體（進料量之和）-（出料量之和）=（系統(tǒng)累積量）當系統(tǒng)中有化學反應時可表示為：（進

6、料量之和）-（出料量之和）+（反應消耗量）-（反應生成量）=（系統(tǒng)累積量）基于以上兩個等式，對本分廠工藝所涉及的物料平衡計算。1.3 總項目核算致知2從原料入廠到產(chǎn)品輸出，其工藝路線可分為如下 3 個部分：脫硫工段、反應工段、產(chǎn)品分離精制工段。1.3.1 工段介紹對于本廠，工藝采取年開工 300 天（7200 小時）的連續(xù)操作，其中一年內(nèi)的四五周（約 30 天）用于固定的停車設備檢修及緊急情況處理。物料要任務在于：的主確定對丙烯以及副產(chǎn)品的實際產(chǎn)量以及質(zhì)量指標；確定氫氣、丙烷的循環(huán)量以及損失率等指標；確定工藝中的“三廢”排放量等公共經(jīng)濟指標；確定各主要單元過程的物料，并指導工藝設備的尺寸確定；

7、確定 全流程物料，數(shù)據(jù)用于完成物料流程圖等后續(xù)設計任務。1.3.2 脫硫工段的物料致知3圖 1 脫硫工段工藝路線圖致知4表 1-1 丙烷原料脫硫工藝總物料致知5inoutPFD 中12378647071物流信息含氧水MDEA 水溶液原料丙烷丙烷C4MDEA 富液低濃度的 MDEA 溶液硫醇富液C3H8001014221003581013.7250.0385700C3H600000000C2H400280.53280.490.0040.03500CH400160.42160.421.70.00700C2H600300.69300.620.02190.05200H200000000WATER180

8、1000.03821772.329.93300C3H400000000N200000000致知6O20159.90158.392.060000Cl2000000.00200CO20002.47293.53829E-051.55E-0600COS003.3795560.00331.4E-50.01700CH4S009.62310.00320.0063000.199C2H6S20000.0939.3011000C4H1000000000C2H6S003.20750.06053.1361000.051C4H10S200000000H2S000.43862.35020.00280.00800PtSnA

9、l2O300000000MDEA5958000.0138865.675092.0.10Mass Frac致知7C3H8000.99250.9910.27660.00900C3H600000000C2H4000.02740.00261E-066E-0600CH4000.00150.0015E-091.E-0600C2H6000.00290.00295E-061E-0500H200000000WATER0.232003E-070.48360.0050.9990C3H400000000N200000000O20100.00155E-10000Cl200000000CO20002E-059E-092E

10、-1000COS003E-053E-084E-093E-0600致知8CH4S009E-053E-081E-6000.755C2H6S20009E-070.0253000C4H10000002E-0600C2H6S000.00035E-070.0085000.244C4H10S2000001E-0700H2S004E-062E-057E-071E-0700MDEA0.767001E-070.23620.9850.0030Pt Sn/Al2O300000000Temperature /30303047.783133.861003065Prere/bar1.01382.02652021188Vap

11、orFrac %01100000Liquid Frac %10011111Solid Frac %00000000表 1-2 T0101COS 水解塔物料致知9物流號S21S63T0101-T2Mole Flow kmol/hrC3H8230002300C3H6000C2H410010CH410010C2H610010H2000Density gm/cc1.0420.10.030.40.70803750.9651.1730.912Totalkg/hr109939.72104980致知10WATER010099.9438C3H4000O2000CO2000.056198COS0.05625430

12、5.63E-05CH4S0.2000300.20003C2H6S2000C4H10000C2H6S0.051621600.051622C4H10S2000H2S0.0128700.069068MDEA05050Mole Frac致知11C3H80.986988600.927299C3H6000C2H40.0042912600.004032CH40.0042912600.004032C2H60.0042912600.004032H2000WATER00.6666670.040295C3H4000O2000CO2002.27E-05COS2.41E-0502.27E-08CH4S8.58E-050

13、8.06E-05C2H6S2000致知12C4H10000C2H6S2.22E-0502.08E-05C4H10S2000H2S5.52E-0602.78E-05MDEA00.3333330.020159Mass FracC3H80.992578700.922521C3H6000C2H40.0027455200.002552CH40.0015700400.001459C2H60.002942800.002735H2000WATER00.2321640.016377致知13C3H4000O2000CO2002.25E-05COS3.31E-0503.07E-08CH4S9.42E-0508.75

14、E-05C2H6S2000C4H10000C2H6S3.14E-0502.92E-05C4H10S2000H2S4.29E-0602.14E-05MDEA00.7678360.054195LiqVolFrac60FC3H80.988906800.953361致知14C3H6000C2H40.0041795700.004029CH40.0026424800.002548C2H60.0041795700.004029H2000WATER00.2389150.008581C3H4000O2000CO2001.43E-05COS1.49E-0501.43E-08CH4S5.45E-0505.25E-0

15、5C2H6S2000C4H10000致知15C2H6S1.88E-0501.81E-05C4H10S2000H2S3.40E-0601.76E-05MDEA00.7610850.02735Total Flow kmol/hr2330.3211502480.321Total Flow kg/hr1021807759.716109940Total Flow l/min483062124.0303984005Temperature C303030Prere bar2.02651.013251.01325Vapor Frac100.956795Liquid Frac010.043205Solid Fr

16、ac000Enlpy cal/mol-24699.07-81492.1-27925.9致知16Enlpy cal/gm-563.2861-1575.29-630.026Enlpy cal/sec-15988000-3395500-1.9E+07Entropy cal/mol-K-64.71563-92.8309-64.3765Entropy cal/gm-K-1.475903-1.79448-1.45238Density mol/cc8.04E-050.0201564.20E-05Density gm/cc0.003525441.0427180.001862Average MW43.84817

17、51.7314444.32492Liq Vol 60F l/min3378125.91673503.95Mass Flow kg/hrC3H81014220101422C3H6000C2H4280.53760280.5376CH4160.42760160.4276致知17C2H6300.69640300.6964H2000WATER01801.5281800.516C3H4000O2000CO2002.473265COS3.37955600.00338CH4S9.62319509.623195C2H6S2000C4H10000C2H6S3.20754103.207541C4H10S2000H2

18、S0.438633802.353969表 1-3 T0102 水洗塔物料致知18T0101-T2T0102-TSP2-OUTMole Flow kmol/hrC3H823002298.8651.134751C3H6000C2H4109.9987430.001257CH4109.9995580.000442C2H6109.9982690.001731H2000MDEA05958.1885958.188TOTALkg/hr2330.322630.32致知19WATER99.943898.282181.661621C3H4000O2000CO20.0561980.0561916.75E-06COS5

19、.63E-055.62E-052.57E-08CH4S0.200030.1996690.000361C2H6S2000C4H10000C2H6S0.0516220.0514470.000175C4H10S2000H2S0.0690680.0690432.48E-05MDEA507.26466742.73533Mole Frac致知20C3H80.9272990.9441760.02492C3H6000C2H40.0040320.0041072.76E-05CH40.0040320.0041079.71E-06C2H60.0040320.0041063.80E-05H2000WATER0.040

20、2950.0403660.036491C3H4000O2000CO22.27E-052.31E-051.48E-07COS2.27E-082.31E-085.65E-10CH4S8.06E-058.20E-057.94E-06C2H6S2000致知21C4H10000C2H6S2.08E-052.11E-053.84E-06C4H10S2000H2S2.78E-052.84E-055.45E-07MDEA0.0201590.0029840.938502Mass FracC3H80.9225210.967590.009674C3H6000C2H40.0025520.0026776.82E-06C

21、H40.0014590.0015311.37E-06C2H60.0027350.002871.01E-05H2000WATER0.0163770.01690.005787致知22C3H4000O2000CO22.25E-052.36E-055.74E-08COS3.07E-083.22E-082.99E-10CH4S8.75E-059.17E-053.36E-06C2H6S2000C4H10000C2H6S2.92E-053.05E-052.10E-06C4H10S2000H2S2.14E-052.25E-051.64E-07MDEA0.0541950.0082630.984515LiqVol

22、Frac60FC3H80.9533610.9763130.019606致知23C3H6000C2H40.0040290.0041282.11E-05CH40.0025480.002614.70E-06C2H60.0040290.0041282.91E-05H2000WATER0.0085810.0086450.005946C3H4000O2000CO21.43E-051.47E-057.17E-08COS1.43E-081.47E-082.73E-10CH4S5.25E-055.37E-053.96E-06C2H6S2000C4H10000致知24C2H6S1.81E-051.85E-052.

23、55E-06C4H10S2000H2S1.76E-051.80E-052.64E-07MDEA0.027350.0040710.974386Total Flow kmol/hr2480.3212434.78545.5357Total Flow kg/hr1099401047675172.6Total Flow l/min984005125898089.54606Temperature C30100100Prere bar1.0132511Vapor Frac0.95679510Liquid Frac0.04320501Solid Frac000Enlpy cal/mol-27925.9-249

24、05.2-100510致知25Enlpy cal/gm-630.026-578.795-884.819Enlpy cal/sec-1.9E+07-1.7E00Entropy cal/mol-K-64.3765-57.1964-182.39Entropy cal/gm-K-1.45238-1.32924-1.60562Density mol/cc4.20E-053.22E-050.008475Density gm/cc0.0018620.0013870.962745Average MW44.3249243.02943113.5944Liq Vol 60F l/min3503.953419.888

25、84.06256Mass Flow kg/hrC3H810142210137250.03857C3H6000C2H4280.5376280.50230.035263CH4160.4276160.42050.007094致知26C2H6300.6964300.64440.052049H2000WATER1800.5161770.58129.93457C3H4000O2000CO22.4732652.4729680.000297COS0.003380.0033781.55E-06CH4S9.6231959.6058070.017388C2H6S2000C4H10000C2H6S3.2075413.

26、1966830.010859C4H10S2000H2S2.3539692.3531230.000846表 1-4 T0103 硫醇氧化塔物料致知27T0102-TO2-0103-TMole Flow kmol/hrC3H82298.86502298.865C3H6000C2H49.99874309.998743CH49.99955809.999558C2H69.99826909.998269H2000MDEA5958.188865.6855092.503TOTALkg/hr109940109939.6致知28WATER98.28218098.38192C3H4000O2054.95E+00CO

27、25.62E-020.00E+005.62E-02COS5.62E-0505.62E-05CH4S0.199668600.0002C2H6S2000.099734C4H10000C2H6S0.051446800.051447C4H10S2000.00E+00H2S0.069043200.069043MDEA7.26466707.264667Mole Frac致知29C3H80.944175800.94226C3H6000.00E+00C2H40.004106604.10E-03CH40.00410704.10E-03C2H60.004106400.004098H2000WATER0.04036

28、5800.040325C3H4000O20.00E+001.00E+002.03E-03CO22.31E-050.00E+002.30E-05COS2.31E-080.00E+002.30E-08CH4S8.20E-0508.18E-08C2H6S2004.09E-05致知30C4H100.00E+000.00E+000.00E+00C2H6S2.11E-0502.11E-05C4H10S20.00E+000.00E+000.00E+00H2S2.84E-0502.83E-05MDEA0.002983700.002978Mass FracC3H80.967590400.966115C3H600

29、0.00E+00C2H40.002677402.67E-03CH40.001531201.53E-03C2H60.002869600.002865H2000WATER0.016900100.016891致知31C3H4000O20.00E+001.00E+001.51E-03CO22.36E-050.00E+002.36E-05COS3.22E-080.00E+003.22E-08CH4S9.17E-0509.15E-08C2H6S2008.95E-05C4H100.00E+000.00E+000.00E+00C2H6S3.05E-0503.05E-05C4H10S20.00E+000.00E

30、+000.00E+00H2S2.25E-0502.24E-05MDEA0.008262900.00825LiqVolFrac60FC3H80.976312600.975054致知32C3H6000.00E+00C2H40.004127904.12E-03CH40.0026102.61E-03C2H60.004127700.004122H2000WATER0.008645500.008643C3H4000O20.00E+001.00E+001.29E-03CO21.47E-050.00E+001.46E-05COS1.47E-080.00E+001.47E-08CH4S5.37E-0505.37

31、E-08C2H6S2004.32E-05C4H100.00E+000.00E+000.00E+00致知33C2H6S1.85E-0501.84E-05C4H10S20.00E+000.00E+000.00E+00H2S1.80E-0501.80E-05MDEA0.004071500.004066Total Flow kmol/hr2434.78552439.735Total Flow kg/hr104767159.994104927Total Flow l/min1258980262.5511175420Temperature C1003080Prere bar181.01325Vapor F

32、rac110.997533Liquid Frac000.002467Solid Frac000Enlpy cal/mol-24905.2135.06111-25294.5致知34Enlpy cal/gm-578.79481.095701-588.14Enlpy cal/sec-1684400048.69599-1.7E+07Entropy cal/mol-K-57.1964-3.986686-58.2834Entropy cal/gm-K-1.33E+00-1.25E-01-1.35519Density mol/cc3.22E-050.00031743.46E-05Density gm/cc0

33、.00138690.01015630.001488Average MW43.0294331.998843.00771Liq Vol 60F l/min3419.8884.463153424.301Mass Flow kg/hrC3H81013720101372C3H6000C2H4280.50230280.5023CH4160.42050160.4205致知35C2H6300.64440300.6444H2000WATER1770.58101772.378C3H4000O20159.994158.3983CO22.47296802.47E+00COS0.00337800.003378CH4S9

34、.60580700.009606C2H6S2009.395149C4H10000C2H6S3.19668303.196683C4H10S2000H2S2.35312302.353123致知36MDEA865.6850865.685Liq Vol 60F l/minC3H83338.8803338.88C3H6000C2H414.11683014.11683CH48.92590508.925905C2H614.11616014.11616H2000WATER29.56656029.59656C3H4000O204.463154.42E+00CO25.02E-020.00E+005.02E-02C

35、OS5.02E-0505.02E-05表 1-5 T0104C3+C4 精餾塔物料致知37T0103-TNEW-FEEDT0104OUTSubstream: MIXEDCH4S0.183794900.000184C2H6S2000.148093C4H10000C2H6S0.063166900.063167C4H10S2000.00E+00H2S0.0616300.06163MDEA13.92395013.92395TOTALkg/hr10476716787690致知38Mole Flow kmol/hrC3H82298.8652275.87722.98865C3H6000C2H49.99874

36、39.9985980.000145CH49.9995589.9995571.09E-06C2H69.9982699.997540.000729H2000WATER98.381920.00212198.37979C3H4000.00E+00O24.9501334.9501336.44E-08CO20.05619130.056198.04E-07COS5.62E-055.60E-052.46E-07CH4S0.0001996696.84E-050.000131致知39C2H6S20.09973440.0009970.098737C4H10000C2H6S0.05144680.0009740.050

37、473C4H10S2000H2S0.06904320.068968.33E-05MDEA7.2646670.0001167.264551Mole FracC3H80.94226010.9848220.178507C3H6000C2H40.004098290.0043271.13E-06CH40.004098620.0043278.43E-09C2H60.00409810.0043265.66E-06H2000致知40WATER0.04032489.18E-077.64E-01C3H40.00E+0000.00E+00O22.03E-030.0021425.00E-10CO22.30E-052.

38、43E-056.24E-09COS2.30E-082.42E-081.91E-09CH4S8.18E-082.96E-081.02E-06C2H6S24.09E-054.32E-070.000767C4H100.00E+0000.00E+00C2H6S2.11E-054.21E-070.000392C4H10S2000H2S2.83E-052.98E-056.47E-07MDEA0.002977655.01E-080.056409Mass Frac致知41C3H80.96611510.9910630.276655C3H6000C2H40.00267330.002771.11E-06CH40.0

39、01528870.0015844.75E-09C2H60.002865260.0029695.98E-06H2000WATER0.01689143.77E-074.84E-01C3H40.00E+0000.00E+00O21.51E-030.0015645.62E-10CO22.36E-052.44E-059.66E-09COS3.22E-083.32E-084.03E-09CH4S9.15E-083.25E-081.72E-06C2H6S28.95E-059.28E-070.002538致知42C4H100.00E+0000.00E+00C2H6S3.05E-055.98E-070.0008

40、56C4H10S2000H2S2.24E-052.32E-057.75E-07MDEA0.008250321.36E-070.236251LiqVolFrac60FC3H80.97505440.9875440.432955C3H6000C2H40.004122540.0042172.66E-06CH40.002606640.0026671.26E-08C2H60.004122350.0042171.33E-05H2000WATER0.00864311.91E-073.84E-01致知43C3H40.00E+0000.00E+00O21.29E-030.001327.45E-10CO21.46E

41、-051.50E-059.31E-09COS1.47E-081.49E-082.84E-09CH4S5.37E-081.88E-081.57E-06C2H6S24.32E-054.42E-070.001901C4H100.00E+0000.00E+00C2H6S1.84E-053.57E-070.000804C4H10S2000H2S1.80E-051.84E-059.64E-07MDEA0.004066226.64E-080.18055Total Flow kmol/hr2439.7352310.952128.7833Total Flow kg/hr1049271012633664.203致

42、知44Total Flow l/min11754203744.32386.25256Temperature C8047.78397133.8698Prere bar1.013252021Vapor Frac0.99753300Liquid Frac0.0024670211Solid Frac000Enlpy cal/mol-25294.54-27341.2-60378.4Enlpy cal/gm-588.1397-623.96-2122.08Enlpy cal/sec-1.71E+07-1.8E+07#Entropy cal/mol-K-58.28342-77.1304-46.6728Entr

43、opy cal/gm-K-1.355185-1.76021-1.64038Density mol/cc3.46E-050.0102860.024885Density gm/cc0.00148780.4507410.708038致知45Average MW43.0077143.8188328.45247Liq Vol 60F l/min3424.3013347.18277.11845Mass Flow kg/hrC3H81013721003581013.72C3H6000C2H4280.5023280.49830.004072CH4160.4205160.42051.74E-05C2H6300.

44、6444300.62240.021917H2000WATER1772.3780.0382081772.34C3H4000O2158.3983158.39832.06E-06CO22.4729682.4729323.54E-051.3.3 脫氫反應工段的物料致知46COS0.003378010.0033631.48E-05CH4S0.009605810.0032920.006314C2H6S29.3951490.0939519.301197C4H10000C2H6S3.1966830.0605233.13616圖二 丙烷脫氫反應工藝路線圖致知47表 1-6 丙烷脫氫反應工段總物料致知48InOu

45、tInPFD 中1213202172物流信息原料混合氣催化劑產(chǎn)物混和氣積碳催化劑氫氣Mass Flow kg/hrC3H8215760012105500C3H618978.58010882000C2H4280.49830620.769200CH4160.42050364.274200C2H6300.62240317.992300H2100.79404403.4810.028228650WATER80.64956080.6495600C3H400000致知49O2158.39830158.398300CO22.47293202.47293200COS0.0035578300.0035578300

46、CH4S0.013899900.013899900C2H6S20.14764900.14764900C4H1000000C2H6S0.119175600.119175600C4H10S200000H2S2.35074602.35074600Pt Sn/Al2O300.19634900.1963490MDEA0.013809500.013809500Mass FracC3H80.914915400.513324700致知50C3H60.080477300.461441900C2H40.0011894300.0026323300CH40.00068025200.0015446800C2H60.00

47、12747700.0013484200H20.0004274100.018672601.00E+00WATER0.00034198900.00034198900C3H400000O20.00067167700.00067167700CO21.04863E-0501.04863E-0500COS1.50867E-0801.50867E-0800CH4S5.89416E-0805.89416E-0800C2H6S26.26095E-0706.26095E-0700C4H1000000致知51C2H6S5.05356E-0705.05356E-0700C4H10S200000H2S9.96817E-

48、0609.96817E-0600MDEA5.85583E-0805.85583E-0800Pt Sn/Al2O301010.00E+00Temperature /6000499.1643070Prere/bar1.101.215901Vapor Frac %10101Liquid Frac %00000.00E+00Solid Frac %01010.00E+00Density gm/cc0.0006576431.130.0005890681.138.90E-021.3.4 產(chǎn)品分離精制工段物料圖三 分離精制工段一工藝路線總圖表 1-7 產(chǎn)品分離精制工段總物料致知52致知53物流號122022

49、2627.000028Mass Flow kg/hrC3H821576012105501188350100358C3H618978.58108820010721500C2H4280.4983620.76920618.94580280.4983CH4160.4205364.27420364.03280160.4205C2H6300.6224317.99230316.46820300.6224H2100.7944403.48104403.36100WATER80.6495680.6495636030.561441.70136030.560.0382082C3H4000000O2158.398315

50、8.39830158.34120158.3983CO22.4729322.47293202.46300802.472932COS0.003557830.0035578300.0034965700.00336326致知54CH4S0.01389990.013899900.012415300.00329168C2H6S20.1476490.14764900.138233800.0939514C4H10000000C2H6S0.11917560.119175600.091188800.0605229C4H10S2000000H2S2.3507462.35074602.31888502.350284P

51、t Sn/Al2O3000000.0138095MDEA0.01380950.0138095000Mass Frac0.50924040.9910631C3H80.91491540.513324700.459443300C3H60.08047730.461441900.0026523500.00276999C2H40.001189430.0026323300.0015599800.00158419CH40.0006802520.0015446800.0013561500.00296872致知55C2H60.001274770.0013484200.018869500H20.000427410.

52、018672600.0061780800WATER0.0003419890.0003419891010C3H40000.00067853400.00156422O20.0006716770.0006716770000CO21.04863E-051.04863E-050000COS1.50867E-081.50867E-080000CH4S5.89416E-085.89416E-080000C2H6S26.26095E-076.26095E-070000C4H10000000C2H6S5.05356E-075.05356E-070000C4H10S2000002.32097E-05H2S9.96

53、817E-069.96817E-060000致知56MDEA5.85583E-085.85583E-080000Pt Sn/Al2O3000000Temperature /600499.164325107597.84734Prere/bar1.11.215911.11458120Vapor Frac %110101Liquid Frac %001010Solid Frac %000000Density gm/cc0.0006576430.0005890680.9939570.001459960.9939570.02841141220222627.000028Mass Flow kg/hrC3H

54、821576012105501188350100358C3H618978.58108820010721500C2H4280.4983620.76920618.94580280.4983致知57CH4160.4205364.27420364.03280160.4205C2H6300.6224317.99230316.46820300.6224H2100.7944403.48104403.36100WATER80.6495680.6495636030.561441.70136030.560.0382082C3H4000000O2158.3983158.39830158.34120158.3983C

55、O22.4729322.47293202.46300802.472932COS0.003557830.0035578300.0034965700.00336326CH4S0.01389990.013899900.012415300.00329168C2H6S20.1476490.14764900.138233800.0939514C4H10000000C2H6S0.11917560.119175600.091188800.0605229C4H10S2000000致知58H2S2.3507462.35074602.31888502.350284Pt Sn/Al2O3000000.0138095M

56、DEA0.01380950.0138095000Mass Frac0.50924040.9910631C3H80.91491540.513324700.459443300C3H60.08047730.461441900.0026523500.00276999C2H40.001189430.0026323300.0015599800.00158419CH40.0006802520.0015446800.0013561500.00296872C2H60.001274770.0013484200.018869500H20.000427410.018672600.0061780800WATER0.00

57、03419890.0003419891010C3H40000.00067853400.00156422O20.0006716770.0006716770000致知59CO21.04863E-051.04863E-050000COS1.50867E-081.50867E-080000CH4S5.89416E-085.89416E-080000C2H6S26.26095E-076.26095E-070000C4H10000000C2H6S5.05356E-075.05356E-070000C4H10S2000002.32097E-05H2S9.96817E-069.96817E-060000MDE

58、A5.85583E-085.85583E-080000Pt Sn/Al2O3000000Temperature /600499.164325107597.84734Prere/bar1.11.215911.11458120Vapor Frac %110101致知60Liquid Frac %001010Solid Frac %000000Density gm/cc0.0006576430.0005890680.9939570.001459960.9939570.0284114表 1-9 T0401 急冷塔物料致知61物流號S22T0401-EDT0401-ECT0401-EBT0401-EAM

59、ole Flow kmol/hrC3H82745.227686.3066686.3066686.3066686.3066C3H62585.979646.4948646.4948646.4948646.4948C2H422.127845.5319615.5319615.5319615.531961CH422.706465.6766145.6766145.6766145.676614C2H610.575192.6437982.6437982.6437982.643798H22184.396546.0991546.0991546.0991546.0991WATER2004.477501.119250

60、1.1192501.1192501.1192C3H400000O24.9501331.2375331.2375331.2375331.237533CO20.05619040.01404760.01404760.01404760.0140476致知62COS5.92E-051.48E-051.48E-051.48E-051.48E-05CH4S0.0002889277.22E-057.22E-057.22E-057.22E-05C2H6S20.001567370.0003918430.0003918430.0003918430.000391843C4H1000000C2H6S0.00191799