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HALOGENFREE

低煙無(wú)鹵電纜培訓(xùn)WELCOMEatGLTSEMINAR 2002-02-20RhodeIslandClub,USA

2001-01-01Volendam,NL

2000-11-11Kitzsteinhorn,A

1996-04-11DusseldorfAirport,DHarmonizedHalogenFreeCables

協(xié)調(diào)標(biāo)準(zhǔn)下的低煙無(wú)鹵電線(xiàn)InternationalDesignationH05Z1Z1-FHD21.14國(guó)際統(tǒng)一名稱(chēng)H05Z1Z1-FHD21.14(flexiblecablesinsulatedandsheathedwithhalogen-freethermoplasticcompounds)低煙無(wú)鹵熱塑絕緣和護(hù)套的軟線(xiàn)InternationalDesignationH05(7)Z1-U,R,KHD21.15國(guó)際統(tǒng)一名稱(chēng)H05(7)Z1-U,R,KHD21.15(singlecorecablesinsulatedwithhalogenfreethermoplasticcompoundforfixedwiring)低煙無(wú)鹵熱塑絕緣單芯固定線(xiàn)InternationalDesignationH07Z-U,R,KHD22.9國(guó)際統(tǒng)一名稱(chēng)H07Z-U,R,KHD22.9(singlecorenon-sheathedcablesforfixedwiringhavingcross-linkedpolymerandhavinglowemissionofsmokeandcorrosivegases)含有交聯(lián)聚合物和低煙以及腐蝕性氣體的單芯無(wú)護(hù)套固定線(xiàn)InternationalDesignationH07ZZ-FHD22.13國(guó)際統(tǒng)一名稱(chēng)H07ZZ-FHD22.13(flexiblecablesinsulatedandsheathedwithcross-linkedpolymerandhavinglowemissionofsmokeandcorrosivegases)護(hù)套和絕緣為交聯(lián)聚合物并含有低煙和腐蝕性氣體的軟線(xiàn)MainTestStandardsforHF

低煙無(wú)鹵電線(xiàn)的主要測(cè)試標(biāo)準(zhǔn)

Non-HalogenVerification無(wú)鹵驗(yàn)證

DINVDE0472part815,EN50267-2-1, DINVDE482part267,IEC60754-1

Determinationoftheamountofhalogenacidgas;theproofofhalogeniseffectedbychemicalanalysis. ThustheproofofhalogenacidcontentlikeHCLandHBristheresult.Theaccuracyofthistestisupto5mg/g,notformaterialscontaininglessthanthat.

判定鹵酸氣含量,鹵素的驗(yàn)證受化學(xué)分析影響。測(cè)出鹵酸氣所含物質(zhì)如:氯化氫和溴化氫為該驗(yàn)證結(jié)果。本測(cè)試精度所要求材料含量高達(dá)5mg/g,若材料含量少于此要求則不適用。Standards

標(biāo)準(zhǔn)

DINVDE0472part815 Non-HalogenVerificationtestingofCables,WiresandFlexibleCords

適用于電纜、電線(xiàn)和軟線(xiàn)的無(wú)鹵驗(yàn)證測(cè)試TestMethodA:totestforhalogensChlorine,Bromine,Iodine測(cè)試法A:測(cè)試鹵素:氯、溴、碘

TestMethodB:totestforthehalogenFluorine測(cè)試法B:測(cè)試鹵素:氟TestGoalsinEN/HDStandards

EN和協(xié)調(diào)標(biāo)準(zhǔn)的測(cè)試目標(biāo)

0 HD21.14Halogen:FluroineChlorine

Ifnegative:stoptest

andBromineIfpositive:continue

鹵素:氟、氯和溴若結(jié)果為“-”:停止測(cè)試若結(jié)果為“+”:繼續(xù)1EN50267-2-2 pHvalueand ≥4,3 Conductivity ≤10μS/mmpH值和導(dǎo)電率2EN50267-2-1 ContentofHCL

≤0,5%

氯化氫含量

3 EN60684-2

Fluorinecontent

≤0,1%

氟含量

acceptmaterialTestStandards

測(cè)試標(biāo)準(zhǔn)

CorrosivityofCombustionGases燃燒氣體的腐蝕性

DINVDE0482part2672-2,EN50267-2-2, IEC60754-2andHD602

Insulationandjacketmaterialsaretobeputinthemoveablefurnace,pre-heatedto750to800°C.Theburninggasisconductedthroughtwogas-washingbottles.Thetestshallberegardedaspassedwhenthemeasuredconductivityis≤10μS/mm.Duringthistestallthenotdesiredcomponentsofthematerialsareprecipitatedsuchasallhalogens,sulphurandnitrogen.Thecorrosiontestofgasescausedbyfireiscarriedouttothetestmaterials,notthecompletecablesamples

將絕緣和護(hù)套材料放入移動(dòng)烤箱中預(yù)熱至750℃到800℃。將燃燒氣體導(dǎo)至兩個(gè)洗氣瓶。當(dāng)測(cè)到導(dǎo)電率≤10μS/mm時(shí)測(cè)試認(rèn)為通過(guò)。測(cè)試過(guò)程中,材料中所有無(wú)要求的元素會(huì)沉淀,如所有鹵素,硫和氮。由燃燒產(chǎn)生的腐蝕性氣體的測(cè)試只針對(duì)測(cè)試材料而非整個(gè)電線(xiàn)樣品。TubeFurnace–Drawing

烤箱管道圖MeasuringofCorrosivity

腐蝕性測(cè)量TubeFurnaceThepresenceofHalogencomponentswillbedetectedinsmallestquantitiesThesampleofinsulationorjacketmaterialisinthesilicatube,onacombustionboat出現(xiàn)的鹵素成分將取最小量測(cè)量絕緣或護(hù)套材料樣品放入二氧化硅試管中,置于燃燒皿上AirEntryandTubeforFurnace

syntheticair,speedrate1l/minFurnacewithEntryandExitTubeFurnaceWashingBottleGasWashingBottlesResultofTestHalogensandTestStandards

鹵素和測(cè)試標(biāo)準(zhǔn)

HalogencontentofHCLundHBrofinsulation:

絕緣材料中鹵素:氯化氫和溴化氫的含量EN50267-2-1(VDE482Teil267-2-1):max0,5% FluorineHFofinsulation:絕緣材料中:氟化氫

EN60684-2(VDE0341Teil2):max0,1% HCLandHBrofsheath:護(hù)套材料中:氯化氫和溴化氫

EN50267-2-1(VDE482Teil267-2-1):max0,5% FluorineHFofsheath:

護(hù)套材料中:氟化氫EN60684-2(VDE0341Teil2):max0,1%

LSF LSHF/LSZH

Therearemanytermsusedtodescribeacable‘sbehaviorduringafire.Mostdealwiththelevelofsmokeandpoisonousfumesgivenoff.LSFcables(LowSmoke&Fume)aresometimesnomorethanmodifiedPVCgivingoffanythingupto18%HClemissions!Cablesthatgiveoffbelow0.5%ofHClareclassedasLowSmokeHalogenFree(LSHF),LowSmokeZeroHalogen(LSZH)etc.

描述電線(xiàn)在燃燒過(guò)程中狀態(tài)的術(shù)語(yǔ)很多。大部分都與釋放出的煙霧指數(shù)和有毒氣體相關(guān)。電線(xiàn)釋放出低于0.5%的氯化氫稱(chēng)為低煙無(wú)鹵電線(xiàn),或低煙零鹵線(xiàn)等。H05Z1Z1-FH05Z1Z1-Fisalightduty,harmonized,flexible,halogen-free,blackjacketedmulticonductor300/500V.Europeancord.Recommendedwhenhalogen-free,low-smokeandcorrosivegaspropertiesarerequiredincaseoffire.Applicationsincludeconnecting

electricalappliancesundermediummechanicalstressesenvironmentsinoffices,kitchensandhouseholds.H05Z1Z1-Fcancommonlybefoundinconnectionstorefrigerators,washingmachinesandspin-dryers.Thesecablescanalsobeusedincookingandheatingapparatusifnotindirectcontactwithhotpartsoftheapparatus.H05Z1Z1-F為輕型、符合協(xié)調(diào)標(biāo)準(zhǔn)、細(xì)軟、無(wú)鹵、黑色護(hù)套多芯線(xiàn)300/500V歐洲線(xiàn)型。為了防火,推薦使用符合無(wú)鹵、低煙和腐蝕性氣體要求的電線(xiàn)。此類(lèi)電線(xiàn)適用于連接辦公室、廚房和家庭中受介質(zhì)機(jī)械應(yīng)力環(huán)境的電器。H05Z1Z1-F通常用于冰箱,洗衣機(jī)和自旋式干燥機(jī)。若不直接與器具的熱部件連接,此類(lèi)電線(xiàn)還可用于烹飪和加熱器具。H07ZZ-FH07ZZ-Fisaharmonized,heavy-duty,flexible,halogen-free,blackjacketedmulti-conductor450/750V.Europeancable.Recommendedforuseinelectricalequipmentundermediumstressindoors;notsuitableforcontinuousoutdooruse.Recommendedwhenhalogen-freelowsmokeandcorrosivegaspropertiesarerequiredincaseoffire.H07ZZ-Fcablesareusedforequipmentinindustryworkssuchasboilers,heatingplates,handlamps,electrictoolssuchasdrills,circularsaws,inhomeworktoolsandtransportablemotorsormachinesatsite.H07ZZ-F為符合協(xié)調(diào)標(biāo)準(zhǔn)、重型、細(xì)軟、無(wú)鹵、黑色護(hù)套多芯線(xiàn)450/750V歐洲線(xiàn)纜。推薦用于室內(nèi)電器設(shè)備;不適合戶(hù)外長(zhǎng)期使用。為了防火,推薦使用符合無(wú)鹵、低煙和腐蝕性氣體要求的電線(xiàn)。H07ZZ-F型線(xiàn)纜用于工業(yè)用途的設(shè)備,如:鍋爐,加熱板,手提燈,電動(dòng)工具如:電鉆,圓盤(pán)鋸,家用工具和工地用運(yùn)輸馬達(dá)或機(jī)械。S03Z1Z1H2-F

S03Z1Z1-FThermoplasticCable熱塑電線(xiàn)HD21.14S1:2003Acc.toVDE-RegNr7907(S03Z1Z1)and7908(S05Z1Z1)Temperatureatloadacc.toHD+70°C按協(xié)調(diào)標(biāo)準(zhǔn)帶負(fù)荷溫度+70°CTemperaturerange(3000h)–20°Cto

+80°CInsulation絕緣HalogenfreePolymercompoundTI6Acc.toHD21.14根據(jù)HD21.14無(wú)鹵聚合材料:TI6Sheath護(hù)套HalogenfreePolymercompoundFRNC=FlameRetardantNonCorrosiveTM7

無(wú)鹵聚合物:FRNC=阻燃非腐蝕性TM7Acc.toHD21.14Voltage300/300VU0/UInsulationandSheath

Materials

絕緣和護(hù)套材料ThermoplastsandTPE熱塑性材料和TPEPVC,PE,PA,PP–TPE-U,TPE-E,TPE-O,TP-CElastomers合成橡膠CR,CSM,CM,EPR,EVA,SIRThermoplastics/Elastomers

Crosslinked

by

Irradiatian熱塑/合成橡膠交聯(lián)輻射XLPE,XTPU,mod.X-PER,XPVDF,XETFEHighTemperature

Materials高溫材料X-PER,PEIC,PVDF,ETFE,SIR,FEP,PI,PEEK,PFA,PTFEHalogenfree,FlameRedardant

Compounds無(wú)鹵,阻燃聚合物PE-Cop,XPE-Cop,TPE-U,TPE-U,TPE,PP,EVA,TP-CHalogenFreeFlameRetardant

無(wú)鹵阻燃Halogen-free:Polymerslikepolyethylene(PE)orpolypropylene(PP)arehalogen-free.Thesematerialsareeasyflammableandnotself-extinguishing.無(wú)鹵:聚合物如PE或PP都為無(wú)鹵。這些材料都易燃且不會(huì)自動(dòng)熄滅Halogen-freecablesforsecurityrequirementsmustbehardlyflammableandself-extinguishing.Thishappensbyusingthespecialpolymercompounds,containingtheconsiderablepercentageofflameprotectivematerials.符合安全要求的無(wú)鹵線(xiàn)纜必需不易燃且能自動(dòng)熄滅。這樣就需要用特殊的聚合物,該材料含有相當(dāng)比例的防火材料。Suchkindofprotectivematerialsconsistof,forexample,analuminumhydroxidewhichononesidecoolsthefirelocationbysettingfreecrystalwaterandontheothersidethereleasedwatervaporhinderstheadmittanceofoxygenandtherebythissuffocatestheflame.此類(lèi)防火材料包含,如:氫氧化鋁,一方面通過(guò)結(jié)成水晶液降低火焰溫度,另一方面釋放水蒸氣阻止氧氣進(jìn)入而滅火。ReasonforHalogenFree

ToxicGasescankillorharmhumanbeings有毒氣體對(duì)人體有害甚至致命Damagetoexpensiveequipmentthroughcorrosion

腐蝕昂貴設(shè)備

- Halogen-freecableswillnotcausecorrosiontometals.

無(wú)鹵電線(xiàn)不會(huì)腐蝕金屬 - Whenhalogen-containingcablesburn,thegasesgenerated incombustionofthesheathingandinsulationmaycause corrosion.

當(dāng)含有鹵素的線(xiàn)纜燃燒時(shí),絕緣和護(hù)套燃燒產(chǎn)生的氣體會(huì)導(dǎo)致腐蝕 - Thesecondaryeffectsafterafireareoftenmanytimeslarger thanthedamagescausedbythefireitself.

火災(zāi)造成的的第二影響往往比火災(zāi)本身造成的危害更大BurningBehavior–Self-Extinguishing

燃燒特性-自動(dòng)熄滅 DINVDE0482-332-1

IEC332-1

Sample

1

樣品

Length

60cm

長(zhǎng)度

Duration

<65sec

時(shí)間

IEC332-1/EN60332-1

old:EN50265-2-1TestonsingleverticalcableTestmethodB在單根垂直電線(xiàn)上測(cè)試測(cè)試法BVerticalflametestIEC332-3

垂直火焰測(cè)試

Burningbehavioronbunchedcables束狀電纜的燃燒特性EN50266-2-4flamepropagation,

火焰延伸 TestmethodC測(cè)試法CSmokeDensityChamber

煙霧密度箱ChamberThechamberis3x3x3mandhasaphotometricsystemwithalightsourceof100W容器為3X3X3m,且?guī)в泄庠礊?00W的光度測(cè)定系統(tǒng)Abathwithalcohol,abovethebathinhorizontaldirectionthecablesamples:alcoholisignited帶酒精的容器,電線(xiàn)樣品置于容器上方水平線(xiàn)方向:酒精點(diǎn)燃Thephotocellregisterstheweakeningoflight光電管記錄光的弱化Afterextinguishingofalcoholthelightshouldstayover5minandnotgetweakerortestdurationof40min酒精燃燒熄滅后光應(yīng)保持超過(guò)5分鐘不變?nèi)趸驕y(cè)試持續(xù)40分鐘ComparisonbetweenPVCandHF

無(wú)鹵電線(xiàn)和PVC電線(xiàn)的比較SecurityCablesRHEYHALON?

Security

Cables

SecurityCables

Security

cables

are

products

thatwillnot

letofftoxicandcorrosive

gasesincaseoffire. Some

cables

haveafire

integrity

that

gurantees

the

function

of

importantsystemsfor

evacuationandfire fighting. The

cables

are

usedinbuildings

with

hug

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