北京科技大學(xué)有機化學(xué)試題庫合成題及解答

#/14TM89HOCH2CH20H.Cr03AH3O：TM.保護醛基90HNO3LKMnO］廣Fer(CH3C0)20.HNO3；H30+ NaN02-H20「H2SO4△ HCl H2so4 HCl<5℃91.CHqCH°CH°BrNaOH■HBr軸Na?tm3 2 2乙醇92.93.94．OCH3cH2cOCl_HNO3H2SO4.Z-Hg92.93.94．BrCH2CH2CH3TOC\o"1-5"\h\zAlCl3 BrCH2CH2CH3CH3cH2COC1廣 Br2尸Zn-HgAlCl3 FeCl3 HClCH3Br HN03.KMnO,4 4 4AlCl3 H2sO4△ H+95.CH2=CHCH2CHNBSrNaOH尸95.CH2=CHCH2CH3 乙醇高溫96.①CH3cH2cH2MgX>HSO?①B2H6}CH2CH2CH3②H2O/H+ △ ②H2O2/OH- OH或①CH3cH2cH2MgX廣HSO4廣①HBr/H2O2>②H2O/H+ △ ②NaOH/H2O①CH3cH2MgX尸HSO4一①B2H6-［丫CH2CH3②H2O/H+ △ ②H2O2/OH- OH或①CH3CH2MgX-HSO4=①HBr/H2O2一一②H2O/H+ △ ②NaOH/HO22①CHXCH@MgXrHSO4十①B2H6./X^CH2CH2CH2CH3②H2O/H+ △ ②H2O2/OH- LOH或①CH3(CH2)3MgXLHSO4谷①HBr/H2O2「一②H2O/H+ △ ②NaOH/HO22①CH3cH2cH2MgXLHSO4/①B2H6廣 CH2cH2CH3②H2O/H+ △ ②H2O2/OH- O~OH或 ①CH3CH2CH2MgX - HSO4 一 ①HBr/H2O2 一3!<'>>1 ^^^^^^"^^2②H2O/H+ △ ②NaOH/HO22CH3Br廣_HNO3 _KMnO4AlCl3 H2sO4△ H+土②H2O/H+O上Ahno°.

Fe 土②H2O/H+O上Ahno°.

Fe H2sO4h2o:so2cLOH_Br^Fe0H3-—一旦170℃NaOHCH2CH2CH2Cl104. koh.Br.rkoh?n(CH3)3Cx "H(c%)3CCH2cHe%*OH*--Br^^OH^液氨^ H，C-C、CHBr 3105cH三CHNaNH2?EtBANaNH2.EtB>pH/c.KMnO^CH3cH2CHCHCH2cH320H冷ohoh106.OUC2_^IMq?CH3CH0t.-H3O^TM光干醚106.107.TMFeBr3107.TMFeBr3光一CH三CNa-HgSO「一109.光2 cHCNa'VTM(CH3cH2cH2cH)2-CuL+^;HcH2Br——CH2CHCH2CH2CH3CH3 CH3(CH3cH)2-CuLi+CH3cH2cH2cH2Br ?CH3CHCH2CH2CH2CH3CH3 CH333232?OH；HNO3.Fe H2sO4△ H2OH2sO4Cl? 叫TMFe H2SO4△H2sO4△H2OH0SO OH--115.￡jOHCH3cH2cH2cH2OH170r4A4-麗^TM115.￡jOHCH3Br_Na0H_CH3cH2B.TMAlCl3116.+||---HB^(2>BrMg.CH3C0CH3?H3O：,TM116.117.+krTM118.CH產(chǎn)CHCHqB”CH產(chǎn)CHCH.BrCl2?CH.-CH-CH.2 3高溫2 2室溫c12clBr2119